HRP20210156T1 - Postupak za pripremu sredstava za obradu kože koja imaju hidrofobni učinak - Google Patents
Postupak za pripremu sredstava za obradu kože koja imaju hidrofobni učinak Download PDFInfo
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- HRP20210156T1 HRP20210156T1 HRP20210156TT HRP20210156T HRP20210156T1 HR P20210156 T1 HRP20210156 T1 HR P20210156T1 HR P20210156T T HRP20210156T T HR P20210156TT HR P20210156 T HRP20210156 T HR P20210156T HR P20210156 T1 HRP20210156 T1 HR P20210156T1
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- Prior art keywords
- acrylate
- methacrylate
- component
- alcohol
- mixtures
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- 239000010985 leather Substances 0.000 title claims 5
- 230000002209 hydrophobic effect Effects 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 19
- 239000003921 oil Substances 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 7
- 239000011541 reaction mixture Substances 0.000 claims 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 5
- 229940048053 acrylate Drugs 0.000 claims 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 5
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims 5
- 229920006395 saturated elastomer Polymers 0.000 claims 5
- -1 alcohol hydrogenated methacrylate Chemical class 0.000 claims 3
- 238000007334 copolymerization reaction Methods 0.000 claims 3
- 239000006185 dispersion Substances 0.000 claims 3
- 239000002245 particle Substances 0.000 claims 3
- 238000002360 preparation method Methods 0.000 claims 3
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 claims 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims 2
- VEPKQEUBKLEPRA-UHFFFAOYSA-N VX-745 Chemical compound FC1=CC(F)=CC=C1SC1=NN2C=NC(=O)C(C=3C(=CC=CC=3Cl)Cl)=C2C=C1 VEPKQEUBKLEPRA-UHFFFAOYSA-N 0.000 claims 2
- 239000012190 activator Substances 0.000 claims 2
- 239000002585 base Substances 0.000 claims 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims 2
- 239000003995 emulsifying agent Substances 0.000 claims 2
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 239000003760 tallow Substances 0.000 claims 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims 1
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 claims 1
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 claims 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims 1
- 239000005642 Oleic acid Substances 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- 239000012298 atmosphere Substances 0.000 claims 1
- 235000019400 benzoyl peroxide Nutrition 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 239000012986 chain transfer agent Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- OCDWICPYKQMQSQ-UHFFFAOYSA-N docosyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)C(C)=C OCDWICPYKQMQSQ-UHFFFAOYSA-N 0.000 claims 1
- KHAYCTOSKLIHEP-UHFFFAOYSA-N docosyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)C=C KHAYCTOSKLIHEP-UHFFFAOYSA-N 0.000 claims 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- ZNAOFAIBVOMLPV-UHFFFAOYSA-N hexadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(C)=C ZNAOFAIBVOMLPV-UHFFFAOYSA-N 0.000 claims 1
- CFBXDFZIDLWOSO-UHFFFAOYSA-N icosyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCCCOC(=O)C(C)=C CFBXDFZIDLWOSO-UHFFFAOYSA-N 0.000 claims 1
- NGYRYRBDIPYKTL-UHFFFAOYSA-N icosyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCCCOC(=O)C=C NGYRYRBDIPYKTL-UHFFFAOYSA-N 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 claims 1
- 229940065472 octyl acrylate Drugs 0.000 claims 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 claims 1
- 239000012429 reaction media Substances 0.000 claims 1
- 238000005185 salting out Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229940047670 sodium acrylate Drugs 0.000 claims 1
- 230000003068 static effect Effects 0.000 claims 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical class OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
- C08F220/68—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/04—Mineral tanning
- C14C3/06—Mineral tanning using chromium compounds
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/10—Vegetable tanning
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/18—Chemical tanning by organic agents using polycondensation products or precursors thereof
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/08—Chemical tanning by organic agents
- C14C3/22—Chemical tanning by organic agents using polymerisation products
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
- C14C3/28—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/54—Aqueous solutions or dispersions
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (17)
1. Postupak pripreme hidrofobizirajućih pripravaka za obradu kože koji uključuje korake
a) započinjanje radikalne kopolimerizacije
i) najmanje jedne etilenski nezasićene karboksilne kiseline ili njezinih derivata, i
ii) najmanje jednog (met)akrilata primarno zasićenog C8 do C22 alkohola,
b) miješanje reakcijske smjese dobivene nakon koraka a) s vodom,
c) soljenje najmanje nekih karboksilnih skupina reakcijske smjese dobivene nakon koraka b) s bazom, i
d) rezanje reakcijske smjese dobivene nakon koraka c) na prosječnu veličinu čestica od 0,05-10 µm, izmjerenu uređajem tipa LS 230 proizvedenim od tvrtke Beckman Coulter,
pri čemu se korak a) provodi u ulju kao reakcijskom mediju i pri čemu atmosfera u koraku a) sadrži manje od 0,1 volumenskih% oksidirajućeg plina.
