JP2006523596A - 水素、及び水素と一酸化炭素との混合物の製造方法 - Google Patents

水素、及び水素と一酸化炭素との混合物の製造方法 Download PDF

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JP2006523596A
JP2006523596A JP2006505546A JP2006505546A JP2006523596A JP 2006523596 A JP2006523596 A JP 2006523596A JP 2006505546 A JP2006505546 A JP 2006505546A JP 2006505546 A JP2006505546 A JP 2006505546A JP 2006523596 A JP2006523596 A JP 2006523596A
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hydrogen
steam reforming
product
steam
mixture
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JP2006523596A5 (OSRAM
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ティアン・ホエイ・ティオ
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Shell Internationale Research Maatschappij BV
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Shell Internationale Research Maatschappij BV
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    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
JP2006505546A 2003-04-15 2004-04-13 水素、及び水素と一酸化炭素との混合物の製造方法 Pending JP2006523596A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP03076114 2003-04-15
PCT/EP2004/050500 WO2004092061A1 (en) 2003-04-15 2004-04-13 Process for the preparation hydrogen and a mixture of hydrogen and carbon monoxide

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Publication Number Publication Date
JP2006523596A true JP2006523596A (ja) 2006-10-19
JP2006523596A5 JP2006523596A5 (OSRAM) 2007-06-07

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JP2006505546A Pending JP2006523596A (ja) 2003-04-15 2004-04-13 水素、及び水素と一酸化炭素との混合物の製造方法
JP2006505545A Pending JP2006523595A (ja) 2003-04-15 2004-04-13 水蒸気改質反応を行うための反応容器及び合成ガスの製造方法
JP2006505548A Pending JP2006523597A (ja) 2003-04-15 2004-04-13 合成ガスの製造方法
JP2006505550A Pending JP2006523598A (ja) 2003-04-15 2004-04-13 合成ガスの製造方法

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JP2006505545A Pending JP2006523595A (ja) 2003-04-15 2004-04-13 水蒸気改質反応を行うための反応容器及び合成ガスの製造方法
JP2006505548A Pending JP2006523597A (ja) 2003-04-15 2004-04-13 合成ガスの製造方法
JP2006505550A Pending JP2006523598A (ja) 2003-04-15 2004-04-13 合成ガスの製造方法

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US (5) US20080028680A1 (OSRAM)
EP (4) EP1622828A1 (OSRAM)
JP (4) JP2006523596A (OSRAM)
KR (1) KR20050120719A (OSRAM)
CN (4) CN100381353C (OSRAM)
WO (4) WO2004092063A1 (OSRAM)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7557759B1 (ja) * 2023-10-23 2024-09-30 株式会社 ユーリカ エンジニアリング 熱電併給一体型合成ガス製造システムおよび熱電併給一体型合成ガス製造方法

