ES2309737T5 - Partículas de agente de blanqueo recubiertas con un material soluble en agua - Google Patents
Partículas de agente de blanqueo recubiertas con un material soluble en agua Download PDFInfo
- Publication number
- ES2309737T5 ES2309737T5 ES05728973.8T ES05728973T ES2309737T5 ES 2309737 T5 ES2309737 T5 ES 2309737T5 ES 05728973 T ES05728973 T ES 05728973T ES 2309737 T5 ES2309737 T5 ES 2309737T5
- Authority
- ES
- Spain
- Prior art keywords
- acid
- weight
- peroxocarboxylic
- core
- polyvinyl alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
- Air Humidification (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004018790A DE102004018790B4 (de) | 2004-04-15 | 2004-04-15 | Wasserlöslich umhüllte Bleichmittelteilchen |
| DE102004018790 | 2004-04-15 | ||
| PCT/EP2005/003699 WO2005100525A1 (de) | 2004-04-15 | 2005-04-08 | Wasserlöslich umhüllte bleichmittelteilchen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2309737T3 ES2309737T3 (es) | 2008-12-16 |
| ES2309737T5 true ES2309737T5 (es) | 2014-11-19 |
Family
ID=34963186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES05728973.8T Expired - Lifetime ES2309737T5 (es) | 2004-04-15 | 2005-04-08 | Partículas de agente de blanqueo recubiertas con un material soluble en agua |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7897556B2 (https=) |
| EP (1) | EP1735422B2 (https=) |
| JP (1) | JP4920576B2 (https=) |
| AT (1) | ATE405629T1 (https=) |
| DE (2) | DE102004018790B4 (https=) |
| ES (1) | ES2309737T5 (https=) |
| WO (1) | WO2005100525A1 (https=) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050187782A1 (en) * | 2004-02-24 | 2005-08-25 | First Data Corporation | System for maintaining account and presentation instrument data |
| GB0509377D0 (en) | 2005-05-09 | 2005-06-15 | Reckitt Benckiser Nv | Detergent composition |
| DE102005063108A1 (de) * | 2005-12-30 | 2007-07-12 | Advanced Micro Devices, Inc., Sunnyvale | Technik zur Herstellung eines Isolationsgrabens als eine Spannungsquelle für die Verformungsverfahrenstechnik |
| ES2386650T3 (es) * | 2006-04-04 | 2012-08-24 | Basf Se | Sistemas de blanqueo revestidos en forma de capa con polímeros |
| US8772220B2 (en) | 2007-08-24 | 2014-07-08 | Sekisui Specialty Chemicals America, Llc | Chemical delivery product and process for making the same |
| JP5401034B2 (ja) * | 2007-12-19 | 2014-01-29 | ライオン株式会社 | 漂白助剤、および該漂白助剤を含有する漂白助剤粒子 |
| GB0906281D0 (en) | 2009-04-09 | 2009-05-20 | Reckitt Benckiser Nv | Detergent compositions |
| GB0918914D0 (en) * | 2009-10-28 | 2009-12-16 | Revolymer Ltd | Composite |
| GB201003892D0 (en) | 2010-03-09 | 2010-04-21 | Reckitt Benckiser Nv | Detergent composition |
| US20110294715A1 (en) * | 2010-05-26 | 2011-12-01 | Johan Smets | Encapsulates |
| MX2013000792A (es) * | 2010-07-20 | 2013-02-27 | Procter & Gamble | Particulas con una pluralidad de recubrimientos. |
| GB201019623D0 (en) | 2010-11-19 | 2010-12-29 | Reckitt Benckiser Nv | Coated bleach materials |
| GB201019628D0 (en) | 2010-11-19 | 2010-12-29 | Reckitt Benckiser Nv | Dyed coated bleach materials |
