ES2608102T3 - Partícula expandible de polímero a base de poliuretano - Google Patents
Partícula expandible de polímero a base de poliuretano Download PDFInfo
- Publication number
- ES2608102T3 ES2608102T3 ES13734102.0T ES13734102T ES2608102T3 ES 2608102 T3 ES2608102 T3 ES 2608102T3 ES 13734102 T ES13734102 T ES 13734102T ES 2608102 T3 ES2608102 T3 ES 2608102T3
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- tpu
- polymerization
- polymer
- polymer particles
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- 229920000642 polymer Polymers 0.000 title claims abstract description 99
- 239000002245 particle Substances 0.000 title claims abstract description 46
- 229920002635 polyurethane Polymers 0.000 title description 9
- 239000004814 polyurethane Substances 0.000 title description 8
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 112
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 99
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 35
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 18
- 238000010526 radical polymerization reaction Methods 0.000 claims abstract description 18
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 36
- 239000006260 foam Substances 0.000 claims description 33
- 239000000178 monomer Substances 0.000 claims description 33
- 239000003380 propellant Substances 0.000 claims description 25
- 239000000126 substance Substances 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 20
- 150000003254 radicals Chemical class 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 15
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 11
- 239000004793 Polystyrene Substances 0.000 claims description 9
- 229920002223 polystyrene Polymers 0.000 claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 7
- 230000008961 swelling Effects 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 3
- 239000007900 aqueous suspension Substances 0.000 claims description 3
- 150000001451 organic peroxides Chemical class 0.000 claims description 3
- 239000003505 polymerization initiator Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 2
- 239000012757 flame retardant agent Substances 0.000 claims description 2
- 230000009477 glass transition Effects 0.000 claims description 2
- 238000010348 incorporation Methods 0.000 claims description 2
- 239000011810 insulating material Substances 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
- OZCRKDNRAAKDAN-UHFFFAOYSA-N but-1-ene-1,4-diol Chemical compound O[CH][CH]CCO OZCRKDNRAAKDAN-UHFFFAOYSA-N 0.000 claims 1
- 239000000084 colloidal system Substances 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 29
- 239000000203 mixture Substances 0.000 description 27
- 239000012948 isocyanate Substances 0.000 description 19
- -1 4.4 ' - Chemical class 0.000 description 18
- 150000002513 isocyanates Chemical class 0.000 description 18
- 239000000463 material Substances 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 15
- 239000008187 granular material Substances 0.000 description 15
- 239000003054 catalyst Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 11
- 239000004794 expanded polystyrene Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 229920006347 Elastollan Polymers 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 239000004721 Polyphenylene oxide Substances 0.000 description 9
- 229920000570 polyether Polymers 0.000 description 9
- 238000003860 storage Methods 0.000 description 9
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 8
- XZTWHWHGBBCSMX-UHFFFAOYSA-J dimagnesium;phosphonato phosphate Chemical compound [Mg+2].[Mg+2].[O-]P([O-])(=O)OP([O-])([O-])=O XZTWHWHGBBCSMX-UHFFFAOYSA-J 0.000 description 8
- 239000003063 flame retardant Substances 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 235000019589 hardness Nutrition 0.000 description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000000454 talc Substances 0.000 description 6
- 235000012222 talc Nutrition 0.000 description 6
- 229910052623 talc Inorganic materials 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 125000005442 diisocyanate group Chemical group 0.000 description 5
- 150000002009 diols Chemical class 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000012963 UV stabilizer Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 229960005150 glycerol Drugs 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920006393 polyether sulfone Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- QDOXQIRWYQMOKT-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione;styrene Chemical compound C=CC1=CC=CC=C1.O=C1C=CC(=O)N1C1=CC=CC=C1 QDOXQIRWYQMOKT-UHFFFAOYSA-N 0.000 description 2
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 2
- 229920006329 Styropor Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001728 carbonyl compounds Chemical class 0.000 description 2
