BR7502651A - Processo para producao de n-fosfono-metil-glicina - Google Patents

Processo para producao de n-fosfono-metil-glicina

Info

Publication number
BR7502651A
BR7502651A BR3371/75A BR7503371A BR7502651A BR 7502651 A BR7502651 A BR 7502651A BR 3371/75 A BR3371/75 A BR 3371/75A BR 7503371 A BR7503371 A BR 7503371A BR 7502651 A BR7502651 A BR 7502651A
Authority
BR
Brazil
Prior art keywords
phosphone
glycine
methyl
production
Prior art date
Application number
BR3371/75A
Other languages
English (en)
Inventor
A Hershman
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of BR7502651A publication Critical patent/BR7502651A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
BR3371/75A 1974-05-01 1975-04-30 Processo para producao de n-fosfono-metil-glicina BR7502651A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/465,976 US3969398A (en) 1974-05-01 1974-05-01 Process for producing N-phosphonomethyl glycine
KR7500924A KR790000297B1 (en) 1974-05-01 1975-04-30 Process for producing n-phosphono methyl gylcine

Publications (1)

Publication Number Publication Date
BR7502651A true BR7502651A (pt) 1976-03-16

Family

ID=26625851

Family Applications (1)

Application Number Title Priority Date Filing Date
BR3371/75A BR7502651A (pt) 1974-05-01 1975-04-30 Processo para producao de n-fosfono-metil-glicina

Country Status (27)

Country Link
US (1) US3969398A (pt)
JP (1) JPS5330690B2 (pt)
KR (1) KR790000297B1 (pt)
AR (1) AR215840A1 (pt)
AT (1) AT336637B (pt)
BE (1) BE828599A (pt)
BG (1) BG26398A3 (pt)
BR (1) BR7502651A (pt)
CA (1) CA1030157A (pt)
CH (1) CH613210A5 (pt)
CS (1) CS179938B2 (pt)
DD (1) DD119241A5 (pt)
DE (1) DE2519388C3 (pt)
DK (1) DK138655B (pt)
EG (1) EG11700A (pt)
ES (1) ES437154A1 (pt)
FR (1) FR2269533B1 (pt)
GB (1) GB1467778A (pt)
IE (1) IE41118B1 (pt)
IT (1) IT1037766B (pt)
MY (1) MY7800280A (pt)
NL (1) NL161763C (pt)
PH (1) PH12324A (pt)
RO (1) RO70907A (pt)
SE (1) SE427752B (pt)
YU (1) YU40117B (pt)
ZA (1) ZA752792B (pt)

