ES2506096T3 - Polímeros funcionalizados y artículos preparados a partir de los mismos - Google Patents
Polímeros funcionalizados y artículos preparados a partir de los mismos Download PDFInfo
- Publication number
- ES2506096T3 ES2506096T3 ES08781609.6T ES08781609T ES2506096T3 ES 2506096 T3 ES2506096 T3 ES 2506096T3 ES 08781609 T ES08781609 T ES 08781609T ES 2506096 T3 ES2506096 T3 ES 2506096T3
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- Prior art keywords
- propylene
- carbon
- agent
- interpolymer
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000642 polymer Polymers 0.000 title claims abstract description 157
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 173
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 173
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 143
- 239000000203 mixture Substances 0.000 claims abstract description 112
- 150000002978 peroxides Chemical class 0.000 claims abstract description 36
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims abstract description 33
- 239000000126 substance Substances 0.000 claims abstract description 22
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- 150000002430 hydrocarbons Chemical group 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 8
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000002541 furyl group Chemical group 0.000 claims abstract description 5
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims description 4
- 230000007423 decrease Effects 0.000 claims description 4
- 238000001938 differential scanning calorimetry curve Methods 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 238000002441 X-ray diffraction Methods 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
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- -1 polypropylene Polymers 0.000 description 89
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 73
- 229920001155 polypropylene Polymers 0.000 description 63
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 51
- 239000005977 Ethylene Substances 0.000 description 51
- 150000003254 radicals Chemical class 0.000 description 50
- 238000000034 method Methods 0.000 description 49
- 239000004743 Polypropylene Substances 0.000 description 48
- 239000000178 monomer Substances 0.000 description 36
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 27
- 238000006243 chemical reaction Methods 0.000 description 27
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 25
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 22
- 239000004711 α-olefin Substances 0.000 description 21
- 239000003963 antioxidant agent Substances 0.000 description 19
- 239000000835 fiber Substances 0.000 description 17
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 15
- 239000000155 melt Substances 0.000 description 15
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 14
- BMMJLSUJRGRSFN-UHFFFAOYSA-N 4-ethenoxybutyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCOC=C BMMJLSUJRGRSFN-UHFFFAOYSA-N 0.000 description 14
- 230000015556 catabolic process Effects 0.000 description 14
- 238000007306 functionalization reaction Methods 0.000 description 14
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- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 description 13
- 229920001038 ethylene copolymer Polymers 0.000 description 13
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- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 11
- 239000000654 additive Substances 0.000 description 11
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- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 125000003118 aryl group Chemical group 0.000 description 10
- 239000003446 ligand Substances 0.000 description 10
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- 238000012545 processing Methods 0.000 description 10
- PJANXHGTPQOBST-VAWYXSNFSA-N trans-stilbene Chemical compound C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 10
- ZMYIIHDQURVDRB-UHFFFAOYSA-N 1-phenylethenylbenzene Chemical group C=1C=CC=CC=1C(=C)C1=CC=CC=C1 ZMYIIHDQURVDRB-UHFFFAOYSA-N 0.000 description 9
- 230000003078 antioxidant effect Effects 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 8
- 239000012190 activator Substances 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 8
- 229920000573 polyethylene Polymers 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 7
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- 239000003999 initiator Substances 0.000 description 7
