JP2004265685A - リチウムイオン伝導性硫化物ガラス及びガラスセラミックスの製造方法並びに該ガラスセラミックスを用いた全固体型電池 - Google Patents
リチウムイオン伝導性硫化物ガラス及びガラスセラミックスの製造方法並びに該ガラスセラミックスを用いた全固体型電池 Download PDFInfo
- Publication number
- JP2004265685A JP2004265685A JP2003053782A JP2003053782A JP2004265685A JP 2004265685 A JP2004265685 A JP 2004265685A JP 2003053782 A JP2003053782 A JP 2003053782A JP 2003053782 A JP2003053782 A JP 2003053782A JP 2004265685 A JP2004265685 A JP 2004265685A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- ion conductive
- lithium ion
- sulfide glass
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002203 sulfidic glass Substances 0.000 title claims abstract description 56
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 9
- 239000007787 solid Substances 0.000 title description 2
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000013078 crystal Substances 0.000 claims abstract description 23
- 238000003701 mechanical milling Methods 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 19
- 239000000919 ceramic Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 230000009477 glass transition Effects 0.000 claims abstract description 6
- 239000007858 starting material Substances 0.000 claims description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 239000011574 phosphorus Substances 0.000 claims description 11
- 239000007784 solid electrolyte Substances 0.000 claims description 11
- 238000010304 firing Methods 0.000 claims description 9
- 239000011261 inert gas Substances 0.000 claims description 7
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 3
- 229910018091 Li 2 S Inorganic materials 0.000 description 22
- 239000011521 glass Substances 0.000 description 18
- CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000008188 pellet Substances 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910020346 SiS 2 Inorganic materials 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004017 vitrification Methods 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Glass Melting And Manufacturing (AREA)
- Conductive Materials (AREA)
- Secondary Cells (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003053782A JP2004265685A (ja) | 2003-02-28 | 2003-02-28 | リチウムイオン伝導性硫化物ガラス及びガラスセラミックスの製造方法並びに該ガラスセラミックスを用いた全固体型電池 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003053782A JP2004265685A (ja) | 2003-02-28 | 2003-02-28 | リチウムイオン伝導性硫化物ガラス及びガラスセラミックスの製造方法並びに該ガラスセラミックスを用いた全固体型電池 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004265685A true JP2004265685A (ja) | 2004-09-24 |
| JP2004265685A5 JP2004265685A5 (enExample) | 2006-06-15 |
Family
ID=33118288
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003053782A Pending JP2004265685A (ja) | 2003-02-28 | 2003-02-28 | リチウムイオン伝導性硫化物ガラス及びガラスセラミックスの製造方法並びに該ガラスセラミックスを用いた全固体型電池 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2004265685A (enExample) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007015409A1 (ja) * | 2005-08-02 | 2007-02-08 | Idemitsu Kosan Co., Ltd. | 固体電解質シート |
| JP2008103281A (ja) * | 2006-10-20 | 2008-05-01 | Idemitsu Kosan Co Ltd | 固体電解質及びそれを用いた固体二次電池 |
