JP2006063214A - 蛍光体及びその製造方法並びに光源 - Google Patents
蛍光体及びその製造方法並びに光源 Download PDFInfo
- Publication number
- JP2006063214A JP2006063214A JP2004248405A JP2004248405A JP2006063214A JP 2006063214 A JP2006063214 A JP 2006063214A JP 2004248405 A JP2004248405 A JP 2004248405A JP 2004248405 A JP2004248405 A JP 2004248405A JP 2006063214 A JP2006063214 A JP 2006063214A
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- JP
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- Prior art keywords
- phosphor
- light
- elements
- fluorine
- boron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 163
- 238000004519 manufacturing process Methods 0.000 title claims description 27
- 229910052796 boron Inorganic materials 0.000 claims abstract description 48
- 239000000203 mixture Substances 0.000 claims abstract description 45
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 42
- 239000011737 fluorine Substances 0.000 claims abstract description 42
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000001301 oxygen Substances 0.000 claims abstract description 25
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 25
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 14
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 9
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 8
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 7
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 6
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 6
- 229910052738 indium Inorganic materials 0.000 claims abstract description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 6
- 229910052716 thallium Inorganic materials 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims description 59
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 37
- 239000000843 powder Substances 0.000 claims description 34
- 229910004261 CaF 2 Inorganic materials 0.000 claims description 14
- 150000002222 fluorine compounds Chemical class 0.000 claims description 13
- 150000001639 boron compounds Chemical class 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 7
- 229910052788 barium Inorganic materials 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 229910052712 strontium Inorganic materials 0.000 claims description 5
- 229910016569 AlF 3 Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 230000005284 excitation Effects 0.000 abstract description 29
- 229910052797 bismuth Inorganic materials 0.000 abstract description 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 30
- 229910052582 BN Inorganic materials 0.000 description 29
- 239000011575 calcium Substances 0.000 description 23
- 150000004767 nitrides Chemical class 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 238000010304 firing Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 14
- 239000007791 liquid phase Substances 0.000 description 13
- 238000002156 mixing Methods 0.000 description 13
- 238000003746 solid phase reaction Methods 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000012190 activator Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 9
- 102100032047 Alsin Human genes 0.000 description 8
- 101710187109 Alsin Proteins 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 238000005245 sintering Methods 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 238000005286 illumination Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000009877 rendering Methods 0.000 description 6
- 238000000295 emission spectrum Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- -1 for example Chemical compound 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910052772 Samarium Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000007580 dry-mixing Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910016657 EuF Inorganic materials 0.000 description 1
- 229910016655 EuF 3 Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 229910003668 SrAl Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004248405A JP2006063214A (ja) | 2004-08-27 | 2004-08-27 | 蛍光体及びその製造方法並びに光源 |
| US11/211,751 US7476338B2 (en) | 2004-08-27 | 2005-08-26 | Phosphor and manufacturing method for the same, and light source |
