JP2006312302A - 多層物品及びその製造方法 - Google Patents
多層物品及びその製造方法 Download PDFInfo
- Publication number
- JP2006312302A JP2006312302A JP2005221092A JP2005221092A JP2006312302A JP 2006312302 A JP2006312302 A JP 2006312302A JP 2005221092 A JP2005221092 A JP 2005221092A JP 2005221092 A JP2005221092 A JP 2005221092A JP 2006312302 A JP2006312302 A JP 2006312302A
- Authority
- JP
- Japan
- Prior art keywords
- boride
- core layer
- cap layer
- absorbing additive
- tungsten oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000010410 layer Substances 0.000 claims abstract description 86
- 239000012792 core layer Substances 0.000 claims abstract description 85
- 239000000654 additive Substances 0.000 claims abstract description 82
- 230000000996 additive effect Effects 0.000 claims abstract description 74
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 59
- 239000000203 mixture Substances 0.000 claims abstract description 49
- 239000006096 absorbing agent Substances 0.000 claims abstract description 18
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 11
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 11
- 239000004417 polycarbonate Substances 0.000 claims description 46
- 229920000515 polycarbonate Polymers 0.000 claims description 45
- 229920000728 polyester Polymers 0.000 claims description 45
- 125000002723 alicyclic group Chemical group 0.000 claims description 22
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 16
- 229920001230 polyarylate Polymers 0.000 claims description 15
- 238000002834 transmittance Methods 0.000 claims description 15
- 239000012760 heat stabilizer Substances 0.000 claims description 13
- VPXSRGLTQINCRV-UHFFFAOYSA-N dicesium;dioxido(dioxo)tungsten Chemical compound [Cs+].[Cs+].[O-][W]([O-])(=O)=O VPXSRGLTQINCRV-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- AAQNGTNRWPXMPB-UHFFFAOYSA-N dipotassium;dioxido(dioxo)tungsten Chemical group [K+].[K+].[O-][W]([O-])(=O)=O AAQNGTNRWPXMPB-UHFFFAOYSA-N 0.000 claims description 5
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 5
- BDYJTMSAJACSQH-UHFFFAOYSA-N oxotungsten;rubidium Chemical compound [Rb].[W]=O BDYJTMSAJACSQH-UHFFFAOYSA-N 0.000 claims description 5
- 229910052716 thallium Inorganic materials 0.000 claims description 5
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 5
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 5
- 238000002835 absorbance Methods 0.000 claims description 4
- 239000002105 nanoparticle Substances 0.000 claims description 4
- 125000000962 organic group Chemical group 0.000 claims description 4
- OFEAOSSMQHGXMM-UHFFFAOYSA-N 12007-10-2 Chemical compound [W].[W]=[B] OFEAOSSMQHGXMM-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 3
- 229910052691 Erbium Inorganic materials 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims description 3
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 3
- 229910052689 Holmium Inorganic materials 0.000 claims description 3
- 229910052779 Neodymium Inorganic materials 0.000 claims description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 3
- 229910052772 Samarium Inorganic materials 0.000 claims description 3
- 229910052771 Terbium Inorganic materials 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- LRTTZMZPZHBOPO-UHFFFAOYSA-N [B].[B].[Hf] Chemical compound [B].[B].[Hf] LRTTZMZPZHBOPO-UHFFFAOYSA-N 0.000 claims description 3
