ES2950684T3 - Composiciones de polímero de siloxanilo reticulado - Google Patents
Composiciones de polímero de siloxanilo reticulado Download PDFInfo
- Publication number
- ES2950684T3 ES2950684T3 ES14720632T ES14720632T ES2950684T3 ES 2950684 T3 ES2950684 T3 ES 2950684T3 ES 14720632 T ES14720632 T ES 14720632T ES 14720632 T ES14720632 T ES 14720632T ES 2950684 T3 ES2950684 T3 ES 2950684T3
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- Prior art keywords
- polymer
- cross
- siloxanyl
- composite material
- hydroxyl
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims abstract description 210
- 125000005401 siloxanyl group Chemical group 0.000 title claims abstract description 112
- 239000000203 mixture Substances 0.000 title claims abstract description 106
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 73
- 229910052796 boron Inorganic materials 0.000 claims abstract description 73
- 150000001639 boron compounds Chemical class 0.000 claims abstract description 22
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 110
- 239000002131 composite material Substances 0.000 claims description 74
- 238000004132 cross linking Methods 0.000 claims description 65
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 58
- 150000001875 compounds Chemical class 0.000 claims description 57
- -1 polydiphenylsiloxane Polymers 0.000 claims description 56
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 50
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 40
- 239000000463 material Substances 0.000 claims description 36
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 34
- 239000011236 particulate material Substances 0.000 claims description 34
- 230000008569 process Effects 0.000 claims description 32
- 239000004327 boric acid Substances 0.000 claims description 30
- 239000003431 cross linking reagent Substances 0.000 claims description 28
- 239000008187 granular material Substances 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 17
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 14
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 229920002554 vinyl polymer Polymers 0.000 claims description 12
- 238000006482 condensation reaction Methods 0.000 claims description 8
- 239000004005 microsphere Substances 0.000 claims description 8
- KXJLGCBCRCSXQF-UHFFFAOYSA-N [diacetyloxy(ethyl)silyl] acetate Chemical compound CC(=O)O[Si](CC)(OC(C)=O)OC(C)=O KXJLGCBCRCSXQF-UHFFFAOYSA-N 0.000 claims description 7
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 7
- UQMGAWUIVYDWBP-UHFFFAOYSA-N silyl acetate Chemical class CC(=O)O[SiH3] UQMGAWUIVYDWBP-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
- TVJPBVNWVPUZBM-UHFFFAOYSA-N [diacetyloxy(methyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(OC(C)=O)OC(C)=O TVJPBVNWVPUZBM-UHFFFAOYSA-N 0.000 claims description 5
- 239000011324 bead Substances 0.000 claims description 5
- 239000005388 borosilicate glass Substances 0.000 claims description 5
- AJFXNBUVIBKWBT-UHFFFAOYSA-N disodium;boric acid;hydrogen borate Chemical compound [Na+].[Na+].OB(O)O.OB(O)O.OB(O)O.OB([O-])[O-] AJFXNBUVIBKWBT-UHFFFAOYSA-N 0.000 claims description 5
- 229920006037 cross link polymer Polymers 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- YZVRVDPMGYFCGL-UHFFFAOYSA-N triacetyloxysilyl acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)OC(C)=O YZVRVDPMGYFCGL-UHFFFAOYSA-N 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 125000004185 ester group Chemical group 0.000 claims description 3
