DE60125787T2 - Pvc-harze und herstellungsverfahren und verwendung in der fertigung geweissten pvc-schaumes - Google Patents
Pvc-harze und herstellungsverfahren und verwendung in der fertigung geweissten pvc-schaumes Download PDFInfo
- Publication number
- DE60125787T2 DE60125787T2 DE60125787T DE60125787T DE60125787T2 DE 60125787 T2 DE60125787 T2 DE 60125787T2 DE 60125787 T DE60125787 T DE 60125787T DE 60125787 T DE60125787 T DE 60125787T DE 60125787 T2 DE60125787 T2 DE 60125787T2
- Authority
- DE
- Germany
- Prior art keywords
- polyvinyl chloride
- dry
- group
- additive
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006260 foam Substances 0.000 title claims abstract description 59
- 239000011347 resin Substances 0.000 title claims description 141
- 229920005989 resin Polymers 0.000 title claims description 141
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 151
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 151
- 150000003839 salts Chemical class 0.000 claims abstract description 71
- 238000000034 method Methods 0.000 claims abstract description 34
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000002360 preparation method Methods 0.000 claims abstract description 21
- GNBVPFITFYNRCN-UHFFFAOYSA-M sodium thioglycolate Chemical compound [Na+].[O-]C(=O)CS GNBVPFITFYNRCN-UHFFFAOYSA-M 0.000 claims abstract description 20
- 150000003452 sulfinic acid derivatives Chemical class 0.000 claims abstract description 13
- 150000003458 sulfonic acid derivatives Chemical class 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims description 82
- 229910052751 metal Inorganic materials 0.000 claims description 67
- 239000002184 metal Substances 0.000 claims description 67
- 239000006185 dispersion Substances 0.000 claims description 60
- 229920001944 Plastisol Polymers 0.000 claims description 58
- 239000004999 plastisol Substances 0.000 claims description 58
- 230000000996 additive effect Effects 0.000 claims description 57
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims description 24
- 239000001257 hydrogen Substances 0.000 claims description 24
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 22
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 22
- 150000002739 metals Chemical class 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 22
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 21
- 125000000524 functional group Chemical group 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 18
- 238000009472 formulation Methods 0.000 claims description 18
- 229910052708 sodium Inorganic materials 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 18
- 229910052783 alkali metal Inorganic materials 0.000 claims description 17
- 150000001340 alkali metals Chemical class 0.000 claims description 17
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 17
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 17
- 229910052723 transition metal Chemical class 0.000 claims description 17
- 150000003624 transition metals Chemical class 0.000 claims description 17
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 8
- 229920000126 latex Polymers 0.000 claims description 8
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 claims description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- 229910002651 NO3 Inorganic materials 0.000 claims description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 7
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 claims description 7
- 239000004816 latex Substances 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- YNJORDSKPXMABC-UHFFFAOYSA-M sodium;2-hydroxypropane-2-sulfonate Chemical compound [Na+].CC(C)(O)S([O-])(=O)=O YNJORDSKPXMABC-UHFFFAOYSA-M 0.000 claims description 7
