ES2927109T3 - Materiales de cátodo de óxido de litio y metal mejorados y método para fabricarlos - Google Patents
Materiales de cátodo de óxido de litio y metal mejorados y método para fabricarlos Download PDFInfo
- Publication number
- ES2927109T3 ES2927109T3 ES15724497T ES15724497T ES2927109T3 ES 2927109 T3 ES2927109 T3 ES 2927109T3 ES 15724497 T ES15724497 T ES 15724497T ES 15724497 T ES15724497 T ES 15724497T ES 2927109 T3 ES2927109 T3 ES 2927109T3
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- Prior art keywords
- lithium metal
- metal oxide
- precursor
- particles
- olm
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- 229910021450 lithium metal oxide Inorganic materials 0.000 title claims abstract description 67
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000010406 cathode material Substances 0.000 title claims description 12
- 239000002243 precursor Substances 0.000 claims abstract description 98
- 239000002245 particle Substances 0.000 claims abstract description 65
- 239000011163 secondary particle Substances 0.000 claims abstract description 65
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 56
- 238000000034 method Methods 0.000 claims abstract description 53
- 239000011164 primary particle Substances 0.000 claims abstract description 37
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 20
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 12
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052744 lithium Inorganic materials 0.000 claims description 37
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 35
- 239000001301 oxygen Substances 0.000 claims description 35
- 229910052760 oxygen Inorganic materials 0.000 claims description 35
- 239000000203 mixture Substances 0.000 claims description 33
- 238000010438 heat treatment Methods 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 13
- 239000012697 Mn precursor Substances 0.000 claims description 8
- 239000011888 foil Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 5
- 230000007423 decrease Effects 0.000 claims description 4
- 230000036961 partial effect Effects 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract description 13
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001947 lithium oxide Inorganic materials 0.000 abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 95
- 239000011572 manganese Substances 0.000 description 64
- 241000400041 Proteidae Species 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 23
- 239000007787 solid Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000007788 liquid Substances 0.000 description 15
- -1 oxides Chemical class 0.000 description 13
- 238000009826 distribution Methods 0.000 description 12
- 238000011068 loading method Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 238000003801 milling Methods 0.000 description 8
- 238000001694 spray drying Methods 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- GEYXPJBPASPPLI-UHFFFAOYSA-N manganese(iii) oxide Chemical compound O=[Mn]O[Mn]=O GEYXPJBPASPPLI-UHFFFAOYSA-N 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 235000021317 phosphate Nutrition 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000008151 electrolyte solution Substances 0.000 description 6
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- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
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- 125000006850 spacer group Chemical group 0.000 description 5
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
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- 229910003002 lithium salt Inorganic materials 0.000 description 4
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 3
- 239000010405 anode material Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 3
- 229910052808 lithium carbonate Inorganic materials 0.000 description 3
- 235000006748 manganese carbonate Nutrition 0.000 description 3
- 239000011656 manganese carbonate Substances 0.000 description 3