| GB201106377D0 (en) * | 2011-04-15 | 2011-06-01 | Reckitt & Colman Overseas | Novel composite |
| BR112014005193A2 (pt) * | 2011-09-13 | 2017-03-21 | Procter & Gamble | encapsulados |
| FR2990685B1 (fr) | 2012-05-21 | 2014-11-21 | Eurocopter France | Procede de commande des volets d'ailes et de l'empennage horizontal d'un helicoptere hybride |
| GB201402257D0 (en) * | 2014-02-10 | 2014-03-26 | Revolymer Ltd | Novel Peracid - containing particle |
| US9273270B2 (en) * | 2014-02-20 | 2016-03-01 | Church & Dwight Co., Inc. | Unit dose cleaning products for delivering a peroxide-containing bleaching agent |
| US9783766B2 (en) | 2015-04-03 | 2017-10-10 | Ecolab Usa Inc. | Enhanced peroxygen stability using anionic surfactant in TAED-containing peroxygen solid |
| US10280386B2 (en) | 2015-04-03 | 2019-05-07 | Ecolab Usa Inc. | Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid |
| EP4349951B1 (en) | 2018-06-15 | 2026-03-18 | Ecolab USA Inc. | Enhanced peroxygen stability using fatty acid in bleach activating agent containing peroxygen solid |
| GB2628608A (en) | 2023-03-30 | 2024-10-02 | Reckitt Benckiser Vanish Bv | Bleach catalyst with improved performance and composition comprising said catalyst |
Family Cites Families (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3158615A (en) * | 1960-07-20 | 1964-11-24 | Union Carbide Corp | Stabilized polymerizable vinyl pyridines |
| DE1519429B2 (de) † | 1964-06-02 | 1973-08-02 | Wyner, Jay S., Jamaica, N. Y. (V.St.A.) | Ueberzugs- und poliermittel |
| US3770816A (en) * | 1969-07-23 | 1973-11-06 | Ppg Industries Inc | Diperisophthalic acid compositions |
| US3908045A (en) * | 1973-12-07 | 1975-09-23 | Lever Brothers Ltd | Encapsulation process for particles |
| GB1568358A (en) * | 1975-11-18 | 1980-05-29 | Interox Chemicals Ltd | Aromatic peroxyacids and their use in bleaching processes |
| DE3128336A1 (de) * | 1981-07-17 | 1983-01-27 | Henkel KGaA, 4000 Düsseldorf | "verfahren zur herstellung umhuellter koerniger bleichaktivatoren" |
| DE3266563D1 (en) * | 1981-09-08 | 1985-10-31 | Interox Chemicals Ltd | Granulation |
| JPS58217598A (ja) | 1982-06-10 | 1983-12-17 | 日本油脂株式会社 | 洗剤組成物 |
| US4524009A (en) * | 1984-01-31 | 1985-06-18 | A. E. Staley Manufacturing Company | Detergent builder |
| CA1238917A (en) | 1984-01-31 | 1988-07-05 | Vivian B. Valenty | Detergent builder |
| DE3413571A1 (de) * | 1984-04-11 | 1985-10-24 | Hoechst Ag, 6230 Frankfurt | Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung |
| US4639325A (en) * | 1984-10-24 | 1987-01-27 | A. E. Staley Manufacturing Company | Detergent builder |
| FR2597473B1 (fr) | 1986-01-30 | 1988-08-12 | Roquette Freres | Procede d'oxydation de di-, tri-, oligo- et polysaccharides en acides polyhydroxycarboxyliques, catalyseur mis en oeuvre et produits ainsi obtenus. |
| DE3706036A1 (de) * | 1987-02-25 | 1988-09-08 | Basf Ag | Polyacetale, verfahren zu deren herstellung aus dialdehyden und polyolcarbonsaeuren und verwendung der polyacetale |
