JP2005514338A5 - - Google Patents
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- Publication number
- JP2005514338A5 JP2005514338A5 JP2003537581A JP2003537581A JP2005514338A5 JP 2005514338 A5 JP2005514338 A5 JP 2005514338A5 JP 2003537581 A JP2003537581 A JP 2003537581A JP 2003537581 A JP2003537581 A JP 2003537581A JP 2005514338 A5 JP2005514338 A5 JP 2005514338A5
- Authority
- JP
- Japan
- Prior art keywords
- substituted
- amide monomer
- acid amide
- polymerizable
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000178 monomer Substances 0.000 claims 81
- 239000000203 mixture Substances 0.000 claims 44
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 43
- 150000001408 amides Chemical class 0.000 claims 36
- 230000002378 acidificating effect Effects 0.000 claims 26
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 15
- 125000000542 sulfonic acid group Chemical group 0.000 claims 15
- 150000001875 compounds Chemical class 0.000 claims 10
- 230000007062 hydrolysis Effects 0.000 claims 9
- 238000006460 hydrolysis reaction Methods 0.000 claims 9
- 230000001588 bifunctional effect Effects 0.000 claims 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 239000003479 dental cement Substances 0.000 claims 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 5
- 125000002877 alkyl aryl group Chemical group 0.000 claims 5
- 125000005213 alkyl heteroaryl group Chemical group 0.000 claims 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims 5
- 125000003118 aryl group Chemical group 0.000 claims 5
- 238000005530 etching Methods 0.000 claims 5
- 125000001072 heteroaryl group Chemical group 0.000 claims 5
- 238000000034 method Methods 0.000 claims 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- 125000002993 cycloalkylene group Chemical group 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 3
- 239000000853 adhesive Substances 0.000 claims 3
- 230000001070 adhesive effect Effects 0.000 claims 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims 3
- 238000004128 high performance liquid chromatography Methods 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 150000003334 secondary amides Chemical class 0.000 claims 3
- 238000003860 storage Methods 0.000 claims 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims 2
- -1 alkyl acrylic acid Chemical compound 0.000 claims 2
- 150000004985 diamines Chemical class 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- ZTWTYVWXUKTLCP-UHFFFAOYSA-L ethenyl-dioxido-oxo-$l^{5}-phosphane Chemical compound [O-]P([O-])(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-L 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- 150000007522 mineralic acids Chemical class 0.000 claims 2
- 150000007524 organic acids Chemical class 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 229920000768 polyamine Polymers 0.000 claims 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims 2
- 150000003568 thioethers Chemical class 0.000 claims 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001350 alkyl halides Chemical class 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 210000003298 dental enamel Anatomy 0.000 claims 1
- 210000004268 dentin Anatomy 0.000 claims 1
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 claims 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-M ethenesulfonate Chemical compound [O-]S(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-M 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 1
