HU209448B - Process for obtaining and purifying the gallium contents of solutions of the bayer process - Google Patents
Process for obtaining and purifying the gallium contents of solutions of the bayer process Download PDFInfo
- Publication number
- HU209448B HU209448B HU882785A HU278588A HU209448B HU 209448 B HU209448 B HU 209448B HU 882785 A HU882785 A HU 882785A HU 278588 A HU278588 A HU 278588A HU 209448 B HU209448 B HU 209448B
- Authority
- HU
- Hungary
- Prior art keywords
- gallium
- solution
- process according
- resin
- organic
- Prior art date
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- 229910052733 gallium Inorganic materials 0.000 title claims description 167
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title claims description 165
- 238000000034 method Methods 0.000 title claims description 57
- 238000004131 Bayer process Methods 0.000 title claims description 5
- 239000000243 solution Substances 0.000 claims description 127
- 229920005989 resin Polymers 0.000 claims description 65
- 239000011347 resin Substances 0.000 claims description 65
- 238000000605 extraction Methods 0.000 claims description 40
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 30
- 238000005406 washing Methods 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 25
- 238000010828 elution Methods 0.000 claims description 25
- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 claims description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 17
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 17
- 238000000746 purification Methods 0.000 claims description 17
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 15
- 230000002378 acidificating effect Effects 0.000 claims description 14
- 239000008346 aqueous phase Substances 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 13
- 239000003960 organic solvent Substances 0.000 claims description 12
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 12
- 239000003463 adsorbent Substances 0.000 claims description 11
- 238000001556 precipitation Methods 0.000 claims description 10
- DNUARHPNFXVKEI-UHFFFAOYSA-K gallium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Ga+3] DNUARHPNFXVKEI-UHFFFAOYSA-K 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000002244 precipitate Substances 0.000 claims description 9
- 239000005725 8-Hydroxyquinoline Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910021513 gallium hydroxide Inorganic materials 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 229960003540 oxyquinoline Drugs 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- 239000003929 acidic solution Substances 0.000 claims description 7
- 238000000638 solvent extraction Methods 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 238000011084 recovery Methods 0.000 claims description 6
- 238000005470 impregnation Methods 0.000 claims description 5
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 5
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 5
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910001218 Gallium arsenide Inorganic materials 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003849 aromatic solvent Substances 0.000 claims description 4
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical group [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 150000002258 gallium Chemical class 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 239000008267 milk Substances 0.000 claims description 3
- 210000004080 milk Anatomy 0.000 claims description 3