2. Postupak u skladu s patentnim zahtjevom 1, naznačen time što se najmanje jedna etilenski nezasićena karboksilna kiselina ili njezini derivati komponente i) odabire iz skupine koja sadrži akrilnu kiselinu, metakrilnu kiselinu, itakonsku kiselinu, fumarnu kiselinu i maleinsku kiselinu i također njihove derivate, poželjno anhidride, poželjnije maleinski anhidrid, i soli alkalijskih metala, poželjno natrijev akrilat i njihove smjese.
3. Postupak u skladu s bilo kojim od patentnih zahtjeva 1 i 2, naznačen time što je najmanje jedan (met)akrilat primarno zasićenog C8 do C22 alkohola komponente ii) odabran iz skupine koja sadrži oktil akrilat, oktil metakrilat, 2-etilheksil akrilat, 2-etilheksil metakrilat, metakrilni ester hidrogeniranog alkohola iz lojne masti, akrilni ester hidrogeniranog alkohola iz lojne masti, stearil metakrilat, stearil akrilat, heksadecil akrilat, heksadecil metakrilat, dodecil akrilat, dodecil metakrilat, eikozanil akrilat, eikozanil metakrilat, dokozanil metakrilat i dokozanil akrilat i njihove smjese, poželjno iz skupine koju čine heksadecil akrilat, stearil metakrilat i njihove smjese.
4. Postupak prema bilo kojem od patentnih zahtjeva 1-3, naznačen time što kopolimerizaciju započinje najmanje jedan aktivator odabran iz skupine koju čine tercijarni butil hidroperoksid, ditercijarni butil peroksid, dibenzoil peroksid, sukcinski peroksid, kumen hidroperoksid, tercijarni butil perbenzoat, 2,2'-azobis(2-metilbutironitril), 2,2'-azobisizobutironitril i njihove smjese, poželjno koju čine ditercijarni butil peroksid, 2,2'-azobis(2-metilbutironitril) i njihove smjese.
5. Postupak prema bilo kojem od patentnih zahtjeva 1-4, naznačen time što se ulje koje se koristi u koraku a) bira iz skupine koja se sastoji od sintetičkih ulja, prirodnih ulja i njihovih smjesa, po mogućnosti od sintetičkih ulja, poželjnije od bijelog ulja.
6. Postupak prema bilo kojem od patentnih zahtjeva 1-5, naznačen time što korak a) koristi najmanje jedno sredstvo za prijenos lanca, poželjno odabrano iz skupine koja se sastoji od alkil merkaptana, tioglikolnih estera, fenola, nezasićenih spojeva, poželjno od oleinske kiseline, nižih alkohola, poželjno n-butanola i tert-butanola, i aldehida.
7. Postupak prema bilo kojem od patentnih zahtjeva 1-6, naznačen time što maseni omjer najmanje jedne etilenski nezasićene karboksilne kiseline ili njezinih derivata komponente i) prema najmanje jednom (met)akrilatu primarnog zasićenog C8 do C22 alkohola komponenti ii) iznosi 1:10-10:1, poželjno 1:7-4:1, poželjnije 1:4-2:1 i najpoželjnije 1:3-1:1.