- 239000003505 polymerization initiator Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000011877 solvent mixture Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 claims 1
- 0 *[C@](C(C(*)=C)=O)N=CC(C(*)=C)=O Chemical compound *[C@](C(C(*)=C)=O)N=CC(C(*)=C)=O 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34599401P | 2001-10-26 | 2001-10-26 | |
| PCT/EP2002/011940 WO2003035013A1 (en) | 2001-10-26 | 2002-10-25 | Hydrolysis stable self-etching, self-priming adhesive |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005514338A JP2005514338A (ja) | 2005-05-19 |
| JP2005514338A5 true JP2005514338A5 (enExample) | 2006-01-05 |
| JP4664591B2 JP4664591B2 (ja) | 2011-04-06 |
Family
ID=23357472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003537581A Expired - Fee Related JP4664591B2 (ja) | 2001-10-26 | 2002-10-25 | 加水分解に安定な自己エッチングかつ自己下塗り用接着剤 |
Country Status (5)
| Country | Link |
|---|---|
| US (3) | US20040266906A1 (enExample) |
| EP (1) | EP1437999B1 (enExample) |
| JP (1) | JP4664591B2 (enExample) |
| DE (1) | DE60216951T2 (enExample) |
| WO (1) | WO2003035013A1 (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4269010B2 (ja) * | 2001-07-09 | 2009-05-27 | 学校法人日本大学 | 歯科用セルフエッチングプライマー処理剤 |
| EP1437999B1 (en) * | 2001-10-26 | 2006-12-20 | DENTSPLY DETREY GmbH | Hydrolysis stable self-etching, self-priming adhesive |
| EP1548021B1 (en) * | 2003-12-23 | 2007-03-21 | DENTSPLY DETREY GmbH | One-part self-etching, self-priming dental adhesive composition |
| JP4514469B2 (ja) * | 2004-02-16 | 2010-07-28 | クラレメディカル株式会社 | ２液型の無柱エナメル質用接着剤 |
| JP4514470B2 (ja) * | 2004-02-17 | 2010-07-28 | クラレメディカル株式会社 | ２液型の無柱エナメル質用接着剤 |
| WO2005080454A1 (ja) * | 2004-02-24 | 2005-09-01 | Uni-Chemical Co., Ltd. | リン系酸残基含有(メタ）アクリルアミド、それを用いた重合体とその用途、及びそれらの製造方法 |
| CA2584733A1 (en) * | 2004-10-20 | 2006-04-27 | Pentron Clinical Technologies, Llc | Dental self-etching composition and method of use |
| DE102004061924B4 (de) | 2004-12-22 | 2010-01-28 | Ivoclar Vivadent Ag | Hydrolysestabiles selbstätzendes Einkomponentendentaladhäsiv |
| DE102004061925A1 (de) * | 2004-12-22 | 2006-07-13 | Ivoclar Vivadent Ag | Selbstätzende Dentalmaterialien auf Basis von (Meth)acrylamidphosphaten |
| DE102005002330A1 (de) | 2005-01-17 | 2006-07-20 | Heraeus Kulzer Gmbh | Hydrolysestabile Monomere mit Säuregruppen |
| EP1838661A1 (en) * | 2005-01-20 | 2007-10-03 | E.I.Du pont de nemours and company | Norbornane based cycloaliphatic compounds containing methylene amine groups |
| JP2009500481A (ja) * | 2005-07-08 | 2009-01-08 | チバ ホールディング インコーポレーテッド | （メタ）アクリルアミドリンモノマー組成物 |
| WO2008006489A1 (en) * | 2006-07-13 | 2008-01-17 | Dentsply De Trey Gmbh | Total etch dental adhesive composition |
| ES2461560T3 (es) * | 2006-07-13 | 2014-05-20 | Dentsply Detrey Gmbh | Composición adhesiva dental de grabado total |
| ES2381500T3 (es) | 2007-02-07 | 2012-05-28 | Dentsply Detrey Gmbh | Composición autoadhesiva para restauración dental |
| EP1974712B1 (de) | 2007-03-15 | 2010-10-27 | Ivoclar Vivadent AG | Dentalmaterialien auf der Basis von radikalisch polymerisationsfähigen, N,O-funktionalisierten Acrylsäure-hydroxamiden |
| US7963769B2 (en) | 2007-10-08 | 2011-06-21 | Kerr Corporation | Dental adhesive and method of use |