- 235000013336 milk Nutrition 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 3
- 230000005526 G1 to G0 transition Effects 0.000 claims description 2
- 230000036571 hydration Effects 0.000 claims description 2
- 238000006703 hydration reaction Methods 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 239000004133 Sodium thiosulphate Substances 0.000 claims 2
- 238000000184 acid digestion Methods 0.000 claims 1
- 238000010908 decantation Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000008151 electrolyte solution Substances 0.000 claims 1
- 239000003791 organic solvent mixture Substances 0.000 claims 1
- 239000012047 saturated solution Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 28
- 239000012074 organic phase Substances 0.000 description 21
- 239000000203 mixture Substances 0.000 description 17
- 239000011701 zinc Substances 0.000 description 15
- 239000012535 impurity Substances 0.000 description 14
- 239000000284 extract Substances 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 229910052742 iron Inorganic materials 0.000 description 11
- YWACCMLWVBYNHR-UHFFFAOYSA-N 7-(5-ethylnonan-2-yl)quinolin-8-ol Chemical compound C1=CC=NC2=C(O)C(C(C)CCC(CC)CCCC)=CC=C21 YWACCMLWVBYNHR-UHFFFAOYSA-N 0.000 description 10
- 238000005868 electrolysis reaction Methods 0.000 description 10
- 229910052725 zinc Inorganic materials 0.000 description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000002609 medium Substances 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 238000000622 liquid--liquid extraction Methods 0.000 description 5
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000008139 complexing agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 3
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 2
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- -1 amide oxime Chemical class 0.000 description 2
- 229910001570 bauxite Inorganic materials 0.000 description 2
- 229920001429 chelating resin Polymers 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 150000004325 8-hydroxyquinolines Chemical group 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229940024548 aluminum oxide Drugs 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- XOYLJNJLGBYDTH-UHFFFAOYSA-M chlorogallium Chemical compound [Ga]Cl XOYLJNJLGBYDTH-UHFFFAOYSA-M 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910000743 fusible alloy Inorganic materials 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- 238000009849 vacuum degassing Methods 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28095—Shape or type of pores, voids, channels, ducts
- B01J20/28097—Shape or type of pores, voids, channels, ducts being coated, filled or plugged with specific compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3206—Organic carriers, supports or substrates
- B01J20/3208—Polymeric carriers, supports or substrates
- B01J20/321—Polymeric carriers, supports or substrates consisting of a polymer obtained by reactions involving only carbon to carbon unsaturated bonds
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
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- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
- B01J20/3253—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising a cyclic structure not containing any of the heteroatoms nitrogen, oxygen or sulfur, e.g. aromatic structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
