WO1994000524A1 - Uv-absorbing polymer latex - Google Patents
Uv-absorbing polymer latex Download PDFInfo
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- WO1994000524A1 WO1994000524A1 PCT/US1993/005938 US9305938W WO9400524A1 WO 1994000524 A1 WO1994000524 A1 WO 1994000524A1 US 9305938 W US9305938 W US 9305938W WO 9400524 A1 WO9400524 A1 WO 9400524A1
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- latex
- vinyl
- polymer
- absorbing
- agent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
Definitions
- UV-ABSORBING POLYMER LATEX Disclosed herein are aqueous latices of UV- absorbing polymer adapted to forming laminate coatings of visible light transparent, coherent polymeric film and methods of making and using such latices and laminates.
- Japanese Ko ai 57-45169 and 58-38269 disclose solvent polymerization of copolymers containing UV-absorbing monomer units useful as coating additives. Specifically disclosed copolymers comprise up to about 22 mole percent (about 30 weight percent) benzotriazole UV-absorbing monomer units an a non-UV-absorbing co onomer such as methyl ethacry- late, styrene or butyl acrylate.
- U.S. Patent 4,528,311 discloses optically clear UV-absorbing copolymers comprising up to 20 weight percent of 2-hydroxy-5-acrylyloxyphenyl-2H- benzotriazoles for UV-absorbing films that afford 85% absorption at 400 nanometers and 1 millimeter thickness.
- U.S. Patent 4,576,870 discloses coextruded laminates comprising UV-absorbing polymer coatings (10-100 microns thick) comprising up to 20 weight percent of 2-hydroxyphenylbenzotriazole monomers.
- U.S. Patents 4,785,063 and 4,892,915 disclose incorporation of 2-(2-hydroxy-5-acryloyl- oxyalkyl)-phenyl-2H-benzotriazoles UV-absorbing copolymerizable additives at low levels, e.g. at about 2 percent, in acrylate coatings which are cured by E- beam radiation.
- U.S. Patent 4,927,891 discloses acrylic coating resins with up to 20 weight percent hydrazide functionalized light stabilizers, e.g. hindered amine light stabilizers, 2-hydroxybenzophenones, 2-(2- hydroxyphenyl)-2H-benzotriazoles, aryl salicylates and oxalanilides.
- EPO 0 282 294 discloses optically clear silicone polymers containing vinylsilylalkoxy arylben- zotriazole monomer units.
- U.S. Patents 3,745,010 and 3,761,272 disclose emulsion polymerized, UV-absorbing benzotria ⁇ zole acrylate copolymers useful in photographic appli ⁇ cations, e.g. to protect photographic film against UV radiation.
- Copolymers e.g. of methylmethacrylate or butylacrylate and 2-70% benzotriazole-functionalized methacrylates, are useful at up to 40% by weight in
- UV-absorbing layers For instance, glass coated with gelatin and emulsions of such UV-absorbing copolymers provided photographic filters having a maximum absorp ⁇ tion at 352 nm.
- U.S. Patents 4,612,358 and 4,652,656 disclose UV-absorbing copolymers of 20-60 percent benzotriazole-functionalized acrylamides useful for protective layers for UV sensitive plastics. Bulk polymerized copolymers comprised methyl methacrylate and 20 weight percent benzotriazole monomer. Emulsion polymerized copolymers comprising methylmethacrylate and 50 weight percent'benzotriazole monomer were prepared in large particle size (100 micron) . Such UV-absorbing copolymers are said to be useful for providing a UV protective layer for a UV sensitive plastic.
- U.S. Patents 4,443,534 and 4,455,368 disclose UV-absorbing copolymer latex useful in UV- absorbing protective layers for photographic film, e.g. light sensitive silver halide material.
- This invention provides aqueous latices adapted to forming visible light-transparent, coherent polymeric films, e.g. in laminates, as protective coatings or as adhesives.
- the latices comprise colloidal particles of a UV-absorbing polymer suspended in a substantially aqueous medium. wherein said particles are less than 5 micrometers in diameter.
- Useful UV-absorbing polymer include homopolymers and copolymers of vinyl-functionalized monomer of benzotriazole or benzophenone and mixtures with plasticizer and/or coalescing agent. Plasticizer and coalescing agents are useful for providing polymer with reduced glass transition temperature (Tg) to facilitate coalescence of polymer particles into coherent films.
- Useful additives for the latices of this invention include wetting agents, surfactants, and crosslinking agents, anti-oxidants and radical scavengers.
- the latices of this invention are particularly useful in providing clear, thin coatings on UV-susceptible substrates; such coatings can be applied as topcoats, as intermediate layers in a laminate or as adhesive layers.
- the specific application of the UV-absorbing polymer coating will depend on the intended use of the substrate, e.g. as a coating to protect outdoor articles such as tents, labels, posters and signs, as a UV barrier on glass or plastic windows, display cases and containers, as an intermediate or top coat on flooring; as an adhesive to apply decals or transparent films to transparent substrates, or as a compounding additive for colorfast inks.
- FIGS 1 and 2 illustrate the efficacy of films of copolymers of this invention in abating transmission of UV radiation.
- Figures 3A and 3B illustrate the efficacy of a copolymer of this invention in abating transmission of UV radiation from fluorescent lamps.
- DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS The aqueous latices of this invention are adapted to forming visible light-transparent, coherent polymeric films, e.g. in laminates, as protective coatings or as adhesives.
- the latices comprise colloidal particles of a UV-absorbing polymer suspended in a substantially aqueous medium, i.e. the medium is primarily water with minor amounts of organic adjuvants which may be useful in providing enhanced coating properties or solubility to additives.
