HRP20230132T1 - Metode za obnovljiva goriva - Google Patents

Metode za obnovljiva goriva Download PDF

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Publication number
HRP20230132T1
HRP20230132T1 HRP20230132TT HRP20230132T HRP20230132T1 HR P20230132 T1 HRP20230132 T1 HR P20230132T1 HR P20230132T T HRP20230132T T HR P20230132TT HR P20230132 T HRP20230132 T HR P20230132T HR P20230132 T1 HRP20230132 T1 HR P20230132T1
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HR
Croatia
Prior art keywords
renewable fuel
fuel oil
cellulosic
biomass
separated
Prior art date
Application number
HRP20230132TT
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English (en)
Inventor
Barry A. Freel
Robert G. Graham
Original Assignee
Ensyn Renewables, Inc.
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Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=48570736&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=HRP20230132(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ensyn Renewables, Inc. filed Critical Ensyn Renewables, Inc.
Publication of HRP20230132T1 publication Critical patent/HRP20230132T1/hr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/008—Feed or outlet control devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
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    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
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    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C10G3/55—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
    • C10G3/57—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds according to the fluidised bed technique
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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
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    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
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Claims (12)

1. Metoda pripreme goriva koja sadrži ko-procesiranje u fluidiziranoj jedinici katalitičkog krekiranja (FCC) sirovine naftne frakcije s obnovljivom sirovinom loživog ulja u prisutnosti katalizatora, pri čemu je obnovljivo loživo ulje neobogaćeno obnovljivo loživo ulje nastalo iz mljevene biomase brzom termičkom preradom, pri čemu neobogaćeno obnovljivo loživo ulje ne prolazi nikakvu daljnju prethodnu ili naknadnu preradu uključujući bez hidrodeoksigenacije, bez hidrotretiranja, bez katalitičkog izlaganja ili kontakta, pri čemu obnovljivo loživo ulje uključuje cjelokupnu tekućinu proizvedenu termomehaničkom pretvorbom biomase, pri čemu se neobogaćeno obnovljivo loživo ulje koristi u količini manjoj od 6 tež.%, manjoj od oko 5 tež.% ili manjoj od oko 3 tež. .% u odnosu na ukupnu težinu dovedene sirovine, i pri čemu sirovina naftne frakcije sadrži sirovinu plinskog ulja (GO), sirovinu vakuumskog plinskog ulja (VGO), ili sirovinu teškog plinskog ulja (HGO).
2. Metoda prema zahtjevu 1, naznačena time što je obnovljivo loživo ulje tekućina nastala iz samljevene biomase brzom termičkom preradom, pri čemu je rezultirajuća tekućina najmanje 60 tež.%, najmanje 70 tež.%, najmanje 75 tež.%, 80 tež.% ili najmanje 85 tež.% ukupne težine prerađene biomase.
3. Metoda prema zahtjevu 2, naznačena time što rezultirajuća tekućina čini najmanje 70 tež.%, najmanje 75 tež.%, 80 tež.% ili najmanje 85 tež.% ukupne težine prerađene biomase.
4. Metoda prema zahtjevu 1, naznačena time što obnovljivo loživo ulje ima pH u rasponu od 0.5 do 8.
5. Metoda prema zahtjevu 1, naznačena time što obnovljivo loživo ulje ima sadržaj krutine manji od 5 tež.%.
6. Metoda prema zahtjevu 1, naznačena time što celulozna biomasa sadrži drvo, drvne ostatke, piljevinu, koru od rezanja, prorede, šumske ostatke, bagasu, kukuruzna vlakna, kukuruzne stabljike, prazne grozdove voća (EFB), lišće, lišće palme, lan, slamu, slamu s niskim udjelom pepela, energetske usjeve, palmino ulje, neprehrambene materijale od biomase, ostatke žetve, uvelu vegetaciju, pred-komercijalne prorede i ostatke drveća, jednogodišnje pokrovne usjeve, divlje proso, miskantus, komponente koje sadrže celulozu, celulozne komponente odvojenog dvorišnog otpada, celulozne komponente odvojenog otpada od hrane, celulozne komponente odvojenog krutog komunalnog otpada (MSW), ili njihove kombinacije.
7. Metoda prema zahtjevu 6, naznačena time što celulozna biomasa sadrži koru, prorede, bagasu, kukuruzna vlakna, kukuruzne stabljike, prazne grozdove voća (EFB), lišće, lišće palme, lan, slamu, slamu s niskim udjelom pepela, energetske usjeve, palmino ulje, neprehrambene materijale od biomase, ostatke žetve, uvelu vegetaciju, pred-komercijalne prorede, jednogodišnje pokrovne usjeve, divlje proso, miskantus, komponente koje sadrže celulozu, celulozne komponente odvojenog dvorišnog otpada, celulozne komponente odvojenog otpada od hrane, celulozne komponente odvojenog krutog komunalnog otpada (MSW), ili njihove kombinacije.
8. Metoda prema zahtjevu 6, naznačena time što celulozna biomasa sadrži komadiće kore, prorede, prazne grozdove voća (EFB), lišće, lišće palme, lan, palmino ulje, neprehrambene materijale od biomase, ostatke žetve, uvelu vegetaciju, pred-komercijalne prorede, jednogodišnje pokrovne usjeve, divlje proso, miskantus, komponente koje sadrže celulozu, celulozne komponente odvojenog dvorišnog otpada, celulozne komponente odvojenog otpada od hrane, celulozne komponente odvojenog krutog komunalnog otpada (MSW), ili njihove kombinacije.
9. Metoda prema zahtjevu 1, naznačena time što se sirovina naftne frakcije i sirovina obnovljivog loživog ulja uvode u FCC jedinicu kroz jednu ili više neovisnih ili odvojenih mlaznica za ubrizgavanje.
10. Metoda prema zahtjevu 1, naznačena time što se temperatura miješane zone u FCC jedinici povećava ubrizgavanjem između 0.05 do 15 tež.% obnovljive sirovine za loživo ulje preko sustava uspona za gašenje nizvodno od uvođenja mlaznice za ubrizgavanje frakcije nafte.
11. Metoda prema zahtjevu 1, naznačena time što neobogaćeno obnovljivo loživo ulje ima temperaturu koja ne prelazi 65.5 °C (150 °F) na putu do uvođenja u FCC jedinicu.
12. Metoda prema zahtjevu 1, naznačena time što je količina obnovljivog loživog ulja u rasponu većem od 1% težine i manje od 5% težine.
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