8. Postupak prema bilo kojem od patentnih zahtjeva 1-7, naznačen time što je rezanje u koraku d) do prosječne veličine čestica od 0,1-8 µm.
9. Postupak prema bilo kojem od patentnih zahtjeva 1-8, naznačen time što se u postupku koriste razne dodane tvari, odabrane iz skupine koja se sastoji od organskih otapala, emulgatora, konzervansa i najmanje još jednog daljnjeg komonomera komponente iii), navedeni daljnji komonomer se koristi u koraku a).
10. Postupak prema bilo kojem od patentnih zahtjeva 1-9, naznačen time što su količine komponenata korištenih u koracima a)-d) postupka, u odnosu na ukupnu suhu količinu reakcijske smjese dobivene nakon koraka d), kako slijedi:
- najmanje jedna etilenski nezasićena karboksilna kiselina ili njezini derivati komponenta i) :
3,0 do 25,0 mas,%, poželjno 5,0 do 20,0 mas,%, poželjnije 5,0 do 10,0 mas,%,
- najmanje jedan (met)akrilat primarnog zasićenog C8 do C22 alkohola komponenta ii):
8,0 do 20,0 mas,%, poželjno 10,0 do 20,0 mas,%, poželjnije 10,0 do 15,0 mas,%,
- najmanje jedan aktivator:
0,12 do 5 mas,%, poželjno 0,35 do 2,0 mas,%, poželjnije 0,42 do 1,0 mas,%,
- najmanje jedno sredstvo za prijenos lanca:
0,02 do 2,0 mas,%, poželjno 0,05 do 1,2 mas,%, poželjnije 0,08 do 1,0 mas,%,
- najmanje jedna baza:
1,8 do 7,0 mas,%, poželjno 2,1 do 6,0 mas,%, poželjnije 3,0 do 4,5 mas,%,
- ulje:
50,0 do 87,0 mas,%, poželjno 60,0 do 82,5 mas,%, poželjnije 63,0 do 81,5 mas,%, i
- razne dodane tvari:
0,0 do 8,0 mas,%, poželjno 0,0 do 5,0 mas,%, poželjnije 0,0 do 2,0 mas,%.
11. Postupak prema bilo kojem od patentnih zahtjeva 1-10, naznačen time što postupak koristi manje od 2 mas.%, poželjno manje od 1 mas.% i poželjnije manje od 0,5 mas.% organskog otapala, u odnosu na ukupnu suhu količinu reakcijske smjese dobivene nakon koraka d).
12. Postupak prema bilo kojem od patentnih zahtjeva 1-11, naznačen time što postupak koristi manje od 2 mas.%, poželjno manje od 1 mas.% i poželjnije manje od 0,5 mas.% emulgatora, u odnosu na ukupnu suhu količinu reakcijske smjese dobivene nakon koraka d).
13. Hidrofobizirajući pripravak za obradu kože, dobiven postupkom prema bilo kojem od patentnih zahtjeva 1-12.
14. Vodena disperzija koja sadrži
- najmanje jedan kopolimer koji se može dobiti započinjanjem radikalne kopolimerizacije najmanje jedne etilenski nezasićene karboksilne kiseline ili njezinih derivata komponente i) s najmanje jednim (met)akrilatom primarno zasićenog C8 do C22 alkohola komponente ii), i
- najmanje jedno ulje,
pri čemu je prosječna veličina čestica disperzije 0,05-10 µm, poželjno 0,1-8 µm.
15. Postupak za štavljenje kože upotrebom hidrofobirajućeg pripravka za obradu kože prema patentnom zahtjevu 13 ili vodene disperzije prema patentnom zahtjevu 14.