Families Citing this family (92)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4127649A (en) * 1975-01-27 1978-11-28 Hoffmann-La Roche Inc. Compositions having antibiotic properties
US4100275A (en) * 1975-01-27 1978-07-11 Hoffmann-La Roche Inc. Compositions having antibiotic properties
IL48835A (en) * 1975-01-27 1979-05-31 Sparamedica Ag Amino acyl and peptidyl derivatives of phophonic acids, their preparation and pharmaceutical compositions containingthem
US4134972A (en) * 1976-07-21 1979-01-16 Hoffmann-La Roche Inc. Compositions having antibiotic properties
NL7713959A (nl) * 1976-12-20 1978-06-22 Monsanto Co Werkwijze voor het bereiden van n-fosfono- methylglycinezouten.
HU184168B (en) * 1979-05-11 1984-07-30 Mta Koezponti Kemiai Kutato In Process for producing n-bracket-phosphono-methyl-bracket closed-glycine
US4454043A (en) * 1980-11-17 1984-06-12 Monsanto Company Column switching procedure
IL65187A (en) * 1982-03-08 1985-03-31 Geshuri Lab Ltd N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
US4442041A (en) * 1982-06-30 1984-04-10 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4617415A (en) * 1983-12-02 1986-10-14 Monsanto Company α-Substituted N-phosphonomethyliminodiacetic acid
US4654429A (en) * 1983-12-02 1987-03-31 Monsanto Company Process for the preparation of a glyphosate product
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US5874612A (en) * 1984-12-28 1999-02-23 Baysdon; Sherrol L. Process for the preparation of glyphosate and glyphosate derivatives
US5068404A (en) * 1984-12-28 1991-11-26 Monsanto Company Thermal dealkylation of N-alkyl N-phosphonomethylglycine
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
DE3532344A1 (de) * 1985-09-11 1987-03-19 Hoechst Ag Verfahren zur herstellung von n-phosphonomethylglycin
US4684483A (en) * 1985-09-23 1987-08-04 Monsanto Company Preparation of N-substituted amino acids
US4694082A (en) * 1985-09-23 1987-09-15 Monsanto Company Compound 1,4-diisopropyl-2,5-diketopiperazine
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US4740608A (en) * 1985-10-09 1988-04-26 Monsanto Company (Phosphonomethyl)trifluoromethyl sulfonates
US4853159A (en) * 1987-10-26 1989-08-01 Monsanto Company Process for producing N-phosphonomethylglycine
US4898972A (en) * 1988-09-26 1990-02-06 Monsanto Company Process for producing N-phosphonomethylglycine
US4965403A (en) * 1988-11-07 1990-10-23 Monsanto Company Oxidation/dealkylation process
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5312973A (en) * 1993-03-25 1994-05-17 Finchimica S.P.A. Process for producing n-phosphono-methyl-imino-diacetic acid
GB9410524D0 (en) * 1993-06-21 1994-07-13 Zeneca Ltd Manufacture of n- phosphonomethylglycine and its salts
SI9400449A (en) * 1994-12-20 1996-06-30 Pinus D D Process for preparing N-phosphonomethyl glycin
DE19500121A1 (de) * 1995-01-04 1996-07-11 Bayer Ag Verfahren zur Herstellung von N-Phosphonomethylglycin
TW322481B (pt) * 1995-03-07 1997-12-11 Sankyo Co
JPH10504242A (ja) * 1995-03-14 1998-04-28 モンサント・カンパニー ホルムアルデヒド含有廃棄物流の処理
US6365772B1 (en) 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
US6054608A (en) * 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
CZ164699A3 (cs) * 1998-02-12 1999-12-15 Monsanto Company Způsob přípravy glyfosatu, jeho soli nebo esteru oxidací N-substituovaných glyfosatů a oxidační katalyzátor používaný při provádění tohoto způsobu
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
ATE241274T1 (de) 1998-03-09 2003-06-15 Monsanto Technology Llc Mischungen zur unkrautbekampfung in glyphosat- tolerante sojabohnen
US5942643A (en) * 1998-05-14 1999-08-24 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon
US5962729A (en) * 1998-05-14 1999-10-05 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
CN1319102A (zh) * 1998-08-12 2001-10-24 孟山都公司 制备n－(膦酰甲基)亚氨基二乙酸的连续方法
BR9907000A (pt) * 1998-09-08 2000-09-26 Hampshire Chemical Corp Sìntese de ácido fosfonometiliminodiacético com efluente reduzido
US6194604B1 (en) 1998-12-10 2001-02-27 Monsanto Company Process for producing phosphorous acid
CN1159323C (zh) 1999-07-23 2004-07-28 巴斯福股份公司 草甘膦或其盐的制备方法
CZ20022134A3 (cs) 1999-12-21 2002-10-16 Monsanto Technology Llc Pouľití doplňkového promotoru ve spojení s katalyzátorem, který je nanesen na uhlíku, obsahujícím vzácný kov při oxidačních reakcích prováděných v kapalné fázi
DE10007702A1 (de) * 2000-02-19 2001-08-23 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-(Phosphonomethyl)glycin
US6274760B1 (en) 2000-03-14 2001-08-14 Monsanto Co. Preparation of formylphosphonic acid from tertiary aminomethylphosphonic acid N-oxides
