ES2584777T3 - Composición activado suavizante de telas - Google Patents

Composición activado suavizante de telas Download PDF

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Publication number
ES2584777T3
ES2584777T3 ES13701783.6T ES13701783T ES2584777T3 ES 2584777 T3 ES2584777 T3 ES 2584777T3 ES 13701783 T ES13701783 T ES 13701783T ES 2584777 T3 ES2584777 T3 ES 2584777T3
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ES
Spain
Prior art keywords
fabric softener
esterquats
composition
dispersion
groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES13701783.6T
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English (en)
Inventor
Dennis A PARRISH
Jens Hildebrand
Miyako HISAMOTO
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Evonik Operations GmbH
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Evonik Degussa GmbH
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Publication date
Application filed by Evonik Degussa GmbH filed Critical Evonik Degussa GmbH
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Publication of ES2584777T3 publication Critical patent/ES2584777T3/es
Active legal-status Critical Current
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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • C11D3/0015Softening compositions liquid
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Una composición activa de suavizante de telas, que comprende: a) esterquats de fórmula (I): en la que R1, R2 y R3 son hidrógeno o un grupo C(O)R5; R5 es un grupo alquilo o alquenilo que comprende de 11 a 21 átomos de carbono; A- es un anión compatible con suavizante de telas; R4 es metilo o etilo; y en la que: i) en una base normalizada de % en peso: el 33-38 % de dichos esterquats son monoésteres; el 52-55 % de dichos esterquats son diésteres; y el 7-12 % de dichos esterquats son triésteres; y ii) dichos grupos R5 tienen un valor de yodo, calculado para el ácido graso libre R5COOH, de 65 a 85 y la relación cis a trans de los enlaces insaturados de dichos grupos R5 es de menos de 12:1; y b) el 10-25 % en peso de un disolvente alcohólico; y en la que, a una temperatura de más de 15 ºC y hasta al menos 25 ºC, dicha composición está en forma de un líquido transparente.

Description

imagen1
imagen2
imagen3
imagen4
mezcla adicional de 10 minutos. Se hacen ajustes finales a la viscosidad añadiendo solución de cloruro de calcio.
Formulación de suavizante de telas a baja temperatura (20 -30 ºC) con productos líquidos
5 Se equilibra agua desionizada hasta 25 ºC y se agita con una mezcladora suspendida a 500 min-1. El activo de suavizante de telas equilibrado hasta 25 ºC se añade de un modo lento, constante. Se añade cloruro de calcio en forma de una solución activa al 25 % según lo necesario para mantener un vórtice definido. Una vez se ha completado la adición del activo de suavizante de telas active, se agita la dispersión a 25 ºC durante 10 minutos a 500 min-1 . Después de la mezcla, se pueden añadir ingredientes opcionales tales como fragancia, espesante, y
10 conservantes, seguido de un tiempo de mezcla adicional de 10 minutos. Se hacen ajustes finales a la viscosidad añadiendo solución de cloruro de calcio.
La Tabla 3 resumen los resultados que se obtuvieron con los productos A a L siguiendo estos procedimientos de formulación de suavizante de telas, usando las temperaturas de dispersión y los contenidos de activo de suavizante
15 de telas dados. No pudieron alcanzarse los contenidos de activos indicados como diana, ya que la mezcla gelificaba antes de añadirse todos los activos del suavizante de telas.
Tabla 3: Condiciones y resultados de dispersión de esterquat de TEA
Producto
Temperatura de dispersión en ºC Contenido de activos en % en peso Resultado de dispersión
A*
50 15 Proceso convencional de dispersión; sin problemas
A*
25 -- Quat no es líquido; no puede dispersarse
B*
50 15 Proceso convencional de dispersión; sin problemas
B*
25 -- Quat no es líquido; no puede dispersarse
C*
50 16 Proceso convencional de dispersión; sin problemas
C*
25 -- Quat no es líquido; no puede dispersarse
D*
50 15 (diana) Gelificado durante la dispersión
D*
25 15 (diana) Gelificado durante la dispersión
E*
45 10 (diana) Gelificado durante la dispersión
E*
30 20 (diana) Gelificado durante la dispersión
F*
24 20 No fácilmente dispersado
G*
25 20 Fácilmente dispersado
H*
23 20 (diana) Gelificado durante la dispersión
I*
23 20 No fácilmente dispersado
J
30 5 Muy fácilmente dispersado
J
20 22 Muy fácilmente dispersado
J
21 5 Muy fácilmente dispersado
J
23 20 Muy fácilmente dispersado
K*
23 20 Muy fácilmente dispersado
L
22 20 Muy fácilmente dispersado
*no de acuerdo con la invención
20 Todas las referencias citadas en este documento se incorporan en su totalidad por referencia. Habiendo descrito ahora completamente la invención, lo expertos en la materia entenderán que la invención puede ponerse en práctica dentro de un intervalo amplio y equivalente de condiciones, parámetros y similares, sin afectar al alcance de la invención o cualquier realización de la misma.
25
6

