FR2269533A1 - - Google Patents

Info

Publication number
FR2269533A1
FR2269533A1 FR7513700A FR7513700A FR2269533A1 FR 2269533 A1 FR2269533 A1 FR 2269533A1 FR 7513700 A FR7513700 A FR 7513700A FR 7513700 A FR7513700 A FR 7513700A FR 2269533 A1 FR2269533 A1 FR 2269533A1
Authority
FR
France
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7513700A
Other languages
French (fr)
Other versions
FR2269533B1 (enExample
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of FR2269533A1 publication Critical patent/FR2269533A1/fr
Application granted granted Critical
Publication of FR2269533B1 publication Critical patent/FR2269533B1/fr
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
FR7513700A 1974-05-01 1975-04-30 Expired FR2269533B1 (enExample)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/465,976 US3969398A (en) 1974-05-01 1974-05-01 Process for producing N-phosphonomethyl glycine
KR7500924A KR790000297B1 (en) 1974-05-01 1975-04-30 Process for producing n-phosphono methyl gylcine

Publications (2)

Publication Number Publication Date
FR2269533A1 true FR2269533A1 (enExample) 1975-11-28
FR2269533B1 FR2269533B1 (enExample) 1978-02-24

Family

ID=26625851

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7513700A Expired FR2269533B1 (enExample) 1974-05-01 1975-04-30

Country Status (27)

Country Link
US (1) US3969398A (enExample)
JP (1) JPS5330690B2 (enExample)
KR (1) KR790000297B1 (enExample)
AR (1) AR215840A1 (enExample)
AT (1) AT336637B (enExample)
BE (1) BE828599A (enExample)
BG (1) BG26398A3 (enExample)
BR (1) BR7502651A (enExample)
CA (1) CA1030157A (enExample)
CH (1) CH613210A5 (enExample)
CS (1) CS179938B2 (enExample)
DD (1) DD119241A5 (enExample)
DE (1) DE2519388C3 (enExample)
DK (1) DK138655B (enExample)
EG (1) EG11700A (enExample)
ES (1) ES437154A1 (enExample)
FR (1) FR2269533B1 (enExample)
GB (1) GB1467778A (enExample)
IE (1) IE41118B1 (enExample)
IT (1) IT1037766B (enExample)
MY (1) MY7800280A (enExample)
NL (1) NL161763C (enExample)
PH (1) PH12324A (enExample)
RO (1) RO70907A (enExample)
SE (1) SE427752B (enExample)
YU (1) YU40117B (enExample)
ZA (1) ZA752792B (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2374328A1 (fr) * 1976-12-20 1978-07-13 Monsanto Co Procede de production de sels de n-phosphonomethylglycine et nouveaux produits ainsi obtenus
WO1996019485A1 (en) * 1994-12-20 1996-06-27 Pinus D.D. Process for preparing n-phosphonomethyl glycine
FR2865468A1 (fr) * 2004-01-22 2005-07-29 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.

