FI113453B - Kasvimateriaalin kromatografinen fraktiointi - Google Patents
Kasvimateriaalin kromatografinen fraktiointi Download PDFInfo
- Publication number
- FI113453B FI113453B FI991985A FI19991985A FI113453B FI 113453 B FI113453 B FI 113453B FI 991985 A FI991985 A FI 991985A FI 19991985 A FI19991985 A FI 19991985A FI 113453 B FI113453 B FI 113453B
- Authority
- FI
- Finland
- Prior art keywords
- pectin
- chromatographic separation
- process according
- fraction
- resin
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims description 26
- 238000005194 fractionation Methods 0.000 title abstract description 10
- 229920001277 pectin Polymers 0.000 claims abstract description 128
- 239000001814 pectin Substances 0.000 claims abstract description 127
- 235000010987 pectin Nutrition 0.000 claims abstract description 126
- 238000000034 method Methods 0.000 claims abstract description 53
- 235000000346 sugar Nutrition 0.000 claims abstract description 46
- 150000003839 salts Chemical class 0.000 claims abstract description 41
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 claims abstract description 29
- 235000021536 Sugar beet Nutrition 0.000 claims abstract description 29
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003729 cation exchange resin Substances 0.000 claims abstract description 12
- 239000000243 solution Substances 0.000 claims description 53
- 239000011347 resin Substances 0.000 claims description 36
- 229920005989 resin Polymers 0.000 claims description 36
- 238000013375 chromatographic separation Methods 0.000 claims description 33
- 150000002500 ions Chemical class 0.000 claims description 22
- 238000004587 chromatography analysis Methods 0.000 claims description 17
- 241000196324 Embryophyta Species 0.000 claims description 14
- 238000005342 ion exchange Methods 0.000 claims description 12
- 150000001768 cations Chemical class 0.000 claims description 11
- 238000000108 ultra-filtration Methods 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 230000007717 exclusion Effects 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 150000001450 anions Chemical class 0.000 claims description 7
- 235000020971 citrus fruits Nutrition 0.000 claims description 7
- 238000004132 cross linking Methods 0.000 claims description 6
- 238000005374 membrane filtration Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000003463 adsorbent Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 229920006026 co-polymeric resin Polymers 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 3
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 claims description 2
- 238000007385 chemical modification Methods 0.000 claims description 2
- 239000012607 strong cation exchange resin Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims 4
- 239000000413 hydrolysate Substances 0.000 abstract 1
- 239000005418 vegetable material Substances 0.000 abstract 1
- 150000008163 sugars Chemical class 0.000 description 22
- 230000007062 hydrolysis Effects 0.000 description 16
- 238000006460 hydrolysis reaction Methods 0.000 description 16
- 238000000926 separation method Methods 0.000 description 14
- 239000002253 acid Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000007858 starting material Substances 0.000 description 10
- 235000016068 Berberis vulgaris Nutrition 0.000 description 8
- 241000335053 Beta vulgaris Species 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 7
- 239000012527 feed solution Substances 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229920001282 polysaccharide Polymers 0.000 description 6
- 239000005017 polysaccharide Substances 0.000 description 6
- -1 polysaccharide compounds Chemical class 0.000 description 6
