GB1113979A - Modified carbohydrate material for smoking mixtures - Google Patents

Modified carbohydrate material for smoking mixtures

Info

Publication number
GB1113979A
GB1113979A GB22270/66A GB2227066A GB1113979A GB 1113979 A GB1113979 A GB 1113979A GB 22270/66 A GB22270/66 A GB 22270/66A GB 2227066 A GB2227066 A GB 2227066A GB 1113979 A GB1113979 A GB 1113979A
Authority
GB
United Kingdom
Prior art keywords
acid
product
gum
ammonium
degraded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22270/66A
Inventor
James Forrester Morman
James Brown Parker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB22270/66A priority Critical patent/GB1113979A/en
Priority to DE1692921A priority patent/DE1692921C3/en
Priority to DE1792740A priority patent/DE1792740C3/en
Priority to BE698359D priority patent/BE698359A/xx
Priority to LU53689D priority patent/LU53689A1/xx
Priority to ES340685A priority patent/ES340685A1/en
Priority to NO168199A priority patent/NO116233B/no
Priority to SE6706978A priority patent/SE383891B/en
Priority to FR106958A priority patent/FR1523686A/en
Priority to CH704667A priority patent/CH529175A/en
Priority to DK262567AA priority patent/DK127671B/en
Priority to NL676706991A priority patent/NL141770B/en
Priority to ES344777A priority patent/ES344777A1/en
Publication of GB1113979A publication Critical patent/GB1113979A/en
Priority to US876219A priority patent/US3545448A/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10—Chemical features of tobacco products or tobacco substitutes
    • A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • A24B15/165—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes comprising as heat source a carbon fuel or an oxidized or thermally degraded carbonaceous fuel, e.g. carbohydrates, cellulosic material

Abstract

Polysaccharides are subjected to a catalysed degradation at 100-250 DEG C. until the weight of the degraded material is less than 90% of the starting material. Specified catalysts are sulphamic acid, ammonium sulphamate, phosphoric acid, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, sulphuric acid, hydrochloric acid, ferric chloride, sodium hydroxide or sodium carbonate. The polysaccharide may be a -cellulose, methyl cellulose, starch, alginic acid, pectin, gum tragacanth, gum arabic or locust bean gum. The treated product may be further treated with nitric acid, hydrogen peroxide or ammonia to improve the colour. The product is useful in compounding smoking mixtures (see Division A2), but must be washed free of NaOH or sodium carbonate if these catalyst were used.ALSO:A smoking mixture comprises a carbohydrate which has been catalytically degraded at 100-250 DEG C. to less than 90% of its original weight. Specified carbohydrates are a -cellulose, methyl cellulose, glucose, sucrose, starch, alginic acid, pectin, gum tragacanth, gum arabic or locust bean gum. The degraded product may have been further treated with nitric acid, hydrogen peroxide or ammonia to improve colour. Other adjuvants include glow-promoting catalysts, e.g. alkali metal compounds; ash improvers, e.g. ammonium, alkaline earth or alkali metal salts; flavours, e.g. tobacco extract, organic esters, essential oils, menthol, touka bean or vanillin; humectants, e.g. glycols or glycerol; and combustion improvers, e.g. carbonates. Any alkali catalyst, and, desirably any acid catalyst remaining in the treated material is neutralized before use. The product, together with the other ingredients, may be conditioned to 5-15% water content in a humid atmosphere. The product may be in sheet form, which can be shredded, optionally with film-forming agents such as methyl cellulose, sodium CMC, PVA, starch, pectin, gum or mucilage.ALSO:Wood-pulp or a -cellolose optionally in the form of sheets is catalytically degraded at 100-250 DEG C until the product is less than 90% of the weight of the starting material. Specified catalysts are sulphamic acid, ammonium sulphamate, phosphoric acid, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, sulphuric acid, ammonium sulphate, hydrochloric acid, ferric chloride, sodium hydroxide and sodium carbonate. The degraded product may be further treated with nitric acid, hydrogen peroxide or ammonia to improve the colour. The sheets may be held together with such binders as methyl cellulose, sodium CMC, PVA, starch, pectin, gum or mucilage. Optionally, sheets may be formed of the final treated product, using binders as specified above. The product, e.g. in the form of shredded sheets, is useful in making smoking mixtures (see Div. A2), but must first be washed free of any alkaline degradation catalyst used.
GB22270/66A 1966-05-19 1966-05-19 Modified carbohydrate material for smoking mixtures Expired GB1113979A (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
GB22270/66A GB1113979A (en) 1966-05-19 1966-05-19 Modified carbohydrate material for smoking mixtures
DE1692921A DE1692921C3 (en) 1966-05-19 1967-05-10 Process for the production of tobacco-free smoking products and the use thereof for tobacco-free or tobacco-containing smoking products
DE1792740A DE1792740C3 (en) 1966-05-19 1967-05-10 Method of making a combustible material
BE698359D BE698359A (en) 1966-05-19 1967-05-11
LU53689D LU53689A1 (en) 1966-05-19 1967-05-17
SE6706978A SE383891B (en) 1966-05-19 1967-05-18 METHOD OF MANUFACTURING A THERMALLY DECOMPOSED CARBOHYDRATE, SUITABLE FOR USE AS A TOBACCO REPLACEMENT SMOKING MATERIAL
NO168199A NO116233B (en) 1966-05-19 1967-05-18
ES340685A ES340685A1 (en) 1966-05-19 1967-05-18 Process for making a modified carbohydrate material for smoking mixtures and the material made thereby
FR106958A FR1523686A (en) 1966-05-19 1967-05-19 Modified carbohydrate for smoking mixes
CH704667A CH529175A (en) 1966-05-19 1967-05-19 Process for the production of modified carbohydrates
DK262567AA DK127671B (en) 1966-05-19 1967-05-19 Process for the preparation of a modified carbohydrate material for smoking mixtures.
NL676706991A NL141770B (en) 1966-05-19 1967-05-19 PROCEDURE FOR PREPARING A SMOKE SUBSTITUTE.
ES344777A ES344777A1 (en) 1966-05-19 1967-09-06 Process for making a modified carbohydrate material for smoking mixtures and the material made thereby
US876219A US3545448A (en) 1966-05-19 1969-12-01 Process for making a modified carbohydrate material for smoking mixtures and the material made thereby