Claims (1)

  1. imagen1
    imagen2
ES13701783.6T 2012-01-30 2013-01-30 Composición activado suavizante de telas Active ES2584777T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261592248P 2012-01-30 2012-01-30
US201261592248P 2012-01-30
PCT/EP2013/051753 WO2013113735A1 (en) 2012-01-30 2013-01-30 Fabric softener active composition

Publications (1)

Publication Number Publication Date
ES2584777T3 true ES2584777T3 (es) 2016-09-29

Family

ID=47520971

Family Applications (1)

Application Number Title Priority Date Filing Date
ES13701783.6T Active ES2584777T3 (es) 2012-01-30 2013-01-30 Composición activado suavizante de telas

Country Status (19)

Country Link
US (1) US8883713B2 (es)
EP (1) EP2809758B9 (es)
JP (1) JP5843981B2 (es)
KR (1) KR102004012B1 (es)
CN (1) CN104160008B (es)
AU (1) AU2013214283B2 (es)
BR (1) BR112014018676B1 (es)
CA (1) CA2863276C (es)
CO (1) CO7061087A2 (es)
ES (1) ES2584777T3 (es)
MX (1) MX339151B (es)
MY (1) MY170907A (es)
PH (1) PH12014501411B1 (es)
RU (1) RU2612130C2 (es)
SA (1) SA113340238B1 (es)
SG (1) SG11201404392YA (es)
UA (1) UA114189C2 (es)
WO (2) WO2013113453A1 (es)
ZA (1) ZA201405607B (es)

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EP2563889B1 (de) 2010-04-28 2017-03-15 Evonik Degussa GmbH Textilweichmachende zusammensetzung
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BR102014025172B1 (pt) 2013-11-05 2020-03-03 Evonik Degussa Gmbh Método para fabricação de um éster de ácido graxo de metisulfato de tris-(2-hidroxietil)-metilamônio, e composição ativa de amaciante de roupa
UA119182C2 (uk) 2014-10-08 2019-05-10 Евонік Дегусса Гмбх Активна композиція для пом'якшувача тканини
RU2740475C2 (ru) 2016-12-06 2021-01-14 Эвоник Корпорейшн Органофильные глины и буровые растворы, содержащие их
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BR112014018676A2 (es) 2017-06-20
MX2014008752A (es) 2014-08-27
JP2015505585A (ja) 2015-02-23
KR20140119709A (ko) 2014-10-10
PH12014501411A1 (en) 2014-09-22
AU2013214283A1 (en) 2014-07-03
CN104160008B (zh) 2017-05-03
WO2013113735A1 (en) 2013-08-08
ZA201405607B (en) 2015-11-25
KR102004012B1 (ko) 2019-07-25
RU2014135272A (ru) 2016-03-20
SA113340238B1 (ar) 2015-07-07
EP2809758B9 (en) 2016-07-13
CA2863276A1 (en) 2013-08-08
CN104160008A (zh) 2014-11-19
SG11201404392YA (en) 2014-08-28
MY170907A (en) 2019-09-14
CA2863276C (en) 2017-03-14
PH12014501411B1 (en) 2014-09-22
US20130196894A1 (en) 2013-08-01
CO7061087A2 (es) 2014-09-19
BR112014018676B1 (pt) 2021-01-19
EP2809758A1 (en) 2014-12-10
BR112014018676A8 (pt) 2017-07-11
MX339151B (es) 2016-05-13
UA114189C2 (uk) 2017-05-10
EP2809758B1 (en) 2016-04-27
JP5843981B2 (ja) 2016-01-13
US8883713B2 (en) 2014-11-11
RU2612130C2 (ru) 2017-03-02
AU2013214283B2 (en) 2015-08-20
WO2013113453A1 (en) 2013-08-08

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