- the UV-absorbing polymers of this invention include homopolymers of vinyl-functionalized UV-absorbing monomer of benzotriazole or benzophenone, e.g. an acrylate or methacrylate functionalized benzotriazole or benzophenone such as 2-(2'-hydroxy-5- methacrylyloxyethylphenyl)-2H-benzotriazole, 2-(2'- hydroxy-3-tertbutyl-5-(methacrylyloxyethyl)phenyl prop'ionate)-2H-benzotriazole and 2-hydroxy-4-acrylyl oxyethoxy benzophenone.
- an acrylate or methacrylate functionalized benzotriazole or benzophenone such as 2-(2'-hydroxy-5- methacrylyloxyethylphenyl)-2H-benzotriazole, 2-(2'- hydroxy-3-tertbutyl-5-(methacrylyloxyethyl)phenyl prop'ionate)-2H-benzo
- Preferred UV-absorbing polymers useful in this invention are copolymers of at least 20 weight percent of vinyl-functionalized monomer of benzotriazole or benzophenone and up to 80 percent by weight of one or more other vinyl monomers. More preferably, the UV-absorbing copolymers of this invention comprise at least 30 weight percent vinyl- functionalized UV-absorbing monomer, even more preferably at least 40 weight percent and not more than 80 weight percent of UV-absorbing monomer, say between 45 and 75 weight percent.
- vinyl monomers useful in the copolymers of this invention include acrylic acid and esters thereof such as ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, hydroxyethyl acrylate, hydroxypropyl acrylate and carboxyethy1aerylate; methacrylic acid and esters thereof such as methyl ⁇ methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate and decylmethacrylate; hydroxyvinyl compounds such as hydroxyethyl methacrylate, hydroxypropyl methacrylate and hydroxyethylacrylate; vinyl aromatics such as styrene; cyano compounds such as acrylonitrile and acrylamide; vinyl acids such a maleic acid, maleic anhydride or acrylic acid; vinyl esters such as vinyl acetate, vinyl formal and vinyl butyral; crosslinking monomers such as glycidy
- Preferred other vinyl monomers include predominately acrylates and methacrylates.
- the selection of the non-UV-absorbing comonomers will generally be made depending on application performance criteria, such as desired Tg, adhesiveness, compatibility with other materials in a laminate, toughness, flexibility, etc.
- a mixture of non-UV- absorbing monomers can be useful, e.g. methylmethacrylate can provide high Tg and hydroxyethyl acrylate can provide enhanced adhesion.
- aqueous latices for providing UV- absorbing films provides an environmental advantage, e.g. the avoidance of volatile organic solvents.
- Such latices can be prepared by emulsion polymerization of the monomer units using well known techniques using surfactants and modifiers such as acrylic acid, carboxyethylacrylate and hydroxyethylmethacrylate.
- Useful surfactants include non-ionic alkaryl polyether alcohols and anionic alkaryl polyether sulfonates.
- Mixtures of surfactant dispersed vinyl monomers can be polymerized by the action of a radical initiator, e.g. potassium persulfate.
- a radical initiator e.g. potassium persulfate.
- colloidal latices of the polymers of this invention in desirable particle size diameter, e.g. less than 5 micrometers, more preferably less than l micrometer, even more preferably between 0.05 and 0.5 micrometers.
- Small particle size of colloidal polymer facilitates the preparations of desirable thin films, e.g. less than 25 micrometers, preferably on the order of 1 to 5 micrometers.
- the polymers of this invention can have a Tg in the range of -50 ⁇ C to 150 °C depending on the desired application.
- preferred coatings of UV-absorbing copolymers have a Tg greater than 20 °C, preferably at least 50 'C or higher.
- Higher Tg copolymers can be prepared by selecting appropriate comonomers, e.g. higher levels of monomers such as methylmethacrylate, styrene or acrylonitrile and lower levels of monomers such as butyl acrylate.
- heat treatment may be necessary to achieve sufficient coalescence of polymer particles to effect a coherent, uniform, smooth coating.
- high Tg copolymer coatings can be achieved by providing a latex of a crosslinkable polymer, e.g. a copolymer with crosslinking monomer units.
- Cross- linking monomer units can comprise a variety of pendant groups, e.g. vinyl, acid, hydroxyl, epoxy or isocyante groups or mixtures thereof.
- UV-absorbing copolymer comprising small amounts of vinyl alcohol and glycidyl methacrylate monomer units can readily self polymerize to provide a crosslinked film.
- Adjunct crosslinking agents can be also incorporated into the dispersed polymer or be independently dispersed in the aqueous medium.
- adjunct crosslinking agents can comprise metal driers such as ammonium zirconylcarbonate, calcium acetate, zinc oxide, drying oils such as surfactant-stabilized unsaturated fatty acids, polyepoxy or polyvinyl compounds or mixtures thereof, urea-formaldhyde compounds such as methylated urea-formaldehyde resin or melamine-formaldehyde compounds such as methylated melamine-formaldehyde resin.
- metal driers such as ammonium zirconylcarbonate, calcium acetate, zinc oxide
- drying oils such as surfactant-stabilized unsaturated fatty acids, polyepoxy or polyvinyl compounds or mixtures thereof
- urea-formaldhyde compounds such as methylated urea-formaldehyde resin or melamine-formaldehyde compounds such as methylated melamine-formaldehyde resin.
- a stablized UV-absorbing copolymer film can be also be achieved by blending a latex of the UV- absorbing copolymer with a latex of a crosslinked network-forming resin such as an alkyd resin.
- Cross ⁇ linking can promote high Tg, toughness, solvent resistance.