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB22270/66A GB1113979A (en) 1966-05-19 1966-05-19 Modified carbohydrate material for smoking mixtures

Publications (1)

Publication Number Publication Date
GB1113979A true GB1113979A (en) 1968-05-15

Family

ID=10176655

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22270/66A Expired GB1113979A (en) 1966-05-19 1966-05-19 Modified carbohydrate material for smoking mixtures

Country Status (11)

Country Link
US (1) US3545448A (en)
BE (1) BE698359A (en)
CH (1) CH529175A (en)
DE (2) DE1792740C3 (en)
DK (1) DK127671B (en)
ES (2) ES340685A1 (en)
GB (1) GB1113979A (en)
LU (1) LU53689A1 (en)
NL (1) NL141770B (en)
NO (1) NO116233B (en)
SE (1) SE383891B (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3934594A (en) * 1972-03-02 1976-01-27 Tamag Basel Ag Process for the manufacture of tobacco substitute
US3964494A (en) * 1974-10-21 1976-06-22 R. J. Reynolds Tobacco Company Compositions for smoking
US3978866A (en) * 1974-09-03 1976-09-07 R. J. Reynolds Tobacco Company Smoking compositions
DE3042937A1 (en) * 1979-11-16 1981-05-27 Imperial Group Ltd., London SMOKING ITEM
US4474191A (en) * 1982-09-30 1984-10-02 Steiner Pierre G Tar-free smoking devices
EP0129227A2 (en) * 1983-06-18 1984-12-27 Cpc International Inc. Flame-resistant starch, process for its preparation and its use
EP0337506A2 (en) * 1984-09-14 1989-10-18 R.J. Reynolds Tobacco Company Smoking article
US5060676A (en) * 1982-12-16 1991-10-29 Philip Morris Incorporated Process for making a carbon heat source and smoking article including the heat source and a flavor generator
US6769437B2 (en) 2002-04-08 2004-08-03 Philip Morris Incorporated Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette
US8701681B2 (en) 2003-10-27 2014-04-22 Philip Morris Usa Inc. Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3738374A (en) * 1970-03-05 1973-06-12 B Lab Cigar or cigarette having substitute filler
GB1299296A (en) * 1970-03-23 1972-12-13 Ici Ltd Improved smoking mixture
US4008723A (en) * 1970-03-23 1977-02-22 Imperial Chemical Industries Limited Smoking mixture
GB1317584A (en) * 1970-03-23 1973-05-23 Ici Ltd Smoking mixture
GB1312483A (en) * 1970-03-23 1973-04-04 Ici Ltd Smoking mixture
US3951155A (en) * 1970-07-11 1976-04-20 Carreras Rothmans Limited Smoking materials
US4005718A (en) * 1970-07-11 1977-02-01 Carreras Rothmans Limited Smoking materials
GB1332503A (en) * 1970-10-15 1973-10-03 British American Tobacco Co Smoking compositions
BE788198A (en) * 1971-09-08 1973-02-28 Ici Ltd IMPROVED SMOKING MIX
US3892244A (en) * 1971-12-15 1975-07-01 Ici Ltd Smoking mixtures
GB1364103A (en) * 1971-12-15 1974-08-21 Ici Ltd Smoking mixtures
US4319591A (en) * 1972-02-09 1982-03-16 Celanese Corporation Smoking compositions
US3812864A (en) * 1972-02-09 1974-05-28 Celanese Corp Tobacco replacement material
NL7301732A (en) * 1972-02-10 1973-08-14
US3831609A (en) * 1972-02-14 1974-08-27 Sutton Res Corp Smokable substitute material and smoking products thereof
US4002176A (en) * 1972-03-02 1977-01-11 Imperial Chemical Industries Limited Tobacco based smoking material
GB1362613A (en) * 1972-03-16 1974-08-07 Ici Ltd Smoking mixtures