US6376708B1 (en) 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
ES2271022T3 (es) * 2000-05-15 2007-04-16 Monsanto Technology Llc Preparacion de compuestos de acido imnidiacetico a partir de sustratos de monoetanolamina.
BR0111041A (pt) 2000-05-22 2004-06-15 Monsanto Technology Llc Sistemas de reação para produzir compostos de n-(fosfonometil)glicina
CN101311183B (zh) * 2000-05-22 2011-08-31 孟山都技术有限责任公司 制备n-(膦酰基甲基)甘氨酸化合物的反应系统
US6927304B2 (en) 2000-05-22 2005-08-09 Monsanto Technology Llc De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
US6441223B1 (en) 2000-11-30 2002-08-27 Monsanto Technology Llc Method of making phosphorus-containing compounds and products thereof
US6818450B2 (en) 2001-05-22 2004-11-16 Monsanto Technology Llc Use of infrared spectroscopy for on-line process control and endpoint detection
DE10130136A1 (de) * 2001-06-22 2003-01-02 Basf Ag Verfahren zur Gewinnung von N-Phosphonomethylglycin
CA2463776A1 (en) 2001-10-18 2003-04-24 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
MX284594B (es) * 2002-02-14 2011-03-10 Monsanto Technology Llc Catalizador de oxidacion y procedimiento para su preparacion y procedimiento para oxidacion mediante el uso del mismo.
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
US6921834B2 (en) 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
JP4202047B2 (ja) * 2002-05-24 2008-12-24 富士通株式会社 ヘッド位置制御方法及びデイスク記憶装置
AU2003247825B2 (en) * 2002-06-28 2008-04-10 Monsanto Technology Llc Use of tellurium in carbon-supported, noble metal-containing catalysts for liquid phase oxidation reactions
EP2460586A3 (en) 2003-08-14 2012-11-14 Monsanto Technology LLC Process for oxidation of N-(phosphonomethyl)iminodiacetic acid or salt thereof
AR045763A1 (es) * 2003-09-17 2005-11-09 Monsanto Technology Llc Proceso para recuperar un producto de n-(fosfonometil) glicina de una solucion acuosa
FR2865468B1 (fr) * 2004-01-22 2006-04-28 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
NZ550322A (en) 2004-03-30 2012-02-24 Monsanto Technology Llc Methods for controlling plant pathogens using glyphosate
CN100372857C (zh) * 2004-05-12 2008-03-05 江苏好收成韦恩农药化工有限公司 N-膦酰基甲基甘氨酸的生产方法
WO2006028035A1 (ja) * 2004-09-06 2006-03-16 Japan Envirochemicals, Ltd. 酸化反応触媒およびそれを用いた化合物の製法
TW200624171A (en) * 2004-09-15 2006-07-16 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
AR054096A1 (es) * 2004-11-12 2007-06-06 Monsanto Technology Llc Recuperacion de metales nobles de corrientes de proceso acuosas y proceso de preparacion de n-(fosfonometil)-glicina
EP1858642A2 (en) 2005-02-17 2007-11-28 Monsanto Technology, LLC Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
MX344108B (es) 2005-03-04 2016-12-05 Monsanto Technology Llc Mitigacion de la necrosis en plantas de algodon transgenicas tolerantes al glifosato tratadas con formulaciones herbicidas de glifosato.
BRPI0708081A2 (pt) * 2006-02-17 2011-05-17 Monsanto Technology Llc catalisadores contendo metal de transição e processos para a sua preparação e uso como catalisadores de pilha termoelétrica
CN100460408C (zh) * 2007-01-26 2009-02-11 捷马化工股份有限公司 资源再利用的催化氧化制备草甘膦方法
US7771494B2 (en) * 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
CN101337978B (zh) * 2008-05-13 2011-06-29 浙江新安化工集团股份有限公司 一种利用富氧气体催化氧化双甘膦制取草甘膦的方法
CN101481387B (zh) * 2008-11-27 2012-02-01 浙江新安化工集团股份有限公司 一种催化氧化合成草甘膦的制备方法
CN101508701B (zh) * 2008-12-10 2012-09-05 上海泰禾(集团)有限公司 一种活性碳作催化剂氧气氧化双甘膦制备草甘膦的方法
US8669396B2 (en) 2009-05-18 2014-03-11 Monsanto Technology Llc Recovery of phosphorus values and salt impurities from aqueous waste streams
CN101781332B (zh) * 2010-03-02 2012-10-24 广西壮族自治区化工研究院 活性炭催化空气氧化双甘膦制备草甘膦的方法
CN102241703B (zh) * 2011-05-07 2014-05-07 安徽国星生物化学有限公司 一种改进的双甘膦制备草甘膦的方法
EP2875038A1 (en) 2012-07-17 2015-05-27 Straitmark Holding AG Method for the synthesis of n-phosphonomethyliminodiacetic acid
US20150232493A1 (en) 2012-07-17 2015-08-20 Straitmark Holding Ag Method for the synthesis of alpha-aminoalkylenephosphonic acid
US9150599B2 (en) 2012-07-17 2015-10-06 Straitmark Holding Ag Method for the synthesis of N-(phosphonomethyl)glycine
EP2875037B1 (en) 2012-07-17 2016-09-07 Straitmark Holding AG Method for the synthesis of n-(phosphonomethyl)glycine
RU2694047C2 (ru) 2012-07-17 2019-07-09 МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи Способ синтеза аминоалкиленфосфоновой кислоты
WO2019005718A1 (en) 2017-06-26 2019-01-03 Monsanto Technology Llc PHOSPHORUS CONTROL FOR WASTE FLOWS FROM GLYPHOSATE MANUFACTURING PROCESSES

