JP2005520016A5 - - Google Patents

Info

Publication number

JP2005520016A5

JP2005520016A5 JP2003574749A JP2003574749A JP2005520016A5 JP 2005520016 A5 JP2005520016 A5 JP 2005520016A5 JP 2003574749 A JP2003574749 A JP 2003574749A JP 2003574749 A JP2003574749 A JP 2003574749A JP 2005520016 A5 JP2005520016 A5 JP 2005520016A5

Authority

JP

Japan

Prior art keywords

group

coating

rubber

acid

acrylate

Prior art date

2003-03-08

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Granted

Links

• Espacenet
• Global Dossier
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• 238000000576 coating method Methods 0.000 claims description 175
• 229920000642 polymer Polymers 0.000 claims description 156
• 229920001971 elastomer Polymers 0.000 claims description 151
• 239000011248 coating agent Substances 0.000 claims description 145
• -1 isocyanate polyol Chemical class 0.000 claims description 114
• 125000000524 functional group Chemical group 0.000 claims description 87
• 239000000806 elastomer Substances 0.000 claims description 85
• 238000000034 method Methods 0.000 claims description 84
• 229920001577 copolymer Polymers 0.000 claims description 79
• 239000000178 monomer Substances 0.000 claims description 76
• 229920000459 Nitrile rubber Polymers 0.000 claims description 59
• 239000000203 mixture Substances 0.000 claims description 57
• 239000002904 solvent Substances 0.000 claims description 56
• 239000012948 isocyanate Substances 0.000 claims description 51
• 239000008199 coating composition Substances 0.000 claims description 47
• 229920001228 polyisocyanate Polymers 0.000 claims description 40
• 239000005056 polyisocyanate Substances 0.000 claims description 40
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 37
• 244000043261 Hevea brasiliensis Species 0.000 claims description 32
• 229920003052 natural elastomer Polymers 0.000 claims description 32
• 229920001194 natural rubber Polymers 0.000 claims description 32
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 31
• 239000007788 liquid Substances 0.000 claims description 31
• 239000002245 particle Substances 0.000 claims description 29
• 150000002148 esters Chemical class 0.000 claims description 20
• BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 18
• 229920005862 polyol Polymers 0.000 claims description 18
• 229920001897 terpolymer Polymers 0.000 claims description 17
• 229920002943 EPDM rubber Polymers 0.000 claims description 16
• 150000008064 anhydrides Chemical class 0.000 claims description 16
• 239000002923 metal particle Substances 0.000 claims description 16
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 15
• 239000005977 Ethylene Substances 0.000 claims description 15
• 229920002857 polybutadiene Polymers 0.000 claims description 13
• 150000004756 silanes Chemical class 0.000 claims description 13
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 12
• 150000001735 carboxylic acids Chemical class 0.000 claims description 12
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 11
• 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 11
• BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 11
• 125000003545 alkoxy group Chemical group 0.000 claims description 9
• 229920003987 resole Polymers 0.000 claims description 9
• 229920003180 amino resin Polymers 0.000 claims description 6
• 150000001991 dicarboxylic acids Chemical class 0.000 claims description 6
• HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 6
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
• 229920003048 styrene butadiene rubber Polymers 0.000 claims description 5
• 125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
• 238000005507 spraying Methods 0.000 claims description 4
• 229920001567 vinyl ester resin Polymers 0.000 claims description 4
• ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
• 230000001680 brushing effect Effects 0.000 claims description 3
• 238000007598 dipping method Methods 0.000 claims description 3
• 229920002313 fluoropolymer Polymers 0.000 claims description 3
• 239000011630 iodine Substances 0.000 claims description 3
• 229910052740 iodine Inorganic materials 0.000 claims description 3
• 229920003986 novolac Polymers 0.000 claims description 3
• 150000003512 tertiary amines Chemical class 0.000 claims description 3
• RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical compound FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 claims description 2
• LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
• UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 2
• 239000004811 fluoropolymer Substances 0.000 claims description 2