- 239000004579 marble Substances 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 claims description 3
- YGHFDTDSFZTYBW-UHFFFAOYSA-N O-silylhydroxylamine Chemical class NO[SiH3] YGHFDTDSFZTYBW-UHFFFAOYSA-N 0.000 claims description 2
- IVHXEBVFCNBWED-UHFFFAOYSA-N prop-1-en-2-yloxysilane Chemical class CC(=C)O[SiH3] IVHXEBVFCNBWED-UHFFFAOYSA-N 0.000 claims description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 229920004482 WACKER® Polymers 0.000 description 30
- 239000002245 particle Substances 0.000 description 24
- 239000000126 substance Substances 0.000 description 20
- 239000000047 product Substances 0.000 description 17
- 239000000945 filler Substances 0.000 description 15
- 229920001296 polysiloxane Polymers 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 14
- 238000007792 addition Methods 0.000 description 13
- 239000000654 additive Substances 0.000 description 13
- 239000004971 Cross linker Substances 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 8
- 239000012467 final product Substances 0.000 description 7
- 125000000524 functional group Chemical group 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 230000033228 biological regulation Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000001723 curing Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000003534 oscillatory effect Effects 0.000 description 6
- 229920000151 polyglycol Polymers 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 239000010695 polyglycol Substances 0.000 description 5
- 230000008707 rearrangement Effects 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 238000010979 pH adjustment Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000013006 addition curing Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000013005 condensation curing Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 239000004945 silicone rubber Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 238000005903 acid hydrolysis reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- 229920005987 OPPANOL® Polymers 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012969 di-tertiary-butyl peroxide Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical compound C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 1
- 230000009982 effect on human Effects 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000004633 polyglycolic acid Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000010059 sulfur vulcanization Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/56—Boron-containing linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/55—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
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| GBGB1308072.6A GB201308072D0 (en) | 2013-05-03 | 2013-05-03 | Compositions and methods |
| PCT/EP2014/059019 WO2014177710A1 (en) | 2013-05-03 | 2014-05-02 | Crosslinked siloxanyl polymer compositions |
Publications (1)
| Publication Number | Publication Date |
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| ES2950684T3 true ES2950684T3 (es) | 2023-10-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES14720632T Active ES2950684T3 (es) | 2013-05-03 | 2014-05-02 | Composiciones de polímero de siloxanilo reticulado |
