JP2001524151A - 化学組成物およびそれより得られるポリマーと高分子物質 - Google Patents
化学組成物およびそれより得られるポリマーと高分子物質Info
- Publication number
- JP2001524151A JP2001524151A JP54801698A JP54801698A JP2001524151A JP 2001524151 A JP2001524151 A JP 2001524151A JP 54801698 A JP54801698 A JP 54801698A JP 54801698 A JP54801698 A JP 54801698A JP 2001524151 A JP2001524151 A JP 2001524151A
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- Prior art keywords
- polymerizable composition
- monomer
- brominated
- refractive index
- alkyl
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F220/343—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate in the form of urethane links
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/38—Esters containing sulfur
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 一般式: (式中、xは1〜4であり、Rは-Hまたは-CH3であり、RAはアルキルである) により表されるアルキル置換臭素化フェノールエステル(メタ)アクリレートモ ノマーと、 高屈折率のコモノマー、 を含む重合性組成物。 2. 前記臭素化モノマーの屈折率が少なくとも約1.50である、請求項1に 記載の重合性組成物。 3. 前記臭素化モノマーの屈折率が少なくとも約1.55である、請求項1に 記載の重合性組成物。 4. 前記臭素化モノマーの融点が約60℃未満である、請求項1に記載の重 合性組成物。 5. 前記臭素化モノマーの融点が約35℃未満である、請求項1に記載の重 合性組成物。 6. 前記臭素化モノマーが室温および周囲圧力において液体である、請求 項目1に記載の重合性組成物。 7. RAが1〜18個の炭素原子を有する直鎖状の或いは分岐したアルキルで ある、請求項1に記載の重合性組成物。 8. 前記臭素化モノマーが、一般式:(式中、Rとxは定義通りであり、R1が約1〜18個の炭素原子を有するアルキルで ある) により表される請求項1に記載の重合性組成物。 9. R1が約3〜4個の炭素原子を有するアルキルである、請求項8に記載の 重合性組成物。 10. xが2である、請求項8に記載の重合性組成物。 11.臭素化モノマーが、一般式: (式中、R1は定義通りである) により表される請求項8に記載の重合性組成物。 12.前記臭素化モノマーが4,6-ジブロモ-2-sec-ブチルフェニルアクリレー トを含む、請求項11に記載の重合性組成物。 13.前記臭素化モノマーが、4,6-ジブロモ-2-tert-ブチルフェニルアクリレ ートを含む、請求項11に記載の重合性組成物。 14.前記臭素化モノマーが、4,6-ジブロモ-2-イソプロピルフェニルアクリ レートを含む、請求項11に記載の重合性組成物。 15.前記臭素化モノマーが、一般式:(式中、Rとxは定義通りであり、R2が約1〜18個の炭素原子を有するアルキルで ある) により表される請求項1に記載の重合性組成物。 16.R2が約1〜12個の炭素原子を有するアルキルである、請求項15に記載の 重合性組成物。 17.xが2である、請求項15に記載の重合性組成物。 18.前記臭素化モノマーが、一般式: (式中、R2は定義通りである) により表される請求項15に記載の重合性組成物。 19.前記臭素化モノマーが一般式: により表される請求項18に記載の重合性組成物。 20.前記臭素化モノマーが一般式: により表される請求項18に記載の重合性組成物。 21.前記高屈折率コモノマーが、少なくとも約1.50の屈折率を有する1種あ るいは複数種のコモノマーを含む、請求項1に記載の重合性組成物。 22.前記高屈折率コモノマーが不飽和芳香族モノマーを含む、請求項21に記 載の重合性組成物。 23.前記高屈折率コモノマーが、メチルスチレンモノマーを含む、請求項21 に記載の重合性組成物。 24.前記高屈折率コモノマーが、芳香族(メタ)アクリレートモノマーを含 む、請求項21に記載の重合性組成物。 25.前記高屈折率コモノマーが、臭素化芳香族(メタ)アクリレートモノマ ーを含む、請求項21に記載の重合性組成物。 26.融点が約30℃未満である請求項1に記載の重合性組成物。 27.室温および常圧において液体である請求項1に記載の重合性組成物。 28.屈折率が少なくとも約1.56である請求項1に記載の重合性組成物。 29.屈折率が少なくとも約1.57である請求項1に記載の重合性組成物。 30.100重量部の重合性組成物に基づいて約5〜50重量部のアルキル置換臭素 化芳香族エステル(メタ)アクリレートモノマーを含む、請求項1に記載の重合 性組成物。 31.約25〜40重量部のアルキル置換臭素化芳香族エステル(メタ)アクリレ ートモノマーと、約45〜70重量部の(メタ)アクリレートモノマーと、約5〜15 重量部のメチルスチレンモノマーとを含む請求項1に記載の重合性組成物。 32.少なくとも1.50の屈折率のアルキル置換臭素化芳香族エステル(メタ) アクリレートモノマーを含む、室温および常圧で液体である重合性組成物。 33.23℃において10,000センチポアズ以下の粘度を有する請求項32に記載の 重合性組成物。 34.一般式: (式中、xは1〜4、Rは-Hまたは-CH3、RAは直鎖または分岐アルキルである) により表されるアルキル置換臭素化芳香族エステル(メタ)アクリレートモノマ ーと、 高屈折率のコモノマー、 を含む構成成分から得られるモノマー単位を含む高分子物質。 35.前記臭素化モノマーの屈折率が少なくとも約1.50である、請求項34に記 載の高分子物質。 36.RAが1〜18個の炭素原子を有する直鎖状の或いは分岐したアルキルであ る、請求項34に記載の高分子物質。 37.前記臭素化モノマーが、一般式: (式中、Rとxが定義の通りでありR1が3〜4個の炭素原子を有するアルキルである ) により表される請求項36に記載の高分子物質。 38.前記臭素化モノマーが、一般式: (式中、Rとxが定義の通りでありR2が1〜12個の炭素原子を有するアルキルであ る) により表される請求項36に記載の高分子物質。 39.前記コモノマーが(メタ)アクリレートモノマーと、臭素化(メタ)ア クリレートモノマーと、メチルスチレンモノマーから構成される群から選択され る1種類あるいは複数種の高屈折率モノマーを含む、請求項36に記載の高分子物 質。 40.屈折率が少なくとも約1.590である、請求項36に記載の高分子物質。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/853,995 | 1997-05-09 | ||