16. Koža naznačena time što je dobivena postupkom prema patentnom zahtjevu 15.
17. Koža prema patentnom zahtjevu 16, naznačena time što ima MAESER vrijednost veću od 15 000, poželjno veću od 30 000 i poželjnije veću od 50 000, i/ili statičku apsorpciju vode manju od 35%, poželjno manju od 30%, izmjereno prema ASTM D-2099-70.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16203590.1A EP3336202A1 (de) | 2016-12-13 | 2016-12-13 | Verfahren zur herstellung hydrophobierender lederbehandlungsmittel |
| EP17822564.5A EP3555322B1 (de) | 2016-12-13 | 2017-12-04 | Verfahren zur herstellung hydrophobierender lederbehandlungsmittel |
| PCT/EP2017/081289 WO2018108595A1 (de) | 2016-12-13 | 2017-12-04 | Verfahren zur herstellung hydrophobierender lederbehandlungsmittel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20210156T1 true HRP20210156T1 (hr) | 2021-03-19 |
Family
ID=57777383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20210156TT HRP20210156T1 (hr) | 2016-12-13 | 2021-01-29 | Postupak za pripremu sredstava za obradu kože koja imaju hidrofobni učinak |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US11365456B2 (hr) |
| EP (2) | EP3336202A1 (hr) |
| KR (1) | KR102490984B1 (hr) |
| CN (1) | CN110050076B (hr) |
| AR (1) | AR110350A1 (hr) |
| AU (1) | AU2017375242B2 (hr) |
| BR (1) | BR112019011140B1 (hr) |
| ES (1) | ES2848730T3 (hr) |
| HR (1) | HRP20210156T1 (hr) |
| MX (1) | MX2019006302A (hr) |
| PT (1) | PT3555322T (hr) |
| TW (1) | TWI766910B (hr) |
| WO (1) | WO2018108595A1 (hr) |
| ZA (1) | ZA201903804B (hr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109517103A (zh) * | 2018-10-10 | 2019-03-26 | 许昌鑫瑞德化工科技有限公司 | 一种皮革使用丙烯酸复鞣剂的制备方法 |
| KR102128872B1 (ko) * | 2020-01-09 | 2020-07-08 | (주)수문상사 | 친환경 가죽 및 그 제조 방법 |
| CN116444737B (zh) * | 2023-04-26 | 2023-10-10 | 四川大学 | 阳离子丙烯酸树脂复鞣剂及其制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3231420A (en) * | 1962-07-06 | 1966-01-25 | Rohm & Haas | Process for treating leather and leathers obtained |
| US4077926A (en) * | 1970-11-12 | 1978-03-07 | Rohm And Haas Company | Pressure sensitive adhesive containing polymerized alkoxyalkyl ester of unsaturated carboxylic acid |
| TNSN89128A1 (fr) | 1988-12-02 | 1991-02-04 | Rohn And Haas Company Independance Mall West | Traitement du cuir avec des copolymeres amphiphites choisis |
| US5348807A (en) * | 1991-02-05 | 1994-09-20 | Rohm And Haas Company | Polymeric retan fatliquor for low fogging upholstery leather |
| AU713882B2 (en) | 1995-08-03 | 1999-12-16 | Rohm And Haas Company | Method for waterproofing leather |
| DE19625984C2 (de) | 1996-06-28 | 1999-07-29 | Stockhausen Chem Fab Gmbh | Wäßrige Polymerdispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung in der Lederherstellung |
| DE59906530D1 (de) | 1999-09-18 | 2003-09-11 | Trumpler Gmbh & Co Chem Fab | Lederbehandlungsmittel |
| JP4609608B2 (ja) * | 1999-10-28 | 2011-01-12 | 昭和電工株式会社 | 乳化重合法及び組成物 |
| DE19959949A1 (de) * | 1999-12-13 | 2001-06-21 | Bayer Ag | Hydrophobierung mit carboxylgruppenhaltigen Polysiloxanen |
| BR0300234B8 (pt) * | 2002-03-05 | 2013-02-19 | composiÇço oligomÉrica, mÉtodo para melhorar as propriedades do couro curtido, e, artigo. | |