- 229940093474 manganese carbonate Drugs 0.000 description 3
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 3
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 3
- 238000009782 nail-penetration test Methods 0.000 description 3
- 229910021508 nickel(II) hydroxide Inorganic materials 0.000 description 3
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- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
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- 229910052783 alkali metal Inorganic materials 0.000 description 2
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- 239000007900 aqueous suspension Substances 0.000 description 2
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- 238000006243 chemical reaction Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
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- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
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- 229910000733 Li alloy Inorganic materials 0.000 description 1
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- 229910000552 LiCF3SO3 Inorganic materials 0.000 description 1
- 229910013191 LiMO2 Inorganic materials 0.000 description 1
- 229910013385 LiN(SO2C2F5)2 Inorganic materials 0.000 description 1
- 229910012748 LiNi0.5Mn0.3Co0.2O2 Inorganic materials 0.000 description 1
- 229910013876 LiPF2 Inorganic materials 0.000 description 1
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 241000364021 Tulsa Species 0.000 description 1
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- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
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- 229940011182 cobalt acetate Drugs 0.000 description 1
- UUCGKVQSSPTLOY-UHFFFAOYSA-J cobalt(2+);nickel(2+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Co+2].[Ni+2] UUCGKVQSSPTLOY-UHFFFAOYSA-J 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 description 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
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- 229910052906 cristobalite Inorganic materials 0.000 description 1
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- VJYFKVYYMZPMAB-UHFFFAOYSA-N ethoprophos Chemical compound CCCSP(=O)(OCC)SCCC VJYFKVYYMZPMAB-UHFFFAOYSA-N 0.000 description 1
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
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- NPLZZSLZTJVZSX-UHFFFAOYSA-L iron(2+);oxalate;dihydrate Chemical compound O.O.[Fe+2].[O-]C(=O)C([O-])=O NPLZZSLZTJVZSX-UHFFFAOYSA-L 0.000 description 1
- 238000010902 jet-milling Methods 0.000 description 1
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- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- DVATZODUVBMYHN-UHFFFAOYSA-K lithium;iron(2+);manganese(2+);phosphate Chemical compound [Li+].[Mn+2].[Fe+2].[O-]P([O-])([O-])=O DVATZODUVBMYHN-UHFFFAOYSA-K 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
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- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 1
- ZWXOQTHCXRZUJP-UHFFFAOYSA-N manganese(2+);manganese(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Mn+2].[Mn+3].[Mn+3] ZWXOQTHCXRZUJP-UHFFFAOYSA-N 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical group [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
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- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
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- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
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- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical class O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 238000000352 supercritical drying Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical group [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
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- H01M4/02—Electrodes composed of, or comprising, active material