US08/853,995 US6355754B1 (en) | 1997-05-09 | 1997-05-09 | High refractive index chemical composition and polymers and polymeric material derived therefrom |
PCT/US1997/015862 WO1998050442A1 (en) | 1997-05-09 | 1997-09-09 | Chemical composition and polymers and polymeric materials derived therefrom |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2001524151A true JP2001524151A (ja) | 2001-11-27 |
JP2001524151A5 JP2001524151A5 (ja) | 2005-06-16 |
Family
ID=25317470
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP54801698A Ceased JP2001524151A (ja) | 1997-05-09 | 1997-09-09 | 化学組成物およびそれより得られるポリマーと高分子物質 |
Country Status (9)
Country | Link |
---|---|
US (1) | US6355754B1 (ja) |
EP (1) | EP0980398B1 (ja) |
JP (1) | JP2001524151A (ja) |
KR (1) | KR100477187B1 (ja) |
AU (1) | AU727717B2 (ja) |
CA (1) | CA2288065A1 (ja) |
DE (1) | DE69717507T2 (ja) |
ES (1) | ES2185044T3 (ja) |
WO (1) | WO1998050442A1 (ja) |
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JP2007517110A (ja) * | 2003-12-30 | 2007-06-28 | スリーエム イノベイティブ プロパティズ カンパニー | 光学物品用重合性組成物 |
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- 1997-05-09 US US08/853,995 patent/US6355754B1/en not_active Expired - Fee Related
- 1997-09-09 AU AU41847/97A patent/AU727717B2/en not_active Ceased
- 1997-09-09 CA CA002288065A patent/CA2288065A1/en not_active Abandoned
- 1997-09-09 KR KR10-1999-7010291A patent/KR100477187B1/ko not_active IP Right Cessation
- 1997-09-09 DE DE69717507T patent/DE69717507T2/de not_active Expired - Fee Related
- 1997-09-09 JP JP54801698A patent/JP2001524151A/ja not_active Ceased
- 1997-09-09 ES ES97939847T patent/ES2185044T3/es not_active Expired - Lifetime
- 1997-09-09 EP EP97939847A patent/EP0980398B1/en not_active Expired - Lifetime
- 1997-09-09 WO PCT/US1997/015862 patent/WO1998050442A1/en active IP Right Grant
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005030819A1 (ja) * | 2003-09-30 | 2005-04-07 | Mitsubishi Rayon Co., Ltd. | エンジニアリングプラスチック用流動性向上剤およびこれを含有する熱可塑性樹脂組成物ならびにその成形品 |
US8729205B2 (en) | 2003-09-30 | 2014-05-20 | Mitsubishi Rayon Co., Ltd. | Flowability improver for engineering plastics, thermoplastic resin compositions containing the same and molded articles of the compositions |
JP2007517110A (ja) * | 2003-12-30 | 2007-06-28 | スリーエム イノベイティブ プロパティズ カンパニー | 光学物品用重合性組成物 |
Also Published As
Publication number | Publication date |
---|---|
EP0980398B1 (en) | 2002-11-27 |
AU4184797A (en) | 1998-11-27 |
WO1998050442A1 (en) | 1998-11-12 |
KR20010012339A (ko) | 2001-02-15 |
ES2185044T3 (es) | 2003-04-16 |
KR100477187B1 (ko) | 2005-03-18 |
AU727717B2 (en) | 2000-12-21 |
DE69717507T2 (de) | 2003-09-11 |
DE69717507D1 (de) | 2003-01-09 |
US6355754B1 (en) | 2002-03-12 |
CA2288065A1 (en) | 1998-11-12 |
EP0980398A1 (en) | 2000-02-23 |
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