- preferred latices which are more amenable to coating applications comprise suspended polymer having a Tg lower than the Tg desired for the polymer coating application.
- Such latices comprise copolymer having a Tg greater than 0 °C, preferably greater than 20 ⁇ C.
- desirable UV-absorbing films can be achieved using polymers that are enhanced with plasticizer and/or coalescing agents which can reduce the Tg of the polymer to facilitate film formation at lower temperatures.
- Useful coalescing agents comprise volatile solvent for said polymer added in an amount sufficient to swell the polymer and thereby reduce the Tg of the polymer in the latex to less than 50 °C, preferably to less than 30 ⁇ C. Upon drying and film formation the volatile coalescing agent should be expelled from the polymer providing a film with a substantially increased Tg as compared to the Tg of the latex-dispersed polymer.
- Useful latices of this invention comprising otherwise high Tg polymer can comprise up to 20 percent by weight of a volatile solvent as a coalescing agent.
- fast evaporating solvents such as acetone, ethyl acetate, methyl ethyl ketone, isopropyl acetate, isopropyl ether and tetrahydro- furan
- medium evaporating solvents such as isobutyl acetate, n-butyl acetate, sec-butyl acetate, sec-butyl alcohol, tert-butyl alcohol, diethyl ketone, ethyl alcohol, methyl alcohol, methyl isobutyl ketone, methyl isopropyl ketone, methyl n-propyl ketone, 2-nitropropane, n-propyl acetate, isopropyl alcohol and n-propyl alcohol; and slow evaporating solvents such as amyl acetate, tert-amyl alcohol, isobutyl alcohol, n-butyl alcohol, diethylene glycol monobutyl
- Especially preferred coalescing agents are selected from the group consisting of diethylene glycol monoethyl ether, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, diethylene glycol monobutyl ether, ethylene glycol monobutyl ether, propylene glycol monobutyl ether and N-methyl-2-pyrrolidone.
- plasticizer can also impart other desirable properties to films made from the polymers having a high level of UV-absorbing monomer. Properties imparted by plasticizer include flexibility, toughness, flame retardance, low temperature flexibility and improved adhesion.
- the type and amount of plasticizer can be selected by those skilled in the acrylic polymer compounding art, regardless of whether a polymer of this invention is applied as a soft adhesive film, a tough thermoplastic film or a crosslinked thermosetting film. Plasticizer can be added to the polymer during emulsion polymeri- zation.
- Plasticizer can also be incorporated by intimately mixing dispersed plasticizer with dispersed polymer.
- Useful plasticizer can include alkyl adipate esters such as dioctyl adipate, alkyl aryl adipate esters such as benzyl octyl adipate, benzoate esters such as diethylene glycol dibenzoate, alkyl phthalate esters such as di-2-ethylhexyl phthalate and mixed alkyl phthalate esters such as heptyl nonyl undecyl phthalate, aryl phthalate esters such as diphenyl phthalate, alkyl aryl phthalate esters such as butyl benzyl phthalate, alkyl citrate esters such as triethyl citrate and aryl phosphate esters such as triphenyl phosphate.
- Preferred plasticizers for acrylic polymers of this invention include alkyl aryl phosphate esters such as 2-ethylhexyl diphenyl phosphate and isodecyl diphenyl phosphate which provide desired clarity, low temperature flexibility and fire retardance.
- a plasticizer such as butyl benzyl phthalate is useful.
- coalescing agent and plasticizer into the latex-dispersed polymer of this invention.
- the latices of this invention can be enhanced by a variety of other common coating additives, e.g. thickening agents, wetting agents, anti-oxidants such as hindered phenols, radical scavengers such as hindered amines, slip and mar agents such as silicones, biocides, fire retardants and even pigments or dyes.
- the latices of this invention typically comprise less than 1 percent by weight of a water soluble thickening agent including natural gums such as alginates, cellulosics such as methylcellulose, carboxymethylcellulose and hydroxypropyl methylcellu ⁇ lose, polyacrylic acids and salts thereof, and water soluble polyuretane thickeners such as non-ionic polyethylene oxide urethane block copolymers; a variety of useful thickening agents is available from Rohm and Haas Company.
- a water soluble thickening agent including natural gums such as alginates, cellulosics such as methylcellulose, carboxymethylcellulose and hydroxypropyl methylcellu ⁇ lose, polyacrylic acids and salts thereof, and water soluble polyuretane thickeners such as non-ionic polyethylene oxide urethane block copolymers; a variety of useful thickening agents is available from Rohm and Haas Company.
- the amount of thickening agent is determined by routine experimentation to provide the latex with a viscosity at 25 °C greater than 40 centipoises, preferably greater than 100 centipoises, more preferably greater than 200 centipoises or higher, e.g. greater than 300 centipoises.
- Such latex viscosity can be readily determined using common apparatus such as Brookfield viscometer using a No. 1 spindle rotating in the latex at 5 rpm.
- the ability of a latex to effectively coat a substrate depends in large degree on the relative values of surface tension of the latex and the substrate surface.
- surface tension varies by polymer species and with temperature, e.g. surface tension typically decreases with increasing temperature.
- the surface tension at 25 °C is about 45 dynes/cm 2 for polyethylene terephthalate, about 43 for polycarbonate, about 43 for styrene-acrylonitrile copolymer (33 mole % acrylonitrile) , about 42 for polyvinyl chloride, about 38 for polyvinyl butyral, about 35 for branched polyethylene, about 30 for polypropylene and about 24 for polytetrafluoro-ethylene.
- Polymer latex prepared with a minimal amount of surfactant to maintain a colloidal suspension of polymer may have a surface tension in the range of 45 to 50 dynes/cm 2 .
