GB1467778A - Process for the production of an amino acid - Google Patents

Process for the production of an amino acid

Info

Publication number
GB1467778A
GB1467778A GB1795575A GB1795575A GB1467778A GB 1467778 A GB1467778 A GB 1467778A GB 1795575 A GB1795575 A GB 1795575A GB 1795575 A GB1795575 A GB 1795575A GB 1467778 A GB1467778 A GB 1467778A
Authority
GB
United Kingdom
Prior art keywords
phosphonomethyl
production
amino acid
glycine
pulverulent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1795575A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1467778A publication Critical patent/GB1467778A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
GB1795575A 1974-05-01 1975-04-30 Process for the production of an amino acid Expired GB1467778A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/465,976 US3969398A (en) 1974-05-01 1974-05-01 Process for producing N-phosphonomethyl glycine
KR7500924A KR790000297B1 (en) 1974-05-01 1975-04-30 Process for producing n-phosphono methyl gylcine

Publications (1)

Publication Number Publication Date
GB1467778A true GB1467778A (en) 1977-03-23

Family

ID=26625851

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1795575A Expired GB1467778A (en) 1974-05-01 1975-04-30 Process for the production of an amino acid

Country Status (27)

Country Link
US (1) US3969398A (enExample)
JP (1) JPS5330690B2 (enExample)
KR (1) KR790000297B1 (enExample)
AR (1) AR215840A1 (enExample)
AT (1) AT336637B (enExample)
BE (1) BE828599A (enExample)
BG (1) BG26398A3 (enExample)
BR (1) BR7502651A (enExample)
CA (1) CA1030157A (enExample)
CH (1) CH613210A5 (enExample)
CS (1) CS179938B2 (enExample)
DD (1) DD119241A5 (enExample)
DE (1) DE2519388C3 (enExample)
DK (1) DK138655B (enExample)
EG (1) EG11700A (enExample)
ES (1) ES437154A1 (enExample)
FR (1) FR2269533B1 (enExample)
GB (1) GB1467778A (enExample)
IE (1) IE41118B1 (enExample)
IT (1) IT1037766B (enExample)
MY (1) MY7800280A (enExample)
NL (1) NL161763C (enExample)
PH (1) PH12324A (enExample)
RO (1) RO70907A (enExample)
SE (1) SE427752B (enExample)
YU (1) YU40117B (enExample)
ZA (1) ZA752792B (enExample)