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WO2006037805A2 (en) 2004-10-08 2006-04-13 Shell Internationale Research Maatschappij B.V. Process to prepare ethylene and/or propylene from a carbon containing feedstock
WO2006045744A1 (en) * 2004-10-20 2006-05-04 Shell Internationale Research Maatschappij B.V. Process for steam and/or co2 reforming of a hydrocarbonaceous feedstock
FR2877939B1 (fr) * 2004-11-16 2007-02-02 Air Liquide Procede et installation pour la production combinee d'hydrogene et de dioxyde de carbone
KR101127688B1 (ko) * 2004-12-07 2012-03-23 에스케이이노베이션 주식회사 원통형 소형 개질 장치
DE102005021500A1 (de) * 2005-05-10 2006-11-16 Uhde Gmbh Verfahren zur Aufheizung eines Dampf-/Erdgasgemisches im Bereich eines Gassammelrohres nach einem Primärreformer
US7485767B2 (en) 2005-06-29 2009-02-03 Exxonmobil Chemical Patents Inc. Production of synthesis gas blends for conversion to methanol or Fischer-Tropsch liquids
EP1938406A4 (en) 2005-08-25 2010-04-21 Ceramatec Inc ELECTROCHEMICAL CELL FOR PRODUCING SYNTHESIS GAS USING ATMOSPHERIC AIR AND WATER
WO2007101831A1 (en) 2006-03-07 2007-09-13 Shell Internationale Research Maatschappij B.V. Process to prepare a fischer-tropsch synthesis product
FR2898518B1 (fr) * 2006-03-17 2009-01-16 Inst Francais Du Petrole Reacteur echangeur a combustion interne pour reaction endothermique en lit fixe
WO2007142739A2 (en) 2006-05-31 2007-12-13 Exxonmobil Chemical Patents Inc. Synthesis gas production and use
WO2008006787A2 (en) 2006-07-11 2008-01-17 Shell Internationale Research Maatschappij B.V. Process to prepare a synthesis gas
RU2462444C2 (ru) * 2006-08-25 2012-09-27 Эксонмобил Кемикэл Пейтентс Инк. Получение ароматических соединений из метана
EP1916233A1 (en) * 2006-10-20 2008-04-30 BP Chemicals Limited Process for the conversion of hydrocarbons to alcohols
US7695708B2 (en) * 2007-03-26 2010-04-13 Air Products And Chemicals, Inc. Catalytic steam reforming with recycle
US8460630B2 (en) * 2007-03-29 2013-06-11 Nippon Oil Corporation Method and apparatus for producing hydrogen and recovering carbon dioxide
US9212059B2 (en) * 2007-12-13 2015-12-15 Gyco, Inc. Method and apparatus for improving the efficiency of an SMR process for producing syngas while reducing the CO2 in a gaseous stream
US7850944B2 (en) * 2008-03-17 2010-12-14 Air Products And Chemicals, Inc. Steam-hydrocarbon reforming method with limited steam export
US7988948B2 (en) * 2008-03-17 2011-08-02 Air Products And Chemicals, Inc. Steam-hydrocarbon reforming method with limited steam export
US8105402B1 (en) * 2008-07-30 2012-01-31 Bossard Peter R Micro-channel steam reformer and system for extracting ultra-pure hydrogen gas from a hydrocarbon fuel
CN102159684A (zh) * 2008-08-18 2011-08-17 辛吉斯特公司 使用加压多级逐渐扩大流化床气化器将生物质转化为合成气、然后通过氧吹自热重整炉减少甲烷和焦油的方法
BRPI0904285B1 (pt) * 2009-10-30 2019-09-10 Petroleo Brasileiro Sa Petrobras dispositivo para resfriamento e distribuição de cargas mistas sobre leitos fixos de catalisador
CN101721957B (zh) * 2009-12-03 2011-08-31 太原理工大学 一种连续炭催化ch4-co2重整反应器
US9611437B2 (en) * 2010-01-12 2017-04-04 Lummus Technology Inc. Producing low methane syngas from a two-stage gasifier
US9227844B2 (en) * 2010-01-19 2016-01-05 Haldor Topsoe A/S Heat exchange reformer with double-tubes for reforming hydrocarbons
GB2482263B8 (en) * 2010-03-01 2012-11-14 Plascoenergy Ip Holdings S L Carbon conversion system with integrated processing zones
US9321641B1 (en) 2011-02-11 2016-04-26 Emerging Fuels Technology, Inc. Process to convert natural gas into liquid fuels and chemicals
US9034208B1 (en) 2011-02-11 2015-05-19 Emerging Fuels Technology, Inc. Process to convert natural gas into liquid fuels and chemicals
CN103765986B (zh) 2011-08-04 2017-03-29 S·L·坎宁安 等离子电弧炉和应用
EP2607301A1 (de) * 2011-12-20 2013-06-26 Karl-Heinz Tetzlaff Vorrichtung und Verfahren zur Erdgasreformierung
CA2862527C (en) * 2012-02-06 2021-06-29 Helbio Societe Anonyme Hydrogen And Energy Production Systems Heat integrated reformer with catalytic combustion for hydrogen production
EP2671842A1 (en) * 2012-06-06 2013-12-11 Ammonia Casale S.A. A process for gas-heated reforming of a hydrocarbon source and a related plant
AU2013332200A1 (en) * 2012-09-26 2015-03-05 Enerkem, Inc. Synthesis gas separation and reforming process
WO2014078226A1 (en) * 2012-11-15 2014-05-22 Phillips 66 Company Process scheme for catalytic production of renewable hydrogen from oxygenate feedstocks
EP2801550A1 (en) * 2013-05-10 2014-11-12 Ammonia Casale S.A. A process for producing ammonia synthesis gas with high temperature shift and low steam-to-carbon ratio
US9243190B2 (en) * 2013-11-04 2016-01-26 Me Resource Corp Method and apparatus for producing chemicals from a methane-containing gas
DE102014004264A1 (de) * 2014-03-14 2015-09-17 Universität Stuttgart Wärmeintegrierte Hochtemperatur-Reaktoren für die autotherme partielle Oxidation
EP3140601A4 (en) 2014-05-09 2017-11-08 Stephen Lee Cunningham Arc furnace smeltering system & method
WO2016016251A1 (en) 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/sr process for producing synthesis gas
WO2016016257A1 (en) 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/pox process for producing synthesis gas
US9843062B2 (en) 2016-03-23 2017-12-12 Energyield Llc Vortex tube reformer for hydrogen production, separation, and integrated use
US9840413B2 (en) 2015-05-18 2017-12-12 Energyield Llc Integrated reformer and syngas separator
FR3040313B1 (fr) * 2015-08-24 2017-08-25 Air Liquide Echangeur-reacteur integrant les reactions de vaporeformage et de gaz a l'eau pour la production d'hydrogene
DE102016212757A1 (de) * 2016-07-13 2018-01-18 Thyssenkrupp Ag Kompakter Methanolreformer für ein Unterseeboot
CN106082127B (zh) * 2016-08-25 2018-09-11 晋城市阿邦迪能源有限公司 选择性氧化净化co的甲醇重整反应器
CN106145036B (zh) * 2016-08-25 2018-12-04 晋城市阿邦迪能源有限公司 甲烷化反应净化co的甲醇重整反应器
EP3296255A1 (de) * 2016-09-14 2018-03-21 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Reformerrohr mit strukturiertem katalysator und verbessertem wärmehaushalt
CN109996760B (zh) * 2016-10-25 2022-09-02 法国德西尼布 用于重整的催化剂管
AU2017356668B2 (en) 2016-11-09 2023-04-20 8 Rivers Capital, Llc Systems and methods for power production with integrated production of hydrogen
US11066298B2 (en) 2017-11-09 2021-07-20 8 Rivers Capital, Llc Systems and methods for production and separation of hydrogen and carbon dioxide
GB201813431D0 (en) * 2018-08-17 2018-10-03 Weedon Geoffrey Gerald Process & apparatus for steam reforming
CN109261083A (zh) * 2018-12-03 2019-01-25 宁夏宝丰能源集团股份有限公司 一种固定床放空换热器以及固定床反应器
IT201900008280A1 (it) * 2019-06-06 2020-12-06 Amec Foster Wheeler Italiana S R L Reattore, in particolare reattore di reforming con vapore, e suo uso in un processo di reforming con vapore
KR20220020842A (ko) 2019-06-13 2022-02-21 8 리버스 캐피탈, 엘엘씨 추가 생성물들의 공동 발생을 구비하는 동력 생산
IT201900013239A1 (it) * 2019-07-29 2021-01-29 Milano Politecnico Impianto per la produzione di syngas a partire da polimeri plastici di recupero pretrattati
GB2593179B (en) * 2020-03-17 2022-04-27 Nordic Electrofuel As Production of hydrocarbons
CN112573482B (zh) * 2020-12-10 2022-07-08 洛阳沃达节能科技有限公司 一种制氢装置的制氢管以及制氢装置
KR20240113795A (ko) 2021-11-18 2024-07-23 8 리버스 캐피탈, 엘엘씨 수소 생산 장치
US12358792B2 (en) 2023-10-09 2025-07-15 8 Rivers Capital, Llc Systems and methods for producing hydrogen with integrated capture of carbon dioxide

