JP2004508445A - ポリ塩化ビニル樹脂及び調製方法及び白化したポリ塩化ビニルフォームの製造におけるその使用 - Google Patents
ポリ塩化ビニル樹脂及び調製方法及び白化したポリ塩化ビニルフォームの製造におけるその使用 Download PDFInfo
- Publication number
- JP2004508445A JP2004508445A JP2002525274A JP2002525274A JP2004508445A JP 2004508445 A JP2004508445 A JP 2004508445A JP 2002525274 A JP2002525274 A JP 2002525274A JP 2002525274 A JP2002525274 A JP 2002525274A JP 2004508445 A JP2004508445 A JP 2004508445A
- Authority
- JP
- Japan
- Prior art keywords
- polyvinyl chloride
- resin
- sodium
- group
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 137
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 135
- 239000011347 resin Substances 0.000 title claims abstract description 131
- 229920005989 resin Polymers 0.000 title claims abstract description 131
- 239000006260 foam Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 22
- 238000002360 preparation method Methods 0.000 title abstract description 3
- 150000003839 salts Chemical class 0.000 claims abstract description 60
- 239000000203 mixture Substances 0.000 claims abstract description 44
- 238000009472 formulation Methods 0.000 claims abstract description 31
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims abstract description 26
- GNBVPFITFYNRCN-UHFFFAOYSA-M sodium thioglycolate Chemical compound [Na+].[O-]C(=O)CS GNBVPFITFYNRCN-UHFFFAOYSA-M 0.000 claims abstract description 19
- 150000003458 sulfonic acid derivatives Chemical class 0.000 claims abstract description 15
- 239000000654 additive Substances 0.000 claims description 65
- 229910052751 metal Inorganic materials 0.000 claims description 62
- 239000002184 metal Substances 0.000 claims description 62
- 229920001944 Plastisol Polymers 0.000 claims description 51
- 239000004999 plastisol Substances 0.000 claims description 51
- 238000002156 mixing Methods 0.000 claims description 31
- 229910052739 hydrogen Inorganic materials 0.000 claims description 28
- 239000001257 hydrogen Substances 0.000 claims description 28
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 28
- 125000000217 alkyl group Chemical group 0.000 claims description 27
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 26
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 26
- 125000000524 functional group Chemical group 0.000 claims description 26
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 26
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 25
- 150000002739 metals Chemical class 0.000 claims description 24
- 229910052708 sodium Inorganic materials 0.000 claims description 17
- 239000011734 sodium Substances 0.000 claims description 17
- 229910052783 alkali metal Inorganic materials 0.000 claims description 16
- 150000001340 alkali metals Chemical class 0.000 claims description 16
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 16
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 16
- 229910052723 transition metal Chemical class 0.000 claims description 16
- 150000003624 transition metals Chemical class 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 12
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 239000004816 latex Substances 0.000 claims description 7
- 229920000126 latex Polymers 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 claims description 5
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- YNJORDSKPXMABC-UHFFFAOYSA-M sodium;2-hydroxypropane-2-sulfonate Chemical compound [Na+].CC(C)(O)S([O-])(=O)=O YNJORDSKPXMABC-UHFFFAOYSA-M 0.000 claims description 4
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims description 4
- 239000011135 tin Substances 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 150000001805 chlorine compounds Chemical group 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 4
- 229920002554 vinyl polymer Polymers 0.000 claims 4