| US5096781A (en) | 1988-12-19 | 1992-03-17 | Ciba-Geigy Corporation | Water-soluble compounds as light stabilizers |
| DE3914131A1 (de) | 1989-04-28 | 1990-10-31 | Henkel Kgaa | Verwendung von calcinierten hydrotalciten als katalysatoren fuer die ethoxylierung bzw. propoxylierung von fettsaeureestern |
| DK0427349T3 (da) | 1989-11-10 | 1995-11-20 | Tno | Fremgangsmåde til fremstilling af polydicarboxysaccharider, og erstatninger for phosphater i detergenter baseret på polydicarboxsaccharider |
| US5200236A (en) † | 1989-11-15 | 1993-04-06 | Lever Brothers Company, Division Of Conopco, Inc. | Method for wax encapsulating particles |
| YU221490A (sh) | 1989-12-02 | 1993-10-20 | Henkel Kg. | Postupak za hidrotermalnu izradu kristalnog natrijum disilikata |
| DE4012769A1 (de) * | 1990-04-21 | 1991-10-24 | Hoechst Ag | Stabile peroxicarbonsaeuregranulate |
| IT1249883B (it) | 1990-08-13 | 1995-03-30 | Ferruzzi Ricerca & Tec | Agenti sequestranti del calcio a base di carboidrati ossidati e loro impiego come builder per detergenti |
| IT1245063B (it) | 1991-04-12 | 1994-09-13 | Ferruzzi Ricerca & Tec | Procedimento per l'ossidazione di carboidrati |
| EP0510761B1 (en) | 1991-04-24 | 1995-03-08 | Unilever N.V. | Wax-encapsulated particles and method for making same |
| JP3008047B2 (ja) | 1991-05-31 | 2000-02-14 | 株式会社ネリキ | ボンベバルブ用ガス充填装置 |
| DE4134914A1 (de) | 1991-10-23 | 1993-04-29 | Henkel Kgaa | Wasch- und reinigungsmittel mit ausgewaehlten builder-systemen |
| ATE166362T1 (de) | 1991-11-14 | 1998-06-15 | Procter & Gamble | C6/c2-c3 oxidierte stärke als waschmittelbestandteil |
| DE4221381C1 (de) | 1992-07-02 | 1994-02-10 | Stockhausen Chem Fab Gmbh | Pfropf-Copolymerisate von ungesättigten Monomeren und Zuckern, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE4203923A1 (de) * | 1992-02-11 | 1993-08-12 | Henkel Kgaa | Verfahren zur herstellung von polycarboxylaten auf polysaccharid-basis |
| WO1994000524A1 (en) † | 1992-06-23 | 1994-01-06 | Monsanto Company | Uv-absorbing polymer latex |
| DE4300772C2 (de) * | 1993-01-14 | 1997-03-27 | Stockhausen Chem Fab Gmbh | Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE4303320C2 (de) | 1993-02-05 | 1995-12-21 | Degussa | Waschmittelzusammensetzung mit verbessertem Schmutztragevermögen, Verfahren zu dessen Herstellung und Verwendung eines geeigneten Polycarboxylats hierfür |
| DE4317519A1 (de) * | 1993-05-26 | 1994-12-01 | Henkel Kgaa | Herstellung von Polycarboxylaten auf Polysaccharid-Basis |
| DE4321022A1 (de) | 1993-06-24 | 1995-01-05 | Henkel Kgaa | Sulfatierte Hydroxymischether |
| NL194919C (nl) | 1993-09-07 | 2003-07-04 | Tno | Werkwijze voor het oxideren van koolhydraten. |
| NL9301905A (nl) | 1993-11-04 | 1995-06-01 | Inst Voor Agrotech Onderzoek | Werkwijze voor het oxideren van koolhydraten. |
| US5434069A (en) * | 1993-11-12 | 1995-07-18 | Lever Brothers Company, Division Of Conopco, Inc. | Capsule comprising oil surrounding hydrophobic or hydrophilic active and polymeric shell surrounding oil |