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- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
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- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- H—ELECTRICITY
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- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
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- C01P2002/52—Solid solutions containing elements as dopants
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- C—CHEMISTRY; METALLURGY
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
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- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
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- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H—ELECTRICITY
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-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
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- Organic Chemistry (AREA)
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- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Cell Electrode Carriers And Collectors (AREA)
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| JP6650956B2 (ja) * | 2018-02-01 | 2020-02-19 | Ｊｘ金属株式会社 | リチウムイオン電池用正極活物質、リチウムイオン電池及びリチウムイオン電池用正極活物質の製造方法 |
| CN108428888B (zh) * | 2018-03-26 | 2021-06-11 | 安徽同心新材料科技有限公司 | 一种球形表面密实镍钴铝三元材料、其前驱体及其制备方法和应用 |
| US10787368B2 (en) * | 2018-06-06 | 2020-09-29 | Basf Corporation | Process for producing lithiated transition metal oxides |
| CN109768273A (zh) * | 2018-12-17 | 2019-05-17 | 中南大学 | 一种锂电池正极材料及其制备方法 |
| JP6651604B1 (ja) * | 2018-12-20 | 2020-02-19 | 住友化学株式会社 | リチウム二次電池用正極活物質前駆体、リチウム二次電池用正極活物質前駆体の製造方法、及びリチウム二次電池用正極活物質の製造方法 |
| JP2022546264A (ja) * | 2019-08-29 | 2022-11-04 | ノボニクス バッテリー テクノロジー ソリューションズ インコーポレイテッド | 改善されたミクロ粒状化法及びその製品粒子 |
| CN110492097B (zh) * | 2019-08-30 | 2021-04-27 | 中南大学 | 一种ncm三元复合正极材料及其制备和应用 |
| WO2021174480A1 (zh) | 2020-03-05 | 2021-09-10 | 宁德新能源科技有限公司 | 正极材料和包括其的电化学装置及电子装置 |
| CN115836414A (zh) * | 2020-05-29 | 2023-03-21 | 密执安州立大学董事会 | 用于锂电池快速充电的离子导电涂层的原子层沉积法 |
| CN112456560B (zh) * | 2020-12-09 | 2023-03-21 | 安徽科技学院 | 一种纳米颗粒自组装形成的二维锰氧化物材料的制备方法 |
| WO2022200766A1 (en) * | 2021-03-24 | 2022-09-29 | Ev Metals Uk Limited | Process for producing an electrochemically active oxide material |
| EP4095102A1 (en) * | 2021-05-28 | 2022-11-30 | Basf Se | Process for making a particulate electrode active material, and electrode active material |
| CN113839025B (zh) * | 2021-09-24 | 2023-06-16 | 四川朗晟新能源科技有限公司 | 一种锂离子电池高镍三元正极材料及其改性方法 |
| EP4441823A1 (en) * | 2021-12-03 | 2024-10-09 | Sylvatex, Inc. | Method for the manufacture of cathode materials |
| EP4439726A4 (en) * | 2022-08-04 | 2025-07-23 | Lg Energy Solution Ltd | LITHIUM SECONDARY BATTERY, BATTERY MODULE AND BATTERY PACK |
| KR20240037680A (ko) * | 2022-09-15 | 2024-03-22 | 주식회사 엘지화학 | 양극 활물질 전구체의 제조 방법 |
| WO2025065466A1 (en) * | 2023-09-28 | 2025-04-03 | Wildcat Discovery Technologies, Inc. | Anionic redox high energy cathodes |
| CN117923563A (zh) * | 2023-12-15 | 2024-04-26 | 中伟新材料股份有限公司 | 高振实密度小粒径正极材料前驱体、正极材料及制备方法、锂离子电池和涉电设备 |
| CN121641952A (zh) * | 2024-08-30 | 2026-03-10 | 宁德时代新能源科技股份有限公司 | 电池单体及其制备方法、用电装置 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5393622A (en) | 1992-02-07 | 1995-02-28 | Matsushita Electric Industrial Co., Ltd. | Process for production of positive electrode active material |
| JP3846601B2 (ja) | 1996-06-13 | 2006-11-15 | 株式会社ジーエス・ユアサコーポレーション | リチウム電池用正極活物質およびその製造方法ならびに前記活物質を備えた電池 |
| TW363940B (en) | 1996-08-12 | 1999-07-11 | Toda Kogyo Corp | A lithium-nickle-cobalt compound oxide, process thereof and anode active substance for storage battery |
| US5858324A (en) | 1997-04-17 | 1999-01-12 | Minnesota Mining And Manufacturing Company | Lithium based compounds useful as electrodes and method for preparing same |
| JP3524762B2 (ja) | 1998-03-19 | 2004-05-10 | 三洋電機株式会社 | リチウム二次電池 |
| JPH11307094A (ja) | 1998-04-20 | 1999-11-05 | Chuo Denki Kogyo Co Ltd | リチウム二次電池用正極活物質とリチウム二次電池 |