- 239000005060 rubber Substances 0.000 description 7
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 6
- 239000004952 Polyamide Substances 0.000 description 6
- 230000009102 absorption Effects 0.000 description 6
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- 239000006229 carbon black Substances 0.000 description 6
- 235000019241 carbon black Nutrition 0.000 description 6
- 230000003993 interaction Effects 0.000 description 6
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- 229920000728 polyester Polymers 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 238000004364 calculation method Methods 0.000 description 5
- 238000003776 cleavage reaction Methods 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 230000007017 scission Effects 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 229920002397 thermoplastic olefin Polymers 0.000 description 5
- PJANXHGTPQOBST-UHFFFAOYSA-N trans-Stilbene Natural products C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
- 102100026816 DNA-dependent metalloprotease SPRTN Human genes 0.000 description 4
- 101710175461 DNA-dependent metalloprotease SPRTN Proteins 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 150000002334 glycols Chemical class 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 4
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 4
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- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
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- MEFKPARLYKPHAU-UHFFFAOYSA-N 1-methyl-2-(2-phenylethenyl)pyrrole Chemical compound CN1C=CC=C1C=CC1=CC=CC=C1 MEFKPARLYKPHAU-UHFFFAOYSA-N 0.000 description 3
- MHQZDNQHLGFBRN-UHFFFAOYSA-N 5-ethenyl-1h-imidazole Chemical compound C=CC1=CNC=N1 MHQZDNQHLGFBRN-UHFFFAOYSA-N 0.000 description 3
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- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
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- 125000004429 atom Chemical group 0.000 description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
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- 125000000753 cycloalkyl group Chemical group 0.000 description 3
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- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
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- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
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- QANMHLXAZMSUEX-UHFFFAOYSA-N kinetin Chemical compound N=1C=NC=2N=CNC=2C=1NCC1=CC=CO1 QANMHLXAZMSUEX-UHFFFAOYSA-N 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- UZRCGISJYYLJMA-UHFFFAOYSA-N phenol;styrene Chemical class OC1=CC=CC=C1.C=CC1=CC=CC=C1 UZRCGISJYYLJMA-UHFFFAOYSA-N 0.000 description 1
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- 229910052711 selenium Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
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- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XBFJAVXCNXDMBH-UHFFFAOYSA-N tetracyclo[6.2.1.1(3,6).0(2,7)]dodec-4-ene Chemical compound C1C(C23)C=CC1C3C1CC2CC1 XBFJAVXCNXDMBH-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
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- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/04—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Polymerization Catalysts (AREA)
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| US950006P | 2007-07-16 | ||
| PCT/US2008/069639 WO2009012113A1 (en) | 2007-07-16 | 2008-07-10 | Functionalized polymers, articles prepared therefrom, and methods for making the same |
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| ES2506096T3 true ES2506096T3 (es) | 2014-10-13 |
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| ES08781609.6T Active ES2506096T3 (es) | 2007-07-16 | 2008-07-10 | Polímeros funcionalizados y artículos preparados a partir de los mismos |
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| RU (1) | RU2010105230A (OSRAM) |
| TW (1) | TW200916489A (OSRAM) |
| WO (1) | WO2009012113A1 (OSRAM) |
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| KR20100063004A (ko) * | 2007-07-16 | 2010-06-10 | 다우 글로벌 테크놀로지스 인크. | 관능화 중합체, 이로부터 제조된 물품, 및 그 제조방법 |
| GB0812187D0 (en) * | 2008-07-03 | 2008-08-13 | Dow Corning | Modified polyethylene |
| GB0812186D0 (en) * | 2008-07-03 | 2008-08-13 | Dow Corning | Modified polyolefins |
| GB0812185D0 (en) * | 2008-07-03 | 2008-08-13 | Dow Corning | Polymers modified by silanes |