- 229920002230 Pectic acid Polymers 0.000 description 5
- 150000004676 glycans Chemical class 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 150000002772 monosaccharides Chemical class 0.000 description 5
- 239000010318 polygalacturonic acid Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- 241000207199 Citrus Species 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical class CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 4
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 4
- 150000001720 carbohydrates Chemical class 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 150000003384 small molecules Chemical class 0.000 description 4
- SRBFZHDQGSBBOR-HWQSCIPKSA-N L-arabinopyranose Chemical compound O[C@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-HWQSCIPKSA-N 0.000 description 3
- 238000005903 acid hydrolysis reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005352 clarification Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 229920001542 oligosaccharide Polymers 0.000 description 3
- 150000002482 oligosaccharides Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000006188 syrup Substances 0.000 description 3
- 235000020357 syrup Nutrition 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920001202 Inulin Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 235000008504 concentrate Nutrition 0.000 description 2
- 238000011033 desalting Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003480 eluent Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 description 2
- 229940029339 inulin Drugs 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 102100021935 C-C motif chemokine 26 Human genes 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000723343 Cichorium Species 0.000 description 1
- 235000007542 Cichorium intybus Nutrition 0.000 description 1
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 101000897493 Homo sapiens C-C motif chemokine 26 Proteins 0.000 description 1
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 1
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 1
- 108010029541 Laccase Proteins 0.000 description 1
- 229930186657 Lat Natural products 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- CZMRCDWAGMRECN-UHFFFAOYSA-N Rohrzucker Natural products OCC1OC(CO)(OC2OC(CO)C(O)C(O)C2O)C(O)C1O CZMRCDWAGMRECN-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- IAJILQKETJEXLJ-RSJOWCBRSA-N aldehydo-D-galacturonic acid Chemical group O=C[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-RSJOWCBRSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- AEMOLEFTQBMNLQ-BKBMJHBISA-N alpha-D-galacturonic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-BKBMJHBISA-N 0.000 description 1
- SRBFZHDQGSBBOR-QMKXCQHVSA-N alpha-L-arabinopyranose Chemical compound O[C@H]1CO[C@@H](O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-QMKXCQHVSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000001785 ferulic acid Nutrition 0.000 description 1
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 description 1
- 229940114124 ferulic acid Drugs 0.000 description 1
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000008264 rhamnoses Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 125000000969 xylosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)CO1)* 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0045—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Galacturonans, e.g. methyl ester of (alpha-1,4)-linked D-galacturonic acid units, i.e. pectin, or hydrolysis product of methyl ester of alpha-1,4-linked D-galacturonic acid units, i.e. pectinic acid; Derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction
- B01D15/361—Ion-exchange
- B01D15/362—Cation-exchange