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| EP (1) | EP2992040B1 (https=) |
| JP (1) | JP6577457B2 (https=) |
| KR (1) | KR102344551B1 (https=) |
| CN (1) | CN105492501B (https=) |
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| PL (1) | PL2992040T3 (https=) |
| RU (1) | RU2680827C2 (https=) |
| WO (1) | WO2014177710A1 (https=) |
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| WO2015034692A1 (en) * | 2013-09-03 | 2015-03-12 | 3M Innovative Properties Company | Hydroxyl terminated pdms-borate acid putty as dental isolation material |
| AU2017249740B2 (en) | 2016-04-15 | 2020-03-05 | Delta Of Sweden Ab | Composition |
| CN107805311B (zh) * | 2016-09-09 | 2022-04-01 | 翁秋梅 | 一种具有杂化交联网络的动态聚合物及其应用 |
| CN107805308B (zh) * | 2016-09-09 | 2022-04-15 | 翁秋梅 | 一种具有杂化交联网络的动态聚合物及其应用 |
| CN107805309B (zh) * | 2016-09-09 | 2021-03-19 | 翁秋梅 | 一种非共价交联结构的动态聚合物及其应用 |
| JP6850973B2 (ja) * | 2016-11-07 | 2021-03-31 | 東京電力ホールディングス株式会社 | 自己修復機能を有する塗料 |
| CN108251095A (zh) * | 2016-12-29 | 2018-07-06 | 中国石油化工股份有限公司 | 一种有机硼交联剂及其制备方法和应用 |
| CN108341954A (zh) * | 2017-01-25 | 2018-07-31 | 翁秋梅 | 一种具有杂化交联结构的动态聚合物及其应用 |
| CN108341961B (zh) * | 2017-01-25 | 2023-08-25 | 厦门天策材料科技有限公司 | 一种含有组合动态共价键的动态聚合物制备及其应用 |
| CN108341951B (zh) * | 2017-01-25 | 2023-06-20 | 厦门天策材料科技有限公司 | 一种具有杂化交联结构的动态聚合物及其应用 |
| CN108341974A (zh) * | 2017-01-25 | 2018-07-31 | 翁秋梅 | 一种具有杂化交联结构的动态聚合物及其应用 |
| CN108342072A (zh) * | 2017-01-25 | 2018-07-31 | 翁秋梅 | 一种具有杂化交联结构的动态聚合物及其应用 |
| CN108342062A (zh) * | 2017-01-25 | 2018-07-31 | 翁秋梅 | 一种杂化动态聚合物组成及其应用 |
| CN107163584B (zh) * | 2017-05-23 | 2020-07-03 | 义乌聚邦玩具有限公司 | 凝胶状材料及其制备方法与应用 |
| WO2019018147A1 (en) * | 2017-07-19 | 2019-01-24 | Avantor Performance Materials, Llc | CURABLE COMPOSITION OF ORGANOPOLYSILOXANE CONTAINING DYNAMIC COVALENT POLYSILOXANE |
| WO2019023837A1 (en) | 2017-07-31 | 2019-02-07 | Dow Silicones Corporation | HANDLING ADDITIVE FOR SILICONE ELASTOMERS |
| CN107474544B (zh) * | 2017-08-29 | 2020-12-22 | 湖南御邦华安新材料科技有限公司 | 一种轻质剪切增稠凝胶及其制备方法 |
| US11891484B2 (en) | 2019-09-17 | 2024-02-06 | Crayola Llc | Putty and putty base compounds and methods of making thereof |
| CN111286199B (zh) * | 2020-03-20 | 2022-04-05 | 宁波俊瑆玩具科技有限公司 | 一种高弹性高韧性康复胶 |
| CN116157485A (zh) * | 2021-04-27 | 2023-05-23 | 美国陶氏有机硅公司 | 自由基固化的有机硅压敏粘合剂和组合物及其制备方法以及在柔性显示设备中的用途 |
| CN116249734B (zh) * | 2021-04-27 | 2025-06-13 | 美国陶氏有机硅公司 | 形成粘附到光学有机硅弹性体的有机硅压敏粘合剂的硅氢加成反应可固化组合物及其制备和在柔性显示设备中的使用方法 |
| EP4086300A1 (en) * | 2021-05-07 | 2022-11-09 | Oulun Yliopisto | Self-healing elastomers and method of making the same |
| EP4086301A1 (en) * | 2021-05-07 | 2022-11-09 | Oulun Yliopisto | Self-healing elastomers and method of making the same |
| CN113583447A (zh) * | 2021-08-18 | 2021-11-02 | 常州市诺普新材料有限公司 | 有机硅增强助剂及其制备方法以及有机硅材料 |
| CN117701079B (zh) * | 2023-12-15 | 2025-09-05 | 河南省科学院化学研究所 | 一种pH诱导限域固-液转变自修复涂层材料 |
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| US2431878A (en) | 1943-03-30 | 1947-12-02 | Corning Glass Works | Treating dimethyl silicone polymer with boric oxide |
| US2541851A (en) | 1944-12-23 | 1951-02-13 | Gen Electric | Process for making puttylike elastic plastic, siloxane derivative composition containing zinc hydroxide |
| US2568672A (en) | 1948-03-29 | 1951-09-18 | Dow Corning | Methyl siloxane rubber |
| US3177176A (en) | 1961-10-02 | 1965-04-06 | Gen Electric | Adding silica prior to condensation of boron-polysiloxane |