- KRGHSTOILKFQEJ-UHFFFAOYSA-M sodium;hydrogen sulfite;methane Chemical compound C.[Na+].OS([O-])=O KRGHSTOILKFQEJ-UHFFFAOYSA-M 0.000 claims description 7
- UOULCEYHQNCFFH-UHFFFAOYSA-M sodium;hydroxymethanesulfonate Chemical compound [Na+].OCS([O-])(=O)=O UOULCEYHQNCFFH-UHFFFAOYSA-M 0.000 claims description 7
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 7
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 claims description 7
- 239000011135 tin Substances 0.000 claims description 7
- 229910052718 tin Inorganic materials 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
- KKQDDPHKTJKNOG-UHFFFAOYSA-L [Na+].[Na+].[O-]S[O-].CC1=CC=CC=C1 Chemical compound [Na+].[Na+].[O-]S[O-].CC1=CC=CC=C1 KKQDDPHKTJKNOG-UHFFFAOYSA-L 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 150000001805 chlorine compounds Chemical group 0.000 claims description 2
- -1 sodium ethane sulfoxylate Chemical compound 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical class OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims description 2
- 150000003464 sulfur compounds Chemical class 0.000 abstract description 16
- 239000011342 resin composition Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 230000004913 activation Effects 0.000 description 17
- 239000000463 material Substances 0.000 description 10
- 230000006872 improvement Effects 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- OMVSWZDEEGIJJI-UHFFFAOYSA-N 2,2,4-Trimethyl-1,3-pentadienol diisobutyrate Chemical compound CC(C)C(=O)OC(C(C)C)C(C)(C)COC(=O)C(C)C OMVSWZDEEGIJJI-UHFFFAOYSA-N 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000004156 Azodicarbonamide Substances 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 3
- 235000019399 azodicarbonamide Nutrition 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 150000002431 hydrogen Chemical group 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- KESQFSZFUCZCEI-UHFFFAOYSA-N 2-(5-nitropyridin-2-yl)oxyethanol Chemical compound OCCOC1=CC=C([N+]([O-])=O)C=N1 KESQFSZFUCZCEI-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- KKVTYAVXTDIPAP-UHFFFAOYSA-M sodium;methanesulfonate Chemical compound [Na+].CS([O-])(=O)=O KKVTYAVXTDIPAP-UHFFFAOYSA-M 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0033—Use of organic additives containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23065900P | 2000-09-07 | 2000-09-07 | |
| US230659P | 2000-09-07 | ||
| PCT/GB2001/004025 WO2002020660A2 (en) | 2000-09-07 | 2001-09-07 | Polyvinyl chloride resins and method of preparation and use in the production of whitened polyvinyl chloride foam |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60125787D1 DE60125787D1 (de) | 2007-02-15 |
| DE60125787T2 true DE60125787T2 (de) | 2007-10-31 |
Family
ID=22866088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60125787T Expired - Fee Related DE60125787T2 (de) | 2000-09-07 | 2001-09-07 | Pvc-harze und herstellungsverfahren und verwendung in der fertigung geweissten pvc-schaumes |
Country Status (13)
| Country | Link |
|---|---|
| US (3) | US6500873B2 (https=) |
| EP (1) | EP1315774B1 (https=) |
| JP (1) | JP2004508445A (https=) |
| CN (1) | CN100360606C (https=) |
| AT (1) | ATE350420T1 (https=) |
| AU (1) | AU2001284302A1 (https=) |
| BR (1) | BR0113530A (https=) |
| DE (1) | DE60125787T2 (https=) |
| DK (1) | DK1315774T3 (https=) |
| ES (1) | ES2280394T3 (https=) |
| MX (1) | MXPA03001340A (https=) |
| NO (1) | NO20030698L (https=) |
| WO (1) | WO2002020660A2 (https=) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007294116A (ja) * | 2006-04-21 | 2007-11-08 | Yamaha Motor Co Ltd | 燃料電池システム |
| US20070260006A1 (en) * | 2006-05-03 | 2007-11-08 | Whitson Russell L | Rigid polyvinyl chloride polymer compositions having improved impact properties |