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3345088A1 (de) * 1983-12-13 1985-06-13 Linde Ag, 6200 Wiesbaden Verfahren zur erzeugung von synthesegas
JPS61222903A (ja) * 1985-03-05 1986-10-03 インペリアル・ケミカル・インダストリーズ・ピーエルシー 水素及び炭素酸化物類を含むガス流の製造方法及びそのための装置
EP0291111A1 (en) * 1987-05-12 1988-11-17 Shell Internationale Researchmaatschappij B.V. Process for partial oxidation of a hydrocarbon-containing gaseous fuel
JPH01501224A (ja) * 1986-09-15 1989-04-27 エル・ウント・ツエ・シユタインミユラア・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング 水蒸気によってガス状の炭化水素を触媒分解するための改質器、およびそのための１次改質器と２次改質器を備えた設備
JPH04215837A (ja) * 1990-02-02 1992-08-06 Haldor Topsoe As 熱交換を改質するプロセスと反応系
WO1993015999A1 (en) * 1992-02-18 1993-08-19 Davy Mckee (London) Limited Process for the production of synthesis gas
JPH0948601A (ja) * 1995-07-31 1997-02-18 Texaco Dev Corp 部分酸化装置ガス供給システムの熱含量連続制御方法
JPH11510431A (ja) * 1995-08-07 1999-09-14 インペリアル ケミカル インダストリーズ パブリック リミティド カンパニー 熱交換装置及び方法
JP2003520747A (ja) * 2000-01-25 2003-07-08 インペリアル・ケミカル・インダストリーズ・ピーエルシー スチーム改質装置

