ES2361797T3 - Composiciones de moldeo termoplásticas pirorretardantes. - Google Patents
Composiciones de moldeo termoplásticas pirorretardantes. Download PDFInfo
- Publication number
- ES2361797T3 ES2361797T3 ES08774866T ES08774866T ES2361797T3 ES 2361797 T3 ES2361797 T3 ES 2361797T3 ES 08774866 T ES08774866 T ES 08774866T ES 08774866 T ES08774866 T ES 08774866T ES 2361797 T3 ES2361797 T3 ES 2361797T3
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- flame retardant
- copolymer
- graft
- thermoplastic
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- 239000000203 mixture Substances 0.000 title claims abstract description 103
- 238000009757 thermoplastic moulding Methods 0.000 title claims abstract description 41
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 99
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- 238000000465 moulding Methods 0.000 claims abstract description 20
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
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- 150000001451 organic peroxides Chemical class 0.000 description 3
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- 235000011176 polyphosphates Nutrition 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
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- 238000010526 radical polymerization reaction Methods 0.000 description 3
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
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- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 239000012431 aqueous reaction media Substances 0.000 description 2
- 229910021383 artificial graphite Inorganic materials 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
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- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 238000000825 ultraviolet detection Methods 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- LIXMWXLDPHIZBZ-UHFFFAOYSA-N 4-methyl-5-phenylpenta-2,4-dienenitrile Chemical compound N#CC=CC(C)=CC1=CC=CC=C1 LIXMWXLDPHIZBZ-UHFFFAOYSA-N 0.000 description 1
- XQMVBICWFFHDNN-UHFFFAOYSA-N 5-amino-4-chloro-2-phenylpyridazin-3-one;(2-ethoxy-3,3-dimethyl-2h-1-benzofuran-5-yl) methanesulfonate Chemical compound O=C1C(Cl)=C(N)C=NN1C1=CC=CC=C1.C1=C(OS(C)(=O)=O)C=C2C(C)(C)C(OCC)OC2=C1 XQMVBICWFFHDNN-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
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- 239000004698 Polyethylene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
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- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
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- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
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- 239000004797 high-impact polystyrene Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
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- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
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- VNNBZUFJRRODHO-UHFFFAOYSA-N prop-2-enenitrile;prop-1-en-2-ylbenzene Chemical compound C=CC#N.CC(=C)C1=CC=CC=C1 VNNBZUFJRRODHO-UHFFFAOYSA-N 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
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- 239000011342 resin composition Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- QLUMLEDLZDMGDW-UHFFFAOYSA-N sodium;1h-naphthalen-1-ide Chemical compound [Na+].[C-]1=CC=CC2=CC=CC=C21 QLUMLEDLZDMGDW-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
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- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/06—Copolymers with vinyl aromatic monomers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| EP07112183 | 2007-07-10 | ||