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
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- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002314 glycerols Chemical class 0.000 description 2
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 2
- 229920012128 methyl methacrylate acrylonitrile butadiene styrene Polymers 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 150000003018 phosphorus compounds Chemical class 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
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- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
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- 239000005020 polyethylene terephthalate Substances 0.000 description 2
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- 239000003223 protective agent Substances 0.000 description 2
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- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 2
- 229960003656 ricinoleic acid Drugs 0.000 description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229910001927 ruthenium tetroxide Inorganic materials 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 229960004274 stearic acid Drugs 0.000 description 2
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- 239000012747 synergistic agent Substances 0.000 description 2
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
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- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 1
- QVCUKHQDEZNNOC-UHFFFAOYSA-N 1,2-diazabicyclo[2.2.2]octane Chemical compound C1CC2CCN1NC2 QVCUKHQDEZNNOC-UHFFFAOYSA-N 0.000 description 1
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
- XSCLFFBWRKTMTE-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)cyclohexane Chemical compound O=C=NCC1CCCC(CN=C=O)C1 XSCLFFBWRKTMTE-UHFFFAOYSA-N 0.000 description 1
- SXMPQZFGMQBFMT-UHFFFAOYSA-N 1,3-dihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(O)CCO SXMPQZFGMQBFMT-UHFFFAOYSA-N 0.000 description 1
- IKYNWXNXXHWHLL-UHFFFAOYSA-N 1,3-diisocyanatopropane Chemical compound O=C=NCCCN=C=O IKYNWXNXXHWHLL-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- UTFSEWQOIIZLRH-UHFFFAOYSA-N 1,7-diisocyanatoheptane Chemical compound O=C=NCCCCCCCN=C=O UTFSEWQOIIZLRH-UHFFFAOYSA-N 0.000 description 1
- QUPKOUOXSNGVLB-UHFFFAOYSA-N 1,8-diisocyanatooctane Chemical compound O=C=NCCCCCCCCN=C=O QUPKOUOXSNGVLB-UHFFFAOYSA-N 0.000 description 1
- NUIPOEWADWHGSP-UHFFFAOYSA-N 1-hydroxypropyl 2-methylprop-2-enoate Chemical compound CCC(O)OC(=O)C(C)=C NUIPOEWADWHGSP-UHFFFAOYSA-N 0.000 description 1
- BPMBELVMIAUTNV-UHFFFAOYSA-N 2,2-dihydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(O)O BPMBELVMIAUTNV-UHFFFAOYSA-N 0.000 description 1
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 1
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- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
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- KNXVOGGZOFOROK-UHFFFAOYSA-N trimagnesium;dioxido(oxo)silane;hydroxy-oxido-oxosilane Chemical compound [Mg+2].[Mg+2].[Mg+2].O[Si]([O-])=O.O[Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O KNXVOGGZOFOROK-UHFFFAOYSA-N 0.000 description 1
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- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/14—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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Landscapes
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- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
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| EP12175270.3A EP2682427A1 (de) | 2012-07-06 | 2012-07-06 | Polyurethan basierte expandierbare Polymerpartikel |
| EP12175270 | 2012-07-06 | ||
| PCT/EP2013/064248 WO2014006182A1 (de) | 2012-07-06 | 2013-07-05 | Polyurethan basierte expandierbare polymerpartikel |
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| US9598548B2 (en) | 2012-08-09 | 2017-03-21 | Basf Se | Producing polymer foams comprising imide groups |
| WO2014023794A1 (de) | 2012-08-09 | 2014-02-13 | Basf Se | Kombinationsschaum |
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| DE102013202291C5 (de) | 2013-02-13 | 2026-01-15 | Adidas Ag | Dämpfungselement für Sportbekleidung und Schuh mit einem solchen Dämpfungselement |
| US9610746B2 (en) | 2013-02-13 | 2017-04-04 | Adidas Ag | Methods for manufacturing cushioning elements for sports apparel |
| ES2684020T3 (es) * | 2013-03-20 | 2018-10-01 | Basf Se | Composición de polímero a base de poliuretano |
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| RU2017101855A (ru) * | 2014-06-23 | 2018-07-24 | Ковестро Дойчланд Аг | Применение порошков термопластичных полиуретанов |
