JP2000017041A5 - - Google Patents
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- Publication number
- JP2000017041A5 JP2000017041A5 JP1998190228A JP19022898A JP2000017041A5 JP 2000017041 A5 JP2000017041 A5 JP 2000017041A5 JP 1998190228 A JP1998190228 A JP 1998190228A JP 19022898 A JP19022898 A JP 19022898A JP 2000017041 A5 JP2000017041 A5 JP 2000017041A5
- Authority
- JP
- Japan
- Prior art keywords
- polyurethane
- acid
- molecular weight
- titanium
- thermoplastic polyurethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002635 polyurethane Polymers 0.000 description 17
- 239000004814 polyurethane Substances 0.000 description 17
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 12
- -1 cyclic diol Chemical class 0.000 description 12
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 12
- 210000004177 elastic tissue Anatomy 0.000 description 11
- 150000002009 diols Chemical class 0.000 description 10
- 229920005906 polyester polyol Polymers 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229910052719 titanium Inorganic materials 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 239000004970 Chain extender Substances 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 150000003077 polyols Chemical class 0.000 description 5
- 229910052718 tin Inorganic materials 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- WXUAQHNMJWJLTG-UHFFFAOYSA-N 2-methylbutanedioic acid Chemical compound OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 description 2
- XJMMNTGIMDZPMU-UHFFFAOYSA-N 3-methylglutaric acid Chemical compound OC(=O)CC(C)CC(O)=O XJMMNTGIMDZPMU-UHFFFAOYSA-N 0.000 description 2
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 150000003384 small molecules Chemical class 0.000 description 2
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 1
- JZUMVFMLJGSMRF-UHFFFAOYSA-N 2-Methyladipic acid Chemical compound OC(=O)C(C)CCCC(O)=O JZUMVFMLJGSMRF-UHFFFAOYSA-N 0.000 description 1
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 1
- IHEDBVUTTQXGSJ-UHFFFAOYSA-M 2-[bis(2-oxidoethyl)amino]ethanolate;titanium(4+);hydroxide Chemical compound [OH-].[Ti+4].[O-]CCN(CC[O-])CC[O-] IHEDBVUTTQXGSJ-UHFFFAOYSA-M 0.000 description 1
- KTXWGMUMDPYXNN-UHFFFAOYSA-N 2-ethylhexan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-] KTXWGMUMDPYXNN-UHFFFAOYSA-N 0.000 description 1
- KIBVFIDMXQZCBS-UHFFFAOYSA-N 2-methyloctanedioic acid Chemical compound OC(=O)C(C)CCCCCC(O)=O KIBVFIDMXQZCBS-UHFFFAOYSA-N 0.000 description 1
- HYPIHGLKOQBQNW-UHFFFAOYSA-N 3,7-dimethyldecanedioic acid Chemical compound OC(=O)CCC(C)CCCC(C)CC(O)=O HYPIHGLKOQBQNW-UHFFFAOYSA-N 0.000 description 1
- CPSKVIYXUCHQAR-UHFFFAOYSA-N 3,8-dimethyldecanedioic acid Chemical compound OC(=O)CC(C)CCCCC(C)CC(O)=O CPSKVIYXUCHQAR-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- FCIJNJJXVFLNCL-UHFFFAOYSA-N 4-ethoxybutyl 3-sulfanylpropanoate Chemical class CCOCCCCOC(=O)CCS FCIJNJJXVFLNCL-UHFFFAOYSA-N 0.000 description 1
- GAYWCADKXYCKCG-UHFFFAOYSA-N 5-pyridin-3-yl-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1NC(=S)N=C1C1=CC=CN=C1 GAYWCADKXYCKCG-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 description 1
- XMUZQOKACOLCSS-UHFFFAOYSA-N [2-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CO XMUZQOKACOLCSS-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- VGNJJNFWWIDONZ-UHFFFAOYSA-N acetyl acetate;titanium Chemical compound [Ti].CC(=O)OC(C)=O VGNJJNFWWIDONZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- GDFLGQIOWFLLOC-UHFFFAOYSA-N azane;2-hydroxypropanoic acid;titanium Chemical compound [NH4+].[Ti].CC(O)C([O-])=O GDFLGQIOWFLLOC-UHFFFAOYSA-N 0.000 description 1
