ES2414161T3 - Procedimiento de tratamiento de un efluente líquido acuoso nítrico por calcinación y vitrificación - Google Patents
Procedimiento de tratamiento de un efluente líquido acuoso nítrico por calcinación y vitrificación Download PDFInfo
- Publication number
- ES2414161T3 ES2414161T3 ES09799361T ES09799361T ES2414161T3 ES 2414161 T3 ES2414161 T3 ES 2414161T3 ES 09799361 T ES09799361 T ES 09799361T ES 09799361 T ES09799361 T ES 09799361T ES 2414161 T3 ES2414161 T3 ES 2414161T3
- Authority
- ES
- Spain
- Prior art keywords
- nitrate
- effluent
- calcination
- mass
- expressed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000001354 calcination Methods 0.000 title claims abstract description 96
- 238000000034 method Methods 0.000 title claims abstract description 32
- 239000007788 liquid Substances 0.000 title claims abstract description 17
- 238000004017 vitrification Methods 0.000 title claims description 20
- 239000002671 adjuvant Substances 0.000 claims abstract description 74
- 239000000203 mixture Substances 0.000 claims abstract description 46
- 150000001875 compounds Chemical class 0.000 claims abstract description 44
- 238000010790 dilution Methods 0.000 claims abstract description 43
- 239000012895 dilution Substances 0.000 claims abstract description 43
- -1 metalloid nitrates Chemical class 0.000 claims abstract description 24
- 229910052752 metalloid Inorganic materials 0.000 claims abstract description 21
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 16
- 150000002738 metalloids Chemical class 0.000 claims abstract description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 3
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 3
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 38
- 239000011521 glass Substances 0.000 claims description 33
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 19
- 235000010344 sodium nitrate Nutrition 0.000 claims description 19
- 239000004317 sodium nitrate Substances 0.000 claims description 19
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims description 10
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 6
- YWECOPREQNXXBZ-UHFFFAOYSA-N praseodymium(3+);trinitrate Chemical compound [Pr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O YWECOPREQNXXBZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 3
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims description 3
- CFYGEIAZMVFFDE-UHFFFAOYSA-N neodymium(3+);trinitrate Chemical compound [Nd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CFYGEIAZMVFFDE-UHFFFAOYSA-N 0.000 claims description 3
- XWROSHJVVFETLV-UHFFFAOYSA-N [B+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O Chemical compound [B+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XWROSHJVVFETLV-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 229910001960 metal nitrate Inorganic materials 0.000 abstract description 5
- 150000002823 nitrates Chemical class 0.000 description 30
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 229910052593 corundum Inorganic materials 0.000 description 6
- 229910001845 yogo sapphire Inorganic materials 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 4
- 239000002699 waste material Substances 0.000 description 3
- 229910011255 B2O3 Inorganic materials 0.000 description 2
- 229910000421 cerium(III) oxide Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 description 2
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000002308 calcification Effects 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000000763 evoking effect Effects 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G21F9/30—Processing
- G21F9/301—Processing by fixation in stable solid media
- G21F9/302—Processing by fixation in stable solid media in an inorganic matrix
- G21F9/305—Glass or glass like matrix
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/14—Processing by incineration; by calcination, e.g. desiccation
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G21F9/30—Processing
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Glass Melting And Manufacturing (AREA)
- Removal Of Specific Substances (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0859138 | 2008-12-30 | ||
| FR0859138A FR2940717B1 (fr) | 2008-12-30 | 2008-12-30 | Procede de traitement d'un effluent liquide aqueux nitrique par calcination et vitrification |
| PCT/EP2009/067900 WO2010076287A2 (fr) | 2008-12-30 | 2009-12-23 | Procédé de traitement d'un effluent liquide aqueux nitrique par calcination et vitrification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2414161T3 true ES2414161T3 (es) | 2013-07-18 |
Family