- the surface tension of polymer latices of this invention can be modified to more nearly coincide with the surface tension of a substrate to be coated by addition of up to about 10 percent by weight of water soluble wetting agent which can be volatile, e.g. lower aliphatic alcohols, or non-volatile, e.g.
- non-ionic surfactants or anionic surfactants Useful lower aliphatic alcohols include ethanol, n-propanol, isopropanol, n-butanol, iso- butanol, n-pentanol, n-hexanol and cyclohexanol.
- Preferred alcohol wetting agents are the C- j and C 4 alkyl alcohol, e.g. n-propanol or n-butanol.
- a preferred latex has sufficient wetting agent to provide a surface tension of less than 43 dynes/cm 2 , more preferably less than 41 dynes/cm 2 .
- a preferred aspect of this invention provides latex of UV-absorbing copolymers comprising sufficient wetting, thickening and coalescing agents to provide non-sagging wet films of latex on a vertical surface of glass, polymer coatings or molded plastic, e.g. polyethylene, polycarbonate, polyamide, polyethylene terephthalate, polyvinylchloride, ABS, polystyrene or polymethylmethacrylate.
- Such latices preferably provide dry, coherent films of UV-absorbing copolymer of a substantially uniform thickness less than 5 micrometers.
- the latices of this invention are useful for providing thin films, e.g. as a topcoat or an intermediate coating, to provide long term stabilization against adverse effects of UV light. For instance, exposure to UV light can cause white colored substrates to yellow, and brightly colored substrates to fade and transparent substrates to become cloudy.
- the latices of UV-absorbing polymer are useful for providing UV-protective coatings on visually informative substrates such as tags, displays, labels, decals and transparencies bearing words or images; on flooring products such as vinyl and acrylate-coated tile and sheet flooring; on outdoor textiles such as tents, awnings, sails; on outdoor signage such as posters, advertisements and highway signs; on polymeric articles such as plastic furniture, plastic glazing, hoses, vinyl siding and roofing materials; on polymeric packaging materials such as bags, bottles and films; and as an adhesive.
- visually informative substrates such as tags, displays, labels, decals and transparencies bearing words or images
- flooring products such as vinyl and acrylate-coated tile and sheet flooring
- outdoor textiles such as tents, awnings, sails
- outdoor signage such as posters, advertisements and highway signs
- polymeric articles such as plastic furniture, plastic glazing, hoses, vinyl siding and roofing materials
- polymeric packaging materials such as bags, bottles and films; and as an adhesive.
- the latices can also be applied to transparent substrates, such as glass, crystalline or plastic windowpanes or clear plastic films, to prevent the transmission of UV light that may be adverse to the film or windowpane e.g. in the case of plastic materials such as polycarbonate or acrylic glazing, or adverse to UV-sensitive materials enclosed or protected thereby such as archival documents and artworks, draperies, furniture, flooring and carpets.
- transparent substrates include light source materials such as diffusers and fluorescent lamp tubes, where a coating according to this invention can diminish UV-light emitted by the light source.
- one aspect of this invention provides laminates where a UV-sensitive substrate, e.g. a window pane, clear film, printed film, molded article, etc. , is coated with an adherent, coherent, UV- resistant vinyl polymeric film comprising:
- UV-absorbing monomer units of vinyl-functionalized benzotriazole or vinyl- functionalized benzophenone and 0-80 weight percent of at least one other vinyl monomer and (ii) one or more additives selected from the group consisting of plasticizer, crosslinker, nonionic surfactant wetting agent, anionic surfactant wetting agent and thickening agent.
- the UV- resistant polymeric film is a tough thermoplastic film capable of providing other protective topcoat qualities in addition to UV-absorption.
- the UV-resistant polymeric film is provided as an inner layer covered with a UV-stable and durable topcoat.
- the UV-resistant polymer is provided as an adhesive to secure UV- sensitive material to a transparent surface.
- a coating of UV-absorbing polymer can be effective in protecting both the packaging materials as well as the contents against discoloration and quality or aesthetic degradation.
- an adhesive layer on one side of the laminate, depending on the application, so as to take advantage of the UV- absorbing layer.
- an adhesive layer can be on the opposite side of the substrate from said UV-resistant vinyl polymeric film.
- the adhesive layer can be on the UV-resistant vinyl polymeric film.
- the UV- resistant vinyl polymeric film itself, can be adhesive.
- the UV-resistant coatings of this invention are useful for protecting visually informative, UV- sensitive substrates, which can be transparent or opaque.
- the UV-absorbing polymer of this invention can be advantageously applied in thin coatings, e.g. less than 25 micrometers or thinner.
- Preferred coatings will be less than 10 micrometers, more preferably less than 5 micrometers.
- effective coatings can be on the order of 1-2 micrometers in thickness.
- Preferred coatings will comprise 40-80 percent of UV- absorbing monomer units, have a Tg greater than 20 ⁇ C.
- Preferred UV-absorbing copolymer coatings are sufficiently pervious to visible light that at least 70 percent of the visible light at 400 nanometers is transmitted. The amount of UV-absorbing co-monomer and thickness of the coating are selected to reduce the transmission of UV light (between 300 and 330 nanometers) through the coating to less than 20 percent of the incident light at those wavelengths.
- the UV-absorbing copolymer will preferably have a Tg of at least 50 °C, more preferably at least 60 °C.
- the copolymer coating thickness e.g. less than 10 micrometers, and amount of UV-absorbing monomer are selected so that the transmission of UV light through the coating is less then 10 percent of the incident light having a wavelength between 300 and 360 nanometers, greater than 90 percent of the incident light at wavelengths of 400 nanometers.