- UTTHLMXOSUFZCQ-UHFFFAOYSA-N benzene-1,3-dicarbohydrazide Chemical compound NNC(=O)C1=CC=CC(C(=O)NN)=C1 UTTHLMXOSUFZCQ-UHFFFAOYSA-N 0.000 description 1
- SYEOWUNSTUDKGM-UHFFFAOYSA-N beta-methyladipic acid Natural products OC(=O)CC(C)CCC(O)=O SYEOWUNSTUDKGM-UHFFFAOYSA-N 0.000 description 1
- QPKOBORKPHRBPS-UHFFFAOYSA-N bis(2-hydroxyethyl) terephthalate Chemical compound OCCOC(=O)C1=CC=C(C(=O)OCCO)C=C1 QPKOBORKPHRBPS-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical class CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- PYBNTRWJKQJDRE-UHFFFAOYSA-L dodecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PYBNTRWJKQJDRE-UHFFFAOYSA-L 0.000 description 1
- BEGAGPQQLCVASI-UHFFFAOYSA-N ethyl 2-hydroxypropanoate;titanium Chemical compound [Ti].CCOC(=O)C(C)O BEGAGPQQLCVASI-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- SXCBDZAEHILGLM-UHFFFAOYSA-N heptane-1,7-diol Chemical compound OCCCCCCCO SXCBDZAEHILGLM-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- KQJBQMSCFSJABN-UHFFFAOYSA-N octadecan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-] KQJBQMSCFSJABN-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N tolylenediamine group Chemical group CC1=C(C=C(C=C1)N)N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19022898A JP4132244B2 (ja) | 1998-07-06 | 1998-07-06 | 熱可塑性ポリウレタンからなるポリウレタン弾性繊維およびその製造方法 |
| US09/338,432 US6197915B1 (en) | 1998-07-06 | 1999-06-23 | Thermoplastic polyurethanes, polyurethane elastic fibers therefrom, and method for producing the fibers |
| TW088111058A TWI235163B (en) | 1998-07-06 | 1999-06-30 | Thermoplastic polyurethanes, polyurethane elastic fibers therefrom, and method for producing the fibers |
| DE69903382T DE69903382T2 (de) | 1998-07-06 | 1999-07-05 | Thermoplastische Polyurethane, daraus hergestellte elastische Fasern und Verfahren ihrer Herstellung |
| CA002276895A CA2276895C (en) | 1998-07-06 | 1999-07-05 | Thermoplastic polyurethanes, polyurethane elastic fibers therefrom, and method for producing the fibers |
| KR1019990026805A KR100572093B1 (ko) | 1998-07-06 | 1999-07-05 | 열가소성 폴리우레탄, 이를 함유하는 폴리우레탄 탄성섬유 및 상기 섬유의 제조방법 |
| EP99113515A EP0974608B1 (en) | 1998-07-06 | 1999-07-05 | Thermoplastic polyurethanes, elastic fibers therefrom, and method for producing the fibers |
| CN99108972A CN1129622C (zh) | 1998-07-06 | 1999-07-06 | 热塑性聚氨酯、由其制得的聚氨酯弹性纤维及制造纤维的方法 |
| HK00103396.4A HK1024252B (en) | 1998-07-06 | 2000-06-05 | Thermoplastic polyurethanes, polyurethane elastic fibers therefrom, and method for producing the fibers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19022898A JP4132244B2 (ja) | 1998-07-06 | 1998-07-06 | 熱可塑性ポリウレタンからなるポリウレタン弾性繊維およびその製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007324206A Division JP4481328B2 (ja) | 2007-12-17 | 2007-12-17 | 熱可塑性ポリウレタン |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000017041A JP2000017041A (ja) | 2000-01-18 |
| JP2000017041A5 true JP2000017041A5 (enExample) | 2005-06-16 |
| JP4132244B2 JP4132244B2 (ja) | 2008-08-13 |
Family
ID=16254627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19022898A Expired - Fee Related JP4132244B2 (ja) | 1998-07-06 | 1998-07-06 | 熱可塑性ポリウレタンからなるポリウレタン弾性繊維およびその製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6197915B1 (enExample) |
| EP (1) | EP0974608B1 (enExample) |
| JP (1) | JP4132244B2 (enExample) |
| KR (1) | KR100572093B1 (enExample) |
| CN (1) | CN1129622C (enExample) |
| CA (1) | CA2276895C (enExample) |
| DE (1) | DE69903382T2 (enExample) |
