JP2006004858A - 多孔質電極基材およびその製造方法 - Google Patents
多孔質電極基材およびその製造方法 Download PDFInfo
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- JP2006004858A JP2006004858A JP2004182407A JP2004182407A JP2006004858A JP 2006004858 A JP2006004858 A JP 2006004858A JP 2004182407 A JP2004182407 A JP 2004182407A JP 2004182407 A JP2004182407 A JP 2004182407A JP 2006004858 A JP2006004858 A JP 2006004858A
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- Prior art keywords
- resin
- carbon fiber
- electrode substrate
- carbon
- base material
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- 239000000758 substrate Substances 0.000 title claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 99
- 239000004917 carbon fiber Substances 0.000 claims abstract description 99
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 84
- 229920005989 resin Polymers 0.000 claims abstract description 68
- 239000011347 resin Substances 0.000 claims abstract description 68
- 239000000835 fiber Substances 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 35
- 230000035699 permeability Effects 0.000 claims abstract description 32
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000005452 bending Methods 0.000 claims abstract description 27
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 27
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 24
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 229920005613 synthetic organic polymer Polymers 0.000 claims abstract description 5
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 50
- 239000011148 porous material Substances 0.000 claims description 24
- 238000003763 carbonization Methods 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 12
- 238000009499 grossing Methods 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052753 mercury Inorganic materials 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 39
- 239000002585 base Substances 0.000 description 28
- 239000007833 carbon precursor Substances 0.000 description 22
- 239000005011 phenolic resin Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000012360 testing method Methods 0.000 description 9
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- 238000003825 pressing Methods 0.000 description 7
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229920002978 Vinylon Polymers 0.000 description 5
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- 230000000052 comparative effect Effects 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000012495 reaction gas Substances 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
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- 229910052802 copper Inorganic materials 0.000 description 2
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- 238000007599 discharging Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
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- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920006282 Phenolic fiber Polymers 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
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- 239000003792 electrolyte Substances 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007849 furan resin Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000010680 novolac-type phenolic resin Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
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- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920006306 polyurethane fiber Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
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- 238000004804 winding Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004182407A JP2006004858A (ja) | 2004-06-21 | 2004-06-21 | 多孔質電極基材およびその製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004182407A JP2006004858A (ja) | 2004-06-21 | 2004-06-21 | 多孔質電極基材およびその製造方法 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010051686A Division JP2010182682A (ja) | 2010-03-09 | 2010-03-09 | 多孔質電極基材の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006004858A true JP2006004858A (ja) | 2006-01-05 |
JP2006004858A5 JP2006004858A5 (enrdf_load_stackoverflow) | 2007-06-21 |