| US6168887B1 (en) | 1999-01-15 | 2001-01-02 | Chemetals Technology Corporation | Layered lithium manganese oxide bronze and electrodes thereof |
| JP3649953B2 (ja) | 1999-06-23 | 2005-05-18 | 三洋電機株式会社 | 活物質、電極、非水電解液二次電池及び活物質の製造方法 |
| KR100653170B1 (ko) | 1999-07-07 | 2006-12-04 | 쇼와 덴코 가부시키가이샤 | 정극활물질, 그 제조방법 및 2차전지 |
| EP1295851A4 (en) | 2000-11-16 | 2008-08-20 | Hitachi Maxell | LITHIUM-COMPOSITOXIDE AND NON-Aqueous SECONDARY CELL THEREFOR, AND METHOD FOR THE PRODUCTION THEREOF |
| US7592100B2 (en) | 2001-03-22 | 2009-09-22 | Panasonic Corporation | Positive-electrode active material and nonaqueous-electrolyte secondary battery containing the same |
| US6964828B2 (en) | 2001-04-27 | 2005-11-15 | 3M Innovative Properties Company | Cathode compositions for lithium-ion batteries |
| JP4172622B2 (ja) * | 2002-04-11 | 2008-10-29 | 日鉱金属株式会社 | リチウム含有複合酸化物並びにその製造方法 |
| EP1555711B1 (en) | 2002-10-22 | 2011-12-21 | Mitsubishi Chemical Corporation | Nonaqueous electrolytic solution and nonaqueous electrolyte secondary battery containing the same |
| JP4740409B2 (ja) * | 2003-06-11 | 2011-08-03 | 株式会社日立製作所 | 電気自動車或いはハイブリット自動車用リチウム二次電池 |
| US7211237B2 (en) | 2003-11-26 | 2007-05-01 | 3M Innovative Properties Company | Solid state synthesis of lithium ion battery cathode material |
| US7482382B2 (en) | 2004-05-19 | 2009-01-27 | The Texas A&M University System | Process for preparing nano-sized metal oxide particles |
| JP4984413B2 (ja) | 2005-03-28 | 2012-07-25 | 三菱化学株式会社 | リチウム二次電池用リチウム遷移金属複合酸化物の製造方法、並びに、リチウム二次電池用リチウム遷移金属複合酸化物、リチウム二次電池用正極及びリチウム二次電池 |
| CN100547829C (zh) * | 2005-07-01 | 2009-10-07 | 深圳市比克电池有限公司 | 锂复合金属氧化物的制备方法 |
| JP4979319B2 (ja) * | 2005-09-29 | 2012-07-18 | Ａｇｃセイミケミカル株式会社 | リチウム含有複合酸化物の製造方法 |
| US9177689B2 (en) * | 2007-01-29 | 2015-11-03 | Umicore | High density and high voltage stable cathode materials for secondary batteries |
| CN101707252B (zh) * | 2009-11-09 | 2012-01-25 | 深圳市振华新材料股份有限公司 | 多晶钴镍锰三元正极材料及其制备方法、二次锂离子电池 |
| WO2012108513A1 (ja) * | 2011-02-09 | 2012-08-16 | 旭硝子株式会社 | リチウムイオン二次電池用の正極活物質の製造方法 |
| JP2012221855A (ja) * | 2011-04-12 | 2012-11-12 | Sony Corp | 非水電解質電池用正極活物質、非水電解質電池用正極および非水電解質電池、ならびに非水電解質電池を用いた電池パック、電子機器、電動車両、蓄電装置および電力システム |
| JP2013098047A (ja) * | 2011-11-01 | 2013-05-20 | Nissan Motor Co Ltd | 正極活物質の製造方法 |
| JP5861992B2 (ja) | 2011-11-09 | 2016-02-16 | 株式会社Ｇｓユアサ | 非水電解質二次電池用活物質、その活物質の製造方法、非水電解質二次電池用電極及び非水電解質二次電池 |
| KR101443359B1 (ko) * | 2012-07-20 | 2014-09-23 | 주식회사 포스코이에스엠 | 니켈 함량이 높은 리튬-니켈-코발트-망간계 복합 산화물의 제조 방법, 이에 의하여 제조된 니켈 함량이 높은 리튬-니켈-코발트-망간계 복합 산화물, 및 이를 포함하는 리튬 이차 전지 |
| JP6088923B2 (ja) * | 2012-09-04 | 2017-03-01 | 日本碍子株式会社 | リチウム二次電池用正極活物質又はその前駆体の製造方法 |
| CN107021528B (zh) * | 2012-09-28 | 2019-04-02 | 住友金属矿山株式会社 | 镍钴复合氢氧化物的制造方法以及制造装置 |
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2015
- 2015-05-14 ES ES15724497T patent/ES2927109T3/es active Active
- 2015-05-14 CN CN201580026085.3A patent/CN106458635B/zh active Active
- 2015-05-14 EP EP15724497.1A patent/EP3154909B1/en active Active
- 2015-05-14 KR KR1020167035074A patent/KR102425305B1/ko active Active
- 2015-05-14 WO PCT/US2015/030746 patent/WO2015183568A1/en not_active Ceased
- 2015-05-14 US US15/311,863 patent/US11205776B2/en active Active
- 2015-05-14 JP JP2016567492A patent/JP6835593B2/ja active Active
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2019
- 2019-08-19 JP JP2019149663A patent/JP2020002006A/ja not_active Withdrawn
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20170013287A (ko) | 2017-02-06 |
| EP3154909A1 (en) | 2017-04-19 |
| KR102425305B1 (ko) | 2022-07-27 |
| CN106458635B (zh) | 2018-04-24 |
| JP2020002006A (ja) | 2020-01-09 |
| JP2017517847A (ja) | 2017-06-29 |
| JP2022008817A (ja) | 2022-01-14 |
| JP7539358B2 (ja) | 2024-08-23 |
| US20170084919A1 (en) | 2017-03-23 |
| WO2015183568A1 (en) | 2015-12-03 |
| CN106458635A (zh) | 2017-02-22 |
| EP3154909B1 (en) | 2022-08-10 |
| US11205776B2 (en) | 2021-12-21 |
| JP6835593B2 (ja) | 2021-02-24 |
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