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0003—General processes for their isolation or fractionation, e.g. purification or extraction from biomass
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Analytical Chemistry (AREA)
- Sustainable Development (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Medicines Containing Plant Substances (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Jellies, Jams, And Syrups (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Saccharide Compounds (AREA)
Priority Applications (21)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI991985A FI113453B (fi) | 1999-09-17 | 1999-09-17 | Kasvimateriaalin kromatografinen fraktiointi |
| EP00960708A EP1218079B8 (de) | 1999-09-17 | 2000-09-15 | Chromatographische fraktionierung von vegetativem material |
| CA002385109A CA2385109C (en) | 1999-09-17 | 2000-09-15 | Chromatographic fractionation of vegetable material |
| AU72909/00A AU7290900A (en) | 1999-09-17 | 2000-09-15 | Chromatographic fractionation of vegetable material |
| DE60043347T DE60043347D1 (de) | 1999-09-17 | 2000-09-15 | Chromatographische fraktionierung von vegetativem material |
| AT00960708T ATE448848T1 (de) | 1999-09-17 | 2000-09-15 | Chromatographische fraktionierung von vegetativem material |
| JP2001524692A JP2003509575A (ja) | 1999-09-17 | 2000-09-15 | 植物材料のクロマトグラフィー分画 |
| PCT/FI2000/000779 WO2001021271A1 (en) | 1999-09-17 | 2000-09-15 | Chromatographic fractionation of vegetable material |
| HU0202872A HUP0202872A3 (en) | 1999-09-17 | 2000-09-15 | Chomatographic fractionation of vegetable material |
| PL353991A PL196961B1 (pl) | 1999-09-17 | 2000-09-15 | Sposób jednoczesnego oczyszczania i oddzielania pektyny i pektynowych cukrów/oligomerów w wieloetapowym procesie prowadzonym w roztworze wodnym z wysłodków buraków cukrowych |
| CA002384874A CA2384874C (en) | 1999-09-17 | 2000-09-15 | Process for the fractionation of sugar beet pulp |
| EP00960709A EP1227866A1 (de) | 1999-09-17 | 2000-09-15 | Verfahren zur fraktionierung von zuckerrübenpulpe |
| CZ2002948A CZ295865B6 (cs) | 1999-09-17 | 2000-09-15 | Způsob současného čištění a separace pektinu a pektických cukrů či oligomerů z kaše z cukrové řepy |
| PCT/FI2000/000780 WO2001021272A1 (en) | 1999-09-17 | 2000-09-15 | Process for the fractionation of sugar beet pulp |
| HU0203963A HUP0203963A3 (en) | 1999-09-17 | 2000-09-15 | Process for the fractionation of sugar beet pulp |
| AU72910/00A AU7291000A (en) | 1999-09-17 | 2000-09-15 | Process for the fractionation of sugar beet pulp |
| JP2001524693A JP2003509576A (ja) | 1999-09-17 | 2000-09-15 | 甜菜パルプの分画方法 |
| PL356680A PL196962B1 (pl) | 1999-09-17 | 2000-09-15 | Sposób obróbki chromatograficznej materiału roślinnego zawierającego pektynę |
| CZ2002799A CZ295265B6 (cs) | 1999-09-17 | 2000-09-15 | Chromatografické dělení rostlinného materiálu |
| US10/091,891 US6660099B2 (en) | 1999-09-17 | 2002-03-06 | Chromatographic fractionation of vegetable material |
| US10/091,892 US6663717B2 (en) | 1999-09-17 | 2002-03-06 | Process for the fractionation of sugar beet pulp |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI991985A FI113453B (fi) | 1999-09-17 | 1999-09-17 | Kasvimateriaalin kromatografinen fraktiointi |
| FI991985 | 1999-09-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FI19991985A FI19991985A (fi) | 2001-03-17 |
| FI113453B true FI113453B (fi) | 2004-04-30 |
Family
ID=8555306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI991985A FI113453B (fi) | 1999-09-17 | 1999-09-17 | Kasvimateriaalin kromatografinen fraktiointi |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US6660099B2 (de) |
| EP (2) | EP1227866A1 (de) |
| JP (2) | JP2003509575A (de) |