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| DE102014216115B4 (de) | 2014-08-13 | 2022-03-31 | Adidas Ag | Gemeinsam gegossene 3D Elemente |
| DE102015202013B4 (de) | 2015-02-05 | 2019-05-09 | Adidas Ag | Verfahren zur Herstellung eines Kunststoffformteils, Kunststoffformteil und Schuh |
| US11161956B2 (en) * | 2015-03-13 | 2021-11-02 | Bafs Se | Method for producing particle foams based on thermoplastic elastomers, by thermal bonding using microwaves |
| JP6679363B2 (ja) | 2015-03-23 | 2020-04-15 | アディダス アーゲー | ソールおよびシューズ |
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| DE102015209795B4 (de) | 2015-05-28 | 2024-03-21 | Adidas Ag | Ball und Verfahren zu dessen Herstellung |
| USD783264S1 (en) | 2015-09-15 | 2017-04-11 | Adidas Ag | Shoe |
| CN105348665A (zh) * | 2015-12-11 | 2016-02-24 | 绍兴文理学院元培学院 | 一种复合tpu与eps的可发性树脂及其制备方法 |
| DE102016209045B4 (de) | 2016-05-24 | 2022-05-25 | Adidas Ag | Verfahren und vorrichtung zum automatischen herstellen von schuhsohlen, sohlen und schuhe |
| DE102016209044B4 (de) | 2016-05-24 | 2019-08-29 | Adidas Ag | Sohlenform zum Herstellen einer Sohle und Anordnung einer Vielzahl von Sohlenformen |
| DE102016209046B4 (de) | 2016-05-24 | 2019-08-08 | Adidas Ag | Verfahren zur herstellung einer schuhsohle, schuhsohle, schuh und vorgefertigte tpu-gegenstände |
| USD840137S1 (en) | 2016-08-03 | 2019-02-12 | Adidas Ag | Shoe midsole |
| USD840136S1 (en) | 2016-08-03 | 2019-02-12 | Adidas Ag | Shoe midsole |
| USD852475S1 (en) | 2016-08-17 | 2019-07-02 | Adidas Ag | Shoe |
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| DE102016223980B4 (de) | 2016-12-01 | 2022-09-22 | Adidas Ag | Verfahren zur Herstellung eines Kunststoffformteils |
| USD850766S1 (en) | 2017-01-17 | 2019-06-11 | Puma SE | Shoe sole element |
| DE102017205830B4 (de) | 2017-04-05 | 2020-09-24 | Adidas Ag | Verfahren für die Nachbehandlung einer Vielzahl einzelner expandierter Partikel für die Herstellung mindestens eines Teils eines gegossenen Sportartikels, Sportartikel und Sportschuh |
| JP6912317B2 (ja) * | 2017-08-03 | 2021-08-04 | 株式会社ジェイエスピー | ウレタン系熱可塑性エラストマー発泡粒子 |
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| CN111212869B (zh) * | 2017-10-10 | 2023-09-29 | 巴斯夫欧洲公司 | 弹性膜 |
| FR3073539B1 (fr) * | 2017-11-13 | 2020-05-15 | Gerflor | Panneau rigide pour la realisation d'un revetement de sol |
| WO2019202095A1 (de) * | 2018-04-20 | 2019-10-24 | Basf Se | Schaumstoffe auf basis thermoplastischer elastomere |
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| JP7157880B2 (ja) | 2018-12-18 | 2022-10-20 | プーマ エス イー | 靴、特に運動靴、及び該靴を作製する方法 |
| DE102019204579B4 (de) | 2019-04-01 | 2022-10-06 | Adidas Ag | Recycling eines Schuhs |
| CN111234506A (zh) * | 2020-03-19 | 2020-06-05 | 保士特（东莞）塑胶制品有限公司 | 一种可降解塑料紧固胶针及其制备方法 |
| USD944504S1 (en) | 2020-04-27 | 2022-03-01 | Puma SE | Shoe |
| CN112961399B (zh) * | 2021-03-17 | 2021-12-07 | 华东理工大学 | 一种阻燃隔热各向异性复合多孔材料及其制备方法和应用 |
| CN113621304B (zh) * | 2021-08-06 | 2022-03-18 | 浙江禾欣科技有限公司 | 一种自消光水性聚氨酯树脂及其制备方法 |
| WO2023061871A1 (en) * | 2021-10-15 | 2023-04-20 | Basf Se | Thermoplastic polyurethane powders and 3d molding formed from the same |
| US12060524B2 (en) | 2022-06-23 | 2024-08-13 | Saudi Arabian Oil Company | Diverting materials for well stimulation |
| CN121652372A (zh) * | 2026-02-06 | 2026-03-13 | 中国科学技术大学 | 一种高强韧自修复本征阻燃水性聚氨酯弹性体及其制备方法 |
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| GB1239701A (https=) * | 1969-01-27 | 1971-07-21 | Ici Ltd | |
| JPS5858373B2 (ja) | 1978-12-13 | 1983-12-24 | 積水化成品工業株式会社 | 発泡性重合体粒子の製造方法 |
| JP3705664B2 (ja) * | 1996-12-16 | 2005-10-12 | 富士写真フイルム株式会社 | 放射線像変換パネル |
| JPH10206600A (ja) * | 1997-01-23 | 1998-08-07 | Fuji Photo Film Co Ltd | 放射線像変換パネル |
| JP2001011141A (ja) * | 1999-06-29 | 2001-01-16 | Nof Corp | グラフト共重合体及びこれを含有する熱可塑性樹脂組成物 |
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| WO2007082838A1 (de) * | 2006-01-18 | 2007-07-26 | Basf Se | Schaumstoffe auf basis thermoplastischer polyurethane |
| JP5324027B2 (ja) | 2006-02-28 | 2013-10-23 | 積水化成品工業株式会社 | スチレン改質熱可塑性ポリウレタン樹脂粒子、発泡性スチレン改質熱可塑性ポリウレタン樹脂粒子、スチレン改質熱可塑性ポリウレタン樹脂発泡粒子、スチレン改質熱可塑性ポリウレタン樹脂発泡成形体及びそれらの製造方法 |
| WO2010010010A1 (de) | 2008-07-25 | 2010-01-28 | Basf Se | Thermoplastische polymer blends auf der basis von thermoplastischem polyurethan und styrolpolymerisat, daraus hergestellte schaumstoffe und zugehörige herstellungsverfahren |
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| WO2014006182A1 (de) | 2014-01-09 |
| JP6411338B2 (ja) | 2018-10-24 |
| JP2015522680A (ja) | 2015-08-06 |
| EP2870194A1 (de) | 2015-05-13 |
| EP2682427A1 (de) | 2014-01-08 |
| CN104662073A (zh) | 2015-05-27 |
| US20150344661A1 (en) | 2015-12-03 |
| US9447249B2 (en) | 2016-09-20 |
| EP2870194B1 (de) | 2016-09-14 |
| CN104662073B (zh) | 2018-04-17 |
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