- XLNOKJLJDWVOQP-UHFFFAOYSA-L disodium;formaldehyde;sulfite Chemical compound [Na+].[Na+].O=C.[O-]S([O-])=O XLNOKJLJDWVOQP-UHFFFAOYSA-L 0.000 claims 3
- GHHVCJKIKXZLCO-UHFFFAOYSA-L disodium;methane;sulfite Chemical compound C.[Na+].[Na+].[O-]S([O-])=O GHHVCJKIKXZLCO-UHFFFAOYSA-L 0.000 claims 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 2
- 150000003464 sulfur compounds Chemical class 0.000 abstract description 15
- 150000003452 sulfinic acid derivatives Chemical class 0.000 abstract description 4
- 230000004913 activation Effects 0.000 description 16
- 230000006872 improvement Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 239000004156 Azodicarbonamide Substances 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 3
- 235000019399 azodicarbonamide Nutrition 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- OMVSWZDEEGIJJI-UHFFFAOYSA-N 2,2,4-Trimethyl-1,3-pentadienol diisobutyrate Chemical compound CC(C)C(=O)OC(C(C)C)C(C)(C)COC(=O)C(C)C OMVSWZDEEGIJJI-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- AKUNSTOMHUXJOZ-UHFFFAOYSA-N 1-hydroperoxybutane Chemical compound CCCCOO AKUNSTOMHUXJOZ-UHFFFAOYSA-N 0.000 description 1
- KESQFSZFUCZCEI-UHFFFAOYSA-N 2-(5-nitropyridin-2-yl)oxyethanol Chemical compound OCCOC1=CC=C([N+]([O-])=O)C=N1 KESQFSZFUCZCEI-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- MFMORLFSDLJUDS-UHFFFAOYSA-L disodium formaldehyde hydrogen sulfite Chemical compound [Na+].S([O-])(O)=O.[Na+].C=O.S([O-])(O)=O MFMORLFSDLJUDS-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 235000020046 sherry Nutrition 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- NDZMMDGEFAJSKZ-UHFFFAOYSA-M sodium;acetic acid;sulfanide Chemical compound [Na+].[SH-].CC(O)=O NDZMMDGEFAJSKZ-UHFFFAOYSA-M 0.000 description 1
- KRGHSTOILKFQEJ-UHFFFAOYSA-M sodium;hydrogen sulfite;methane Chemical compound C.[Na+].OS([O-])=O KRGHSTOILKFQEJ-UHFFFAOYSA-M 0.000 description 1
- UOULCEYHQNCFFH-UHFFFAOYSA-M sodium;hydroxymethanesulfonate Chemical compound [Na+].OCS([O-])(=O)=O UOULCEYHQNCFFH-UHFFFAOYSA-M 0.000 description 1
- KKVTYAVXTDIPAP-UHFFFAOYSA-M sodium;methanesulfonate Chemical compound [Na+].CS([O-])(=O)=O KKVTYAVXTDIPAP-UHFFFAOYSA-M 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0033—Use of organic additives containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23065900P | 2000-09-07 | 2000-09-07 | |
| PCT/GB2001/004025 WO2002020660A2 (en) | 2000-09-07 | 2001-09-07 | Polyvinyl chloride resins and method of preparation and use in the production of whitened polyvinyl chloride foam |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004508445A true JP2004508445A (ja) | 2004-03-18 |
| JP2004508445A5 JP2004508445A5 (https=) | 2008-07-17 |
Family
ID=22866088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002525274A Pending JP2004508445A (ja) | 2000-09-07 | 2001-09-07 | ポリ塩化ビニル樹脂及び調製方法及び白化したポリ塩化ビニルフォームの製造におけるその使用 |
Country Status (13)
| Country | Link |
|---|---|
| US (3) | US6500873B2 (https=) |
| EP (1) | EP1315774B1 (https=) |
| JP (1) | JP2004508445A (https=) |
| CN (1) | CN100360606C (https=) |
| AT (1) | ATE350420T1 (https=) |
| AU (1) | AU2001284302A1 (https=) |
| BR (1) | BR0113530A (https=) |
| DE (1) | DE60125787T2 (https=) |
| DK (1) | DK1315774T3 (https=) |
| ES (1) | ES2280394T3 (https=) |
| MX (1) | MXPA03001340A (https=) |
| NO (1) | NO20030698L (https=) |
| WO (1) | WO2002020660A2 (https=) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007294116A (ja) * | 2006-04-21 | 2007-11-08 | Yamaha Motor Co Ltd | 燃料電池システム |
| US20070260006A1 (en) * | 2006-05-03 | 2007-11-08 | Whitson Russell L | Rigid polyvinyl chloride polymer compositions having improved impact properties |
| US7741395B2 (en) * | 2007-08-21 | 2010-06-22 | Eastman Chemical Company | Low volatile organic content viscosity reducer |
| US20090124737A1 (en) * | 2007-11-12 | 2009-05-14 | Eastman Chemical Company | Acrylic plastisol viscosity reducers |