- the latices of this invention are also useful for compounding dispersed UV-absorbing polymer into UV-sensitive materials such as polymer resins and inks.
- the UV-absorbing polymer of this invention can be incorporated as a UV- stabilizing additive into polymer by conventional methods, e.g. extruder blending or by mixing with an other emulsion polymerized polymer latex.
- Acrylate polymer resins are especially amenable to UV-stabili- zation with a UV-absorbing polymers of this invention providing non-blooming, long term resistance.
- the latices of this invention provide a convenient source of dispersed polymer for compounding into ink formulations to provide colorfast ink, e.g. by compounding dyes or pigment into a polymer dispersion of this invention.
- the dispersions of UV-absorbing polymer can be used to provide "sun screen" cosmetic compositions by compounding UV-absorbing polymer in a skin lotion base.
- UV-II 2-hydroxy-4-acrylyloxyethoxy benzophenone from American Cyanamide as Cyasorb UV-2098.
- UV-III 2-(2'-hydroxy-3-tertbuty1-5-(methacryly1oxy- ethyl)phenylpropionate)-2H-benzotriazole.
- BA butylacrylate
- BMA butylmethacrylate
- MMA methyl ethacry1ate
- S styrene
- EB Ebecryl 170 acidic acrylate from Radcure
- CEA carboxyethylacrylate
- HEMA hydroxyethylmethacrylate
- 2EHA 2-ethylhexylacrylate
- NMP N-methy-2-pyrrolidone
- Surfactant-1 Alipal EP-120 from Rhone-Poulenc
- Surfactant-2 Triton X-405 from Union Carbide Plasticizer: Santicizer 160 alkyl aryl phosphate ester plasticizer from Monsanto Company.
- PAA a non-crosslinked polyacrylic acid thickening agent, Acrysol ASE-75 from Rohm & Haas Company.
- PAA-XL crosslinked polyacrylic acid thickening agent, Acrysol ASE-60 from Rohm & Haas.
- Tinuvor 3051 HALS a hindered amine light stabilizer from Sandoz chemicals.
- Tinuvin 123 bis-(l-octyloxy-2,2,6,6-tetramethyl-4- piperidinyl)sebacate, hindered aminoether light stabilizer from Ciba-Geigy.
- Tinuvin 292 HALS bis(1,2,2 , 6 ,6-pentamethyl-4-piper- idinyl) sebacate, sterically hindered tertiary amine light stabilizer from Ciba-Geigy.
- Irganox 1010 anti-oxidant and light stabilizer tetrakis[methylene(3,5-di-tert-butyl-4- hydroxyhydrocinnamate) ]methane, a symmetrical molecule with four sterically hindered phenolic hydroxy groups from Ciba-Geigy.
- Irganox 245 anti-oxidant triethyleneglycol bis[3-(3'-tert-butyl-4'- hydroxy-5 '-methylpheny1)propionate] , a sterically hindered phenolic anti-oxidant from Ciba-Geigy.
- Beetle 60 a methylated urea formaldehyde solution, 86% resin in isopropanol, from American
- Resimene 717 a methylated melamine formaldehyde solution, 84% resin of a trimethoxymethyl melamine crosslinker in n-butyl alcohol from Monsanto Company.
- Resimene 745 a methylated melamine formaldehyde solution, 84% liquid hexamethoxymethyl melamine in n-butyl alcohol from Monsanto Company.
- Resimene 7550 a methylated melamine formaldehyde solution, an aqueous solution of 84% dimethoxymethyl melamine from Monsanto Company.
- polymers can be designated by the starting monomeric components using the above abbreviations followed by a weight ratio in parenthesis.
- a polymer may be designated either by reference to the principle monomeric components, e.g. UV-I:MMA (50:50), or by reference to all of the monomeric components, e.g. UV-I:MMA:CEA:HEMA (50:50:1:2) .
- EXAMPLE 1 This example illustrates the preparation of aqueous latices of UV-absorbing copolymers of this invention, i.e. copolymers of 2-(2'-hydroxy-5- methacrylyloxyethyl-phenyl)-2H-benzotriazole (UV-I) .
- a 50 ml flask equipped with an overhead stirrer, condenser and a syringe septum was charged with 3g of UV-I in 4 ml of deaired distilled water, 3 g of MMA, 3 g of BA, 0.1 g of AA, 0.5 g of Surfactant- 1 and 0.5 g of Surfactant-2.
- the flask was purged with nitrogen, then the mixture was heated to reflux and emulsified.
- the emulsified mixture was cooled to 88 ⁇ C and charged with 0.07 g of potassium persulfate and 0.04 g of sodium bicarbonate in 4.5 ml of deaired distilled water.
- the mixture was stirred for 90 minutes then cooled to room temperature.
- Example 2-8 The procedure of Example 1 was essentially repeated to prepare UV-absorbing copolymers of the benzotriazole UV-absorbing monomer UV-I in the component weight ratios indicated in the following Table 1.
- EXAMPLE 9 This example illustrates the preparation of an aqueous latex of a UV-absorbing copolymer according to this invention comprising 2-hydroxy-4- acrylyloxyethoxy benzophenone (UV-II) .
- a 100 ml flask equipped with an overhead stirrer, condenser and a syringe septum was charged with 5g of UV-II in 31 ml of deaired distilled water, 1.1 g of S-l, 0.5 g of S-2 and 0.1 g of sodium bicarbonate.
- the mixture was purged with nitrogen and rapidly stirred for at least 15 minutes to provide an emulsion; while stirring under a nitrogen atmosphere the emulsion was charged with 5 g of BMA, 0.1 g of CEA and 0.2 g of HEMA, heated to 90 "C and charged with 0.1 g of potassium persulfate in 1.7 ml of deaired distilled water.