| TW (1) | TWI235163B (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR9805948A (pt) * | 1997-03-13 | 1999-08-31 | Takemoto Oil & Fat Co Ltd | Agente de tratamento de fibras de poliuretano elásticas e fibras de poliuretano elásticas tratadas com o mesmo. |
| EP0972864B1 (en) * | 1998-01-30 | 2004-10-27 | Nisshinbo Industries, Inc. | Process for producing polyurethane elastomer and elastic filament |
| KR100351742B1 (en) * | 2001-10-10 | 2002-09-05 | Hosung Chemax Co Ltd | Molded article comprising thermoplastic polyurethane consisting of ether-containing polyester polyol |
| US6688143B2 (en) * | 2001-12-05 | 2004-02-10 | Milliken & Company | Elastomeric knit fabric with antiflame properties |
| US7202322B2 (en) * | 2002-11-08 | 2007-04-10 | Noveon, Inc. | Heat resistant high moisture vapor transmission thermoplastic polyurethane |
| US20040198944A1 (en) * | 2003-03-04 | 2004-10-07 | Meltzer Donald A. | Thermoplastic polyurethanes |
| CN100381477C (zh) * | 2003-06-30 | 2008-04-16 | 路博润高级材料公司 | 含有混合多醇的熔融纺丝的聚醚tpu纤维和方法 |
| DE10357160A1 (de) * | 2003-12-06 | 2005-07-07 | Bayer Materialscience Ag | Verfahren zur Aufarbeitung von Polymerdispersionen in Polyesterpolyolen |
| US20090177226A1 (en) * | 2005-05-05 | 2009-07-09 | Jon Reinprecht | Bioabsorbable Surgical Compositions |
| US20100016888A1 (en) * | 2005-05-05 | 2010-01-21 | Allison Calabrese | Surgical Gasket |
| US20100100124A1 (en) * | 2005-05-05 | 2010-04-22 | Tyco Healthcare Group Lp | Bioabsorbable surgical composition |
| US8044234B2 (en) * | 2005-05-05 | 2011-10-25 | Tyco Healthcare Group Lp | Bioabsorbable surgical composition |
| US7998466B2 (en) * | 2005-12-06 | 2011-08-16 | Tyco Healthcare Group Lp | Biocompatible tissue sealants and adhesives |
| CA2628579C (en) * | 2005-12-06 | 2014-07-08 | Tyco Healthcare Group Lp | Carbodiimide crosslinking of functionalized polethylene glycols |
| WO2007067624A2 (en) | 2005-12-06 | 2007-06-14 | Tyco Healthcare Group Lp | Bioabsorbable compounds and compositions containing them |
| JP2009518129A (ja) * | 2005-12-06 | 2009-05-07 | タイコ ヘルスケア グループ リミテッド パートナーシップ | 生体吸収性外科用組成物 |
| JP5333911B2 (ja) * | 2005-12-06 | 2013-11-06 | コヴィディエン リミテッド パートナーシップ | 生体適合性外科用組成物 |
| EP1960447A4 (en) * | 2005-12-08 | 2010-12-01 | Tyco Healthcare | BIOCOMPATIBLE SURGICAL COMPOSITIONS |
| AU2006321856B2 (en) * | 2005-12-08 | 2013-01-31 | Covidien Lp | Biocompatible surgical compositions |
| EP1966311A4 (en) * | 2005-12-08 | 2012-08-15 | Tyco Healthcare | SPRAY COMPOSITIONS WITH REDUCED VISCOSITY |
| US7981509B2 (en) * | 2006-02-13 | 2011-07-19 | Donaldson Company, Inc. | Polymer blend, polymer solution composition and fibers spun from the polymer blend and filtration applications thereof |
| JP2008144031A (ja) * | 2006-12-11 | 2008-06-26 | Okada Engineering:Kk | 熱可塑性ポリウレタン樹脂の製造方法及びこの製造方法によって得られた熱可塑性ポリウレタン樹脂 |
| US20100113634A1 (en) * | 2007-02-27 | 2010-05-06 | Katsumi Tokumoto | Catalyst composition for production of flexible polyurethane foam |
| US8877865B2 (en) * | 2009-03-30 | 2014-11-04 | Kuraray Co., Ltd. | Resin composition and multilayered structure |
| BRPI1015425B1 (pt) * | 2009-06-25 | 2020-10-27 | Lubrizol Advanced Materials, Inc. | fibra elástica fiada por fusão feita a partir de poliuretano termoplástico reticulado, tecido, artigo de vestuário, e, processo para produzir uma fibra elástica |
| AU2011267846B2 (en) * | 2010-06-15 | 2017-03-02 | Lubrizol Advanced Materials, Inc. | Melt spun elastic fibers having flat modulus |
| JP5895312B2 (ja) * | 2011-05-27 | 2016-03-30 | 東レ・オペロンテックス株式会社 | 弾性布帛 |