Families Citing this family (90)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL48835A (en) * 1975-01-27 1979-05-31 Sparamedica Ag Amino acyl and peptidyl derivatives of phophonic acids, their preparation and pharmaceutical compositions containingthem
US4127649A (en) * 1975-01-27 1978-11-28 Hoffmann-La Roche Inc. Compositions having antibiotic properties
US4100275A (en) * 1975-01-27 1978-07-11 Hoffmann-La Roche Inc. Compositions having antibiotic properties
US4134972A (en) * 1976-07-21 1979-01-16 Hoffmann-La Roche Inc. Compositions having antibiotic properties
HU184168B (en) * 1979-05-11 1984-07-30 Mta Koezponti Kemiai Kutato In Process for producing n-bracket-phosphono-methyl-bracket closed-glycine
US4454043A (en) * 1980-11-17 1984-06-12 Monsanto Company Column switching procedure
IL65187A (en) * 1982-03-08 1985-03-31 Geshuri Lab Ltd N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
US4442041A (en) * 1982-06-30 1984-04-10 Stauffer Chemical Company Method for preparation of N-phosphonomethylglycine
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4654429A (en) * 1983-12-02 1987-03-31 Monsanto Company Process for the preparation of a glyphosate product
US4617415A (en) * 1983-12-02 1986-10-14 Monsanto Company α-Substituted N-phosphonomethyliminodiacetic acid
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US5874612A (en) * 1984-12-28 1999-02-23 Baysdon; Sherrol L. Process for the preparation of glyphosate and glyphosate derivatives
US5068404A (en) * 1984-12-28 1991-11-26 Monsanto Company Thermal dealkylation of N-alkyl N-phosphonomethylglycine
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
DE3532344A1 (de) * 1985-09-11 1987-03-19 Hoechst Ag Verfahren zur herstellung von n-phosphonomethylglycin
US4684483A (en) * 1985-09-23 1987-08-04 Monsanto Company Preparation of N-substituted amino acids
US4694082A (en) * 1985-09-23 1987-09-15 Monsanto Company Compound 1,4-diisopropyl-2,5-diketopiperazine
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US4740608A (en) * 1985-10-09 1988-04-26 Monsanto Company (Phosphonomethyl)trifluoromethyl sulfonates
US4853159A (en) * 1987-10-26 1989-08-01 Monsanto Company Process for producing N-phosphonomethylglycine
US4898972A (en) * 1988-09-26 1990-02-06 Monsanto Company Process for producing N-phosphonomethylglycine
US4965403A (en) * 1988-11-07 1990-10-23 Monsanto Company Oxidation/dealkylation process
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5312973A (en) * 1993-03-25 1994-05-17 Finchimica S.P.A. Process for producing n-phosphono-methyl-imino-diacetic acid
GB9410524D0 (en) * 1993-06-21 1994-07-13 Zeneca Ltd Manufacture of n- phosphonomethylglycine and its salts
DE19500121A1 (de) * 1995-01-04 1996-07-11 Bayer Ag Verfahren zur Herstellung von N-Phosphonomethylglycin
TW322481B (enExample) * 1995-03-07 1997-12-11 Sankyo Co
JPH10504242A (ja) * 1995-03-14 1998-04-28 モンサント・カンパニー ホルムアルデヒド含有廃棄物流の処理
US6365772B1 (en) * 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
US6054608A (en) * 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
WO1999041260A1 (en) * 1998-02-12 1999-08-19 Monsanto Company Process for making glyphosate by oxidizing n-substituted glyphosates
US6232494B1 (en) * 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
AU754918C (en) 1998-03-09 2007-05-31 Monsanto Technology Llc Mixtures for weed control in glyphosate tolerant soybeans
US5962729A (en) * 1998-05-14 1999-10-05 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon
US5942643A (en) * 1998-05-14 1999-08-24 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
WO2000009520A1 (en) 1998-08-12 2000-02-24 Monsanto Company Continuous process for the preparation of n-(phosphonomethyl) iminodiacetic acid
US6118022A (en) * 1998-09-08 2000-09-12 Hampshire Chemical Corp. Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
US6194604B1 (en) 1998-12-10 2001-02-27 Monsanto Company Process for producing phosphorous acid
PT1198466E (pt) 1999-07-23 2003-08-29 Basf Ag Processo para producao de glifosatos ou um dos seus sais
AR027063A1 (es) 1999-12-21 2003-03-12 Monsanto Co Uso de un promotor suplementario en conjunto con un catalizador que contiene metal noble con soporte de carbon, en reacciones de oxidacion en fase liquida
DE10007702A1 (de) * 2000-02-19 2001-08-23 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-(Phosphonomethyl)glycin
US6274760B1 (en) 2000-03-14 2001-08-14 Monsanto Co. Preparation of formylphosphonic acid from tertiary aminomethylphosphonic acid N-oxides
US6376708B1 (en) * 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
ES2271022T3 (es) * 2000-05-15 2007-04-16 Monsanto Technology Llc Preparacion de compuestos de acido imnidiacetico a partir de sustratos de monoetanolamina.
CN100393733C (zh) * 2000-05-22 2008-06-11 孟山都技术有限责任公司 制备n-(膦酰基甲基)甘氨酸化合物的反应系统
AU6293001A (en) * 2000-05-22 2001-12-11 Monsanto Technology Llc Reaction systems for making n-(phosphonomethyl)glycine compounds
US6927304B2 (en) 2000-05-22 2005-08-09 Monsanto Technology Llc De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