IE37524B1 (en) * 1972-04-20 1977-08-17 Gallaher Ltd Synthetic smoking product
US4044777A (en) * 1972-04-20 1977-08-30 Gallaher Limited Synthetic smoking product
US3782393A (en) * 1972-08-02 1974-01-01 American Safety Equip Method of making a cigarette of reduced biological damage capability
US4014349A (en) * 1972-08-31 1977-03-29 Imperial Chemical Industries Limited Smoking material
GB1385754A (en) * 1972-08-31 1975-02-26 Ici Ltd Manufacture of a smoking material
GB1398177A (en) * 1972-12-04 1975-06-18 Ici Ltd Smoking mixtures
US3861401A (en) * 1973-03-08 1975-01-21 Theodore S Briskin Smokable tobacco substitute material and method
FR2224099A1 (en) * 1973-04-09 1974-10-31 Gallaher Ltd Base for synthetic tobacco - composed of carbon-contg. flexible and coherent fine fibres
US4019521A (en) * 1973-06-06 1977-04-26 Philip Morris Incorporated Smokable material and method for preparing same
GB1445111A (en) * 1973-07-09 1976-08-04 Ici Ltd Smoking mixture
GB1445124A (en) * 1973-07-09 1976-08-04 Ici Ltd Smoking mixtures
US3861402A (en) * 1973-10-23 1975-01-21 Sutton Res Corp Smokable material and method for preparation of same
US4111211A (en) * 1974-05-02 1978-09-05 Imperial Chemical Industries Limited Smoking mixtures
US4147172A (en) * 1974-07-16 1979-04-03 Imperial Chemical Industries Limited Smoking mixtures
US4133317A (en) * 1975-03-27 1979-01-09 Philip Morris Incorporated Smokable material and method for preparing same
US4034764A (en) * 1975-08-15 1977-07-12 Philip Morris Incorporated Smoking material and method for its preparation
AU1871276A (en) * 1975-11-11 1978-04-20 Brown & Williamson Tobacco Tobacco
US4256126A (en) * 1978-08-02 1981-03-17 Philip Morris Incorporated Smokable material and its method of preparation
US4793365A (en) * 1984-09-14 1988-12-27 R. J. Reynolds Tobacco Company Smoking article
US5076297A (en) * 1986-03-14 1991-12-31 R. J. Reynolds Tobacco Company Method for preparing carbon fuel for smoking articles and product produced thereby
US4893639A (en) * 1986-07-22 1990-01-16 R. J. Reynolds Tobacco Company Densified particulate materials for smoking products and process for preparing the same
US6637439B2 (en) 2001-08-31 2003-10-28 Philip Morris Incorporated Tobacco smoking mixture for smoking articles such as cigarettes
US6817365B2 (en) * 2001-11-15 2004-11-16 Philip Morris Usa Inc. Cigarette paper having heat-degradable filler particles, and cigarette comprising a cigarette paper wrapper having heat-degradable filler particles
WO2012078597A1 (en) 2010-12-07 2012-06-14 Freeman Steven R Vegetable based tobacco alternatives and articles comprising same
CN203388263U (en) * 2013-06-26 2014-01-15 刘秋明 Electronic cigarette, electronic cigarette atomizer and electronic cigarette tip
GB201312501D0 (en) 2013-07-12 2013-08-28 British American Tobacco Co Material for inclusion in a smoking article
US11490653B2 (en) 2017-06-23 2022-11-08 Altria Client Services Llc Smoking article
US10765143B2 (en) 2017-09-14 2020-09-08 Altria Client Services Llc Smoking article with reduced tobacco
WO2023163715A1 (en) * 2022-02-26 2023-08-31 Big 5 Properties Inc. Smoking product and methods of manufacture