Families Citing this family (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4100275A (en) * 1975-01-27 1978-07-11 Hoffmann-La Roche Inc. Compositions having antibiotic properties
US4127649A (en) * 1975-01-27 1978-11-28 Hoffmann-La Roche Inc. Compositions having antibiotic properties
IL48835A (en) * 1975-01-27 1979-05-31 Sparamedica Ag Amino acyl and peptidyl derivatives of phophonic acids, their preparation and pharmaceutical compositions containingthem
US4134972A (en) * 1976-07-21 1979-01-16 Hoffmann-La Roche Inc. Compositions having antibiotic properties
ES465139A1 (es) * 1976-12-20 1978-10-01 Monsanto Co Un procedimiento para preparar una mono-o disal de n-fosfo- nometilglicina.
HU184168B (en) * 1979-05-11 1984-07-30 Mta Koezponti Kemiai Kutato In Process for producing n-bracket-phosphono-methyl-bracket closed-glycine
US4454043A (en) * 1980-11-17 1984-06-12 Monsanto Company Column switching procedure
IL65187A (en) * 1982-03-08 1985-03-31 Geshuri Lab Ltd N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
US4442041A (en) * 1982-06-30 1984-04-10 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4617415A (en) * 1983-12-02 1986-10-14 Monsanto Company α-Substituted N-phosphonomethyliminodiacetic acid
US4654429A (en) * 1983-12-02 1987-03-31 Monsanto Company Process for the preparation of a glyphosate product
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US5068404A (en) * 1984-12-28 1991-11-26 Monsanto Company Thermal dealkylation of N-alkyl N-phosphonomethylglycine
US5874612A (en) * 1984-12-28 1999-02-23 Baysdon; Sherrol L. Process for the preparation of glyphosate and glyphosate derivatives
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
DE3532344A1 (de) * 1985-09-11 1987-03-19 Hoechst Ag Verfahren zur herstellung von n-phosphonomethylglycin
US4694082A (en) * 1985-09-23 1987-09-15 Monsanto Company Compound 1,4-diisopropyl-2,5-diketopiperazine
US4684483A (en) * 1985-09-23 1987-08-04 Monsanto Company Preparation of N-substituted amino acids
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US4740608A (en) * 1985-10-09 1988-04-26 Monsanto Company (Phosphonomethyl)trifluoromethyl sulfonates
US4853159A (en) * 1987-10-26 1989-08-01 Monsanto Company Process for producing N-phosphonomethylglycine
US4898972A (en) * 1988-09-26 1990-02-06 Monsanto Company Process for producing N-phosphonomethylglycine
US4965403A (en) * 1988-11-07 1990-10-23 Monsanto Company Oxidation/dealkylation process
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5312973A (en) * 1993-03-25 1994-05-17 Finchimica S.P.A. Process for producing n-phosphono-methyl-imino-diacetic acid
GB9410524D0 (en) * 1993-06-21 1994-07-13 Zeneca Ltd Manufacture of n- phosphonomethylglycine and its salts
SI9400449A (en) * 1994-12-20 1996-06-30 Pinus D D Process for preparing N-phosphonomethyl glycin
DE19500121A1 (de) * 1995-01-04 1996-07-11 Bayer Ag Verfahren zur Herstellung von N-Phosphonomethylglycin
TW322481B (enExample) * 1995-03-07 1997-12-11 Sankyo Co
HUP9801378A3 (en) * 1995-03-14 2002-08-28 Monsanto Co Treatment of a formaldehyde-containing waste stream
US6365772B1 (en) * 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
US6054608A (en) 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
EP1062221B1 (en) * 1998-02-12 2006-05-10 Monsanto Technology LLC Process for making glyphosate by oxidizing n-substituted glyphosates
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
BR9908694A (pt) 1998-03-09 2000-11-21 Monsanto Co Misturas para o controle de ervas daninhas em sojas tolerantes ao glifosato
US5942643A (en) * 1998-05-14 1999-08-24 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon
US5962729A (en) * 1998-05-14 1999-10-05 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
BR9912923A (pt) * 1998-08-12 2001-10-09 Monsanto Co Processo contìnuo para preparação de ácido n-(fosfonometil) iminodiacético
BR9907000A (pt) * 1998-09-08 2000-09-26 Hampshire Chemical Corp Sìntese de ácido fosfonometiliminodiacético com efluente reduzido
US6194604B1 (en) 1998-12-10 2001-02-27 Monsanto Company Process for producing phosphorous acid
SK1042002A3 (en) 1999-07-23 2002-07-02 Basf Ag Method of producing glyphosate or a salt thereof
KR20020073147A (ko) 1999-12-21 2002-09-19 몬산토 테크놀로지 엘엘씨 탄소-지지된, 귀금속-함유 촉매의 존재하에 보충적촉진제의 액상 산화 반응에서의 용도
DE10007702A1 (de) * 2000-02-19 2001-08-23 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-(Phosphonomethyl)glycin
US6274760B1 (en) 2000-03-14 2001-08-14 Monsanto Co. Preparation of formylphosphonic acid from tertiary aminomethylphosphonic acid N-oxides