| DE2005530C3 (de) | 1970-02-06 | 1975-03-27 | Wacker-Chemie Gmbh, 8000 Muenchen | Springkitte |
| SU423816A1 (ru) * | 1972-08-07 | 1974-04-15 | Б. М. Андреев, М. П. Гринблат, В. В. Корольке , В. Н. Пронс | Способ отверждения диорганополисилоксанов € концевыми гидроксильными группами |
| DE2829045A1 (de) | 1978-07-01 | 1980-01-10 | Degussa | Borhaltige faellungskieselsaeure |
| US4371493A (en) | 1980-09-02 | 1983-02-01 | Minuto Maurice A | Method of making bouncing silicone putty-like compositions |
| US5319021A (en) | 1990-11-01 | 1994-06-07 | Christy George M | Organosilicone composition |
| JPH0737575B2 (ja) * | 1991-06-27 | 1995-04-26 | 信越化学工業株式会社 | シリコーンパテ組成物 |
| US5607993A (en) | 1993-02-16 | 1997-03-04 | North Coast Medical, Inc. | Low-density bouncing putty |
| WO2006070674A1 (en) | 2004-12-27 | 2006-07-06 | Dow Corning Toray Co., Ltd. | Vibration-damping silicone composition |
| SE529971C2 (sv) | 2005-03-23 | 2008-01-22 | Delta Of Sweden Ab | Materialblandning innefattande partiklar eller korn samt ett bindemedel bestående av minst två komponenter |
| JP5121831B2 (ja) | 2006-08-17 | 2013-01-16 | ラムラット リミテッド | 組成物及びその製造方法 |
| TWI502004B (zh) | 2009-11-09 | 2015-10-01 | Dow Corning | 群集官能性聚有機矽氧烷之製法及其使用方法 |
| BR112012016074A2 (pt) * | 2009-12-31 | 2016-08-16 | Oxane Materials Inc | método para produzir uma partícula de cerâmica contendo micro-esfera ou poro, partícula cerâmica contendo micro-esfera ou poro, método para escorar fraturas abertas de formações subterrâneas, método para tratar zonas produtoras subterrâneas, método para produzir propantes, método para produzir formadores de micro-esfera ou poro, formador de micro-esfera ou poro, método para produzir um artigo de vidro-cerâmico, cerâmica, metal, ou combinações destes, artigo de vidro-cerâmico, cerâmica, metal, ou combinações destes, propante cerâmico contendo micro-esfera ou poro e material cerâmico. |
| WO2011112699A1 (en) * | 2010-03-09 | 2011-09-15 | University Of Virginia Patent Foundation | Viscoelastic silicone rubber compositions |
| RU2473216C1 (ru) * | 2011-05-27 | 2013-01-27 | Владимир Игоревич Мащенко | Способ получения масс для лепки с биоцидными свойствами |
| WO2013023174A1 (en) | 2011-08-10 | 2013-02-14 | University Of Virginia Patent Foundation | Viscoelastic silicone rubber compositions |
| GB2535217B (en) * | 2015-02-13 | 2019-10-09 | Delta Of Sweden Ab | Modelling compound |
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| JP6577457B2 (ja) | 2019-09-18 |
| EP2992040A1 (en) | 2016-03-09 |
| CA2911331A1 (en) | 2014-11-06 |
| EP2992040C0 (en) | 2023-06-28 |
| PL2992040T3 (pl) | 2023-10-09 |
| BR112015027755B1 (pt) | 2022-02-01 |
| US10266659B2 (en) | 2019-04-23 |
| BR112015027755A2 (https=) | 2014-11-06 |
| JP2016520690A (ja) | 2016-07-14 |
| BR112015027755A8 (pt) | 2017-08-29 |
| AU2014261363B2 (en) | 2017-03-30 |
| WO2014177710A1 (en) | 2014-11-06 |
| EP2992040B1 (en) | 2023-06-28 |
| CN105492501B (zh) | 2021-05-07 |
| RU2015149341A (ru) | 2017-06-08 |
| CA2911331C (en) | 2021-02-16 |
| CN105492501A (zh) | 2016-04-13 |
| KR20160041851A (ko) | 2016-04-18 |
| AU2014261363A1 (en) | 2015-12-10 |
| RU2680827C2 (ru) | 2019-02-28 |
| KR102344551B1 (ko) | 2021-12-29 |
| GB201308072D0 (en) | 2013-06-12 |
| US20160130405A1 (en) | 2016-05-12 |
| MX2015015191A (es) | 2016-06-06 |
| MX385131B (es) | 2025-03-14 |
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