| DE602005015397T DE602005015397D1 (de) | 2004-08-27 | 2005-08-29 | Leuchtstoff, Verfahren zu seiner Herstellung und diesen Leuchtstoff verwendende Lichtquelle |
| EP05018712A EP1630219B2 (en) | 2004-08-27 | 2005-08-29 | Phosphor and manufacturing mehod for the same, and light source using the same |
| EP08018901A EP2022836B1 (en) | 2004-08-27 | 2005-08-29 | Phosphor and manufacturing mehod for the same, and light source using the same |
| US12/292,889 US7803286B2 (en) | 2004-08-27 | 2008-11-28 | Phosphor and manufacturing method for the same, and light source |
| US12/801,658 US8308981B2 (en) | 2004-08-27 | 2010-06-18 | Phosphor and manufacturing method for the same, and light source |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004248405A JP2006063214A (ja) | 2004-08-27 | 2004-08-27 | 蛍光体及びその製造方法並びに光源 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009272267A Division JP5394903B2 (ja) | 2009-11-30 | 2009-11-30 | 蛍光体及びその製造方法並びに光源 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006063214A true JP2006063214A (ja) | 2006-03-09 |
| JP2006063214A5 JP2006063214A5 (enExample) | 2010-01-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004248405A Pending JP2006063214A (ja) | 2004-08-27 | 2004-08-27 | 蛍光体及びその製造方法並びに光源 |
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| JP (1) | JP2006063214A (enExample) |
Cited By (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006306981A (ja) * | 2005-04-27 | 2006-11-09 | Nichia Chem Ind Ltd | 窒化物蛍光体及びそれを用いた発光装置 |
| JP2007131794A (ja) * | 2005-11-12 | 2007-05-31 | Nichia Chem Ind Ltd | 窒化物系蛍光体及びそれを用いた発光装置 |
| US7252788B2 (en) | 2004-02-27 | 2007-08-07 | Dowa Mining Co., Ltd. | Phosphor, light source and LED |
| US7273568B2 (en) | 2004-06-25 | 2007-09-25 | Dowa Mining Co., Ltd. | Phosphor and production method of the same, method of shifting emission wavelength of phosphor, and light source and LED |
| US7291289B2 (en) | 2004-05-14 | 2007-11-06 | Dowa Electronics Materials Co., Ltd. | Phosphor and production method of the same and light source and LED using the phosphor |
| US7319195B2 (en) | 2003-11-28 | 2008-01-15 | Dowa Electronics Materials Co., Ltd. | Composite conductor, superconductive apparatus system, and composite conductor manufacturing method |
| US7345418B2 (en) | 2004-08-27 | 2008-03-18 | Dowa Mining Co., Ltd. | Phosphor mixture and light emitting device using the same |
| JP2008530334A (ja) * | 2005-02-21 | 2008-08-07 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | 放射線源および発光物質を含む照明系 |
| JP2008189700A (ja) * | 2007-01-31 | 2008-08-21 | Nichia Chem Ind Ltd | 窒化物系蛍光体、酸窒化物系蛍光体及びこれらを用いた発光装置 |
| US7432647B2 (en) | 2004-07-09 | 2008-10-07 | Dowa Electronics Materials Co., Ltd. | Light source having phosphor including divalent trivalent and tetravalent elements |
| US7434981B2 (en) | 2004-05-28 | 2008-10-14 | Dowa Electronics Materials Co., Ltd. | Manufacturing method of metal paste |
| US7443094B2 (en) | 2005-03-31 | 2008-10-28 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method of the same, and light emitting device using the phosphor |
| US7445730B2 (en) | 2005-03-31 | 2008-11-04 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method of the same, and light emitting device using the phosphor |
| US7476336B2 (en) | 2005-04-28 | 2009-01-13 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method for the same, and light emitting device using the phosphor |
| US7476337B2 (en) | 2004-07-28 | 2009-01-13 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method for the same, and light source |
| US7476338B2 (en) | 2004-08-27 | 2009-01-13 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method for the same, and light source |
| US7477009B2 (en) | 2005-03-01 | 2009-01-13 | Dowa Electronics Materials Co., Ltd. | Phosphor mixture and light emitting device |
| US7476335B2 (en) | 2004-08-20 | 2009-01-13 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method therefore, and light source using the phosphor |
| US7514860B2 (en) | 2004-10-28 | 2009-04-07 | Dowa Electronics Materials Co., Ltd. | Phosphor mixture and light emitting device |