US6376708B1 (en) 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
BR0110907A (pt) * 2000-05-15 2003-03-11 Monsanto Technology Llc Preparação de compostos de ácido iminodiacético provenientes de substratos de monoetanolamina
CN102250141B (zh) * 2000-05-22 2014-10-01 孟山都技术有限责任公司 制备n－(膦酰基甲基)甘氨酸化合物的反应系统
US6927304B2 (en) 2000-05-22 2005-08-09 Monsanto Technology Llc De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
CN100393733C (zh) * 2000-05-22 2008-06-11 孟山都技术有限责任公司 制备n-(膦酰基甲基)甘氨酸化合物的反应系统
US6441223B1 (en) * 2000-11-30 2002-08-27 Monsanto Technology Llc Method of making phosphorus-containing compounds and products thereof
WO2002095373A1 (en) 2001-05-22 2002-11-28 Monsanto Technology Llc Use of infrared spectroscopy for on-line process control and endpoint detection
DE10130136A1 (de) * 2001-06-22 2003-01-02 Basf Ag Verfahren zur Gewinnung von N-Phosphonomethylglycin
CA2463776A1 (en) 2001-10-18 2003-04-24 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
BRPI0307672B1 (pt) * 2002-02-14 2015-12-22 Monsanto Technology Llc processo para a oxidação de aminas terciárias
US6921834B2 (en) * 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
JP4202047B2 (ja) * 2002-05-24 2008-12-24 富士通株式会社 ヘッド位置制御方法及びデイスク記憶装置
AR040319A1 (es) * 2002-06-28 2005-03-23 Monsanto Technology Llc Uso de telurio en catalizadores con contenido de metales nobles y con soporte de carbon para reacciones de oxidacion en fase liquida
BRPI0413586A (pt) * 2003-08-14 2006-10-17 Monsanto Technology Llc catalisadores contendo metal de transição e processo para a preparação dos mesmos e uso como catalisadores de oxidação e de desidrogenação
DK1678188T3 (da) * 2003-09-17 2008-05-13 Monsanto Technology Llc Fremgangsmåde til udvinding af krystallinsk produkt fra oplösning
FR2865468B1 (fr) * 2004-01-22 2006-04-28 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
AU2005235111B2 (en) 2004-03-30 2010-10-28 Monsanto Technology Llc Methods for controlling plant pathogens using N-phosphonomethylglycine
CN100372857C (zh) * 2004-05-12 2008-03-05 江苏好收成韦恩农药化工有限公司 N-膦酰基甲基甘氨酸的生产方法
US7893004B2 (en) * 2004-09-06 2011-02-22 Japan Envirochemicals, Ltd. Oxidation reaction catalyst and process for producing a compound using the same
WO2006031938A2 (en) * 2004-09-15 2006-03-23 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
TW200624151A (en) * 2004-11-12 2006-07-16 Monsanto Technology Llc Recovery of noble metals from aqueous process streams
AR055033A1 (es) * 2005-02-17 2007-08-01 Monsanto Company Llc Catalizadores que contienen metales de transicion y combinaciones de catalizadores que incluyen catalizadores que contienen metales de transicion y procesos para su preparacion y uso como catalizadores de oxidacion
WO2006096617A2 (en) 2005-03-04 2006-09-14 Monsanto Technology Llc Mitigating necrosis in transgenic glyphosate-tolerant cotton plants treated with herbicidal glyphosate formulations
WO2007098432A2 (en) * 2006-02-17 2007-08-30 Monsanto Technology Llc Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts
CN100460408C (zh) * 2007-01-26 2009-02-11 捷马化工股份有限公司 资源再利用的催化氧化制备草甘膦方法
US7771494B2 (en) * 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
CN101337978B (zh) * 2008-05-13 2011-06-29 浙江新安化工集团股份有限公司 一种利用富氧气体催化氧化双甘膦制取草甘膦的方法
CN101481387B (zh) * 2008-11-27 2012-02-01 浙江新安化工集团股份有限公司 一种催化氧化合成草甘膦的制备方法
CN101508701B (zh) * 2008-12-10 2012-09-05 上海泰禾(集团)有限公司 一种活性碳作催化剂氧气氧化双甘膦制备草甘膦的方法
CN104058495B (zh) 2009-05-18 2016-04-20 孟山都技术公司 含水废物流中磷有用成分和盐杂质的回收
CN101781332B (zh) * 2010-03-02 2012-10-24 广西壮族自治区化工研究院 活性炭催化空气氧化双甘膦制备草甘膦的方法
CN102241703B (zh) * 2011-05-07 2014-05-07 安徽国星生物化学有限公司 一种改进的双甘膦制备草甘膦的方法
EP2875036A1 (en) 2012-07-17 2015-05-27 Straitmark Holding AG Method for the synthesis of aminoalkylenephosphonic acid
BR112015000988A2 (pt) 2012-07-17 2017-06-27 Straitmark Holding Ag método para a síntese de ácido n-fosfonometiliminodiacético ou derivados do mesmo
WO2014012988A1 (en) 2012-07-17 2014-01-23 Straitmark Holding Ag Method for the synthesis of n-(phosphonomethyl)glycine
US20150232493A1 (en) 2012-07-17 2015-08-20 Straitmark Holding Ag Method for the synthesis of alpha-aminoalkylenephosphonic acid
IN2015DN01080A (enExample) 2012-07-17 2015-06-26 Straitmark Holding Ag
US11279644B2 (en) 2017-06-26 2022-03-22 Monsanto Technology Llc Phosphorus control for waste streams from glyphosate manufacturing processes
CN115215900A (zh) * 2022-07-01 2022-10-21 安徽东至广信农化有限公司 一种草甘膦的节能生产方法