| US7741395B2 (en) * | 2007-08-21 | 2010-06-22 | Eastman Chemical Company | Low volatile organic content viscosity reducer |
| US20090124737A1 (en) * | 2007-11-12 | 2009-05-14 | Eastman Chemical Company | Acrylic plastisol viscosity reducers |
| US20100008553A1 (en) * | 2008-07-08 | 2010-01-14 | Siemens Medical Solutions Usa, Inc. | Structured Medical Data Mapping System |
| EP3201262B1 (en) * | 2014-10-01 | 2021-03-03 | Sika Technology AG | Foamed plasticized pvc article for rock shields |
| KR102349664B1 (ko) * | 2016-12-15 | 2022-01-11 | 가부시키가이샤 리코 | 표면 커버링 형성 방법, 표면 커버링 형성 장치 및 표면 커버링 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2139885B1 (https=) * | 1971-05-29 | 1973-07-13 | Huels Chemische Werke Ag | |
| JPS5135225B2 (https=) * | 1972-12-08 | 1976-10-01 | ||
| GB1465912A (en) * | 1973-07-19 | 1977-03-02 | Ici Ltd | Foamable vinyl polymers containing surfactants |
| US3970620A (en) * | 1974-01-28 | 1976-07-20 | Diamond Shamrock Corporation | Polyvinylchloride compositions for frothing |
| US3945955A (en) * | 1974-12-16 | 1976-03-23 | Diamond Shamrock Corporation | Plasticized polyvinyl chloride compositions containing silicone frothing agents |
| US4228245A (en) * | 1979-07-02 | 1980-10-14 | Monsanto Company | Foam rubber polyblend |
| JPS5825369B2 (ja) * | 1979-12-25 | 1983-05-27 | ロンシール工業株式会社 | 連続気泡体の製造方法 |
| JPH09100379A (ja) * | 1995-10-05 | 1997-04-15 | Tosoh Corp | ペースト塩化ビニル系樹脂およびその製造方法 |
| US5686025A (en) * | 1996-01-05 | 1997-11-11 | Witco Corporation | Stabilizer and blowing agent useful for rigid foamed PVC |
| DE19823491C2 (de) * | 1998-05-26 | 2001-06-07 | Boehme Chem Fab Kg | Verfahren zur Herstellung von Weich-PVC-Schaumstoffen und danach erhältliche Weich-PVC-Schaumstoffe |
-
2001
- 2001-09-06 US US09/947,662 patent/US6500873B2/en not_active Expired - Fee Related
- 2001-09-07 ES ES01963274T patent/ES2280394T3/es not_active Expired - Lifetime
- 2001-09-07 WO PCT/GB2001/004025 patent/WO2002020660A2/en not_active Ceased
- 2001-09-07 MX MXPA03001340A patent/MXPA03001340A/es active IP Right Grant
- 2001-09-07 EP EP01963274A patent/EP1315774B1/en not_active Expired - Lifetime
- 2001-09-07 BR BR0113530-9A patent/BR0113530A/pt not_active Application Discontinuation
- 2001-09-07 AT AT01963274T patent/ATE350420T1/de not_active IP Right Cessation
- 2001-09-07 CN CNB018152805A patent/CN100360606C/zh not_active Expired - Fee Related
- 2001-09-07 DE DE60125787T patent/DE60125787T2/de not_active Expired - Fee Related
- 2001-09-07 DK DK01963274T patent/DK1315774T3/da active
- 2001-09-07 AU AU2001284302A patent/AU2001284302A1/en not_active Abandoned
- 2001-09-07 JP JP2002525274A patent/JP2004508445A/ja active Pending
-
2003
- 2003-01-21 US US10/281,789 patent/US6608115B2/en not_active Expired - Fee Related
- 2003-01-21 US US10/281,552 patent/US6605649B2/en not_active Expired - Fee Related
- 2003-02-13 NO NO20030698A patent/NO20030698L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2004508445A (ja) | 2004-03-18 |
| NO20030698D0 (no) | 2003-02-13 |
| CN1452648A (zh) | 2003-10-29 |
| EP1315774A2 (en) | 2003-06-04 |
| DE60125787D1 (de) | 2007-02-15 |
| BR0113530A (pt) | 2003-07-15 |
| US20030100622A1 (en) | 2003-05-29 |
| AU2001284302A1 (en) | 2002-03-22 |
| DK1315774T3 (da) | 2007-05-07 |
| WO2002020660A3 (en) | 2002-07-25 |
| WO2002020660A2 (en) | 2002-03-14 |
| US20030100620A1 (en) | 2003-05-29 |
| US20020056936A1 (en) | 2002-05-16 |
| NO20030698L (no) | 2003-02-13 |
| ATE350420T1 (de) | 2007-01-15 |
| EP1315774B1 (en) | 2007-01-03 |
| US6605649B2 (en) | 2003-08-12 |
| MXPA03001340A (es) | 2003-06-06 |
| US6500873B2 (en) | 2002-12-31 |
| ES2280394T3 (es) | 2007-09-16 |
| CN100360606C (zh) | 2008-01-09 |
| US6608115B2 (en) | 2003-08-19 |
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