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3934594A (en) * 1972-03-02 1976-01-27 Tamag Basel Ag Process for the manufacture of tobacco substitute
US3978866A (en) * 1974-09-03 1976-09-07 R. J. Reynolds Tobacco Company Smoking compositions
US3964494A (en) * 1974-10-21 1976-06-22 R. J. Reynolds Tobacco Company Compositions for smoking
DE3042937A1 (en) * 1979-11-16 1981-05-27 Imperial Group Ltd., London SMOKING ITEM
JPS56131379A (en) * 1979-11-16 1981-10-14 Imuperiaru Guruupu Ltd Smoking apparatus
JPS585660B2 (en) * 1979-11-16 1983-02-01 インペリアル、グル−プ、リミテツド smoking device
US4596258A (en) * 1982-09-30 1986-06-24 Steiner Pierre G Smoking devices
US4474191A (en) * 1982-09-30 1984-10-02 Steiner Pierre G Tar-free smoking devices
US5060676A (en) * 1982-12-16 1991-10-29 Philip Morris Incorporated Process for making a carbon heat source and smoking article including the heat source and a flavor generator
EP0129227A3 (en) * 1983-06-18 1985-12-11 Cpc International Inc. Flame-resistant starch, process for its preparation and its use
EP0129227A2 (en) * 1983-06-18 1984-12-27 Cpc International Inc. Flame-resistant starch, process for its preparation and its use
EP0337506A2 (en) * 1984-09-14 1989-10-18 R.J. Reynolds Tobacco Company Smoking article
EP0339689A2 (en) * 1984-09-14 1989-11-02 R.J. Reynolds Tobacco Company Smoking article
EP0339689B1 (en) * 1984-09-14 1994-11-30 R.J. Reynolds Tobacco Company Smoking article
EP0337506B1 (en) * 1984-09-14 1994-11-30 R.J. Reynolds Tobacco Company Smoking article
US6769437B2 (en) 2002-04-08 2004-08-03 Philip Morris Incorporated Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette
US7228862B2 (en) 2002-04-08 2007-06-12 Philip Morris Usa Inc. Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette
US8701681B2 (en) 2003-10-27 2014-04-22 Philip Morris Usa Inc. Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette

Also Published As

Publication number Publication date
SE383891B (en) 1976-04-05
NL6706991A (en) 1967-11-20
DE1792740A1 (en) 1973-05-30
NO116233B (en) 1969-02-17
LU53689A1 (en) 1967-07-17
DE1692921C3 (en) 1975-03-13
NL141770B (en) 1974-04-16
DK127671B (en) 1973-12-17
CH529175A (en) 1972-10-15
DE1792740B2 (en) 1974-08-22
ES340685A1 (en) 1968-09-16
ES344777A1 (en) 1968-11-01
DE1692921A1 (en) 1972-06-15
DE1692921B2 (en) 1974-07-25
US3545448A (en) 1970-12-08
BE698359A (en) 1967-11-13
DE1792740C3 (en) 1975-04-10

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