| EP0653485B1 (en) * | 1993-11-12 | 2000-05-17 | Unilever N.V. | Detergent composition |
| GB9326358D0 (en) | 1993-12-23 | 1994-02-23 | Ciba Geigy Ag | Compositions for the treatment of textiles |
| DE4400024A1 (de) | 1994-01-03 | 1995-07-06 | Henkel Kgaa | Silikatische Builder und ihre Verwendung in Wasch- und Reinigungsmitteln sowie Mehrstoffgemische für den Einsatz auf diesem Sachgebiet |
| DE4402051A1 (de) | 1994-01-25 | 1995-07-27 | Henkel Kgaa | Gerüststoff für Wasch- oder Reinigungsmittel |
| WO1995019955A1 (en) | 1994-01-25 | 1995-07-27 | The Procter & Gamble Company | Gemini polyether fatty acid amides and their use in detergent compositions |
| US5512699A (en) | 1994-01-25 | 1996-04-30 | The Procter & Gamble Company | Poly polyhydroxy fatty acid amides |
| US5534197A (en) | 1994-01-25 | 1996-07-09 | The Procter & Gamble Company | Gemini polyhydroxy fatty acid amides |
| DE4402851A1 (de) * | 1994-01-31 | 1995-08-03 | Henkel Kgaa | Wirbelschicht-Oxidationsverfahren zur Herstellung von Polycarboxylaten auf Polysaccharid-Basis |
| US5494448A (en) * | 1994-03-15 | 1996-02-27 | Motorola, Inc. | Cantilever spring and method for temporarily coupling a semiconductor device to a transmission line using the cantilever spring |
| ES2225833T3 (es) | 1994-05-12 | 2005-03-16 | Ciba Specialty Chemicals Holding Inc. | Tratamiento textil. |
| DE4417734A1 (de) | 1994-05-20 | 1995-11-23 | Degussa | Polycarboxylate |
| GB9419091D0 (en) | 1994-09-22 | 1994-11-09 | Cerestar Holding Bv | Process for decreasing the build up of inorganic incrustations on textiles and detergent composition used in such process |
| DE19503061A1 (de) | 1995-02-01 | 1996-08-08 | Henkel Kgaa | Dimeralkohol-bis- und Trimeralkohol-tris-sulfate und -ethersulfate |
| US5547612A (en) | 1995-02-17 | 1996-08-20 | National Starch And Chemical Investment Holding Corporation | Compositions of water soluble polymers containing allyloxybenzenesulfonic acid monomer and methallyl sulfonic acid monomer and methods for use in aqueous systems |
| GB9503474D0 (en) | 1995-02-22 | 1995-04-12 | Ciba Geigy Ag | Compounds and their use |
| DE19513391A1 (de) | 1995-04-08 | 1996-10-10 | Henkel Kgaa | Bi- und multifunktionelle Mischether |
| US5589370A (en) * | 1995-08-01 | 1996-12-31 | Lever Brothers Company, Division Of Conopco, Inc. | Process for encapsulating sensitive materials |
| SK282287B6 (sk) * | 1995-10-16 | 2002-01-07 | Unilever Nv | Zapuzdrené bieliace častice, spôsob ich výroby a bieliaca detergentná zmes |
| DE19540086A1 (de) | 1995-10-27 | 1997-04-30 | Henkel Kgaa | Verwendung von polymeren Aminodicarbonsäuren in Waschmitteln |
| US5922607A (en) * | 1995-12-13 | 1999-07-13 | Bernreuter; Peter | Measuring process for blood gas analysis sensors |
| DE19600018A1 (de) | 1996-01-03 | 1997-07-10 | Henkel Kgaa | Waschmittel mit bestimmten oxidierten Oligosacchariden |
| GB9617322D0 (en) | 1996-08-17 | 1996-09-25 | Ciba Geigy Ag | Triazine derivatives and their use |