| EP07112183 | 2007-07-10 |
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| ES2361797T3 true ES2361797T3 (es) | 2011-06-22 |
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| ES08774866T Active ES2361797T3 (es) | 2007-07-10 | 2008-07-08 | Composiciones de moldeo termoplásticas pirorretardantes. |
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| DE (1) | DE602008005156D1 (https=) |
| ES (1) | ES2361797T3 (https=) |
| PL (1) | PL2178970T3 (https=) |
| WO (1) | WO2009007358A1 (https=) |
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| JP5666902B2 (ja) * | 2007-05-23 | 2015-02-12 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 反応性基を有するイソタクチックポリスチレン |
| WO2009007370A1 (de) | 2007-07-10 | 2009-01-15 | Basf Se | Flammgeschütztes, elastisches blockcopolymerisat |
| WO2009007358A1 (en) | 2007-07-10 | 2009-01-15 | Basf Se | Flame retardant thermoplastic molding compositions |
| EP2190922B1 (de) | 2007-09-14 | 2011-06-22 | Basf Se | Transparente und zähsteife formmassen auf basis von styrol-butadien-blockcopolymermischungen |
| WO2009121821A1 (de) * | 2008-04-01 | 2009-10-08 | Basf Se | Flammgeschützte thermoplastische formmassen |
| WO2011117312A1 (de) * | 2010-03-26 | 2011-09-29 | Basf Se | Thermoplastische formmassen mit verbesserten optischen eigenschaften |
| WO2012049264A2 (de) | 2010-10-15 | 2012-04-19 | Basf Se | Verfahren zur herstellung flammgeschützter thermoplastischer formmassen |
| US20140323606A1 (en) | 2010-12-16 | 2014-10-30 | Basf Se | Rubber-modified flame-retardant moulding compositions and production thereof |
| US20120319031A1 (en) * | 2011-06-15 | 2012-12-20 | Thermal Solution Resources, Llc | Thermally conductive thermoplastic compositions |
| TWI499648B (zh) * | 2012-11-08 | 2015-09-11 | 阻燃塗料及阻燃基材 | |
| BR112015022164B1 (pt) | 2013-03-15 | 2022-03-15 | Trinseo Europe Gmbh | Compósito de múltiplas camadas |
| CN105307860B (zh) | 2013-03-15 | 2018-11-09 | 阿科玛法国公司 | 多层复合材料 |
| CN104292730A (zh) * | 2014-10-23 | 2015-01-21 | 金宝丽科技（苏州）有限公司 | 一种改性hips复合材料的制备方法 |
| KR102462777B1 (ko) * | 2015-03-25 | 2022-11-03 | 이네오스 스티롤루션 그룹 게엠베하 | 최적화된 가교도를 갖는 열가소성 중합체를 생성시키는 공정 |
| JP7243103B2 (ja) * | 2018-09-26 | 2023-03-22 | 富士フイルムビジネスイノベーション株式会社 | 樹脂組成物、及び樹脂成形体 |
| KR102708792B1 (ko) * | 2020-12-24 | 2024-09-23 | 롯데케미칼 주식회사 | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| CN113930044B (zh) * | 2021-11-10 | 2022-11-01 | 北京化工大学 | 一种阻燃abs复合材料、制备方法及其用途 |
| CN115637593B (zh) * | 2022-10-24 | 2024-07-02 | 东莞市雄林新材料科技股份有限公司 | 一种家用纺织膜 |
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| DE1260135B (de) | 1965-01-05 | 1968-02-01 | Basf Ag | Schlagfeste thermoplastische Formmassen |
| US3639517A (en) * | 1969-09-22 | 1972-02-01 | Phillips Petroleum Co | Resinous branched block copolymers |
| GB1482921A (en) * | 1973-07-31 | 1977-08-17 | Glaxo Lab Ltd | Polymers |
| DE2550227C2 (de) | 1975-11-08 | 1984-12-20 | Basf Ag, 6700 Ludwigshafen | Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung |
| DE2829625A1 (de) | 1978-07-06 | 1980-01-24 | Basf Ag | Staubfreie aussenschmierung fuer polyamid |
| JPS5575441A (en) * | 1978-12-04 | 1980-06-06 | Asahi Chem Ind Co Ltd | Styrene resin composition having excellent impact resistance |
| DE2927572A1 (de) | 1979-07-07 | 1981-01-22 | Basf Ag | Themoplastische formmassen |
| US4810742A (en) * | 1988-02-01 | 1989-03-07 | Occidental Chemical Corporation | UV stable, impact resistant, flame retarded ABS composition containing aliphatic resin |
| DE4011162A1 (de) | 1990-04-06 | 1991-10-10 | Basf Ag | Thermoplastische formmasse |