- B01J20/3255—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising a cyclic structure containing at least one of the heteroatoms nitrogen, oxygen or sulfur, e.g. heterocyclic or heteroaromatic structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3425—Regenerating or reactivating of sorbents or filter aids comprising organic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3475—Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
- B01J2220/58—Use in a single column
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/04—Manganese marine modules
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compounds Of Unknown Constitution (AREA)
- Electrolytic Production Of Metals (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Extraction Or Liquid Replacement (AREA)
- Physical Water Treatments (AREA)
- Soy Sauces And Products Related Thereto (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8708013A FR2616157A1 (fr) | 1987-06-02 | 1987-06-02 | Procede d'extraction et de purification du gallium des liqueurs bayer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| HUT48691A HUT48691A (en) | 1989-06-28 |
| HU209448B true HU209448B (en) | 1994-06-28 |
Family
ID=9351848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU882785A HU209448B (en) | 1987-06-02 | 1988-06-01 | Process for obtaining and purifying the gallium contents of solutions of the bayer process |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5102512A (de) |
| EP (1) | EP0297998B1 (de) |
| JP (1) | JPS644435A (de) |
| CN (1) | CN1015437B (de) |
| AT (1) | ATE62466T1 (de) |
| AU (1) | AU604325B2 (de) |
| BR (1) | BR8802654A (de) |
| CA (1) | CA1337021C (de) |
| DE (1) | DE3862346D1 (de) |
| ES (1) | ES2021870B3 (de) |
| FR (1) | FR2616157A1 (de) |
| GR (1) | GR3001757T3 (de) |
| HU (1) | HU209448B (de) |
| IE (1) | IE61367B1 (de) |
| IN (1) | IN169596B (de) |
| RU (1) | RU1813111C (de) |
| YU (1) | YU46913B (de) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1012812B (zh) * | 1986-01-31 | 1991-06-12 | 三菱化成株式会社 | 镓的回收方法 |
| FR2605646B1 (fr) * | 1986-10-24 | 1989-04-21 | Pechiney Aluminium | Extraction du gallium des liqueurs bayer a l'aide d'une resine adsorbante impregnee |
| DE3814916A1 (de) * | 1988-05-03 | 1989-11-16 | Int Gallium Gmbh | Verfahren zur gewinnung von gallium |
| JPH02310326A (ja) * | 1989-05-23 | 1990-12-26 | Tanaka Kikinzoku Kogyo Kk | 貴金属液中からの金の分離回収法 |
| BE1004149A3 (nl) * | 1990-04-27 | 1992-09-29 | Acec Union Miniere | Extractie van metalen door ionenuitwisseling. |
| US5187967A (en) * | 1991-09-16 | 1993-02-23 | General Electric Company | Laser trimming of forgings |
| NL1015961C2 (nl) * | 2000-08-18 | 2002-02-19 | Akzo Nobel Nv | Toepassing van een adsorbens voor de verwijdering van vloeibare, gasvormige en/of opgeloste bestanddelen uit een processtroom. |
| FR2813615A1 (fr) * | 2000-09-07 | 2002-03-08 | Metaleurop Sa | Procede d'extraction du gallium |
| CN100396804C (zh) * | 2005-12-09 | 2008-06-25 | 韶关市华韦实业有限公司 | 用萃取-电解法从冶炼铅锌矿尾渣中提取金属镓的方法 |
| CN102071328A (zh) * | 2010-12-09 | 2011-05-25 | 中国铝业股份有限公司 | 一种树脂吸附法生产的次品镓的提纯方法 |
| CN102021334A (zh) * | 2010-12-15 | 2011-04-20 | 中国铝业股份有限公司 | 拜耳法种分母液中提取镓和钒的方法 |
| CN103388159B (zh) * | 2012-05-11 | 2016-08-03 | 格林美股份有限公司 | 一种从含氮化镓废弃物中回收镓的方法 |
| JP5992796B2 (ja) * | 2012-10-23 | 2016-09-14 | 田中貴金属工業株式会社 | 貴金属の分離回収方法 |
| CN103833057A (zh) * | 2014-03-24 | 2014-06-04 | 连云港乐园新材料科技有限公司 | 一种高纯氧化铝的生产方法 |
| JP6839694B2 (ja) * | 2018-12-17 | 2021-03-10 | 株式会社デンソー | 酸化ガリウム膜の成膜方法 |
| CN109439899B (zh) * | 2018-12-25 | 2020-06-02 | 广东省稀有金属研究所 | 一种从锌置换渣硫酸浸出液中吸附分离镓的方法 |
| RU2712162C1 (ru) * | 2019-07-12 | 2020-01-24 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Способ получения галлатного раствора |