| WO2008072685A1 (ja) | 2006-12-14 | 2008-06-19 | Sumitomo Electric Industries, Ltd. | 電池構造体およびそれを用いたリチウム二次電池 |
| WO2008117549A1 (ja) | 2007-03-23 | 2008-10-02 | Toyota Jidosha Kabushiki Kaisha | 固体電池およびその製造方法 |
| WO2008123394A1 (ja) | 2007-03-23 | 2008-10-16 | Toyota Jidosha Kabushiki Kaisha | 合材層およびその製造方法ならびに固体電池およびその製造方法 |
| JP2009158476A (ja) * | 2007-12-03 | 2009-07-16 | Seiko Epson Corp | 硫化物系リチウムイオン伝導性固体電解質ガラス、全固体リチウム二次電池および全固体リチウム二次電池の製造方法 |
| WO2010004401A1 (en) * | 2008-07-07 | 2010-01-14 | Toyota Jidosha Kabushiki Kaisha | Process for producing sulfide-based solid electrolyte |
| JP2010030889A (ja) * | 2008-07-01 | 2010-02-12 | Idemitsu Kosan Co Ltd | リチウムイオン伝導性硫化物ガラスの製造方法、リチウムイオン伝導性硫化物ガラスセラミックスの製造方法及び硫化物ガラス製造用のメカニカルミリング処理装置 |
| JP2010092828A (ja) * | 2008-09-11 | 2010-04-22 | Toyota Motor Corp | 硫化物系固体電解質 |
| WO2010084583A1 (ja) * | 2009-01-21 | 2010-07-29 | トヨタ自動車株式会社 | 硫化物固体電解質材料 |
| WO2010116732A1 (ja) | 2009-04-10 | 2010-10-14 | 出光興産株式会社 | 固体電解質粒子からなるガラス及びリチウム電池 |
| JP2011129312A (ja) * | 2009-12-16 | 2011-06-30 | Toyota Motor Corp | 硫化物固体電解質材料の製造方法、硫化物固体電解質材料およびリチウム電池 |
| JP2013020894A (ja) * | 2011-07-13 | 2013-01-31 | Toyota Motor Corp | 硫化物固体電解質材料の製造方法 |
| US8637190B2 (en) | 2008-09-19 | 2014-01-28 | Toyota Jidosha Kabushiki Kaisha | Battery unit |
| JP2015195155A (ja) * | 2014-03-19 | 2015-11-05 | 出光興産株式会社 | 固体電解質及び電池 |
| US9356315B2 (en) | 2010-08-26 | 2016-05-31 | Toyota Jidosha Kabushiki Kaisha | Sulfide solid electrolyte material and lithium solid state battery |
| WO2017107397A1 (zh) * | 2015-12-23 | 2017-06-29 | 山东玉皇新能源科技有限公司 | 非晶态硫化物固体电解质的制备 |
-
2003
- 2003-02-28 JP JP2003053782A patent/JP2004265685A/ja active Pending
Cited By (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007015409A1 (ja) * | 2005-08-02 | 2007-02-08 | Idemitsu Kosan Co., Ltd. | 固体電解質シート |
| JP2008103281A (ja) * | 2006-10-20 | 2008-05-01 | Idemitsu Kosan Co Ltd | 固体電解質及びそれを用いた固体二次電池 |
| WO2008072685A1 (ja) | 2006-12-14 | 2008-06-19 | Sumitomo Electric Industries, Ltd. | 電池構造体およびそれを用いたリチウム二次電池 |
| US8021790B2 (en) | 2006-12-14 | 2011-09-20 | Sumitomo Electric Industries, Ltd. | Battery structure and lithium secondary battery using the same |
| US8574766B2 (en) | 2007-03-23 | 2013-11-05 | Toyota Jidosha Kabushiki Kaisha | Composite material layer and method of producing the same, and solid state battery and method of producing the same |
| WO2008117549A1 (ja) | 2007-03-23 | 2008-10-02 | Toyota Jidosha Kabushiki Kaisha | 固体電池およびその製造方法 |
| WO2008123394A1 (ja) | 2007-03-23 | 2008-10-16 | Toyota Jidosha Kabushiki Kaisha | 合材層およびその製造方法ならびに固体電池およびその製造方法 |
| JP2008270137A (ja) * | 2007-03-23 | 2008-11-06 | Toyota Motor Corp | 合材層およびその製造方法ならびに固体電池およびその製造方法 |
| JP2009158476A (ja) * | 2007-12-03 | 2009-07-16 | Seiko Epson Corp | 硫化物系リチウムイオン伝導性固体電解質ガラス、全固体リチウム二次電池および全固体リチウム二次電池の製造方法 |
| JP2010030889A (ja) * | 2008-07-01 | 2010-02-12 | Idemitsu Kosan Co Ltd | リチウムイオン伝導性硫化物ガラスの製造方法、リチウムイオン伝導性硫化物ガラスセラミックスの製造方法及び硫化物ガラス製造用のメカニカルミリング処理装置 |
| KR101498849B1 (ko) * | 2008-07-07 | 2015-03-05 | 도요타지도샤가부시키가이샤 | 황화물계 고체 전해질의 제조 방법 |