| JP3431944B2 (ja) | 1992-03-19 | 2003-07-28 | 東ソー株式会社 | 難燃性ポリオレフィン系樹脂組成物 |
| EP0698639B1 (en) | 1993-03-30 | 1998-12-30 | Nippon Zeon Co., Ltd. | Rubber composition |
| CA2134026C (en) | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
| KR100203633B1 (ko) * | 1994-06-16 | 1999-06-15 | 유현식 | 비할로겐화 난연제를 함유한 난연성 스티렌계 수지조성물 |
| DE4420952A1 (de) * | 1994-06-17 | 1995-12-21 | Basf Ag | Thermoplastisches Elastomer |
| US5942561A (en) * | 1995-03-03 | 1999-08-24 | Tosoh Corporation | Fire-retardant polymer composition |
| DE19810141A1 (de) * | 1998-03-10 | 1999-09-16 | Basf Ag | Polymermischungen aus Styrolpolymeren |
| DE19858141A1 (de) * | 1998-12-16 | 2000-06-21 | Basf Ag | Thermoplasische Formmassen |
| DE19914075A1 (de) | 1999-03-27 | 2000-09-28 | Basf Ag | Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren |
| US6593430B1 (en) * | 1999-03-27 | 2003-07-15 | Basf Aktiengesellschaft | Transparent, impact-resistant polystyrene on a styrene-butadiene block copolymer basis |
| DE10037280A1 (de) | 2000-07-28 | 2002-02-07 | Basf Ag | Verfahren zur Agglomeration dispergierter Kautschuke |
| EP1368425A2 (en) * | 2000-09-15 | 2003-12-10 | Dow Global Technologies Inc. | Styrenic polymer compositions with improved clarity |
| FR2824347B1 (fr) | 2001-05-04 | 2003-08-08 | Filclair Sa | Dispositif de couverture reversible de toiture de batiments de type serre par une bache |
| IL146821A0 (en) | 2001-11-29 | 2002-07-25 | Bromine Compounds Ltd | Fire retarded polymer composition |
| IL161592A0 (en) | 2004-04-22 | 2004-09-27 | Bromine Compounds Ltd | Fire retarded styrene polymer compositions |
| AT500875A1 (de) | 2004-07-23 | 2006-04-15 | Intumex Gmbh | Intumeszierende klippprofile für brandschutzeinrichtungen |
| DE102004058584A1 (de) | 2004-12-03 | 2006-06-08 | Basf Ag | Strahlungshärtbare Beschichtungsmassen |
| DE102005001637A1 (de) | 2005-01-12 | 2006-07-20 | Basf Ag | Styrol-Butadien-Blockcopolymermischungen für Schrumpffolien |
| DE102005006137B4 (de) | 2005-02-10 | 2007-09-13 | Wacker Chemie Ag | Verfahren zum Engergieeintrag durch Heizdampf mittels einer Vorrichtung zur Wärmeübertragung |
| JP4681382B2 (ja) | 2005-07-28 | 2011-05-11 | 帝人化成株式会社 | 熱可塑性樹脂組成物 |
| KR101322076B1 (ko) * | 2006-06-27 | 2013-10-30 | 바스프 에스이 | 고투명성 및 인성-강성 스티렌-부타디엔 블록 공중합체 혼합물 |
| US8545953B2 (en) | 2007-02-28 | 2013-10-01 | Styrolution GmbH | Hollow polystyrene body obtained by injection stretch blow moulding |
| JP5666902B2 (ja) * | 2007-05-23 | 2015-02-12 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 反応性基を有するイソタクチックポリスチレン |
| WO2009007358A1 (en) | 2007-07-10 | 2009-01-15 | Basf Se | Flame retardant thermoplastic molding compositions |
| WO2009037236A1 (de) | 2007-09-18 | 2009-03-26 | Basf Se | Flammgeschütztes polystyrol und schlagzäh modifiziertes polystyrol |
| CN101855271B (zh) | 2007-11-13 | 2013-11-06 | 巴斯夫欧洲公司 | 制备聚芳醚的方法 |
| JP2011506664A (ja) | 2007-12-13 | 2011-03-03 | ビーエーエスエフ ソシエタス・ヨーロピア | 熱可塑性リノリウム |
| WO2009121821A1 (de) | 2008-04-01 | 2009-10-08 | Basf Se | Flammgeschützte thermoplastische formmassen |
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Also Published As
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| CN101688038B (zh) | 2013-01-16 |
| EP2178970B1 (en) | 2011-02-23 |
| KR20100040845A (ko) | 2010-04-21 |
| EP2178970A1 (en) | 2010-04-28 |
| US20100210766A1 (en) | 2010-08-19 |
| DE602008005156D1 (https=) | 2011-04-07 |
| CN101688038A (zh) | 2010-03-31 |
| US8129455B2 (en) | 2012-03-06 |
| ATE499411T1 (de) | 2011-03-15 |
| PL2178970T3 (pl) | 2011-07-29 |
| WO2009007358A1 (en) | 2009-01-15 |
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