| AT (1) | ATE448848T1 (de) |
| AU (2) | AU7290900A (de) |
| CA (2) | CA2385109C (de) |
| CZ (2) | CZ295265B6 (de) |
| DE (1) | DE60043347D1 (de) |
| FI (1) | FI113453B (de) |
| HU (2) | HUP0202872A3 (de) |
| PL (2) | PL196962B1 (de) |
| WO (2) | WO2001021272A1 (de) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI113453B (fi) * | 1999-09-17 | 2004-04-30 | Sohkar Oy | Kasvimateriaalin kromatografinen fraktiointi |
| US7037378B2 (en) * | 2003-09-24 | 2006-05-02 | Danisco Sweetners Oy | Separation of sugars |
| US20050096464A1 (en) | 2003-10-30 | 2005-05-05 | Heikki Heikkila | Separation process |
| GB2407573A (en) * | 2003-10-30 | 2005-05-04 | Danisco Sweeteners Oy | Production of arabinose |
| EP1765874A1 (de) | 2004-03-26 | 2007-03-28 | Glycogenesys, Inc. | Modifizierte pektine und zugehörige zusammensetzungen und verfahren |
| EP1781116A4 (de) * | 2004-06-04 | 2009-07-29 | Horizon Science Pty Ltd | Natürliches süssungsmittel |
| EP1714562A1 (de) * | 2005-04-22 | 2006-10-25 | N.V. Nutricia | Vefahren zur Trocknung von Oligosacchariden mit Uronsäuren |
| WO2006128259A1 (en) | 2005-06-03 | 2006-12-07 | Horizon Science Pty Ltd | Substances having body mass redistribution properties |
| US20070160734A1 (en) * | 2005-12-09 | 2007-07-12 | Danisco A/S | Beverage emulsion |
| AU2006322991A1 (en) * | 2005-12-09 | 2007-06-14 | Dupont Nutrition Biosciences Aps | Stabilised emulsion |
| JP2010503417A (ja) * | 2006-09-19 | 2010-02-04 | ホリズン サイエンス ピーティーワイ リミテッド | サトウキビに由来する抽出物、およびこれらの製造方法 |
| FR2916447B1 (fr) * | 2007-05-25 | 2012-09-21 | Univ Picardie | Procede de production et utilisation de familles d'oligomeres d'acide galacturonique. |
| AU2010282167B2 (en) * | 2009-08-11 | 2015-02-12 | Fpinnovations | Fractionation of a waste liquor stream from nanocrystalline cellulose production |
| EP2672832B1 (de) | 2011-02-08 | 2020-03-25 | The Product Makers (Australia) Pty Ltd | Zuckerextrakte |
| US9253996B2 (en) | 2011-10-26 | 2016-02-09 | Frito-Lay North America, Inc. | Sustainable conversion of citrus peel waste |
| WO2014032100A1 (en) | 2012-08-28 | 2014-03-06 | Phytolin Pty Ltd | Extraction method |
| US10350259B2 (en) | 2013-08-16 | 2019-07-16 | The Product Makers (Australia) Pty Ltd | Sugar cane derived extracts and methods of treatment |
| WO2015187863A1 (en) | 2014-06-03 | 2015-12-10 | Putsch & Company, Inc. | Process for producing pulp from sugar beets |
| CN104744525B (zh) * | 2015-03-24 | 2017-03-01 | 浙江大学 | 一种以阿拉伯胶为原料提取制备高纯度l‑阿拉伯糖的工艺 |
| DK3356563T3 (da) * | 2015-10-02 | 2019-10-28 | Cooeperatie Koninklijke Cosun U A | Fremgangsmåder til berigelse af arabinose-fraktioner |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50148399A (de) * | 1974-05-17 | 1975-11-27 | ||
| JPS5611903A (en) * | 1979-06-11 | 1981-02-05 | Chisso Corp | Preparation of powdery pectin |
| US5008254A (en) * | 1982-09-03 | 1991-04-16 | Weibel Michael K | Sugar beet pectins and their use in comestibles |
| SE453511B (sv) * | 1986-06-10 | 1988-02-08 | Nils Monten | Sett att framstella en polysackaridbaserad konsistensgivare av pektintyp |
| DE3702653A1 (de) * | 1987-01-29 | 1988-08-11 | Sueddeutsche Zucker Ag | Verfahren zur herstellung von kristalliner l-arabinose |
| JPH04502339A (ja) * | 1988-12-05 | 1992-04-23 | ブリティシュ シュガー ピーエルシー | 非分岐アラバンおよびその脂質置換物としての使用 |
| JPH03149201A (ja) * | 1989-11-02 | 1991-06-25 | Atsushi Imai | ペクチンの製造方法 |
| US5952308A (en) | 1991-07-29 | 1999-09-14 | Pola Chemical Industries Inc. | Mineral absorption promoting agent |
| DK0552728T3 (da) | 1992-01-20 | 1999-11-15 | Japan Tobacco Inc | Hidtil ukendt pectinase |
| BE1006377A3 (fr) * | 1992-11-24 | 1994-08-09 | Raffinerie Tirlemontoise Sa | Procede de separation d'une composition polydispersee de saccharides, produits obtenus par ce procede et utilisation des produits obtenus dans des compositions alimentaires. |