ID=41110759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09799361T Active ES2414161T3 (es) | 2008-12-30 | 2009-12-23 | Procedimiento de tratamiento de un efluente líquido acuoso nítrico por calcinación y vitrificación |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8846999B2 (enExample) |
| EP (1) | EP2374135B1 (enExample) |
| JP (1) | JP5818256B2 (enExample) |
| KR (1) | KR101635368B1 (enExample) |
| CN (1) | CN102265352B (enExample) |
| ES (1) | ES2414161T3 (enExample) |
| FR (1) | FR2940717B1 (enExample) |
| RU (1) | RU2532413C2 (enExample) |
| WO (1) | WO2010076287A2 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9804617B2 (en) * | 2015-11-20 | 2017-10-31 | Texas Instruments Incorporated | Detecting an inductor coupled to a power control circuit |
| CN111883279B (zh) * | 2020-07-01 | 2023-03-10 | 中国原子能科学研究院 | 一种用于回转煅烧炉处理放射性废液的分区加热方法 |
| CN113447614B (zh) * | 2021-06-21 | 2022-08-09 | 中国原子能科学研究院 | 放射性废液煅烧过程中脱硝率测量方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3008904A (en) * | 1959-12-29 | 1961-11-14 | Jr Benjamin M Johnson | Processing of radioactive waste |
| US3272756A (en) * | 1965-08-31 | 1966-09-13 | John D Kaser | Radioactive waste disposal using colemanite |
| FR2262854B1 (enExample) * | 1974-02-28 | 1976-12-10 | Commissariat Energie Atomique | |
| US3943062A (en) * | 1974-05-13 | 1976-03-09 | The United States Of America As Represented By The United States Energy Research And Development Administration | Cryolite process for the solidification of radioactive wastes |
| GB1492464A (en) | 1975-01-28 | 1977-11-23 | Us Energy | Process for calcining radioactive wastes containing sodium nitrate |
| JPS5263867A (en) * | 1975-11-21 | 1977-05-26 | Mitsui Eng & Shipbuild Co Ltd | Treating method of waste gas containing sodium nitrate |
| JPS53109100A (en) * | 1977-03-03 | 1978-09-22 | Power Reactor & Nuclear Fuel Dev Corp | Treatmetn method of high level radioactive waste solution cantaining sodium nitrate |
| US4164479A (en) * | 1978-01-12 | 1979-08-14 | The United States Of America As Represented By The United States Department Of Energy | Method for calcining nuclear waste solutions containing zirconium and halides |
| DE2831429A1 (de) * | 1978-07-18 | 1980-01-31 | Nukem Gmbh | Verfahren zur verfestigung von radioaktiven spaltprodukten |
| JPS6046394B2 (ja) * | 1981-07-06 | 1985-10-15 | 工業技術院長 | 高レベル放射性廃液のガラスによる固化処理方法 |
| JPS61132898A (ja) * | 1984-11-30 | 1986-06-20 | 株式会社東芝 | 放射性廃棄物の固化処理方法 |
| JPH0648314B2 (ja) * | 1987-02-13 | 1994-06-22 | 動力炉・核燃料開発事業団 | 放射性廃液の処理方法 |
| JPS63300999A (ja) * | 1987-05-30 | 1988-12-08 | Mitsubishi Metal Corp | 硝酸ナトリウムを含有する放射性廃物質の処理方法 |
| CN1213097C (zh) * | 1997-08-20 | 2005-08-03 | 东芝株式会社 | 废弃物处理方法和废弃物处理装置 |
| RU2203512C2 (ru) * | 2000-10-18 | 2003-04-27 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт неорганических материалов им. акад. А.А. Бочвара" | Способ отверждения жидких радиоактивных отходов и устройство для его осуществления |
| RU2201629C2 (ru) * | 2001-01-09 | 2003-03-27 | Государственное унитарное предприятие Научно-производственное объединение "Радиевый институт им. В.Г.Хлопина" | Способ отверждения концентрата трансплутониевых или трансплутониевых и редкоземельных элементов в металлокерамику |
| FR2940716B1 (fr) * | 2008-12-30 | 2011-09-23 | Areva Nc | Procede de traitement d'un effluent liquide aqueux nitrique par calcination et vitrification |
-
2008
- 2008-12-30 FR FR0859138A patent/FR2940717B1/fr not_active Expired - Fee Related
-
2009
- 2009-12-23 CN CN200980152166.2A patent/CN102265352B/zh active Active
- 2009-12-23 RU RU2011131993/07A patent/RU2532413C2/ru active
- 2009-12-23 ES ES09799361T patent/ES2414161T3/es active Active
- 2009-12-23 EP EP09799361A patent/EP2374135B1/fr active Active
- 2009-12-23 JP JP2011544033A patent/JP5818256B2/ja active Active
- 2009-12-23 KR KR1020117015079A patent/KR101635368B1/ko active Active
- 2009-12-23 WO PCT/EP2009/067900 patent/WO2010076287A2/fr not_active Ceased
- 2009-12-23 US US13/142,243 patent/US8846999B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| RU2011131993A (ru) | 2013-02-10 |
| EP2374135A2 (fr) | 2011-10-12 |
| WO2010076287A3 (fr) | 2010-09-16 |
| FR2940717A1 (fr) | 2010-07-02 |
| KR101635368B1 (ko) | 2016-07-01 |
| JP5818256B2 (ja) | 2015-11-18 |
| JP2012514206A (ja) | 2012-06-21 |
| KR20110107805A (ko) | 2011-10-04 |
| FR2940717B1 (fr) | 2011-09-23 |
| WO2010076287A2 (fr) | 2010-07-08 |
| CN102265352B (zh) | 2014-03-12 |
| CN102265352A (zh) | 2011-11-30 |
| US20120016173A1 (en) | 2012-01-19 |
| EP2374135B1 (fr) | 2013-03-13 |
| US8846999B2 (en) | 2014-09-30 |
| RU2532413C2 (ru) | 2014-11-10 |
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