| DE10250111A1 (de) * | 2002-10-28 | 2004-05-06 | Bayer Ag | Chromfreies, wasserdichtes Leder |
| JP2005272557A (ja) * | 2004-03-24 | 2005-10-06 | Yunimatekku Kk | アクリル系共重合体の製造法 |
| EP2190913B1 (de) | 2007-09-03 | 2015-07-29 | Basf Se | Verfahren zur herstellung von wässrigen formulierungen, wässrige formulierungen und ihre verwendung |
| WO2009030697A1 (de) | 2007-09-04 | 2009-03-12 | Basf Se | Verfahren zur herstellung von leder, dafür geeignete copolymere und weitere verwendungen derselben |
| JP5441376B2 (ja) | 2008-08-01 | 2014-03-12 | 日産自動車株式会社 | 皮革用防汚塗料組成物、並びに、塗装物品およびその製造方法 |
| US8778457B2 (en) | 2010-05-28 | 2014-07-15 | Momentive Performance Materials Gmbh | Hydrophobizing of fibrous materials with polyorganosiloxanes |
| MX2014007301A (es) * | 2011-12-22 | 2014-07-30 | Bayer Ip Gmbh | Dispersiones de copolimeros de poliacrilato bajas en disolvente. |
| JP6161495B2 (ja) | 2013-09-30 | 2017-07-12 | 株式会社志結 | 皮革用コーティング剤 |
| CN103570861A (zh) * | 2013-10-25 | 2014-02-12 | 安徽工贸职业技术学院 | 一种用于防水涂料的乳液及其制备方法 |
| FR3014875B1 (fr) * | 2013-12-17 | 2016-10-21 | Oreal | Dispersion de particules de polymere dans un milieu non aqueux et utilisation en cosmetique |
-
2016
- 2016-12-13 EP EP16203590.1A patent/EP3336202A1/de not_active Withdrawn
-
2017
- 2017-12-04 KR KR1020197016493A patent/KR102490984B1/ko active IP Right Grant
- 2017-12-04 ES ES17822564T patent/ES2848730T3/es active Active
- 2017-12-04 AU AU2017375242A patent/AU2017375242B2/en active Active
- 2017-12-04 CN CN201780076122.0A patent/CN110050076B/zh active Active
- 2017-12-04 PT PT178225645T patent/PT3555322T/pt unknown
- 2017-12-04 MX MX2019006302A patent/MX2019006302A/es unknown
- 2017-12-04 EP EP17822564.5A patent/EP3555322B1/de active Active
- 2017-12-04 BR BR112019011140-9A patent/BR112019011140B1/pt active IP Right Grant
- 2017-12-04 US US16/467,609 patent/US11365456B2/en active Active
- 2017-12-04 WO PCT/EP2017/081289 patent/WO2018108595A1/de unknown
- 2017-12-11 TW TW106143302A patent/TWI766910B/zh active
- 2017-12-12 AR ARP170103472A patent/AR110350A1/es active IP Right Grant
-
2019
- 2019-06-12 ZA ZA2019/03804A patent/ZA201903804B/en unknown
-
2021
- 2021-01-29 HR HRP20210156TT patent/HRP20210156T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018108595A1 (de) | 2018-06-21 |
| CN110050076A (zh) | 2019-07-23 |
| AU2017375242B2 (en) | 2020-06-18 |
| PT3555322T (pt) | 2021-02-04 |
| BR112019011140A2 (pt) | 2019-10-01 |
| CN110050076B (zh) | 2022-10-14 |
| TW201840592A (zh) | 2018-11-16 |
| MX2019006302A (es) | 2019-08-01 |
| US11365456B2 (en) | 2022-06-21 |
| KR20190095282A (ko) | 2019-08-14 |
| ES2848730T3 (es) | 2021-08-11 |
| AU2017375242A1 (en) | 2019-06-27 |
| EP3336202A1 (de) | 2018-06-20 |
| KR102490984B1 (ko) | 2023-01-25 |
| EP3555322B1 (de) | 2020-11-11 |
| AR110350A1 (es) | 2019-03-20 |
| BR112019011140B1 (pt) | 2023-02-14 |
| EP3555322A1 (de) | 2019-10-23 |
| TWI766910B (zh) | 2022-06-11 |
| US20200071779A1 (en) | 2020-03-05 |
| ZA201903804B (en) | 2022-02-23 |
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