| US5472952A (en) | 1993-03-18 | 1995-12-05 | Bristol-Myers Squibb Company | Partially hydrolyzed pectin in nutritional compositions |
| DE4313549C1 (de) * | 1993-04-26 | 1994-10-13 | Herbstreith & Fox Kg Pektin Fa | Verfahren zur Gewinnung von Pektin-Extrakt aus Zuckerrüben und dessen Verwendung |
| FI104500B (fi) * | 1997-08-26 | 2000-02-15 | Cultor Oyj | Menetelmä L-arabinoosin valmistamiseksi sokerijuurikasleikkeestä |
| FI105691B (fi) * | 1997-08-26 | 2000-09-29 | Sohkar Oy | Pektiinin ja sen sukulaisyhdisteiden valmistuksessa käyttökelpoinen raaka-aine ja menetelmä sen valmistamiseksi |
| KR100252194B1 (ko) * | 1997-10-10 | 2000-04-15 | 박호군 | 참당귀에서분리한신규한펙틴질다당류와그분리정제방법및그의면역증강제로서의용도 |
| FI113453B (fi) * | 1999-09-17 | 2004-04-30 | Sohkar Oy | Kasvimateriaalin kromatografinen fraktiointi |
-
1999
- 1999-09-17 FI FI991985A patent/FI113453B/fi active
-
2000
- 2000-09-15 JP JP2001524692A patent/JP2003509575A/ja active Pending
- 2000-09-15 CZ CZ2002799A patent/CZ295265B6/cs not_active IP Right Cessation
- 2000-09-15 HU HU0202872A patent/HUP0202872A3/hu unknown
- 2000-09-15 PL PL356680A patent/PL196962B1/pl not_active IP Right Cessation
- 2000-09-15 CA CA002385109A patent/CA2385109C/en not_active Expired - Fee Related
- 2000-09-15 AT AT00960708T patent/ATE448848T1/de not_active IP Right Cessation
- 2000-09-15 CA CA002384874A patent/CA2384874C/en not_active Expired - Fee Related
- 2000-09-15 AU AU72909/00A patent/AU7290900A/en not_active Abandoned
- 2000-09-15 WO PCT/FI2000/000780 patent/WO2001021272A1/en active IP Right Grant
- 2000-09-15 AU AU72910/00A patent/AU7291000A/en not_active Abandoned
- 2000-09-15 CZ CZ2002948A patent/CZ295865B6/cs not_active IP Right Cessation
- 2000-09-15 HU HU0203963A patent/HUP0203963A3/hu unknown
- 2000-09-15 EP EP00960709A patent/EP1227866A1/de not_active Withdrawn
- 2000-09-15 WO PCT/FI2000/000779 patent/WO2001021271A1/en active IP Right Grant
- 2000-09-15 JP JP2001524693A patent/JP2003509576A/ja active Pending
- 2000-09-15 PL PL353991A patent/PL196961B1/pl not_active IP Right Cessation
- 2000-09-15 EP EP00960708A patent/EP1218079B8/de not_active Expired - Lifetime
- 2000-09-15 DE DE60043347T patent/DE60043347D1/de not_active Expired - Lifetime
-
2002
- 2002-03-06 US US10/091,891 patent/US6660099B2/en not_active Expired - Fee Related
- 2002-03-06 US US10/091,892 patent/US6663717B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU7290900A (en) | 2001-04-24 |
| WO2001021271A1 (en) | 2001-03-29 |
| JP2003509576A (ja) | 2003-03-11 |
| CZ2002799A3 (cs) | 2002-08-14 |
| US20020189606A1 (en) | 2002-12-19 |
| PL356680A1 (en) | 2004-06-28 |
| FI19991985A (fi) | 2001-03-17 |
| ATE448848T1 (de) | 2009-12-15 |
| US6660099B2 (en) | 2003-12-09 |
| CA2385109A1 (en) | 2001-03-29 |
| EP1218079B1 (de) | 2009-11-18 |
| PL196962B1 (pl) | 2008-02-29 |
| CA2385109C (en) | 2008-12-23 |
| EP1218079A1 (de) | 2002-07-03 |
| CZ2002948A3 (cs) | 2002-09-11 |
| AU7291000A (en) | 2001-04-24 |
| EP1218079B8 (de) | 2010-01-06 |
| DE60043347D1 (de) | 2009-12-31 |
| EP1227866A1 (de) | 2002-08-07 |
| US6663717B2 (en) | 2003-12-16 |
| PL353991A1 (en) | 2003-12-15 |
| JP2003509575A (ja) | 2003-03-11 |
| US20020150652A1 (en) | 2002-10-17 |
| CA2384874A1 (en) | 2001-03-29 |
| HUP0203963A3 (en) | 2004-03-01 |
| CZ295865B6 (cs) | 2005-11-16 |
| WO2001021272A1 (en) | 2001-03-29 |
| HUP0202872A3 (en) | 2004-03-01 |
| HUP0203963A2 (hu) | 2003-04-28 |
| CZ295265B6 (cs) | 2005-06-15 |
| PL196961B1 (pl) | 2008-02-29 |
| CA2384874C (en) | 2008-12-23 |
| HUP0202872A2 (hu) | 2002-12-28 |
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