- Example 9 The procedure of Example 9 was essentially repeated to produce UV-absorbing copolymers of the benzophenone UV-absorbing monomer UV-II (Examples 10- 16) and UV-absorbing copolymers of the benzotriazole UV-absorbing monomer UV-I (Examples 17-23) in the component weight ratios indicated in the following Table 2.
- EXAMPLE 24 The procedure of example 9 was essentially repeated to prepare an aqueous latex of a UV-absorbing copolymer of 2-(2'-hydro ⁇ y-3-tert-butyl-5- (methacrylyloxyethyl)phenylpropionate)-2H-benzotria- zole (UV-III) .
- EXAMPLE 25-26 The procedure of example 9 was essentially repeated to prepare an aqueous latex of a UV-absorbing homopolymers of UV-I and UV-II with minor amounts of CEA and HEMA, e.g. the components of the homopolymer of UV-I:CEA:HEMA, Tg 92 °C, and UV-II:CEA:HEMA, Tg 55 °C were in the weight ratio 100:1:2.
- EXAMPLE 27 This example illustrates the efficacy of films of the copolymers of this invention in absorbing UV radiation.
- Latices of the copolymers of UV-I:BMA of Examples 17-22 and the homopolymer of UV-I of Example 25 were coated onto glass plates and dried providing laminates which were subjected to UV light transmission analysis.
- Figure 1 shows the effect of 1 micrometer thick coatings on abating the transmission of UV radiation.
- a film comprising 3 weight percent of UV-absorbing monomer transmits about 75% of the radiation in the range of 300-350 nanometers. At least 30% UV-absorbing monomer is required to reduce UV transmission to below 10% in the range of 300-350 nanometers.
- EXAMPLE 28 An F20T12/WW fluorescent light tube without a water repellant coating was provided with a UV- absorbing copolymer layer by brush coating the glass lamp tube with the aqueous latex of Example 8 (diluted with 2 volumes of water per volume of latex) ; excess liquid was brushed off and the thin wet coating was dried by rotating the glass tube under five 250 watt heat lamps providing a coating of about 1 micrometer thick.
- the UV-absorbing copolymer-coated lamp and 2 uncoated lamps (controls) were monitored for radiation emission in the range of 250-370 nanometers.
- the light flux from the lamps was integrated over the range of 250-370 nanometers of the UV part of the electromagnetic spectrum; the integrated radiation flux is reported in normalized light flux units (lfu) .
- Example 29 The procedure of Example 9 was essentially repeated to provide an aqueous latex comprising 57.2 percent by weight dispersed polymeric compound comprising about 98 parts by weight of a copolymer of the monomer units UV-I:BA:2-EHA (26:16.5:4.7) and about 2 parts by weight of Plasticizer.
- the latex exhibited a surface tension of 45.2 dynes/cm 2 .
- EXAMPLE 30 The procedure of Example 9 was essentially repeated to provide an aqueous latex comprising 57.2 percent by weight dispersed polymeric compound comprising about 98 parts by weight of a copolymer of the monomer units UV-I:BA:2-EHA (26:16.5:4.7) and about 2 parts by weight of Plasticizer.
- the latex exhibited a surface tension of 45.2 dynes/cm 2 .
- EXAMPLE 30 The procedure of Example 9 was essentially repeated to provide an aqueous latex comprising 57.2 percent by weight dispersed polymeric compound comprising about
- Coatings were prepared by adding 5 ml of the aqueous latex of Example 29 to volumes of water and the wetting agents indicated in Table 4 to reduce the surface tension of the latex to facilitate coatings of lower surface tension substrates.
- Latex a. was coated and dried at 61 ⁇ C on PET (surface tension about 43 dynes/cm 2 ) producing a hazy and uneven film; latex b. provided a clear smooth film on PET.
- Latices c. and d. provided uneven coatings on vinyl flooring tiles; latices e. and f. provided even coatings on vinyl flooring tiles.
- EXAMPLE 31 Polyacrylic acid thickening agents were added to the 5 ml quantities of the aqueous latex of Example 29 diluted with 15 ml water to provide the latex indicated in Table 5, where the amount of thickener is indicated in weight percent of the latex. Viscosity was determined using a No. 1 Spindle on a Brookfield viscometer at 25 ⁇ C and the indicated RPM.
- Latices a. and b. provided defective coatings on vinyl flooring tiles; latices c. and d. provided smooth coatings on vinyl flooring tiles.
- Example 32 The procedure of Example 29 was repeated substituting MMA for the 2EHA and omitting the Plasticizer to provide an aqueous latex (35% solid polymer having a Tg of 41 ⁇ C) which provided hazy films. Various coalescing agents were added to improve film clarity.
- a hazy film was provided with 1% ethylene glycol monobutyl ether, commercially known as butyl cellusove (BC) in the latex; a semi-hazy film at 50 °C with 2% BC; a clear film at 50 "C with 3 and 4 % BC; a clear film at 25 °C with 5 and 6 % BC; a semi-clear film at 50 °C with 1% dipropylene glycol methyl ether (DPGME) ; a clear film at 50 °C with 2% DPGME; a clear film at 25 °C with 10% DPGME; a clear film at 50 °C with 3% tripropylene glycol methyl ether (TPGME) ; and a clear film at 25 °C with 5% TPGME.
