ES2140775T3 - Procedimiento para preparar una espuma flexible. - Google Patents

Procedimiento para preparar una espuma flexible.

Info

Publication number
ES2140775T3
ES2140775T3 ES96115320T ES96115320T ES2140775T3 ES 2140775 T3 ES2140775 T3 ES 2140775T3 ES 96115320 T ES96115320 T ES 96115320T ES 96115320 T ES96115320 T ES 96115320T ES 2140775 T3 ES2140775 T3 ES 2140775T3
Authority
ES
Spain
Prior art keywords
weight
polyol
alkaline
preparing
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96115320T
Other languages
English (en)
Inventor
Berend Eling
Eric Huygens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman International LLC
Original Assignee
Huntsman International LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB939307556A external-priority patent/GB9307556D0/en
Priority claimed from GB9401339A external-priority patent/GB9401339D0/en
Application filed by Huntsman International LLC filed Critical Huntsman International LLC
Application granted granted Critical
Publication of ES2140775T3 publication Critical patent/ES2140775T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/593—Dicarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/60—Maleic acid esters; Fumaric acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/60—Unsaturated compounds containing ether groups, groups, groups, or groups the non-carboxylic part of the ether being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/6795—Unsaturated polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
    • C08G65/3324—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof cyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33348—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group
    • C08G65/33355—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group cyclic
    • C08G65/33358—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing isocyanate group cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/338—Polymers modified by chemical after-treatment with inorganic and organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0016—Foam properties semi-rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00—Acoustic or vibration damping material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

UN METODO PARA LA PREPARACION DE ESPUMAS DE POLIURETANO FLEXIBLES POR REACCION DE UN POLIISOCIANATO QUE CONTIENE AL MENOS UN 85 % EN PESO DE 4,4''-DIFENILMETANO DIISOCIANATO O UNA VARIANTE LIQUIDA DE ESTE CON UNA COMPOSICION DE POLIOL QUE COMPRENDE AL MENOS UN POLI(OXIETILENO-OXIALQUILENO) POLIOL QUE TIENE UNA FUNCIONALIDAD HIDROXILO NOMINAL MEDIA DE 2 A 6, UN NUMERO MEDIO DE PESO EQUIVALENTE DE HIDROXILO DE 1000 A 3000, Y UN CONTENIDO DE OXIETILENO MEDIO DEL 50 AL 85 % EN PESO Y CON AGUA EN PRESENCIA DE UNA CANTIDAD CATALITICAMENTE EFECTIVA DE UNA SAL DE CARBOXILATO DE METAL ALCALINO O ALCALINOTERREO.
ES96115320T 1993-04-13 1994-03-23 Procedimiento para preparar una espuma flexible. Expired - Lifetime ES2140775T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB939307556A GB9307556D0 (en) 1993-04-13 1993-04-13 Process for preparing a flexible foam
GB9401339A GB9401339D0 (en) 1994-01-25 1994-01-25 Alkali metal or alkialine earth metal salts of specific organic acids

Publications (1)

Publication Number Publication Date
ES2140775T3 true ES2140775T3 (es) 2000-03-01

Family

ID=26302741

Family Applications (2)

Application Number Title Priority Date Filing Date
ES94912523T Expired - Lifetime ES2108441T3 (es) 1993-04-13 1994-03-23 Proceso para preparar una espuma flexible.
ES96115320T Expired - Lifetime ES2140775T3 (es) 1993-04-13 1994-03-23 Procedimiento para preparar una espuma flexible.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES94912523T Expired - Lifetime ES2108441T3 (es) 1993-04-13 1994-03-23 Proceso para preparar una espuma flexible.