• 229920003049 isoprene rubber Polymers 0.000 claims description 2
• 150000002918 oxazolines Chemical class 0.000 claims description 2
• 229920001084 poly(chloroprene) Polymers 0.000 claims description 2
• 150000002763 monocarboxylic acids Chemical class 0.000 claims 2
• KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims 1
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
• XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims 1
• 150000002462 imidazolines Chemical class 0.000 claims 1
• 229920000554 ionomer Polymers 0.000 claims 1
• 150000004893 oxazines Chemical class 0.000 claims 1
• 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 claims 1
• 150000003458 sulfonic acid derivatives Chemical class 0.000 claims 1
• 239000000758 substrate Substances 0.000 description 84
• 238000001723 curing Methods 0.000 description 79
• 239000005060 rubber Substances 0.000 description 66
• 239000003795 chemical substances by application Substances 0.000 description 64
• 150000001875 compounds Chemical class 0.000 description 64
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 56
• 239000010408 film Substances 0.000 description 49
• 150000002513 isocyanates Chemical class 0.000 description 45
• 238000006243 chemical reaction Methods 0.000 description 42
• 229910052751 metal Inorganic materials 0.000 description 41
• 239000002184 metal Substances 0.000 description 41
• 125000004432 carbon atom Chemical group C* 0.000 description 36
• 239000001257 hydrogen Substances 0.000 description 36
• 229910052739 hydrogen Inorganic materials 0.000 description 36
• 125000004435 hydrogen atom Chemical group [H]* 0.000 description 31
• 229920001973 fluoroelastomer Polymers 0.000 description 30
• 239000000243 solution Substances 0.000 description 30
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 29
• 150000001993 dienes Chemical class 0.000 description 28
• 150000001412 amines Chemical class 0.000 description 26
• 150000003254 radicals Chemical class 0.000 description 26
• KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 25
• 238000004132 cross linking Methods 0.000 description 25
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 24
• 239000000463 material Substances 0.000 description 24
• 239000000049 pigment Substances 0.000 description 24
• 230000005855 radiation Effects 0.000 description 24
• 229920000126 latex Polymers 0.000 description 23
• 239000003054 catalyst Substances 0.000 description 22
• 239000004816 latex Substances 0.000 description 22
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 21
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 21
• 125000000217 alkyl group Chemical group 0.000 description 21
• 229910052782 aluminium Inorganic materials 0.000 description 20
• 238000005984 hydrogenation reaction Methods 0.000 description 20
• 239000000047 product Substances 0.000 description 20
• 239000007787 solid Substances 0.000 description 20
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 19
• 239000002253 acid Substances 0.000 description 18
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 18
• 229920002635 polyurethane Polymers 0.000 description 17
• 239000004814 polyurethane Substances 0.000 description 17
• 239000004711 α-olefin Substances 0.000 description 17
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 16
• NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 16
• 125000001931 aliphatic group Chemical group 0.000 description 16
• 150000001718 carbodiimides Chemical class 0.000 description 16
• 230000000694 effects Effects 0.000 description 16
• 150000003077 polyols Chemical class 0.000 description 16
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 16
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 15
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 15
• 150000001732 carboxylic acid derivatives Chemical class 0.000 description 15
• 125000005442 diisocyanate group Chemical group 0.000 description 15
• 238000006116 polymerization reaction Methods 0.000 description 15
• CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 14
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
• 238000010438 heat treatment Methods 0.000 description 14
• 239000003999 initiator Substances 0.000 description 14
• VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
• 239000003960 organic solvent Substances 0.000 description 14
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 13
• 229920002367 Polyisobutene Polymers 0.000 description 13
• 229920003244 diene elastomer Polymers 0.000 description 13
• 229910052736 halogen Inorganic materials 0.000 description 13