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DE1217950B (de) * 1965-02-25 1966-06-02 Henkel & Cie Gmbh Verfahren zur Herstellung neuer Perhydrate von Aminoalkylphosphonsaeuren
DE2013371B1 (de) * 1970-03-20 1971-11-04 Joh A , Benckiser GmbH, Chemische Fabrik, 6700 Ludwigshafen Verfahren zur Herstellung von Amino methylenphosphonsauren
US3799758A (en) * 1971-08-09 1974-03-26 Monsanto Co N-phosphonomethyl-glycine phytotoxicant compositions

Also Published As

Publication number Publication date
MY7800280A (en) 1978-12-31
NL7505071A (nl) 1975-11-04
FR2269533A1 (enExample) 1975-11-28
DE2519388C3 (de) 1978-03-09
DK138655C (enExample) 1979-02-26
RO70907A (ro) 1980-04-15
NL161763B (nl) 1979-10-15
AU8070175A (en) 1976-11-04
IE41118B1 (en) 1979-10-24
NL161763C (nl) 1980-03-17
US3969398A (en) 1976-07-13
EG11700A (en) 1977-10-31
BR7502651A (pt) 1976-03-16
IT1037766B (it) 1979-11-20
DD119241A5 (enExample) 1976-04-12
BE828599A (fr) 1975-10-30
DE2519388B2 (de) 1977-07-14
SE427752B (sv) 1983-05-02
FR2269533B1 (enExample) 1978-02-24
AT336637B (de) 1977-05-10
KR790000297B1 (en) 1979-04-23
DE2519388A1 (de) 1975-11-13
CS179938B2 (en) 1977-12-30
ZA752792B (en) 1976-04-28
DK138655B (da) 1978-10-09
JPS5330690B2 (enExample) 1978-08-29
JPS50160222A (enExample) 1975-12-25
ATA333975A (de) 1976-09-15
AR215840A1 (es) 1979-11-15
PH12324A (en) 1979-01-16
DK188175A (enExample) 1975-11-02
CH613210A5 (enExample) 1979-09-14
BG26398A3 (bg) 1979-03-15
IE41118L (en) 1975-11-01
CA1030157A (en) 1978-04-25
YU40117B (en) 1985-08-31
YU111575A (en) 1982-06-30
SE7505040L (sv) 1975-11-03
ES437154A1 (es) 1977-01-16

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
704A Declaration that licence is not available as of right for an excepted use (par. 4a/1977)
PE20 Patent expired after termination of 20 years

Effective date: 19950429