| US7524437B2 (en) | 2005-03-04 | 2009-04-28 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method of the same, and light emitting device using the phosphor |
| US7527748B2 (en) | 2004-08-02 | 2009-05-05 | Dowa Electronics Materials Co., Ltd. | Phosphor and phosphor film for electron beam excitation and color display apparatus using the same |
| JP2010018771A (ja) * | 2008-05-19 | 2010-01-28 | Intematix Corp | 窒化物ベースの赤色蛍光体 |
| WO2010061597A1 (ja) * | 2008-11-28 | 2010-06-03 | 昭和電工株式会社 | 表示装置用照明装置及び表示装置 |
| JP2010525092A (ja) * | 2007-04-17 | 2010-07-22 | オスラム ゲゼルシャフト ミット ベシュレンクテル ハフツング | 赤色に放射する蛍光体及びこの種の蛍光体を有する光源 |
| US7854859B2 (en) | 2004-12-28 | 2010-12-21 | Nichia Corporation | Nitride phosphor, method for producing this nitride phosphor, and light emitting device that uses this nitride phosphor |
| JP2012512307A (ja) * | 2008-12-15 | 2012-05-31 | インテマティックス・コーポレーション | Rgb(赤−緑−青)ライティングシステムにおける窒化物系赤色発光蛍光体 |
| JP5200537B2 (ja) * | 2005-06-15 | 2013-06-05 | 日亜化学工業株式会社 | 発光装置 |
| US8608980B2 (en) | 2007-09-03 | 2013-12-17 | National Institute For Materials Science | Phosphor, method for producing the same and light-emitting device using the same |
| KR20140089375A (ko) * | 2011-10-17 | 2014-07-14 | 그리렘 어드밴스드 머티리얼스 캄파니 리미티드 | 질화물 적색 발광재료, 그것을 포함한 발광체 및 발광소자 |
| USRE45640E1 (en) | 2004-08-02 | 2015-08-04 | Dowa Electronics Materials Co., Ltd. | Phosphor for electron beam excitation and color display device using the same |
| WO2017030030A1 (ja) * | 2015-08-19 | 2017-02-23 | 宇部興産株式会社 | 蛍光体及びその製造方法並びに発光装置 |
| US9738829B2 (en) | 2003-11-26 | 2017-08-22 | Mitsubishi Chemical Corporation | Phosphor and light-emitting equipment using phosphor |
| JP2018035346A (ja) * | 2016-08-25 | 2018-03-08 | 日亜化学工業株式会社 | 窒化物蛍光体、その製造方法および発光装置 |
| US10590342B2 (en) | 2016-08-25 | 2020-03-17 | Nichia Corporation | Nitride fluorescent material, method of producing nitride fluorescent material and light emitting device |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006008721A (ja) * | 2003-11-26 | 2006-01-12 | National Institute For Materials Science | 蛍光体と蛍光体を用いた発光器具 |
-
2004
- 2004-08-27 JP JP2004248405A patent/JP2006063214A/ja active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006008721A (ja) * | 2003-11-26 | 2006-01-12 | National Institute For Materials Science | 蛍光体と蛍光体を用いた発光器具 |
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| US9738829B2 (en) | 2003-11-26 | 2017-08-22 | Mitsubishi Chemical Corporation | Phosphor and light-emitting equipment using phosphor |
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| USRE44996E1 (en) | 2004-06-25 | 2014-07-08 | Nichia Corporation | Phosphor and production method of the same, method of shifting emission wavelength of phosphor, and light source and LED |
| US7432647B2 (en) | 2004-07-09 | 2008-10-07 | Dowa Electronics Materials Co., Ltd. | Light source having phosphor including divalent trivalent and tetravalent elements |
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| US7476337B2 (en) | 2004-07-28 | 2009-01-13 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method for the same, and light source |
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| JP2008530334A (ja) * | 2005-02-21 | 2008-08-07 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | 放射線源および発光物質を含む照明系 |
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| US7443094B2 (en) | 2005-03-31 | 2008-10-28 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method of the same, and light emitting device using the phosphor |
| US7445730B2 (en) | 2005-03-31 | 2008-11-04 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method of the same, and light emitting device using the phosphor |
| JP2006306981A (ja) * | 2005-04-27 | 2006-11-09 | Nichia Chem Ind Ltd | 窒化物蛍光体及びそれを用いた発光装置 |
| US7476336B2 (en) | 2005-04-28 | 2009-01-13 | Dowa Electronics Materials Co., Ltd. | Phosphor and manufacturing method for the same, and light emitting device using the phosphor |
| JP5200537B2 (ja) * | 2005-06-15 | 2013-06-05 | 日亜化学工業株式会社 | 発光装置 |
| JP2007131794A (ja) * | 2005-11-12 | 2007-05-31 | Nichia Chem Ind Ltd | 窒化物系蛍光体及びそれを用いた発光装置 |
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