| US20090176194A1 (en) * | 2008-01-07 | 2009-07-09 | Kerr Corporation | Method of cementing prosthetic devices and cementation kit |
| CA2739713A1 (en) | 2008-10-31 | 2010-05-06 | Basf Se | (meth)acrylate phosphonic esters as adhesion promoters |
| US8372896B2 (en) | 2009-01-13 | 2013-02-12 | Dentsply International Inc. | Total etch dental adhesive composition |
| EP2272487A1 (en) * | 2009-07-08 | 2011-01-12 | Dentsply DeTrey GmbH | Process for the preparation of a composition comprising hyperbranched compounds |
| BR112012007330A2 (pt) * | 2009-10-01 | 2017-06-06 | Septodont Confi-Dental Div | compostos, composições contendo os mesmos, uso dos mesmos e processos para a produção dos mesmos. |
| JP2012020975A (ja) * | 2010-07-15 | 2012-02-02 | Tokuyama Dental Corp | 歯質用接着性組成物 |
| US8697769B2 (en) | 2010-09-30 | 2014-04-15 | Voco Gmbh | Lacquer composition comprising a monomer with a polyalicyclic structure element |
| EP2436668B1 (de) | 2010-09-30 | 2012-09-12 | VOCO GmbH | Polymerisierbare Verbindungen umfassend ein polyalicyclisches Strukturelement |
| EP2436365B1 (de) | 2010-09-30 | 2017-03-08 | VOCO GmbH | Kompositmaterial umfassend ein Monomer mit einem polyalicyclischen Strukturelement |
| US8915736B2 (en) | 2010-09-30 | 2014-12-23 | Voco Gmbh | Composition comprising a monomer with a polyalicyclic structure element for filling and/or sealing a root canal |
| EP2444053B1 (en) * | 2010-10-19 | 2020-05-06 | Dentsply DeTrey GmbH | Dental cement composition |
| EP2444054A1 (en) * | 2010-10-19 | 2012-04-25 | Dentsply DeTrey GmbH | Dental composition |
| EP2444052A1 (en) * | 2010-10-19 | 2012-04-25 | Dentsply DeTrey GmbH | Dental composition |
| JP5660411B2 (ja) * | 2010-11-10 | 2015-01-28 | エルジー・ケム・リミテッド | 光学素子 |
| EP2527321A1 (de) | 2011-05-27 | 2012-11-28 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Polymerisierbare Verbindungen mit (Meth)Acryloylresten und Sulfonat- oder Sulfatgruppen sowie deren Verwendung |
| DE102011050672B4 (de) | 2011-05-27 | 2020-06-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Kieselsäure(hetero)polykondensate mit (Meth)acrylresten und entweder Sulfonat- oder Sulfatgruppen, für deren Herstellung geeignete Silane sowie Verfahren zum Herstellen der Kondensate und der Silane |
| US9353226B2 (en) | 2011-05-27 | 2016-05-31 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Compounds containing (meth)acrylate groups and sulfonate or sulfate groups, polymers and condensates made therefrom and use of the polymers and condensates |
| EP2578201B1 (de) | 2011-10-06 | 2020-11-25 | Ivoclar Vivadent AG | Dentalmaterialien mit verbesserter Hydrolysestabilität auf der Basis von Phthalsäuremonomeren |
| JPWO2014041940A1 (ja) | 2012-09-14 | 2016-08-18 | 富士フイルム株式会社 | 硬化性組成物および画像形成方法 |
| JP6277806B2 (ja) | 2013-06-05 | 2018-02-14 | 株式会社リコー | インク |
| EP3052556B1 (en) | 2013-10-03 | 2021-01-20 | 3M Innovative Properties Company | Ligand-functionalized substrates with enhanced binding capacity |
| WO2016031436A1 (ja) * | 2014-08-28 | 2016-03-03 | 富士フイルム株式会社 | 硬化性組成物、高分子機能性硬化物、高分子機能性膜を備えたスタックもしくは装置、アミド化合物およびその製造方法 |
| WO2017161408A1 (en) * | 2016-03-24 | 2017-09-28 | Sdi Limited | Dental adhesive compositions |
| TWI774748B (zh) * | 2017-04-04 | 2022-08-21 | 日商日本精化股份有限公司 | 含有陰離子性親水基之（甲基）丙烯醯胺化合物及含有該化合物之塗料組成物 |
| JP7309723B2 (ja) * | 2018-01-03 | 2023-07-18 | デンツプライ シロナ インコーポレイテッド | 歯科用組成物 |