Country Status (9)

Country Link
EP (2) EP0694048B1 (es)
JP (1) JPH08511287A (es)
CN (2) CN1039423C (es)
CA (1) CA2158653A1 (es)
DE (2) DE69406656T2 (es)
ES (2) ES2108441T3 (es)
HK (2) HK1002684A1 (es)
MY (2) MY131187A (es)
WO (1) WO1994024184A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HUP0100548A2 (hu) * 1997-10-22 2001-06-28 Shell Internationale Research Maatschappij B.V. Poliolkompozíció
EP1172387A1 (en) 2000-07-14 2002-01-16 Huntsman International Llc Process for preparing an elastomer
EP1178063A1 (en) 2000-08-01 2002-02-06 Huntsman International Llc Process for preparing a polyurethane material
EP1234843A1 (en) 2001-02-26 2002-08-28 Huntsman International Llc Process for preparing a flexible polyurethane foam
JP5876492B2 (ja) * 2010-09-29 2016-03-02 ダウ グローバル テクノロジーズ エルエルシー 高官能価芳香族ポリエステル、高官能価芳香族ポリエステルを含むポリオールブレンド、およびそれから得られる生成物
WO2017104600A1 (ja) * 2015-12-16 2017-06-22 株式会社ブリヂストン 軟質ポリウレタンフォーム、及びシート用パッド
CN111072896A (zh) * 2019-12-27 2020-04-28 江苏世丰新材料有限公司 一种车内饰用低气味阻燃聚氨酯泡沫材料及其制备方法
WO2023107358A1 (en) * 2021-12-09 2023-06-15 Dow Global Technologies Llc Flame retardant flexible polyurethane foam for automotive seating

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE795474A (fr) * 1972-02-17 1973-08-16 Bayer Ag Sels alcalins d'acides polyester-carboxyliques, et leur preparation
US4098732A (en) * 1973-12-25 1978-07-04 Bridgestone Tire Co., Ltd. Process for production of flame-resistant and smoke-retardant polyurethane foams
JPS583488B2 (ja) * 1978-05-15 1983-01-21 株式会社ブリヂストン 軟質ポリエ−テルポリウレタンフオ−ムの製造方法
DE3066568D1 (en) * 1979-07-11 1984-03-22 Ici Plc Prepolymers, polyisocyanate compositions prepared therefrom and their use in the preparation of polyurethane foams
JPS5681332A (en) * 1979-12-04 1981-07-03 Dai Ichi Kogyo Seiyaku Co Ltd Production of modified polyisocyanurate foam
JPS57119915A (en) * 1981-01-16 1982-07-26 Bridgestone Corp Preparation of urethane modified isocyanurate foam
JPS5876416A (ja) * 1981-10-30 1983-05-09 Achilles Corp ウレタン変性イソシアヌレ−トフオ−ムの製造方法
US4365025A (en) * 1981-12-08 1982-12-21 W. R. Grace & Co. Flexible polyurethane foams from polymethylene polyphenyl isocyanate containing prepolymers
US4603076A (en) * 1985-03-04 1986-07-29 Norwood Industries, Inc. Hydrophilic foam
US5175229A (en) * 1986-11-18 1992-12-29 W. R. Grace & Co.-Conn. Biocompatible polyurea-urethane hydrated polymers
IT1229756B (it) * 1989-05-17 1991-09-10 Montedipe Spa Schiume poliuretaniche flessibili e procedimento per la loro preparazione
US5114989A (en) * 1990-11-13 1992-05-19 The Dow Chemical Company Isocyanate-terminated prepolymer and polyurethane foam prepared therefrom

Also Published As

Publication number Publication date
HK1003836A1 (en) 1998-11-06
ES2108441T3 (es) 1997-12-16
EP0694048B1 (en) 1997-11-05
AU667779B2 (en) 1996-04-04
WO1994024184A1 (en) 1994-10-27
DE69422198T2 (de) 2000-05-25
EP0694048A1 (en) 1996-01-31
CN1039423C (zh) 1998-08-05
CN1176261A (zh) 1998-03-18
EP0751114B1 (en) 1999-12-15
DE69406656D1 (de) 1997-12-11
EP0751114A3 (en) 1997-01-15
AU6504794A (en) 1994-11-08
DE69422198D1 (de) 2000-01-20
EP0751114A2 (en) 1997-01-02
HK1002684A1 (en) 1998-09-11
MY131187A (en) 2007-07-31
MY132712A (en) 2007-10-31
DE69406656T2 (de) 1998-03-26
JPH08511287A (ja) 1996-11-26
CA2158653A1 (en) 1994-10-27
CN1120849A (zh) 1996-04-17

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