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1217950B (de) * 1965-02-25 1966-06-02 Henkel & Cie Gmbh Verfahren zur Herstellung neuer Perhydrate von Aminoalkylphosphonsaeuren
DE2013371B1 (de) * 1970-03-20 1971-11-04 Joh A , Benckiser GmbH, Chemische Fabrik, 6700 Ludwigshafen Verfahren zur Herstellung von Amino methylenphosphonsauren
US3799758A (en) * 1971-08-09 1974-03-26 Monsanto Co N-phosphonomethyl-glycine phytotoxicant compositions

Also Published As

Publication number Publication date
DK138655C (pt) 1979-02-26
YU111575A (en) 1982-06-30
DE2519388C3 (de) 1978-03-09
DE2519388B2 (de) 1977-07-14
GB1467778A (en) 1977-03-23
IE41118B1 (en) 1979-10-24
FR2269533B1 (pt) 1978-02-24
PH12324A (en) 1979-01-16
DE2519388A1 (de) 1975-11-13
IE41118L (en) 1975-11-01
BE828599A (fr) 1975-10-30
NL161763C (nl) 1980-03-17
NL7505071A (nl) 1975-11-04
DK188175A (pt) 1975-11-02
YU40117B (en) 1985-08-31
ATA333975A (de) 1976-09-15
CA1030157A (en) 1978-04-25
JPS50160222A (pt) 1975-12-25
JPS5330690B2 (pt) 1978-08-29
IT1037766B (it) 1979-11-20
CS179938B2 (en) 1977-12-30
AU8070175A (en) 1976-11-04
EG11700A (en) 1977-10-31
KR790000297B1 (en) 1979-04-23
MY7800280A (en) 1978-12-31
DD119241A5 (pt) 1976-04-12
AR215840A1 (es) 1979-11-15
NL161763B (nl) 1979-10-15
ES437154A1 (es) 1977-01-16
SE427752B (sv) 1983-05-02
RO70907A (ro) 1980-04-15
CH613210A5 (pt) 1979-09-14
DK138655B (da) 1978-10-09
ZA752792B (en) 1976-04-28
FR2269533A1 (pt) 1975-11-28
AT336637B (de) 1977-05-10
BG26398A3 (pt) 1979-03-15
US3969398A (en) 1976-07-13
SE7505040L (sv) 1975-11-03

Similar Documents

Publication Publication Date Title
BR7502651A (pt) Processo para producao de n-fosfono-metil-glicina
BR7508038A (pt) Processo para producao de poliuretanos anionicos
BR7600166A (pt) Processo para a producao de copolimeros
BR7508433A (pt) Processo para a preparacao de matacrilatos
BR7503008A (pt) Processo para a preparacao de fenilguanidinas substituidas
BR7507742A (pt) Processo para a preparacao de eteres
BR7503729A (pt) Processo para a producao de isocianatos
BR7508170A (pt) Processo para a producao de carbonil-aldimino-metano-fosfanatos
BR7500401A (pt) Processo para a preparacao de novos fenolaoetais
BR7506460A (pt) Processo para producao de dicloro-etano
BR7403569D0 (pt) Processo para a fabricacao de solucao de xilose
BR7409871A (pt) Processo para producao de hipoclorito de calcio
BR7507937A (pt) Processo para a preparacao de cianoazocorantes
BR7506872A (pt) Processo para obtencao de resorcinois
BR7503134A (pt) Processo para a preparacao de poli-laurinolactamas
BR7404085A (pt) Processo para a preparacao de 3-fluor-cefalosporinas
BR7502666A (pt) Processo para a preparacao de 2-pirazinometanois
BR7603021A (pt) Processo para a producao de 2-aril-2h-benzotriazois
BR7405092D0 (pt) Processo para producao de nitroftalimidas n-substituidas
BR7508652A (pt) Processo para a preparacao de pinacolona
BR7405112D0 (pt) Processo para producao de polieter-imidas
BR7507248A (pt) Processo para a preparacao de dicclorosilanas
BR7508128A (pt) Processo para a producao de aluminio
BR7603023A (pt) Processo para a producao de 2-aril-2h-benzotriazois
BR7500436A (pt) Processo para a producao de n n-dialildicloroacetamida