| WO2020046654A1 (en) | 2018-08-30 | 2020-03-05 | 3M Innovative Properties Company | (meth)acrylate urethane (urea) phosphonates as adhesion promoters |
| CN110464656B (zh) * | 2019-08-29 | 2022-07-05 | 西安医学院 | 一种补牙用树脂材料及其制备方法 |
| CN113620845B (zh) * | 2021-08-10 | 2023-01-13 | 万华化学集团股份有限公司 | 一种保湿剂及其制备方法 |
| WO2023042716A1 (ja) * | 2021-09-17 | 2023-03-23 | 三井化学株式会社 | （メタ）アクリルアミド化合物の製造方法 |
| KR20240169052A (ko) * | 2022-03-30 | 2024-12-02 | 케이제이 케미칼즈 가부시키가이샤 | 비수용성 다관능 (메트)아크릴아미드 함유의 경화성 조성물 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5821607A (ja) * | 1981-07-30 | 1983-02-08 | Kuraray Co Ltd | 歯科用接着剤 |
| US4539382A (en) * | 1981-07-29 | 1985-09-03 | Kuraray Co., Ltd. | Adhesive composition |
| DD295645A5 (de) * | 1990-07-24 | 1991-11-07 | Friedrich-Schiller-Universitaet Jena,De | Verfahren zur Herstellung Oberflächenversiegelter Dünnfilmbeschichtung |
| US5332429A (en) * | 1991-05-31 | 1994-07-26 | Minnesota Mining And Manufacturing Company | Method for treating fluoroaluminosilicate glass |
| NZ280128A (en) * | 1994-10-07 | 1997-07-27 | Kuraray Co | Antimicrobial adhesive composition for dental use comprising antimicrobial polymerizable monomer |
| WO1997023191A1 (en) * | 1995-12-22 | 1997-07-03 | Tokuyama Corporation | Dental primer composition and polymerization catalyst |
| JP3418778B2 (ja) * | 1997-08-06 | 2003-06-23 | 株式会社トクヤマ | 接着性組成物 |
| US6172131B1 (en) * | 1997-10-16 | 2001-01-09 | Ivoclar Ag | Hydrolysis-stable and polymerizable acrylphosphonic acids |
| JPH11180814A (ja) * | 1997-12-24 | 1999-07-06 | Gc:Kk | 歯質接着剤セット |
| TWI262795B (en) * | 1999-05-31 | 2006-10-01 | Kuraray Co | Adhesive composition and method for producing it |
| JP4675456B2 (ja) * | 1999-05-31 | 2011-04-20 | 株式会社クラレ | 接着性の組成物 |
| US6794467B2 (en) * | 2000-03-27 | 2004-09-21 | Council Of Scientific And Industrial Research | Process for the preparation of polymeric absorbents |
| US6710149B2 (en) * | 2000-04-17 | 2004-03-23 | Ivoclar Vivadent Ag | Hydrolysis-stable and polymerizable acrylophosphonic acid |
| DE10018968C1 (de) * | 2000-04-17 | 2002-01-10 | Ivoclar Vivadent Ag | Hydrolysestabile und polymerisierbare Acrylphosphonsäure |
| EP1169996A1 (de) * | 2000-07-06 | 2002-01-09 | Ernst Mühlbauer Kg | Phosphonsäuren enthaltendes Dentalmaterial |
| US7226960B2 (en) * | 2001-05-10 | 2007-06-05 | Pentron Clinical Technologies, Llc | Self-etching primer adhesive and method of use therefor |
| US6812266B2 (en) * | 2001-08-10 | 2004-11-02 | Dentsply Detrey Gmbh | Hydrolysis stable one-part self-etching, self-priming dental adhesive |
| EP1437999B1 (en) * | 2001-10-26 | 2006-12-20 | DENTSPLY DETREY GmbH | Hydrolysis stable self-etching, self-priming adhesive |
-
2002
- 2002-10-25 EP EP02781286A patent/EP1437999B1/en not_active Expired - Lifetime
- 2002-10-25 DE DE60216951T patent/DE60216951T2/de not_active Expired - Lifetime
- 2002-10-25 JP JP2003537581A patent/JP4664591B2/ja not_active Expired - Fee Related
- 2002-10-25 WO PCT/EP2002/011940 patent/WO2003035013A1/en not_active Ceased
- 2002-10-25 US US10/493,721 patent/US20040266906A1/en not_active Abandoned
-
2008
- 2008-03-20 US US12/077,644 patent/US20080194730A1/en not_active Abandoned
-
2009
- 2009-08-27 US US12/583,860 patent/US20100160485A1/en not_active Abandoned
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