- MMSXTTLREGTYGY-UHFFFAOYSA-N boranylidynelutetium Chemical compound [Lu]#B MMSXTTLREGTYGY-UHFFFAOYSA-N 0.000 claims description 3
- XTDAIYZKROTZLD-UHFFFAOYSA-N boranylidynetantalum Chemical compound [Ta]#B XTDAIYZKROTZLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
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- 239000011651 chromium Substances 0.000 claims description 3
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 3
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 3
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 3
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 3
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 3
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 3
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 3
- 229920005992 thermoplastic resin Polymers 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 229920001634 Copolyester Polymers 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- QVNRRKJFOOCHOA-UHFFFAOYSA-N boranylidynethulium Chemical compound B#[Tm] QVNRRKJFOOCHOA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- AUVPWTYQZMLSKY-UHFFFAOYSA-N boron;vanadium Chemical compound [V]#B AUVPWTYQZMLSKY-UHFFFAOYSA-N 0.000 claims 2
- 229910052775 Thulium Inorganic materials 0.000 claims 1
- OHUPZDRTZNMIJI-UHFFFAOYSA-N [Cs].[W] Chemical group [Cs].[W] OHUPZDRTZNMIJI-UHFFFAOYSA-N 0.000 claims 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 claims 1
- LGLOITKZTDVGOE-UHFFFAOYSA-N boranylidynemolybdenum Chemical compound [Mo]#B LGLOITKZTDVGOE-UHFFFAOYSA-N 0.000 claims 1
- 238000010030 laminating Methods 0.000 claims 1
- FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 claims 1
- 230000005670 electromagnetic radiation Effects 0.000 abstract description 9
- -1 polyarylsulfone Polymers 0.000 description 34
- 239000000155 melt Substances 0.000 description 24
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 18
- 230000005855 radiation Effects 0.000 description 17
- 239000000126 substance Substances 0.000 description 14
- 239000004594 Masterbatch (MB) Substances 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 12
- 125000001183 hydrocarbyl group Chemical group 0.000 description 11
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- 125000003118 aryl group Chemical group 0.000 description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 150000002009 diols Chemical class 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- 229960001755 resorcinol Drugs 0.000 description 8
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 7
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- 125000001931 aliphatic group Chemical group 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
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- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 4
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Abstract
【解決手段】 熱可塑性ポリマーとIR吸収性添加剤を含むコア層でIR吸収性添加剤が金属酸化物であるコア層と、熱可塑性ポリマーと電磁放射吸収性添加剤を含む第一のキャップ層でその一方の表面がコア層の一方の表面に密着して配置された第一のキャップ層とを備える多層シート。多層シートの製造方法であって、熱可塑性ポリマーとIR吸収性添加剤を含む組成物を溶融ブレンドしてコア層を形成し、熱可塑性ポリマーと紫外線吸収剤を含む組成物を溶融ブレンドして第一のキャップ層を形成し、コア層を第一のキャップ層と合体させてキャップ層をコア層の一方の表面に密着して配設することを含んでなる方法についても開示する。
【選択図】 図2
Description
Claims (23)