- BC butyl cellusove
- EXAMPLE 33 This example illustrates the preparation of UV-absorbing polymer films containing radical stabilizers and anti-oxidants. Separate 15 ml volumes of aqueous latex prepared according to the procedure of Example 29 but comprising 12.5% UV-absorbing polymer, 1% n-butanol wetting agent and 0.4 % PAA thickening agent were mixed in a 30 ml vial with one of the following radical stabilizers or anti-oxidants: (a) 0.12 ml of 20% latex of Sanduvor 3051 HALS,
- EXAMPLE 34 This example illustrates the preparation of crosslinked films of UV-absorbing polymer of this invention.
- an aqueous latex of 24% solids UV-absorbing copolymer was prepared containing the monomer units UV-I:BA: MMA:AA;CEA (26:16:4:1:1). Separate volumes of the latex were mixed with each of the following crosslinking agents:
- Resimene 7550 B 5H EXAMPLE 35 This example illustrates the preparation of a film of UV-absorbing copolymer hardened using an alkyd resin.
- 5% of an alkyd resin designated as UN 1866 from Cargill, was added during the let-down stage of the emulsion polymerization.
- the resulting mixed latex was coated onto a glass slide using spin coating technique, the wet film were dried in a 60 °C oven for three minutes. After 5 days the film exhibited a pencil test hardness of HB.
- EXAMPLE 36 This example illustrates the preparation of a film of a self-crosslinking UV-absorbing copolymer.
- a UV-absorbing copolymer was prepared according to the procedure of Example 34 with the addition of 1.4 parts of glycidyl methacrylate monomer units.
- the latex was coated onto a glass slide using spin coating technique, the wet film were dried in a 60 °C oven for three minutes. After 5 days the film exhibited a pencil test hardness of HB.
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Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/360,828 US5629365A (en) | 1992-06-23 | 1993-06-22 | UV-absorbing polymer latex |
EP93915442A EP0648249A1 (en) | 1992-06-23 | 1993-06-22 | Uv-absorbing polymer latex |
AU45422/93A AU4542293A (en) | 1992-06-23 | 1993-06-22 | Uv-absorbing polymer latex |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US90264192A | 1992-06-23 | 1992-06-23 | |
US90262992A | 1992-06-23 | 1992-06-23 | |
US902,629 | 1992-06-23 | ||
US902,641 | 1992-06-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994000524A1 true WO1994000524A1 (en) | 1994-01-06 |
Family
ID=27129331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1993/005938 WO1994000524A1 (en) | 1992-06-23 | 1993-06-22 | Uv-absorbing polymer latex |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0648249A1 (en) |
AU (1) | AU4542293A (en) |
CA (1) | CA2138283A1 (en) |
WO (1) | WO1994000524A1 (en) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0736577A1 (en) * | 1995-04-04 | 1996-10-09 | General Electric Company | UV-curable weather resistant coatings |
WO1997031982A1 (en) * | 1996-03-01 | 1997-09-04 | Eastman Chemical Company | The use of alkyl 3-alkoxypropionates as coalescing agents in aqueous coating compositions |
EP0801328A1 (en) * | 1996-04-09 | 1997-10-15 | Morton International, Inc. | Photoimageable composition having an acrylic-functional UV stabilizer |
WO2000063314A1 (en) * | 1999-04-14 | 2000-10-26 | Basf Aktiengesellschaft | Uv-crosslinked dispersions for film lamination |
US6153309A (en) * | 1994-07-01 | 2000-11-28 | Razavi; Homaune A. | UV-protected vinyl laminates |
US6194330B1 (en) | 1998-07-31 | 2001-02-27 | Milliken & Company | Polymer latex for ultraviolet absorbtion on fabric |
WO2001064803A1 (en) * | 2000-03-03 | 2001-09-07 | Basf Coatings Ag | Curable acrylic coating material with a uv stabilizer polymerized into it, and the use thereof |
JP2002212491A (en) * | 2001-01-15 | 2002-07-31 | Ipposha Oil Ind Co Ltd | Coating agent and structural body using the same |
CN1096939C (en) * | 1996-12-09 | 2002-12-25 | 美国3M公司 | UV protected syndiotactic polystyrene overlay films |
CZ303028B6 (en) * | 2010-11-25 | 2012-02-29 | Centrum organické chemie s.r.o. | Photoprotective film-forming composition, especially for protection and restoration of monuments and use thereof |
EP1735422B2 (en) † | 2004-04-15 | 2014-10-15 | Henkel AG & Co. KGaA | Bleaching agent particles encapsulated in a water-soluble material |
US9120936B2 (en) | 2013-03-15 | 2015-09-01 | Valspar Sourcing, Inc. | Water-based compositions that resist dirt pick-up |
US9822275B2 (en) | 2013-03-15 | 2017-11-21 | Valspar Sourcing, Inc. | Water-based compositions that resist dirt pick-up |
US10196537B2 (en) | 2013-03-15 | 2019-02-05 | The Sherwin-Williams Company | Dirt pick-up resistant composition |
US10221322B2 (en) | 2013-03-15 | 2019-03-05 | The Sherwin-Williams Company | Dirt pick-up resistant composition |
US10421868B2 (en) | 2014-09-12 | 2019-09-24 | The Sherwin-Williams Company | Water-based coating compositions that resist dirt pickup |