| CN111778413B (zh) * | 2020-07-03 | 2022-05-20 | 神华准能资源综合开发有限公司 | 一种基于树脂法从粉煤灰中提取镓的方法 |
| WO2022039017A1 (ja) * | 2020-08-20 | 2022-02-24 | 信越化学工業株式会社 | 成膜方法及び原料溶液 |
| CN113003792A (zh) * | 2021-04-17 | 2021-06-22 | 江苏国创新材料研究中心有限公司 | 一种含喹啉酸类高盐有机废水的处理方法 |
| CN114604882A (zh) * | 2022-04-19 | 2022-06-10 | 四川顺应动力电池材料有限公司 | 一种粉煤灰生产氧化铝且辅料循环利用的方法 |
| CN116272877B (zh) * | 2022-09-08 | 2024-08-20 | 中国科学院城市环境研究所 | 一种碳吸附材料及其制备方法和用途 |
| CN117051267B (zh) * | 2023-10-11 | 2023-12-29 | 矿冶科技集团有限公司 | 一种乳状液膜萃取分离镓的方法 |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB991613A (en) * | 1960-11-28 | 1965-05-12 | Asahi Chemical Ind | Process for the recovery of gallium |
| US3637711A (en) * | 1968-03-25 | 1972-01-25 | Ashland Oil Inc | Beta-alkenyl substituted 8-hydroxyquinolines |
| FR2365641A2 (fr) * | 1976-09-27 | 1978-04-21 | Rhone Poulenc Ind | Procede de recuperation du gallium de solutions tres basiques par extraction liquide/liquide |
| IL50120A (en) * | 1976-07-25 | 1981-03-31 | Yeda Res & Dev | Process for the extraction of metal ions from solutions using polymer impregnated with extraction agent |
| US4169130A (en) * | 1977-07-13 | 1979-09-25 | Rhone-Poulenc Industries | Liquid/liquid extraction of gallium values from highly basic aqueous solutions thereof |
| FR2411894A1 (fr) * | 1977-12-15 | 1979-07-13 | Rhone Poulenc Ind | Procede d'extraction du gallium |
| GB2047564B (en) * | 1978-03-27 | 1983-01-26 | Bend Res Inc | Separator membrane and process using such membrane for removing ions from an aqueous solution |
| FR2460276A1 (fr) * | 1979-07-03 | 1981-01-23 | Rhone Poulenc Ind | Procede de traitement de melanges d'oxydes de terres rares et de gallium |
| US4389379A (en) * | 1980-08-15 | 1983-06-21 | Societe Miniere Et Metallurgique De Penarroya | Process for selective liquid-liquid extraction of germanium |
| FR2495601A1 (fr) * | 1980-12-05 | 1982-06-11 | Rhone Poulenc Ind | Procede de purification de solutions de gallium |
| US4297325A (en) * | 1980-12-08 | 1981-10-27 | Filtrol Corporation | Method of producing pseudoboehmite from aluminum salt solutions |
| AU560201B2 (en) * | 1981-09-17 | 1987-04-02 | Sumitomo Chemical Company, Limited | Gallium recovery |
| JPS5858186A (ja) * | 1981-10-03 | 1983-04-06 | Agency Of Ind Science & Technol | 塩化アルミニウム水溶液よりガリウムを分離濃縮する方法 |
| JPS5896831A (ja) * | 1981-12-02 | 1983-06-09 | Sumitomo Chem Co Ltd | ガリウムの回収法 |
| FR2532296B1 (fr) * | 1982-08-26 | 1985-06-07 | Rhone Poulenc Spec Chim | Procede d'extraction du gallium a l'aide d'hydroxyquinoleines substituees et de composes organophosphores |
| FR2532295A1 (fr) * | 1982-08-26 | 1984-03-02 | Rhone Poulenc Spec Chim | Procede d'extraction du gallium a l'aide d'hydroxyquinoleines substituees et de sulfates ou sulfonates substitues |
| JPS5954626A (ja) * | 1982-09-21 | 1984-03-29 | Sumitomo Chem Co Ltd | 希土類元素及びガリウムの分離回収法 |
| JPS59169933A (ja) * | 1983-03-15 | 1984-09-26 | Sumitomo Chem Co Ltd | キレ−ト樹脂を用いるガリウムの回収方法 |
| JPS59205431A (ja) * | 1983-05-09 | 1984-11-21 | Dowa Mining Co Ltd | ＧａおよびＩｎ微量含有物質からのＧａおよびＩｎの回収方法 |
| JPS59208031A (ja) * | 1983-05-11 | 1984-11-26 | Dowa Mining Co Ltd | ＧａおよびＩｎ微量含有物質からの金属ＧａおよびＩｎの分離採取法 |
| JPS59213622A (ja) * | 1983-05-19 | 1984-12-03 | Showa Alum Ind Kk | ガリウムの回収法 |
| JPS6042234A (ja) * | 1983-08-11 | 1985-03-06 | Mitsubishi Chem Ind Ltd | ガリウムの回収法 |
| CH655710A5 (de) * | 1983-11-17 | 1986-05-15 | Sulzer Ag | Verfahren zur fluessig-fluessig-extraktion von gallium aus natriumaluminatloesung mit hilfe eines organischen extraktionsmittels. |
| JPS60166224A (ja) * | 1984-02-03 | 1985-08-29 | Mitsui Alum Kogyo Kk | アルミニウム製錬ダストからのガリウムの回収方法 |