| US20100008553A1 (en) * | 2008-07-08 | 2010-01-14 | Siemens Medical Solutions Usa, Inc. | Structured Medical Data Mapping System |
| EP3201262B1 (en) * | 2014-10-01 | 2021-03-03 | Sika Technology AG | Foamed plasticized pvc article for rock shields |
| KR102349664B1 (ko) * | 2016-12-15 | 2022-01-11 | 가부시키가이샤 리코 | 표면 커버링 형성 방법, 표면 커버링 형성 장치 및 표면 커버링 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4981469A (https=) * | 1972-12-08 | 1974-08-06 | ||
| JPH09100379A (ja) * | 1995-10-05 | 1997-04-15 | Tosoh Corp | ペースト塩化ビニル系樹脂およびその製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2139885B1 (https=) * | 1971-05-29 | 1973-07-13 | Huels Chemische Werke Ag | |
| GB1465912A (en) * | 1973-07-19 | 1977-03-02 | Ici Ltd | Foamable vinyl polymers containing surfactants |
| US3970620A (en) * | 1974-01-28 | 1976-07-20 | Diamond Shamrock Corporation | Polyvinylchloride compositions for frothing |
| US3945955A (en) * | 1974-12-16 | 1976-03-23 | Diamond Shamrock Corporation | Plasticized polyvinyl chloride compositions containing silicone frothing agents |
| US4228245A (en) * | 1979-07-02 | 1980-10-14 | Monsanto Company | Foam rubber polyblend |
| JPS5825369B2 (ja) * | 1979-12-25 | 1983-05-27 | ロンシール工業株式会社 | 連続気泡体の製造方法 |
| US5686025A (en) * | 1996-01-05 | 1997-11-11 | Witco Corporation | Stabilizer and blowing agent useful for rigid foamed PVC |
| DE19823491C2 (de) * | 1998-05-26 | 2001-06-07 | Boehme Chem Fab Kg | Verfahren zur Herstellung von Weich-PVC-Schaumstoffen und danach erhältliche Weich-PVC-Schaumstoffe |
-
2001
- 2001-09-06 US US09/947,662 patent/US6500873B2/en not_active Expired - Fee Related
- 2001-09-07 ES ES01963274T patent/ES2280394T3/es not_active Expired - Lifetime
- 2001-09-07 WO PCT/GB2001/004025 patent/WO2002020660A2/en not_active Ceased
- 2001-09-07 MX MXPA03001340A patent/MXPA03001340A/es active IP Right Grant
- 2001-09-07 EP EP01963274A patent/EP1315774B1/en not_active Expired - Lifetime
- 2001-09-07 BR BR0113530-9A patent/BR0113530A/pt not_active Application Discontinuation
- 2001-09-07 AT AT01963274T patent/ATE350420T1/de not_active IP Right Cessation
- 2001-09-07 CN CNB018152805A patent/CN100360606C/zh not_active Expired - Fee Related
- 2001-09-07 DE DE60125787T patent/DE60125787T2/de not_active Expired - Fee Related
- 2001-09-07 DK DK01963274T patent/DK1315774T3/da active
- 2001-09-07 AU AU2001284302A patent/AU2001284302A1/en not_active Abandoned
- 2001-09-07 JP JP2002525274A patent/JP2004508445A/ja active Pending
-
2003
- 2003-01-21 US US10/281,789 patent/US6608115B2/en not_active Expired - Fee Related
- 2003-01-21 US US10/281,552 patent/US6605649B2/en not_active Expired - Fee Related
- 2003-02-13 NO NO20030698A patent/NO20030698L/no not_active Application Discontinuation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4981469A (https=) * | 1972-12-08 | 1974-08-06 | ||
| JPH09100379A (ja) * | 1995-10-05 | 1997-04-15 | Tosoh Corp | ペースト塩化ビニル系樹脂およびその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| NO20030698D0 (no) | 2003-02-13 |
| CN1452648A (zh) | 2003-10-29 |
| EP1315774A2 (en) | 2003-06-04 |
| DE60125787D1 (de) | 2007-02-15 |
| BR0113530A (pt) | 2003-07-15 |
| US20030100622A1 (en) | 2003-05-29 |
| AU2001284302A1 (en) | 2002-03-22 |
| DK1315774T3 (da) | 2007-05-07 |
| WO2002020660A3 (en) | 2002-07-25 |
| WO2002020660A2 (en) | 2002-03-14 |
| US20030100620A1 (en) | 2003-05-29 |
| US20020056936A1 (en) | 2002-05-16 |
| NO20030698L (no) | 2003-02-13 |
| ATE350420T1 (de) | 2007-01-15 |
| EP1315774B1 (en) | 2007-01-03 |
| US6605649B2 (en) | 2003-08-12 |
| MXPA03001340A (es) | 2003-06-06 |
| US6500873B2 (en) | 2002-12-31 |
| DE60125787T2 (de) | 2007-10-31 |
| ES2280394T3 (es) | 2007-09-16 |
| CN100360606C (zh) | 2008-01-09 |
| US6608115B2 (en) | 2003-08-19 |
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