• 150000002367 halogens Chemical class 0.000 description 13
• 238000005649 metathesis reaction Methods 0.000 description 13
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
• RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 12
• BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 12
• 125000003118 aryl group Chemical group 0.000 description 12
• 239000002585 base Substances 0.000 description 12
• 229920006168 hydrated nitrile rubber Polymers 0.000 description 12
• IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 12
• 150000002825 nitriles Chemical class 0.000 description 12
• 229910052757 nitrogen Inorganic materials 0.000 description 12
• 150000001451 organic peroxides Chemical class 0.000 description 12
• 229910000077 silane Inorganic materials 0.000 description 12
• 239000000126 substance Substances 0.000 description 12
• 238000004073 vulcanization Methods 0.000 description 12
• JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 11
• VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 11
• BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 11
• LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 11
• 229920000098 polyolefin Polymers 0.000 description 11
• 229920002554 vinyl polymer Polymers 0.000 description 11
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
• 239000004593 Epoxy Substances 0.000 description 10
• VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 10
• 239000005062 Polybutadiene Substances 0.000 description 10
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
• 150000001336 alkenes Chemical class 0.000 description 10
• 125000003277 amino group Chemical group 0.000 description 10
• VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 10
• 239000011976 maleic acid Substances 0.000 description 10
• 229920000058 polyacrylate Polymers 0.000 description 10
• 239000002243 precursor Substances 0.000 description 10
• 230000008569 process Effects 0.000 description 10
• 229910052717 sulfur Inorganic materials 0.000 description 10
• 238000012360 testing method Methods 0.000 description 10
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 10
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
• 229920000800 acrylic rubber Polymers 0.000 description 9
• 239000007795 chemical reaction product Substances 0.000 description 9
• 238000005336 cracking Methods 0.000 description 9
• 238000007306 functionalization reaction Methods 0.000 description 9
• 230000009477 glass transition Effects 0.000 description 9
• 125000005647 linker group Chemical group 0.000 description 9
• 238000002156 mixing Methods 0.000 description 9
• 229910052760 oxygen Inorganic materials 0.000 description 9
• 230000002829 reductive effect Effects 0.000 description 9
• 230000035882 stress Effects 0.000 description 9
• OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 8
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 8
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 8
• 239000003570 air Substances 0.000 description 8
• 238000005452 bending Methods 0.000 description 8
• CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 8
• 239000006185 dispersion Substances 0.000 description 8
• 230000020169 heat generation Effects 0.000 description 8
• 239000003921 oil Substances 0.000 description 8
• 239000001301 oxygen Substances 0.000 description 8
• 150000003141 primary amines Chemical group 0.000 description 8
• 150000003335 secondary amines Chemical class 0.000 description 8
• FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 8
• 239000012855 volatile organic compound Substances 0.000 description 8
• 239000004971 Cross linker Substances 0.000 description 7
• JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 7
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
• XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
• 230000015556 catabolic process Effects 0.000 description 7
• 239000000460 chlorine Substances 0.000 description 7
• 229910052801 chlorine Inorganic materials 0.000 description 7
• 238000006731 degradation reaction Methods 0.000 description 7
• 239000000839 emulsion Substances 0.000 description 7
• 239000000446 fuel Substances 0.000 description 7
• 150000002430 hydrocarbons Chemical class 0.000 description 7
• 230000007062 hydrolysis Effects 0.000 description 7
• 238000006460 hydrolysis reaction Methods 0.000 description 7
• NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 7
• 238000004519 manufacturing process Methods 0.000 description 7
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 7
• 229920001296 polysiloxane Polymers 0.000 description 7