US6441223B1 (en) 2000-11-30 2002-08-27 Monsanto Technology Llc Method of making phosphorus-containing compounds and products thereof
US6818450B2 (en) 2001-05-22 2004-11-16 Monsanto Technology Llc Use of infrared spectroscopy for on-line process control and endpoint detection
DE10130136A1 (de) * 2001-06-22 2003-01-02 Basf Ag Verfahren zur Gewinnung von N-Phosphonomethylglycin
BR0213428A (pt) 2001-10-18 2005-12-20 Monsanto Technology Llc Processo e catalisador para desidrogenação de álcoois primários para fabricação de sais de ácidos carboxìlicos
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
WO2003068387A1 (en) * 2002-02-14 2003-08-21 Monsanto Technology Llc Oxidation catalyst and process for its preparation and process for oxidation using it
US6921834B2 (en) * 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
JP4202047B2 (ja) * 2002-05-24 2008-12-24 富士通株式会社 ヘッド位置制御方法及びデイスク記憶装置
WO2004002622A1 (en) * 2002-06-28 2004-01-08 Monsanto Technology Llc Use of tellurium in carbon-supported, noble metal-containing catalysts for liquid phase oxidation reactions
EP1684900B1 (en) * 2003-08-14 2013-02-27 Monsanto Technology LLC Process for oxidation of N-(phosphonomethyl)iminodiacetic acid or salt thereof
ES2299874T3 (es) * 2003-09-17 2008-06-01 Monsanto Technology Llc Procedimiento para recuperar un producto cristalino de una solucion.
BRPI0509541A (pt) 2004-03-30 2007-09-18 Monsanto Technology Llc métodos para controlar agentes patógenos de planta utilizando n-fosfonometilglicina
CN100372857C (zh) * 2004-05-12 2008-03-05 江苏好收成韦恩农药化工有限公司 N-膦酰基甲基甘氨酸的生产方法
US7893004B2 (en) * 2004-09-06 2011-02-22 Japan Envirochemicals, Ltd. Oxidation reaction catalyst and process for producing a compound using the same
AR051926A1 (es) * 2004-09-15 2007-02-21 Monsanto Technology Llc Catalizadores de oxidacion, procedimientos de preparacion de dichos catalizadores y proceso para la elaboracion de n-( fosfonometil)glicina o una sal de la misma
AR054096A1 (es) * 2004-11-12 2007-06-06 Monsanto Technology Llc Recuperacion de metales nobles de corrientes de proceso acuosas y proceso de preparacion de n-(fosfonometil)-glicina
AU2006214086B2 (en) 2005-02-17 2012-01-19 Monsanto Technology Llc Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
CN101170907B (zh) 2005-03-04 2012-10-03 孟山都技术公司 减轻用除草剂草甘膦制剂处理的草甘膦耐受性转基因棉花植物内的坏死
BRPI0708081A2 (pt) * 2006-02-17 2011-05-17 Monsanto Technology Llc catalisadores contendo metal de transição e processos para a sua preparação e uso como catalisadores de pilha termoelétrica
CN100460408C (zh) * 2007-01-26 2009-02-11 捷马化工股份有限公司 资源再利用的催化氧化制备草甘膦方法
US7771494B2 (en) * 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
CN101337978B (zh) * 2008-05-13 2011-06-29 浙江新安化工集团股份有限公司 一种利用富氧气体催化氧化双甘膦制取草甘膦的方法
CN101481387B (zh) * 2008-11-27 2012-02-01 浙江新安化工集团股份有限公司 一种催化氧化合成草甘膦的制备方法
CN101508701B (zh) * 2008-12-10 2012-09-05 上海泰禾(集团)有限公司 一种活性碳作催化剂氧气氧化双甘膦制备草甘膦的方法
US8669396B2 (en) 2009-05-18 2014-03-11 Monsanto Technology Llc Recovery of phosphorus values and salt impurities from aqueous waste streams
CN101781332B (zh) * 2010-03-02 2012-10-24 广西壮族自治区化工研究院 活性炭催化空气氧化双甘膦制备草甘膦的方法
CN102241703B (zh) * 2011-05-07 2014-05-07 安徽国星生物化学有限公司 一种改进的双甘膦制备草甘膦的方法
CN104812765B (zh) 2012-07-17 2017-06-06 斯特雷特马克控股股份公司 用于合成α‑氨基亚烷基膦酸的方法
US10364262B2 (en) 2012-07-17 2019-07-30 Monsanto Technology Llc Method for the synthesis of N-phosphonomethyliminodiacetic acid
RU2694047C2 (ru) 2012-07-17 2019-07-09 МОНСАНТО ТЕКНОЛОДЖИ ЭлЭлСи Способ синтеза аминоалкиленфосфоновой кислоты
BR112015000995B1 (pt) 2012-07-17 2020-04-28 Monsanto Technology Llc método para a síntese de n-(fosfonometil)glicina ou um de seus derivados selecionados a partir do grupo que consiste em seus sais, seus ésteres de fosfonato e seus sais de éster de fosfonato
IN2015DN01078A (enExample) 2012-07-17 2015-06-26 Straitmark Holding Ag
US11279644B2 (en) 2017-06-26 2022-03-22 Monsanto Technology Llc Phosphorus control for waste streams from glyphosate manufacturing processes
CN115215900A (zh) * 2022-07-01 2022-10-21 安徽东至广信农化有限公司 一种草甘膦的节能生产方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1217950B (de) * 1965-02-25 1966-06-02 Henkel & Cie Gmbh Verfahren zur Herstellung neuer Perhydrate von Aminoalkylphosphonsaeuren
DE2013371B1 (de) * 1970-03-20 1971-11-04 Joh A , Benckiser GmbH, Chemische Fabrik, 6700 Ludwigshafen Verfahren zur Herstellung von Amino methylenphosphonsauren
US3799758A (en) * 1971-08-09 1974-03-26 Monsanto Co N-phosphonomethyl-glycine phytotoxicant compositions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2374328A1 (fr) * 1976-12-20 1978-07-13 Monsanto Co Procede de production de sels de n-phosphonomethylglycine et nouveaux produits ainsi obtenus
WO1996019485A1 (en) * 1994-12-20 1996-06-27 Pinus D.D. Process for preparing n-phosphonomethyl glycine
FR2865468A1 (fr) * 2004-01-22 2005-07-29 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
WO2005080269A3 (fr) * 2004-01-22 2006-07-27 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notament comme support de catalyseur

