GB952477A - Improved process for obtaining ª-ª, ª-ª unsaturated carboxylic esters - Google Patents
Improved process for obtaining ª-ª, ª-ª unsaturated carboxylic estersInfo
- Publication number
- GB952477A GB952477A GB43425/60A GB4342560A GB952477A GB 952477 A GB952477 A GB 952477A GB 43425/60 A GB43425/60 A GB 43425/60A GB 4342560 A GB4342560 A GB 4342560A GB 952477 A GB952477 A GB 952477A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nickel
- methyl
- halide
- unsaturated carboxylic
- carboxylic esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001733 carboxylic acid esters Chemical class 0.000 title abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 5
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 4
- 150000004820 halides Chemical class 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 abstract 1
- 239000007868 Raney catalyst Substances 0.000 abstract 1
- 229910000564 Raney nickel Inorganic materials 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- HXRKEIRKOSVLQO-UHFFFAOYSA-N methyl 5-methylhexa-2,5-dienoate Chemical compound COC(=O)C=CCC(C)=C HXRKEIRKOSVLQO-UHFFFAOYSA-N 0.000 abstract 1
- WLPCOAJZKBINRO-UHFFFAOYSA-N methyl 8,8-dimethylnona-2,5-dienoate Chemical compound CC(CC=CCC=CC(=O)OC)(C)C WLPCOAJZKBINRO-UHFFFAOYSA-N 0.000 abstract 1
- AEKZTVSCWKESCZ-UHFFFAOYSA-N methyl hepta-2,5-dienoate Chemical compound COC(=O)C=CCC=CC AEKZTVSCWKESCZ-UHFFFAOYSA-N 0.000 abstract 1
- ODLGSRPFJDMGNW-UHFFFAOYSA-N methyl hexa-2,5-dienoate Chemical compound COC(=O)C=CCC=C ODLGSRPFJDMGNW-UHFFFAOYSA-N 0.000 abstract 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 abstract 1
- HZPNKQREYVVATQ-UHFFFAOYSA-L nickel(2+);diformate Chemical group [Ni+2].[O-]C=O.[O-]C=O HZPNKQREYVVATQ-UHFFFAOYSA-L 0.000 abstract 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2111259 | 1959-12-18 | ||
| IT1681460 | 1960-09-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB952477A true GB952477A (en) | 1964-03-18 |
Family
ID=26326900
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB43425/60A Expired GB952477A (en) | 1959-12-18 | 1960-12-16 | Improved process for obtaining ª-ª, ª-ª unsaturated carboxylic esters |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3032583A (enrdf_load_stackoverflow) |
| BE (1) | BE598237R (enrdf_load_stackoverflow) |
| DE (1) | DE1274575B (enrdf_load_stackoverflow) |
| DK (1) | DK107804C (enrdf_load_stackoverflow) |
| FR (1) | FR1212892A (enrdf_load_stackoverflow) |
| GB (1) | GB952477A (enrdf_load_stackoverflow) |
| NL (1) | NL124913C (enrdf_load_stackoverflow) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1212892A (fr) * | 1959-12-18 | 1960-03-28 | Montedison Spa | Procédé pour la préparation de dérivés carboxyliques alpha-beta, delta-epsilon-non saturés, et produits obtenus |
| NL126466C (enrdf_load_stackoverflow) * | 1961-06-06 | |||
| US3299111A (en) * | 1963-01-02 | 1967-01-17 | Diamond Alkali Co | Unsaturated acids derived from polyacetylenic compounds |
| DE1280850B (de) * | 1963-07-27 | 1968-10-24 | Hoechst Ag | Verfahren zur Herstellung von Dien-(1, 4)-carbonsaeuren-(1) und deren Estern |
| GB1142750A (en) * | 1966-07-27 | 1969-02-12 | Montedison Spa | Alkyl muconates and maleates |
| IT1142607B (it) * | 1980-12-23 | 1986-10-08 | Donegani Guido Ist | Processo per la preparazione di acidi dienoici |
| NL8103411A (nl) * | 1981-07-17 | 1983-02-16 | Multinorm Bv | Maaier. |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE859617C (de) * | 1937-07-24 | 1952-12-15 | Bayer Ag | Verfahren zur Herstellung von tetracyclischen Derivaten der Sterinreihe |
| DE854948C (de) * | 1939-10-08 | 1952-11-10 | Basf Ag | Verfahren zur Herstellung von Acrylsaeure, ihren Estern und Substitutionserzeugnissen |
| DE868149C (de) * | 1942-08-09 | 1953-02-23 | Basf Ag | Verfahren zur Herstellung von Gemischen aus Carbonsaeureamiden oder -estern |
| DE881650C (de) * | 1943-02-12 | 1953-07-02 | Basf Ag | Verfahren zur Herstellung von Acrylsaeure, ihren Estern und Substitutionserzeugnissen |
| DE944789C (de) * | 1953-11-15 | 1956-06-21 | Basf Ag | Verfahren zur Herstellung von Acrylsaeureestern |
| DE1000806C2 (de) * | 1954-10-26 | 1957-06-19 | Basf Ag | Verfahren zur Herstellung von Acrylsaeure oder deren Derivaten |
| DE1046030B (de) * | 1956-04-18 | 1958-12-11 | Basf Ag | Verfahren zur Herstellung von Acrylsaeureverbindungen |
| FR1212892A (fr) * | 1959-12-18 | 1960-03-28 | Montedison Spa | Procédé pour la préparation de dérivés carboxyliques alpha-beta, delta-epsilon-non saturés, et produits obtenus |
-
1958
- 1958-10-07 FR FR1212892D patent/FR1212892A/fr not_active Expired
-
1960
- 1960-12-02 NL NL258646A patent/NL124913C/xx active
- 1960-12-13 DK DK494860AA patent/DK107804C/da active
- 1960-12-16 BE BE598237A patent/BE598237R/fr active
- 1960-12-16 US US76144A patent/US3032583A/en not_active Expired - Lifetime
- 1960-12-16 DE DEM47421A patent/DE1274575B/de active Pending
- 1960-12-16 GB GB43425/60A patent/GB952477A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL124913C (enrdf_load_stackoverflow) | 1968-09-16 |
| FR1212892A (fr) | 1960-03-28 |
| US3032583A (en) | 1962-05-01 |
| NL258646A (enrdf_load_stackoverflow) | 1964-04-27 |
| DE1274575B (de) | 1968-08-08 |
| DK107804C (da) | 1967-07-10 |
| BE598237R (fr) | 1961-06-16 |
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