| KR101943102B1 (ko) * | 2011-12-21 | 2019-01-29 | 현대모비스 주식회사 | 에어백 쿠션용 우레탄 원단 및 그 제조방법 |
| JP2014136849A (ja) * | 2013-01-18 | 2014-07-28 | Toray Opelontex Co Ltd | ポリウレタン繊維 |
| KR101599399B1 (ko) | 2015-02-23 | 2016-03-03 | (주)두올상사 | 친환경 폴리우레탄 스킨 원단 및 그 제조방법 |
| JP2018528318A (ja) * | 2015-09-24 | 2018-09-27 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 熱可塑性ポリウレタン |
| CN105399920B (zh) * | 2015-11-16 | 2017-11-24 | 四川大学 | 一种基于rim技术制备的水可溶、可纺聚氨酯弹性体 |
| CN105520204B (zh) * | 2015-12-25 | 2017-07-14 | 广东宏杰内衣实业有限公司 | 一种高弹无缝接骨文胸 |
| TWI758322B (zh) | 2016-09-09 | 2022-03-21 | 德商科思創德意志股份有限公司 | 以熱塑性聚胺甲酸酯為主之熔紡複絲、其製造及用途 |
| JP6724743B2 (ja) * | 2016-11-21 | 2020-07-15 | ブリヂストンスポーツ株式会社 | ゴルフボール用塗料組成物 |
| US11148009B2 (en) | 2016-11-21 | 2021-10-19 | Bridgestone Sports Co., Ltd. | Golf ball paint composition |
| CN106592010B (zh) * | 2016-12-16 | 2018-09-21 | 浙江华峰氨纶股份有限公司 | 一种聚氨酯弹性纤维的制备方法及其应用 |
| CN107557903A (zh) * | 2017-08-25 | 2018-01-09 | 浩沙实业（福建）有限公司 | 一种泳衣用耐寒聚氨酯纤维材料 |
| CN108277551A (zh) * | 2017-12-21 | 2018-07-13 | 苏州浩洋聚氨酯科技有限公司 | 一种聚氨酯复合纤维 |
| WO2019213932A1 (en) * | 2018-05-11 | 2019-11-14 | Covestro Deutschland Ag | Thermoplastic polyurethane composition and use thereof |
| CN111118731B (zh) * | 2019-08-26 | 2021-07-13 | 江苏大毛牛新材料有限公司 | 一种高含棉量高弹性布料 |
| CN111499826B (zh) * | 2020-04-08 | 2022-06-17 | 上海抚佳精细化工有限公司 | 一种热塑性聚氨酯弹性体及其制备方法 |
| JP7537068B2 (ja) * | 2020-07-28 | 2024-08-21 | クラレプラスチックス株式会社 | 可撓性ホース |
| TWI785500B (zh) * | 2021-02-18 | 2022-12-01 | 南亞塑膠工業股份有限公司 | 熱塑性聚氨酯彈性纖維與製造方法及包含其之織物 |
| TW202515938A (zh) * | 2023-09-22 | 2025-04-16 | 日商可樂麗股份有限公司 | 熱塑性聚胺基甲酸酯 |
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| US4182898A (en) * | 1978-01-20 | 1980-01-08 | Anderson Development Company | Stable and storable polyester-polyether co-prepolymers |
| JPS59179513A (ja) * | 1983-03-29 | 1984-10-12 | Asahi Chem Ind Co Ltd | 新規なポリエステルポリエ−テル系線状ブロツクポリウレタンの製造法 |
| DE3628141A1 (de) * | 1986-08-19 | 1988-02-25 | Bayer Ag | Lineare polyurethan-elastomere und verfahren zu ihrer herstellung |
| US5118780A (en) | 1989-05-12 | 1992-06-02 | Kuraray Co., Ltd. | Polyester urethane fiber: polyester made from methyl pentane diol |
| DE4414327A1 (de) | 1994-04-25 | 1995-10-26 | Bayer Ag | Verfahren zur Herstellung von Elastanfäden |
| DE19504671C1 (de) | 1995-02-13 | 1996-06-05 | Fischer Karl Ind Gmbh | Verfahren und Vorrichtung zum Schmelzspinnen von Polyurethan und/oder Polyurethanharnstoff und danach erhaltene Fäden |
| US5780573A (en) * | 1995-06-13 | 1998-07-14 | Kuraray Co., Ltd. | Thermoplastic polyurethanes and molded articles comprising them |
| JP3410581B2 (ja) * | 1995-06-13 | 2003-05-26 | 株式会社クラレ | ポリウレタンおよびそれからなる成形品 |
| US5840233A (en) * | 1997-09-16 | 1998-11-24 | Optimer, Inc. | Process of making melt-spun elastomeric fibers |
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1998
- 1998-07-06 JP JP19022898A patent/JP4132244B2/ja not_active Expired - Fee Related
-
1999
- 1999-06-23 US US09/338,432 patent/US6197915B1/en not_active Expired - Lifetime
- 1999-06-30 TW TW088111058A patent/TWI235163B/zh not_active IP Right Cessation
- 1999-07-05 KR KR1019990026805A patent/KR100572093B1/ko not_active Expired - Fee Related
- 1999-07-05 CA CA002276895A patent/CA2276895C/en not_active Expired - Fee Related
- 1999-07-05 DE DE69903382T patent/DE69903382T2/de not_active Expired - Lifetime
- 1999-07-05 EP EP99113515A patent/EP0974608B1/en not_active Expired - Lifetime
- 1999-07-06 CN CN99108972A patent/CN1129622C/zh not_active Expired - Fee Related
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