Also Published As

Publication number Publication date
JPS50160222A (enExample) 1975-12-25
DK138655C (enExample) 1979-02-26
DK138655B (da) 1978-10-09
AU8070175A (en) 1976-11-04
IE41118L (en) 1975-11-01
CH613210A5 (enExample) 1979-09-14
BG26398A3 (bg) 1979-03-15
AT336637B (de) 1977-05-10
IE41118B1 (en) 1979-10-24
IT1037766B (it) 1979-11-20
AR215840A1 (es) 1979-11-15
ES437154A1 (es) 1977-01-16
CA1030157A (en) 1978-04-25
CS179938B2 (en) 1977-12-30
DK188175A (enExample) 1975-11-02
GB1467778A (en) 1977-03-23
PH12324A (en) 1979-01-16
SE427752B (sv) 1983-05-02
DE2519388A1 (de) 1975-11-13
MY7800280A (en) 1978-12-31
NL161763C (nl) 1980-03-17
DD119241A5 (enExample) 1976-04-12
YU111575A (en) 1982-06-30
DE2519388B2 (de) 1977-07-14
ZA752792B (en) 1976-04-28
ATA333975A (de) 1976-09-15
EG11700A (en) 1977-10-31
BR7502651A (pt) 1976-03-16
RO70907A (ro) 1980-04-15
US3969398A (en) 1976-07-13
NL7505071A (nl) 1975-11-04
YU40117B (en) 1985-08-31
FR2269533B1 (enExample) 1978-02-24
SE7505040L (sv) 1975-11-03
JPS5330690B2 (enExample) 1978-08-29
KR790000297B1 (en) 1979-04-23
BE828599A (fr) 1975-10-30
NL161763B (nl) 1979-10-15
DE2519388C3 (de) 1978-03-09

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