Family
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Family Applications (1)
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JP2004182407A Pending JP2006004858A (ja) | 2004-06-21 | 2004-06-21 | 多孔質電極基材およびその製造方法 |
Country Status (1)
Country | Link |
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JP (1) | JP2006004858A (enrdf_load_stackoverflow) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008081872A (ja) * | 2006-09-27 | 2008-04-10 | Takayasu Co Ltd | 炭素繊維不織布及びその製造方法 |
JP2009181738A (ja) * | 2008-01-29 | 2009-08-13 | Mitsubishi Rayon Co Ltd | 多孔質炭素電極基材の製造方法および膜−電極接合体 |
WO2010090164A1 (ja) * | 2009-02-04 | 2010-08-12 | 三菱レイヨン株式会社 | 多孔質電極基材、その製造方法、膜-電極接合体、および固体高分子型燃料電池 |
JP2010182682A (ja) * | 2010-03-09 | 2010-08-19 | Mitsubishi Rayon Co Ltd | 多孔質電極基材の製造方法 |
JP2010257748A (ja) * | 2009-04-24 | 2010-11-11 | Mitsubishi Rayon Co Ltd | 多孔質電極基材およびその製造方法 |
WO2016159352A1 (ja) * | 2015-04-02 | 2016-10-06 | 三菱レイヨン株式会社 | 多孔質電極基材およびその製造方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06295728A (ja) * | 1993-04-08 | 1994-10-21 | Matsushita Electric Ind Co Ltd | 固体高分子型燃料電池用電極およびそれを用いた燃料電池 |
JPH09157052A (ja) * | 1995-12-06 | 1997-06-17 | Toray Ind Inc | 多孔質炭素板とその製造方法 |
WO2001056103A1 (fr) * | 2000-01-27 | 2001-08-02 | Mitsubishi Rayon Co., Ltd. | Materiau d'electrode a base de carbone poreux, son procede de fabrication, et papier a fibres de carbone |
JP2002270191A (ja) * | 2001-03-08 | 2002-09-20 | Mitsubishi Rayon Co Ltd | 炭素電極基材及びその製造方法 |
JP2003151585A (ja) * | 2001-11-12 | 2003-05-23 | Toyota Motor Corp | 燃料電池及び拡散層 |
WO2003087470A1 (fr) * | 2002-04-17 | 2003-10-23 | Mitsubishi Rayon Co., Ltd. | Papier en fibre de carbone et substrat d'electrode en fibre de carbone poreux, destine aux piles |
-
2004
- 2004-06-21 JP JP2004182407A patent/JP2006004858A/ja active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06295728A (ja) * | 1993-04-08 | 1994-10-21 | Matsushita Electric Ind Co Ltd | 固体高分子型燃料電池用電極およびそれを用いた燃料電池 |
JPH09157052A (ja) * | 1995-12-06 | 1997-06-17 | Toray Ind Inc | 多孔質炭素板とその製造方法 |
WO2001056103A1 (fr) * | 2000-01-27 | 2001-08-02 | Mitsubishi Rayon Co., Ltd. | Materiau d'electrode a base de carbone poreux, son procede de fabrication, et papier a fibres de carbone |
JP2002270191A (ja) * | 2001-03-08 | 2002-09-20 | Mitsubishi Rayon Co Ltd | 炭素電極基材及びその製造方法 |
JP2003151585A (ja) * | 2001-11-12 | 2003-05-23 | Toyota Motor Corp | 燃料電池及び拡散層 |
WO2003087470A1 (fr) * | 2002-04-17 | 2003-10-23 | Mitsubishi Rayon Co., Ltd. | Papier en fibre de carbone et substrat d'electrode en fibre de carbone poreux, destine aux piles |
Non-Patent Citations (2)
Title |
---|
JIS P 8117, JPN6010000454, 1998, ISSN: 0001511814 * |
保坂範夫, はじめてのプラスチック成形, vol. 初版, JPN6010000455, 11 August 2003 (2003-08-11), pages 49, ISSN: 0001511813 * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008081872A (ja) * | 2006-09-27 | 2008-04-10 | Takayasu Co Ltd | 炭素繊維不織布及びその製造方法 |
JP2009181738A (ja) * | 2008-01-29 | 2009-08-13 | Mitsubishi Rayon Co Ltd | 多孔質炭素電極基材の製造方法および膜−電極接合体 |
WO2010090164A1 (ja) * | 2009-02-04 | 2010-08-12 | 三菱レイヨン株式会社 | 多孔質電極基材、その製造方法、膜-電極接合体、および固体高分子型燃料電池 |
JP5404609B2 (ja) * | 2009-02-04 | 2014-02-05 | 三菱レイヨン株式会社 | 多孔質電極基材、その製造方法、膜−電極接合体、および固体高分子型燃料電池 |
US8927173B2 (en) | 2009-02-04 | 2015-01-06 | Mitsubishi Rayon Co., Ltd. | Porous electrode substrate, method for producing the same, membrane electrode assembly, and polymer electrolyte fuel cell |
US8986907B2 (en) | 2009-02-04 | 2015-03-24 | Mitsubishi Rayon Co., Ltd. | Porous electrode substrate, method for producing the same, membrane electrode assembly, and polymer electrolyte fuel cell |
JP2010257748A (ja) * | 2009-04-24 | 2010-11-11 | Mitsubishi Rayon Co Ltd | 多孔質電極基材およびその製造方法 |
JP2010182682A (ja) * | 2010-03-09 | 2010-08-19 | Mitsubishi Rayon Co Ltd | 多孔質電極基材の製造方法 |
WO2016159352A1 (ja) * | 2015-04-02 | 2016-10-06 | 三菱レイヨン株式会社 | 多孔質電極基材およびその製造方法 |
JPWO2016159352A1 (ja) * | 2015-04-02 | 2017-04-27 | 三菱レイヨン株式会社 | 多孔質電極基材およびその製造方法 |
CN107408707A (zh) * | 2015-04-02 | 2017-11-28 | 三菱化学株式会社 | 多孔电极基材及其制造方法 |
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