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2324172A (en) * 1940-10-31 1943-07-13 Standard Oil Co Processing well fluids
GB1093943A (en) * 1963-10-07 1967-12-06 Ici Ltd Reforming hydrocarbons
US3549335A (en) * 1965-10-22 1970-12-22 Braun & Co C F Autothermal reactor
DE3244252A1 (de) * 1982-11-30 1984-05-30 Uhde Gmbh, 4600 Dortmund Verfahren und vorrichtung zur erzeugung von produktgas mit wasserstoff- und kohlenoxyde-gehalten
CN87100591A (zh) * 1983-06-09 1988-07-20 联合碳化公司 用于烃类一次及二次催化水蒸汽转化的联合方法及设备
US4650651A (en) * 1983-06-09 1987-03-17 Union Carbide Corporation Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons
GB2163449B (en) 1984-07-18 1988-06-02 Shell Int Research Production of gas mixtures containing hydrogen and carbon monoxide
NL8403144A (nl) * 1984-10-16 1986-05-16 Stamicarbon Werkwijze voor het bereiden van een synthesegas.
JPS62210047A (ja) * 1986-03-10 1987-09-16 Toyo Eng Corp 反応用装置
JP2625443B2 (ja) 1987-09-25 1997-07-02 三菱瓦斯化学株式会社 固定触媒層反応器
US5059299A (en) * 1987-12-18 1991-10-22 Exxon Research And Engineering Company Method for isomerizing wax to lube base oils
US4943672A (en) 1987-12-18 1990-07-24 Exxon Research And Engineering Company Process for the hydroisomerization of Fischer-Tropsch wax to produce lubricating oil (OP-3403)
JPH01261201A (ja) * 1988-04-12 1989-10-18 Mitsubishi Gas Chem Co Inc 炭化水素改質反応器
DE3813863A1 (de) * 1988-04-23 1989-11-02 Uhde Gmbh Einrichtung zur aufnahme von katalysatoren, insbesondere bei der erzeugung von synthesegas
US5029299A (en) 1990-05-09 1991-07-02 Altec Lansing Corporation Power amplifier with current limiting means
JPH0685866B2 (ja) * 1991-01-25 1994-11-02 株式会社日立製作所 触媒反応装置
US5245110A (en) 1991-09-19 1993-09-14 Starchem, Inc. Process for producing and utilizing an oxygen enriched gas
US5254318A (en) * 1992-07-20 1993-10-19 Stone & Webster Engineering Corporation Lined reformer tubes for high pressure reformer reactors
CA2161132C (en) * 1993-04-22 2003-10-07 Kulathu-Iyer Seshan Catalyst for the production of synthesis gas
EP0668342B1 (en) 1994-02-08 1999-08-04 Shell Internationale Researchmaatschappij B.V. Lubricating base oil preparation process
MY115440A (en) 1994-07-22 2003-06-30 Shell Int Research A process for the manufacture of synthesis gas by partial oxidation of a gaseous hydrocarbon-containing fuel using a multi-orifice (co-annular)burner
EG20966A (en) 1995-06-06 2000-07-30 Shell Int Research A method for flame stabilization in a process for preparing synthesis gas
EP1365005B1 (en) 1995-11-28 2005-10-19 Shell Internationale Researchmaatschappij B.V. Process for producing lubricating base oils
US5931978A (en) 1995-12-18 1999-08-03 Shell Oil Company Process for preparing synthesis gas
JPH11106204A (ja) * 1997-10-01 1999-04-20 Sanyo Electric Co Ltd 水素製造装置及び水素製造方法
US6090989A (en) 1997-10-20 2000-07-18 Mobil Oil Corporation Isoparaffinic lube basestock compositions
ES2221235T3 (es) 1997-12-30 2004-12-16 Shell Internationale Research Maatschappij B.V. Catalizador de fischer-trosch a base de cobalto.
DK173742B1 (da) 1998-09-01 2001-08-27 Topsoe Haldor As Fremgangsmåde og reaktorsystem til fremstilling af syntesegas
AU4733199A (en) 1998-09-04 2000-03-16 Linde Aktiengesellschaft Process and primary reformer for generating synthesis gas
JP4860861B2 (ja) 1999-07-26 2012-01-25 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 潤滑基油を製造する方法
US6284217B1 (en) * 1999-08-17 2001-09-04 Battelle Memorial Institute Method and catalyst structure for steam reforming of a hydrocarbon
DE19953641A1 (de) * 1999-11-09 2001-06-07 Metallgesellschaft Ag Verfahren zur katalytischen Dehydrierung von Kohlenwasserstoffen im Röhrenreaktor
GB9927817D0 (en) * 1999-11-26 2000-01-26 Ici Plc Steam reforming apparatus
JP2001206702A (ja) * 2000-01-26 2001-07-31 Nissan Motor Co Ltd 燃料改質装置および燃料電池システム
US6521143B1 (en) * 2000-04-13 2003-02-18 Air Products And Chemicals, Inc. Co-production of carbon monoxide-rich syngas wth high purity hydrogen
US6892225B1 (en) * 2000-07-19 2005-05-10 Fusionone, Inc. Agent system for a secure remote access system
AR032932A1 (es) 2001-03-05 2003-12-03 Shell Int Research Procedimiento para preparar un aceite de base lubricante y un gas oil
MY139353A (en) 2001-03-05 2009-09-30 Shell Int Research Process to prepare a lubricating base oil and a gas oil
AR032941A1 (es) 2001-03-05 2003-12-03 Shell Int Research Un procedimiento para preparar un aceite base lubricante y aceite base obtenido, con sus diversas utilizaciones
MY138154A (en) * 2001-10-22 2009-04-30 Shell Int Research Process to prepare a hydrogen and carbon monoxide containing gas

