ES2572478T3 - Poliésteres aromáticos de alta funcionalidad, mezclas de polioles que comprenden los mismos y productos resultantes de los mismos - Google Patents

Poliésteres aromáticos de alta funcionalidad, mezclas de polioles que comprenden los mismos y productos resultantes de los mismos

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Publication number
ES2572478T3
ES2572478T3 ES11757315T ES11757315T ES2572478T3 ES 2572478 T3 ES2572478 T3 ES 2572478T3 ES 11757315 T ES11757315 T ES 11757315T ES 11757315 T ES11757315 T ES 11757315T ES 2572478 T3 ES2572478 T3 ES 2572478T3
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ES
Spain
Prior art keywords
weight
polyols
mixtures
same
resulting therefrom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES11757315T
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English (en)
Inventor
Jorge Jimenez
Woo-Sung Bae
Giuseppe Y Lista
Mikhail Y Gelfer
Vanni Parenti
Hans Kramer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
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Dow Global Technologies LLC
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Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
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Publication of ES2572478T3 publication Critical patent/ES2572478T3/es
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/668Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672Dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C08G18/4241Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols from dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/4252Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • C08G18/482Mixtures of polyethers containing at least one polyether containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/668Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • C08L75/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00Manufacture of cellular products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0025Foam properties rigid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0041Foam properties having specified density
    • C08G2110/005< 50kg/m3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Un método para preparar un poliéster poliol, que comprende hacer reaccionar en una síntesis de un solo paso al menos: A) un componente aromático que comprende 80 por ciento en moles o más de ácido tereftálico; B) al menos un poliéter poliol que tiene una funcionalidad nominal mayor que 2 y menor que o igual a 4, un peso molecular de 250 a 1.000, y tiene un contenido de polioxipropileno de al menos 70% en peso del poliol; y C) al menos un glicol distinto a B que tiene un peso molecular de 60 a 250; en donde A, B y C están presentes en la reacción en una base en tanto por ciento en peso de 20 a 60 por ciento en peso de A); 15 a 70 por ciento en peso de B); y 10 a 50 por ciento en peso de C), en donde la funcionalidad del poliol es de 2,4 a 3,0.
ES11757315T 2010-09-29 2011-09-15 Poliésteres aromáticos de alta funcionalidad, mezclas de polioles que comprenden los mismos y productos resultantes de los mismos Active ES2572478T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI20101782 2010-09-29
PCT/EP2011/065981 WO2012041709A1 (en) 2010-09-29 2011-09-15 High functionality aromatic polyesters, polyol blends comprising the same and resultant products therefrom

Publications (1)

Publication Number Publication Date
ES2572478T3 true ES2572478T3 (es) 2016-05-31

Family

ID=43738977

Family Applications (1)

Application Number Title Priority Date Filing Date
ES11757315T Active ES2572478T3 (es) 2010-09-29 2011-09-15 Poliésteres aromáticos de alta funcionalidad, mezclas de polioles que comprenden los mismos y productos resultantes de los mismos

Country Status (8)

Country Link
US (1) US20130184366A1 (es)
EP (1) EP2622001B1 (es)
JP (1) JP5876492B2 (es)
KR (1) KR101812831B1 (es)
CN (1) CN103228701B (es)
ES (1) ES2572478T3 (es)
MX (1) MX2013003502A (es)
WO (1) WO2012041709A1 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112014004471A2 (pt) * 2011-08-26 2017-03-28 Bayer Ip Gmbh emulsões estáveis e respectivo uso na produção de espumas à base de isocianato
CA2869739C (en) 2012-04-10 2020-08-11 Huntsman International Llc High functional polyester polyols
PL2855549T3 (pl) * 2012-05-25 2018-03-30 Dow Global Technologies Llc Wytwarzanie płyt z pianką poliizocyjanurową
WO2014019103A1 (en) 2012-07-31 2014-02-06 Bayer Materialscience Ag Method for the production of polyurethane foam using emulsified blowing agent
WO2017058504A1 (en) * 2015-10-02 2017-04-06 Resinate Materials Group, Inc. High performance coatings
US20200339743A1 (en) 2017-11-14 2020-10-29 Dow Global Technologies Llc Composition and synthesis of high molecular weight aromatic polyol polyesters
US11124712B2 (en) 2017-11-14 2021-09-21 Dow Global Technologies Llc Method of using high molecular weight aromatic polyol polyesters as demulsifiers for crude oil treatment
EP3774965B1 (en) 2018-04-03 2023-04-26 Dow Global Technologies LLC Foam formulations
JP7477519B2 (ja) * 2018-10-09 2024-05-01 ダウ グローバル テクノロジーズ エルエルシー 硬質ポリウレタンフォーム配合物およびそれから作製されたフォーム
US20220119427A1 (en) * 2019-01-31 2022-04-21 Dow Global Technologies Llc Beta-hydroxyphosphonate functionalized polyols
EP3763776A1 (de) * 2019-07-12 2021-01-13 Covestro Deutschland AG Verfahren zur herstellung von flammwidrigen pur-/pir-hartschäumen
MX2023006875A (es) * 2020-12-10 2023-06-23 Basf Se Poliol de polieterester y su uso para producir materiales de espuma rigida de poliuretano.
CN113563698B (zh) * 2021-09-23 2021-12-10 苏州宝丽迪材料科技股份有限公司 一种反应型功能聚酯母粒及其制备方法

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Also Published As

Publication number Publication date
CN103228701B (zh) 2016-01-20
JP2013538910A (ja) 2013-10-17
US20130184366A1 (en) 2013-07-18
KR101812831B1 (ko) 2017-12-27
EP2622001A1 (en) 2013-08-07
MX2013003502A (es) 2013-05-20
KR20140020819A (ko) 2014-02-19
CN103228701A (zh) 2013-07-31
EP2622001B1 (en) 2016-04-20
WO2012041709A1 (en) 2012-04-05
JP5876492B2 (ja) 2016-03-02

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