• 239000011593 sulfur Substances 0.000 description 7
• CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 7
• OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 6
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
• 229920000089 Cyclic olefin copolymer Polymers 0.000 description 6
• WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 6
• 239000005058 Isophorone diisocyanate Substances 0.000 description 6
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
• CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 6
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
• 239000004721 Polyphenylene oxide Substances 0.000 description 6
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
• GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
• 229920006170 Therban® Polymers 0.000 description 6
• 125000002947 alkylene group Chemical group 0.000 description 6
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
• FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 6
• 239000012320 chlorinating reagent Substances 0.000 description 6
• LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 6
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
• NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 6
• RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 6
• 229930195733 hydrocarbon Natural products 0.000 description 6
• 239000010410 layer Substances 0.000 description 6
• FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 6
• 230000003647 oxidation Effects 0.000 description 6
• 238000007254 oxidation reaction Methods 0.000 description 6
• 150000002978 peroxides Chemical class 0.000 description 6
• 229920003023 plastic Polymers 0.000 description 6
• 239000004033 plastic Substances 0.000 description 6
• 229920000570 polyether Polymers 0.000 description 6
• 230000009467 reduction Effects 0.000 description 6
• FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 6
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
• 125000003396 thiol group Chemical class [H]S* 0.000 description 6
• 239000008096 xylene Substances 0.000 description 6
• GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 5
• UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
• OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 5
• 239000002841 Lewis acid Substances 0.000 description 5
• PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 5
• UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 5
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
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• 239000005052 trichlorosilane Substances 0.000 description 1
• QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
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• XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
• JLGNHOJUQFHYEZ-UHFFFAOYSA-N trimethoxy(3,3,3-trifluoropropyl)silane Chemical compound CO[Si](OC)(OC)CCC(F)(F)F JLGNHOJUQFHYEZ-UHFFFAOYSA-N 0.000 description 1
• NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 description 1
• UAIFZYSPVVBOPN-UHFFFAOYSA-N trimethyl(prop-1-en-2-yloxy)silane Chemical compound CC(=C)O[Si](C)(C)C UAIFZYSPVVBOPN-UHFFFAOYSA-N 0.000 description 1
• MNMVKGDEKPPREK-UHFFFAOYSA-N trimethyl(prop-2-enoxy)silane Chemical compound C[Si](C)(C)OCC=C MNMVKGDEKPPREK-UHFFFAOYSA-N 0.000 description 1
• HYWCXWRMUZYRPH-UHFFFAOYSA-N trimethyl(prop-2-enyl)silane Chemical compound C[Si](C)(C)CC=C HYWCXWRMUZYRPH-UHFFFAOYSA-N 0.000 description 1
• UYPYRKYUKCHHIB-UHFFFAOYSA-N trimethylamine N-oxide Chemical compound C[N+](C)(C)[O-] UYPYRKYUKCHHIB-UHFFFAOYSA-N 0.000 description 1
• PGQNYIRJCLTTOJ-UHFFFAOYSA-N trimethylsilyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)O[Si](C)(C)C PGQNYIRJCLTTOJ-UHFFFAOYSA-N 0.000 description 1
• CWMFRHBXRUITQE-UHFFFAOYSA-N trimethylsilylacetylene Chemical group C[Si](C)(C)C#C CWMFRHBXRUITQE-UHFFFAOYSA-N 0.000 description 1
• DSROZUMNVRXZNO-UHFFFAOYSA-K tris[(1-naphthalen-1-yl-3-phenylnaphthalen-2-yl)oxy]alumane Chemical compound C=1C=CC=CC=1C=1C=C2C=CC=CC2=C(C=2C3=CC=CC=C3C=CC=2)C=1O[Al](OC=1C(=C2C=CC=CC2=CC=1C=1C=CC=CC=1)C=1C2=CC=CC=C2C=CC=1)OC(C(=C1C=CC=CC1=C1)C=2C3=CC=CC=C3C=CC=2)=C1C1=CC=CC=C1 DSROZUMNVRXZNO-UHFFFAOYSA-K 0.000 description 1
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• 239000005050 vinyl trichlorosilane Substances 0.000 description 1
• UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
• 239000007762 w/o emulsion Substances 0.000 description 1
• 125000005023 xylyl group Chemical group 0.000 description 1
• 238000004383 yellowing Methods 0.000 description 1
• XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1