| IT1289155B1 (it) † | 1997-01-03 | 1998-09-29 | Ausimont Spa | Composizioni granulari di acido e-ftalimmido perossiesanoico |
| JP2000509757A (ja) * | 1997-08-05 | 2000-08-02 | ザ、プロクター、エンド、ギャンブル、カンパニー | 脱色組成物 |
| AU9576798A (en) † | 1998-09-23 | 2000-04-10 | Procter & Gamble Company, The | Coated perborate bleach and compositions containing the same |
| WO2000063336A1 (en) * | 1999-04-19 | 2000-10-26 | The Procter & Gamble Company | Enzyme composite particles having an acidic barrier and a physical barrier coating |
| DE10019936A1 (de) * | 1999-12-04 | 2001-10-25 | Henkel Kgaa | Wasch- und Reinigungsmittel |
| DE10010760A1 (de) * | 2000-03-04 | 2001-09-20 | Henkel Kgaa | Mehrphasige Wasch- und Reinigungsmittelformkörper mit nicht-gepreßten Anteilen |
| AU2001287580A1 (en) * | 2000-07-14 | 2002-01-30 | Henkel Kommanditgesellschaft Auf Aktien | Hollow bodies with compartments |
| JP2004512423A (ja) * | 2000-10-27 | 2004-04-22 | ジェネンコア インターナショナル インコーポレーテッド | 置換されたポリビニルアルコール塗膜を有する粒子 |
| US6492312B1 (en) * | 2001-03-16 | 2002-12-10 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Water soluble sachet with a dishwashing enhancing particle |
| US6475977B1 (en) † | 2001-03-16 | 2002-11-05 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Water soluble sachet with a dishwasher composition |
| DE10237200A1 (de) * | 2002-08-14 | 2004-03-04 | Henkel Kgaa | Portionierte Wasch- oder Reinigungsmittelzusammensetzung |
| WO2004046300A1 (en) * | 2002-11-14 | 2004-06-03 | The Procter & Gamble Company | Rinse aid containing encapsulated glasscare active salt |
| CN1751116A (zh) * | 2003-02-18 | 2006-03-22 | 诺和酶股份有限公司 | 洗涤剂组合物 |
| ES2287711T3 (es) * | 2003-03-11 | 2007-12-16 | Reckitt Benckiser N.V. | Envase que comprende una composicion detergente. |
| DE10313458A1 (de) * | 2003-03-25 | 2004-11-18 | Henkel Kgaa | Wasch- oder Reinigungsmittel |
-
2004
- 2004-04-15 DE DE102004018790A patent/DE102004018790B4/de not_active Expired - Fee Related
-
2005
- 2005-04-08 JP JP2007507716A patent/JP4920576B2/ja not_active Expired - Fee Related
- 2005-04-08 EP EP05728973.8A patent/EP1735422B2/de not_active Expired - Lifetime
- 2005-04-08 AT AT05728973T patent/ATE405629T1/de not_active IP Right Cessation
- 2005-04-08 ES ES05728973.8T patent/ES2309737T5/es not_active Expired - Lifetime
- 2005-04-08 DE DE502005005113T patent/DE502005005113D1/de not_active Expired - Lifetime
- 2005-04-08 WO PCT/EP2005/003699 patent/WO2005100525A1/de not_active Ceased
-
2006
- 2006-10-04 US US11/542,810 patent/US7897556B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1735422A1 (de) | 2006-12-27 |
| US7897556B2 (en) | 2011-03-01 |
| US20070093402A1 (en) | 2007-04-26 |
| WO2005100525A1 (de) | 2005-10-27 |
| DE102004018790B4 (de) | 2010-05-06 |
| ES2309737T3 (es) | 2008-12-16 |
| JP4920576B2 (ja) | 2012-04-18 |
| DE102004018790A1 (de) | 2005-11-10 |
| ATE405629T1 (de) | 2008-09-15 |
| JP2007532727A (ja) | 2007-11-15 |
| EP1735422B1 (de) | 2008-08-20 |
| DE502005005113D1 (de) | 2008-10-02 |
| EP1735422B2 (de) | 2014-10-15 |
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