- 熱可塑性ポリマーとIR吸収性添加剤を含むコア層で、IR吸収性添加剤が酸化カリウムタングステン、酸化ルビジウムタングステン、酸化セシウムタングステン、酸化タリウムタングステン又はこれらの酸化物の1種以上を含む組合せであるコア層と、
熱可塑性ポリマーとUV吸収剤を含む第一のキャップ層で、その一方の表面がコア層の一方の表面に密着して配置された第一のキャップ層と
を備える多層シート。 - さらに、熱可塑性ポリマーとUV吸収剤を含む第二のキャップ層で、第一のキャップ層と接したコア層の表面と反対側の表面に密着して配置された第二のキャップ層を備える、請求項1記載のシート。
- 前記コア層がさらに、ホウ化ランタン(LaB6)、ホウ化プラセオジム(PrB6)、ホウ化ネオジム(NdB6)、ホウ化セリウム(CeB6)、ホウ化ガドリニウム(GdB6)、ホウ化テルビウム(TbB6)、ホウ化ジスプロシウム(DyB6)、ホウ化ホルミウム(HoB6)、ホウ化イットリウム(YB6)、ホウ化サマリウム(SmB6)、ホウ化ユウロピウム(EuB6)、ホウ化エルビウム(ErB6)、ホウ化ツリウム(TmB6)、ホウ化イッテルビウム(YbB6)、ホウ化ルテチウム(LuB6)、ホウ化ストロンチウム(SrB6)、ホウ化カルシウム(CaB6)、ホウ化チタン(TiB2)、ホウ化ジルコニウム(ZrB2)、ホウ化ハフニウム(HfB2)、ホウ化バナジウム(VB2)、ホウ化タンタル(TaB2)、ホウ化クロム(CrB及びCrB2)、ホウ化モリブデン(MoB2、Mo2B5及びMoB)、ホウ化タングステン(W2B5)又はこれらのホウ化物の1種以上を含む組合せを含む、請求項1又は請求項2記載のシート。
- 前記IR吸収性添加剤が200nm以下の平均粒度を有するナノサイズ粒子からなり、IR吸収性添加剤がコア層の表面で測定して0.001〜5g/m2の量で存在する、請求項1乃至請求項3のいずれか1項記載のシート。
- 前記IR吸収性添加剤がコア層の全重量を基準にして0.02〜3000ppmの量で存在する、請求項1乃至請求項3のいずれか1項記載のシート。
- 前記熱可塑性ポリマーがビスフェノールAポリカーボネート、コポリエステルカーボネート、又はポリエステルとポリカーボネートのブレンドである、請求項1又は請求項2記載のシート。
- 前記ポリエステルが、脂環式ポリエステル、ポリアリーレート、又は脂環式ポリエステルとポリアリーレートの組合せである、請求項1、請求項2又は請求項6記載のシート。
- 20%以上の赤外線吸光率、20%以上の紫外線吸光率及び可視域で40%以上の透過率を有する、請求項1記載のシート。
- ポリカーボネートと酸化セシウムタングステンと熱安定剤とUV吸収性添加剤を含むコア層で、IR吸収性添加剤が金属酸化物であるコア層と、
ポリエステルとUV吸収性添加剤を含む第一のキャップ層で、その一方の表面がコア層の一方の表面に密着して配置された第一のキャップ層と
を備える多層シート。 - さらに、ポリエステルとUV吸収性添加剤を含む第二のキャップ層で、第一のキャップ層と接したコア層の表面と反対側の表面に密着して配置された第二のキャップ層を備える、請求項11記載のシート。
- 多層シートの製造方法であって、
熱可塑性ポリマーとIR吸収性添加剤を含むコア層の一方の表面に、熱可塑性ポリマーと紫外線吸収性添加剤を含む第一のキャップ層を配設することを含んでなり、IR吸収性添加剤が酸化カリウムタングステン、酸化ルビジウムタングステン、酸化セシウムタングステン、酸化タリウムタングステン又はこれらの酸化物の1種以上を含む組合せである、方法。 - 前記コア層が第一のキャップ層と同時又は逐次製造される、請求項13記載の方法。
- さらに、熱可塑性ポリマーと紫外線吸収性添加剤を含む第二のキャップ層を、第一のキャップ層と接したコア層の表面と反対側の表面に配設することを含む、請求項13又は請求項14記載の方法。
- 第二のキャップ層が第一のキャップ層及び/又はコア層と同時又は逐次製造される、請求項15記載の方法。
- 多層シートの製造方法であって、
ポリカーボネートとIR吸収性添加剤を含むコア層を、ポリエステルと紫外線吸収剤を含む第一のキャップ層と共押出することを含んでなり、IR吸収性添加剤が酸化カリウムタングステン、酸化ルビジウムタングステン、酸化セシウムタングステン、酸化タリウムタングステン又はこれらの酸化物の1種以上を含む組合せである、方法。 - さらに第二のキャップ層を第一のキャップ層及びコア層と共押出すること或いは前記多層シートに積層することを含む、請求項17記載の方法。
- 熱可塑性樹脂とIR吸収性添加剤を含んでなる組成物であって、IR吸収性添加剤が酸化カリウムタングステン、酸化ルビジウムタングステン、酸化セシウムタングステン、酸化タリウムタングステン又はこれらの酸化物の1種以上を含む組合せからなる金属酸化物である、組成物。
- さらに、ホウ化ランタン(LaB6)、ホウ化プラセオジム(PrB6)、ホウ化ネオジム(NdB6)、ホウ化セリウム(CeB6)、ホウ化ガドリニウム(GdB6)、ホウ化テルビウム(TbB6)、ホウ化ジスプロシウム(DyB6)、ホウ化ホルミウム(HoB6)、ホウ化イットリウム(YB6)、ホウ化サマリウム(SmB6)、ホウ化ユウロピウム(EuB6)、ホウ化エルビウム(ErB6)、ホウ化ツリウム(TmB6)、ホウ化イッテルビウム(YbB6)、ホウ化ルテチウム(LuB6)、ホウ化ストロンチウム(SrB6)、ホウ化カルシウム(CaB6)、ホウ化チタン(TiB2)、ホウ化ジルコニウム(ZrB2)、ホウ化ハフニウム(HfB2)、ホウ化バナジウム(VB2)、ホウ化タンタル(TaB2)、ホウ化クロム(CrB及びCrB2)、ホウ化モリブデン(MoB2、Mo2B5及びMoB)、ホウ化タングステン(W2B5)又はこれらのホウ化物の1種以上を含む組合せを含む、請求項19記載の組成物。
- 請求項1又は請求項11記載の多層シートを備える物品。
- 請求項13又は請求項17記載の方法で製造された物品。
- 請求項19又は請求項20記載の組成物から製造された物品。
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Also Published As
Publication number | Publication date |
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CN100488768C (zh) | 2009-05-20 |
TW200639057A (en) | 2006-11-16 |
AU2005203334B2 (en) | 2007-05-24 |
US7399571B2 (en) | 2008-07-15 |
KR100740353B1 (ko) | 2007-07-16 |
AU2005203334A1 (en) | 2006-11-23 |
TWI413589B (zh) | 2013-11-01 |
CN1857917A (zh) | 2006-11-08 |
EP1724110B1 (en) | 2019-08-21 |
KR20060115560A (ko) | 2006-11-09 |
US20060251996A1 (en) | 2006-11-09 |
JP4638295B2 (ja) | 2011-02-23 |
EP1724110A1 (en) | 2006-11-22 |
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