| US8556197B2 (en) | 2008-07-07 | 2013-10-15 | Toyota Jidosha Kabushiki Kaisha | Process for producing sulfide-based solid electrolyte |
| WO2010004401A1 (en) * | 2008-07-07 | 2010-01-14 | Toyota Jidosha Kabushiki Kaisha | Process for producing sulfide-based solid electrolyte |
| JP2010092828A (ja) * | 2008-09-11 | 2010-04-22 | Toyota Motor Corp | 硫化物系固体電解質 |
| US8637190B2 (en) | 2008-09-19 | 2014-01-28 | Toyota Jidosha Kabushiki Kaisha | Battery unit |
| JP5110093B2 (ja) * | 2009-01-21 | 2012-12-26 | トヨタ自動車株式会社 | 硫化物固体電解質材料 |
| CN101861673B (zh) * | 2009-01-21 | 2013-06-12 | 丰田自动车株式会社 | 硫化物固体电解质材料 |
| WO2010084583A1 (ja) * | 2009-01-21 | 2010-07-29 | トヨタ自動車株式会社 | 硫化物固体電解質材料 |
| US20110274984A1 (en) * | 2009-01-21 | 2011-11-10 | Toyota Jidosha Kabushiki Kaisha | Sulfide solid electrolyte material |
| CN101861673A (zh) * | 2009-01-21 | 2010-10-13 | 丰田自动车株式会社 | 硫化物固体电解质材料 |
| EP3357875A1 (en) | 2009-04-10 | 2018-08-08 | Idemitsu Kosan Co., Ltd. | Glass comprising solid electrolyte particles and lithium battery |
| US9051201B2 (en) | 2009-04-10 | 2015-06-09 | Idemitsu Kosan Co., Ltd. | Glass comprising solid electrolyte particles and lithium battery |
| WO2010116732A1 (ja) | 2009-04-10 | 2010-10-14 | 出光興産株式会社 | 固体電解質粒子からなるガラス及びリチウム電池 |
| US11431024B2 (en) | 2009-04-10 | 2022-08-30 | Idemitsu Kosan Co., Ltd. | Glass comprising solid electrolyte particles and lithium battery |
| US11075404B2 (en) | 2009-04-10 | 2021-07-27 | Idemitsu Kosan Co., Ltd. | Glass comprising solid electrolyte particles and lithium battery |
| US10008735B2 (en) * | 2009-12-16 | 2018-06-26 | Toyota Jidosha Kabushiki Kaisha | Method of producing a sulfide solid electrolyte material, sulfide solid electrolyte material, and lithium battery |
| CN102696141B (zh) * | 2009-12-16 | 2015-05-13 | 丰田自动车株式会社 | 制造硫化物固体电解质材料的方法、硫化物固体电解质材料和锂电池 |
| JP2011129312A (ja) * | 2009-12-16 | 2011-06-30 | Toyota Motor Corp | 硫化物固体電解質材料の製造方法、硫化物固体電解質材料およびリチウム電池 |
| CN102696141A (zh) * | 2009-12-16 | 2012-09-26 | 丰田自动车株式会社 | 制造硫化物固体电解质材料的方法、硫化物固体电解质材料和锂电池 |
| US10707518B2 (en) | 2009-12-16 | 2020-07-07 | Toyota Jidosha Kabushiki Kaisha | Method of producing a sulfide solid electrolyte material, sulfide solid electrolyte material, and lithium battery |
| US20120301796A1 (en) * | 2009-12-16 | 2012-11-29 | Toyota Jidosha Kabushiki Kaisha | Method of producing a sulfide solid electrolyte material, sulfide solid electrolyte material, and lithium battery |
| US9356315B2 (en) | 2010-08-26 | 2016-05-31 | Toyota Jidosha Kabushiki Kaisha | Sulfide solid electrolyte material and lithium solid state battery |
| US10193185B2 (en) | 2010-08-26 | 2019-01-29 | Toyota Jidosha Kabushiki Kaisha | Sulfide solid electrolyte material and lithium solid state battery |
| JP2013020894A (ja) * | 2011-07-13 | 2013-01-31 | Toyota Motor Corp | 硫化物固体電解質材料の製造方法 |
| JP2015195155A (ja) * | 2014-03-19 | 2015-11-05 | 出光興産株式会社 | 固体電解質及び電池 |
| WO2017107397A1 (zh) * | 2015-12-23 | 2017-06-29 | 山东玉皇新能源科技有限公司 | 非晶态硫化物固体电解质的制备 |
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