| US20110172368A1 (en) * | 2008-09-23 | 2011-07-14 | Stolz-Dunn Sandra K | Radically Functionalized Olefin-Based Polymer with Reduced Molecular Weight Change and Method |
| GB201000121D0 (en) | 2010-01-06 | 2010-02-17 | Dow Corning | Modified polyolefins |
| GB201000117D0 (en) * | 2010-01-06 | 2010-02-17 | Dow Corning | Organopolysiloxanes containing an unsaturated group |
| GB201000120D0 (en) | 2010-01-06 | 2010-02-17 | Dow Corning | Process for forming crosslinked and branched polymers |
| KR102059982B1 (ko) | 2014-03-14 | 2019-12-27 | 밀리켄 앤드 캄파니 | 개질된 헤테로상 폴리올레핀 조성물 |
| WO2016014122A1 (en) | 2014-07-25 | 2016-01-28 | Milliken & Company | Modified heterophasic polyolefin composition |
| WO2016085535A1 (en) | 2014-11-26 | 2016-06-02 | Milliken & Company | Modified heterophasic polyolefin composition |
| KR102124239B1 (ko) | 2015-02-10 | 2020-06-17 | 밀리켄 앤드 캄파니 | 열가소성 중합체 조성물 |
| WO2016140690A1 (en) | 2015-03-05 | 2016-09-09 | Milliken & Company | Modified heterophasic polyolefin composition |
| PL3347389T3 (pl) * | 2015-09-13 | 2021-04-19 | Milliken & Company | Sposób wytwarzania heterofazowych kompozycji polimerowych |
| EP3486266A1 (en) * | 2017-11-17 | 2019-05-22 | SABIC Global Technologies B.V. | Process for the production of modified polyolefin materials |
| CN108330687B (zh) * | 2018-01-29 | 2020-09-18 | 西安工程大学 | 基于本体聚合法的热熔性纺织浆料制备方法 |
| BR112022021863A2 (pt) * | 2020-04-29 | 2022-12-20 | China Petroleum & Chem Corp | Material de polipropileno modificado por enxerto para um material isolante, método para preparar um material de polipropileno modificado por enxerto para um material isolante, uso de um material de polipropileno modificado por enxerto, cabo e material isolante |
| US20230174698A1 (en) * | 2020-04-29 | 2023-06-08 | China Petroleum & Chemical Corporation | Polypropylene Graft Containing Anhydride Group and Preparation Method for Polypropylene Graft |
| RU2767530C1 (ru) * | 2020-11-16 | 2022-03-17 | Публичное акционерное общество «СИБУР Холдинг» | Композиция полипропилена с повышенной прочностью расплава и способ её получения |
| WO2022239728A1 (ja) * | 2021-05-10 | 2022-11-17 | Ｍｃｐｐイノベーション合同会社 | 相溶化剤、リサイクル助剤及び相溶化方法 |
| CN117321134A (zh) * | 2021-05-10 | 2023-12-29 | 三菱化学株式会社 | 聚合物组合物及其成形品 |
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| US4130535A (en) | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
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| JP5563195B2 (ja) * | 2005-01-21 | 2014-07-30 | コモンウェルス サイエンティフィック アンドインダストリアル リサーチ オーガナイゼーション | 改質物質を用いる活性化方法 |
| KR20100063004A (ko) * | 2007-07-16 | 2010-06-10 | 다우 글로벌 테크놀로지스 인크. | 관능화 중합체, 이로부터 제조된 물품, 및 그 제조방법 |
-
2008
- 2008-07-10 KR KR1020107003195A patent/KR20100063004A/ko not_active Withdrawn
- 2008-07-10 BR BRPI0812687-9A2A patent/BRPI0812687A2/pt active Search and Examination
- 2008-07-10 RU RU2010105230/04A patent/RU2010105230A/ru not_active Application Discontinuation
- 2008-07-10 US US12/669,194 patent/US9000099B2/en active Active
- 2008-07-10 CN CN200880107335.6A patent/CN101809051B/zh not_active Expired - Fee Related
- 2008-07-10 EP EP08781609.6A patent/EP2170970B1/en active Active
- 2008-07-10 WO PCT/US2008/069639 patent/WO2009012113A1/en not_active Ceased
- 2008-07-10 ES ES12169831.0T patent/ES2543180T3/es active Active
- 2008-07-10 EP EP12169831.0A patent/EP2495268B1/en active Active
- 2008-07-10 JP JP2010517076A patent/JP5697978B2/ja not_active Expired - Fee Related
- 2008-07-10 ES ES08781609.6T patent/ES2506096T3/es active Active
- 2008-07-15 TW TW097126739A patent/TW200916489A/zh unknown
- 2008-07-16 AR ARP080103054A patent/AR067563A1/es not_active Application Discontinuation
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2014
- 2014-10-24 JP JP2014217495A patent/JP6110830B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20100063004A (ko) | 2010-06-10 |
| EP2170970A4 (en) | 2011-12-07 |
| TW200916489A (en) | 2009-04-16 |
| ES2543180T3 (es) | 2015-08-17 |
| US9000099B2 (en) | 2015-04-07 |
| BRPI0812687A2 (pt) | 2014-12-23 |
| EP2170970A1 (en) | 2010-04-07 |
| JP2010533773A (ja) | 2010-10-28 |
| CN101809051B (zh) | 2015-07-29 |
| AR067563A1 (es) | 2009-10-14 |
| RU2010105230A (ru) | 2011-08-27 |
| EP2170970B1 (en) | 2014-09-03 |
| US20100168343A1 (en) | 2010-07-01 |
| EP2495268A1 (en) | 2012-09-05 |
| JP2015042755A (ja) | 2015-03-05 |
| EP2495268B1 (en) | 2015-07-01 |
| CN101809051A (zh) | 2010-08-18 |
| JP5697978B2 (ja) | 2015-04-08 |
| JP6110830B2 (ja) | 2017-04-05 |
| WO2009012113A1 (en) | 2009-01-22 |
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