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3345088A1 (de) * 1983-12-13 1985-06-13 Linde Ag, 6200 Wiesbaden Verfahren zur erzeugung von synthesegas
JPS61222903A (ja) * 1985-03-05 1986-10-03 インペリアル・ケミカル・インダストリーズ・ピーエルシー 水素及び炭素酸化物類を含むガス流の製造方法及びそのための装置
JPH01501224A (ja) * 1986-09-15 1989-04-27 エル・ウント・ツエ・シユタインミユラア・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング 水蒸気によってガス状の炭化水素を触媒分解するための改質器、およびそのための１次改質器と２次改質器を備えた設備
EP0291111A1 (en) * 1987-05-12 1988-11-17 Shell Internationale Researchmaatschappij B.V. Process for partial oxidation of a hydrocarbon-containing gaseous fuel
JPH04215837A (ja) * 1990-02-02 1992-08-06 Haldor Topsoe As 熱交換を改質するプロセスと反応系
WO1993015999A1 (en) * 1992-02-18 1993-08-19 Davy Mckee (London) Limited Process for the production of synthesis gas
JPH0948601A (ja) * 1995-07-31 1997-02-18 Texaco Dev Corp 部分酸化装置ガス供給システムの熱含量連続制御方法
JPH11510431A (ja) * 1995-08-07 1999-09-14 インペリアル ケミカル インダストリーズ パブリック リミティド カンパニー 熱交換装置及び方法
JP2003520747A (ja) * 2000-01-25 2003-07-08 インペリアル・ケミカル・インダストリーズ・ピーエルシー スチーム改質装置

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7557759B1 (ja) * 2023-10-23 2024-09-30 株式会社 ユーリカ エンジニアリング 熱電併給一体型合成ガス製造システムおよび熱電併給一体型合成ガス製造方法
WO2025088659A1 (ja) * 2023-10-23 2025-05-01 株式会社 ユーリカ エンジニアリング 熱電併給一体型合成ガス製造システム

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