US11905434B2 (en) | 2018-05-29 | 2024-02-20 | Swimc Llc | Water-based compositions with long term gloss retention |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2096034A5 (en) * | 1970-06-09 | 1972-02-11 | Agfa Gevaert Nv | |
EP0027284A1 (en) * | 1979-10-15 | 1981-04-22 | Agfa-Gevaert N.V. | Copolymer latex and photographic silver halide materials containing such latex |
DE3401455A1 (en) * | 1983-01-17 | 1984-07-19 | Fuji Photo Film Co., Ltd., Minami-Ashigara, Kanagawa | COLOR PHOTOGRAPHIC LIGHT SENSITIVE SILVER HALOGENIDE MATERIAL AND METHOD FOR PRODUCING A COLOR IMAGE |
-
1993
- 1993-06-22 WO PCT/US1993/005938 patent/WO1994000524A1/en not_active Application Discontinuation
- 1993-06-22 CA CA002138283A patent/CA2138283A1/en not_active Abandoned
- 1993-06-22 EP EP93915442A patent/EP0648249A1/en not_active Withdrawn
- 1993-06-22 AU AU45422/93A patent/AU4542293A/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2096034A5 (en) * | 1970-06-09 | 1972-02-11 | Agfa Gevaert Nv | |
EP0027284A1 (en) * | 1979-10-15 | 1981-04-22 | Agfa-Gevaert N.V. | Copolymer latex and photographic silver halide materials containing such latex |
DE3401455A1 (en) * | 1983-01-17 | 1984-07-19 | Fuji Photo Film Co., Ltd., Minami-Ashigara, Kanagawa | COLOR PHOTOGRAPHIC LIGHT SENSITIVE SILVER HALOGENIDE MATERIAL AND METHOD FOR PRODUCING A COLOR IMAGE |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6153309A (en) * | 1994-07-01 | 2000-11-28 | Razavi; Homaune A. | UV-protected vinyl laminates |
EP0736577A1 (en) * | 1995-04-04 | 1996-10-09 | General Electric Company | UV-curable weather resistant coatings |
US5712324A (en) * | 1995-04-04 | 1998-01-27 | General Electric Company | U-V curable weather resistant coatings made by a cold-cast process |
WO1997031982A1 (en) * | 1996-03-01 | 1997-09-04 | Eastman Chemical Company | The use of alkyl 3-alkoxypropionates as coalescing agents in aqueous coating compositions |
EP0801328A1 (en) * | 1996-04-09 | 1997-10-15 | Morton International, Inc. | Photoimageable composition having an acrylic-functional UV stabilizer |
CN1096939C (en) * | 1996-12-09 | 2002-12-25 | 美国3M公司 | UV protected syndiotactic polystyrene overlay films |
US6194330B1 (en) | 1998-07-31 | 2001-02-27 | Milliken & Company | Polymer latex for ultraviolet absorbtion on fabric |
US6482757B2 (en) | 1998-07-31 | 2002-11-19 | Milliken & Company | Polymer latex for ultraviolet absorption on different substrates |
WO2000063314A1 (en) * | 1999-04-14 | 2000-10-26 | Basf Aktiengesellschaft | Uv-crosslinked dispersions for film lamination |
WO2001064803A1 (en) * | 2000-03-03 | 2001-09-07 | Basf Coatings Ag | Curable acrylic coating material with a uv stabilizer polymerized into it, and the use thereof |
JP2002212491A (en) * | 2001-01-15 | 2002-07-31 | Ipposha Oil Ind Co Ltd | Coating agent and structural body using the same |
EP1735422B2 (en) † | 2004-04-15 | 2014-10-15 | Henkel AG & Co. KGaA | Bleaching agent particles encapsulated in a water-soluble material |
CZ303028B6 (en) * | 2010-11-25 | 2012-02-29 | Centrum organické chemie s.r.o. | Photoprotective film-forming composition, especially for protection and restoration of monuments and use thereof |
US11377571B2 (en) | 2013-03-15 | 2022-07-05 | Swimc Llc | Dirt pick-up resistant composition |
US9120936B2 (en) | 2013-03-15 | 2015-09-01 | Valspar Sourcing, Inc. | Water-based compositions that resist dirt pick-up |
US9822275B2 (en) | 2013-03-15 | 2017-11-21 | Valspar Sourcing, Inc. | Water-based compositions that resist dirt pick-up |
US10196537B2 (en) | 2013-03-15 | 2019-02-05 | The Sherwin-Williams Company | Dirt pick-up resistant composition |
US10221322B2 (en) | 2013-03-15 | 2019-03-05 | The Sherwin-Williams Company | Dirt pick-up resistant composition |
US10301500B2 (en) | 2013-03-15 | 2019-05-28 | The Sherwin-Williams Company | Water-based compositions that resist dirt pick-up |
US10723908B2 (en) | 2013-03-15 | 2020-07-28 | The Sherwin-Williams Company | Dirt pick-up resistant composition |
US10883012B2 (en) | 2013-03-15 | 2021-01-05 | Swimc Llc | Water-based compositions that resist dirt pick-up |
US11884834B2 (en) | 2013-03-15 | 2024-01-30 | Swimc Llc | Dirt pick-up resistant composition |
US11312879B2 (en) | 2013-03-15 | 2022-04-26 | Swimc Llc | Water-based compositions that resist dirt pick-up |
US10421868B2 (en) | 2014-09-12 | 2019-09-24 | The Sherwin-Williams Company | Water-based coating compositions that resist dirt pickup |
US11312867B2 (en) | 2014-09-12 | 2022-04-26 | Swimc Llc | Water-based coating compositions that resist dirt pickup |
US10882999B2 (en) | 2014-09-12 | 2021-01-05 | Swimc Llc | Water-based coating compositions that resist dirt pickup |
US11905434B2 (en) | 2018-05-29 | 2024-02-20 | Swimc Llc | Water-based compositions with long term gloss retention |
Also Published As
Publication number | Publication date |
---|---|
AU4542293A (en) | 1994-01-24 |
CA2138283A1 (en) | 1994-01-06 |
EP0648249A1 (en) | 1995-04-19 |
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