| JPS6114133A (ja) * | 1984-06-29 | 1986-01-22 | Mitsui Alum Kogyo Kk | アルミニウム電解発生ダストからガリウムを回収する方法 |
| JPS6114127A (ja) * | 1984-06-29 | 1986-01-22 | Mitsui Alum Kogyo Kk | アルミニウム電解発生ダストからガリウムを回収する方法 |
| JPS6114129A (ja) * | 1984-06-29 | 1986-01-22 | Mitsui Alum Kogyo Kk | アルミニウム電解発生ダストからガリウムを回収する方法 |
| JPS61111917A (ja) * | 1984-11-01 | 1986-05-30 | Sumitomo Chem Co Ltd | ガリウムの回収方法 |
| DE3508041A1 (de) * | 1985-03-07 | 1986-09-11 | Preussag Ag Metall, 3380 Goslar | Verfahren zur fluessig-fluessig-extraktion von gallium, germanium oder indium aus waessrigen loesungen |
| JPS61286220A (ja) * | 1985-06-10 | 1986-12-16 | Sumitomo Chem Co Ltd | 吸着剤によるガリウム成分の回収方法 |
| JPS62153120A (ja) * | 1985-09-13 | 1987-07-08 | Sumitomo Metal Mining Co Ltd | 三塩化ガリウムの製造方法 |
| US4728505A (en) * | 1985-12-23 | 1988-03-01 | Mitsui Aluminium Co., Ltd. | Process for producing gallium-containing solution from the aluminum smelting dust |
| CN1012812B (zh) * | 1986-01-31 | 1991-06-12 | 三菱化成株式会社 | 镓的回收方法 |
| FR2603034B1 (fr) * | 1986-08-22 | 1990-10-05 | Penarroya Miniere Metall | Procede de recuperation du gallium contenu dans une solution d'aluminate de sodium |
| FR2605646B1 (fr) * | 1986-10-24 | 1989-04-21 | Pechiney Aluminium | Extraction du gallium des liqueurs bayer a l'aide d'une resine adsorbante impregnee |
| DE3814916A1 (de) * | 1988-05-03 | 1989-11-16 | Int Gallium Gmbh | Verfahren zur gewinnung von gallium |
-
1987
- 1987-06-02 FR FR8708013A patent/FR2616157A1/fr active Pending
-
1988
- 1988-05-30 IN IN437/CAL/88A patent/IN169596B/en unknown
- 1988-05-31 CA CA000568190A patent/CA1337021C/fr not_active Expired - Fee Related
- 1988-06-01 YU YU106588A patent/YU46913B/sh unknown
- 1988-06-01 BR BR8802654A patent/BR8802654A/pt not_active IP Right Cessation
- 1988-06-01 IE IE164788A patent/IE61367B1/en not_active IP Right Cessation
- 1988-06-01 RU SU884355838A patent/RU1813111C/ru active
- 1988-06-01 AU AU16967/88A patent/AU604325B2/en not_active Ceased
- 1988-06-01 JP JP63135385A patent/JPS644435A/ja active Pending
- 1988-06-01 AT AT88420176T patent/ATE62466T1/de not_active IP Right Cessation
- 1988-06-01 EP EP88420176A patent/EP0297998B1/de not_active Expired - Lifetime
- 1988-06-01 ES ES88420176T patent/ES2021870B3/es not_active Expired - Lifetime
- 1988-06-01 HU HU882785A patent/HU209448B/hu not_active IP Right Cessation
- 1988-06-01 DE DE8888420176T patent/DE3862346D1/de not_active Expired - Fee Related
- 1988-06-02 CN CN88103282A patent/CN1015437B/zh not_active Expired
-
1990
- 1990-11-30 US US07/620,387 patent/US5102512A/en not_active Expired - Fee Related
-
1991
- 1991-04-11 GR GR91400089T patent/GR3001757T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IN169596B (de) | 1991-11-16 |
| IE61367B1 (en) | 1994-11-02 |
| EP0297998B1 (de) | 1991-04-10 |
| HUT48691A (en) | 1989-06-28 |
| GR3001757T3 (en) | 1992-11-23 |
| CN88103282A (zh) | 1988-12-21 |
| IE881647L (en) | 1988-12-02 |
| ES2021870B3 (es) | 1991-11-16 |
| FR2616157A1 (fr) | 1988-12-09 |
| YU106588A (en) | 1990-04-30 |
| JPS644435A (en) | 1989-01-09 |
| BR8802654A (pt) | 1988-12-27 |
| AU604325B2 (en) | 1990-12-13 |
| ATE62466T1 (de) | 1991-04-15 |
| EP0297998A1 (de) | 1989-01-04 |
| CN1015437B (zh) | 1992-02-12 |
| US5102512A (en) | 1992-04-07 |
| DE3862346D1 (de) | 1991-05-16 |
| AU1696788A (en) | 1988-12-08 |
| YU46913B (sh) | 1994-06-24 |
| RU1813111C (ru) | 1993-04-30 |
| CA1337021C (fr) | 1995-09-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HMM4 | Cancellation of final prot. due to non-payment of fee |