ES2302512T3 - Procedimiento de inmovilizacion de un catalizador homogeneo y material catalitico. - Google Patents
Procedimiento de inmovilizacion de un catalizador homogeneo y material catalitico. Download PDFInfo
- Publication number
- ES2302512T3 ES2302512T3 ES02028863T ES02028863T ES2302512T3 ES 2302512 T3 ES2302512 T3 ES 2302512T3 ES 02028863 T ES02028863 T ES 02028863T ES 02028863 T ES02028863 T ES 02028863T ES 2302512 T3 ES2302512 T3 ES 2302512T3
- Authority
- ES
- Spain
- Prior art keywords
- crystals
- zeotypic
- catalyst
- zeolite
- mesopore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title claims abstract description 37
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims description 23
- 239000003054 catalyst Substances 0.000 title description 39
- 239000013078 crystal Substances 0.000 claims abstract description 31
- 239000002815 homogeneous catalyst Substances 0.000 claims abstract description 14
- 238000002425 crystallisation Methods 0.000 claims abstract description 7
- 230000008025 crystallization Effects 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- 150000004696 coordination complex Chemical class 0.000 claims description 5
- 239000003446 ligand Substances 0.000 claims description 5
- 230000008030 elimination Effects 0.000 claims description 4
- 238000003379 elimination reaction Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 3
- 230000003100 immobilizing effect Effects 0.000 claims 3
- 229910021645 metal ion Inorganic materials 0.000 claims 1
- 239000010457 zeolite Substances 0.000 description 51
- 229910021536 Zeolite Inorganic materials 0.000 description 39
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 39
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000001914 filtration Methods 0.000 description 12
- 239000011572 manganese Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- 239000011148 porous material Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 6
- 238000005342 ion exchange Methods 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000011989 jacobsen's catalyst Substances 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- RRIQVLZDOZPJTH-UHFFFAOYSA-N 3,5-di-tert-butyl-2-hydroxybenzaldehyde Chemical compound CC(C)(C)C1=CC(C=O)=C(O)C(C(C)(C)C)=C1 RRIQVLZDOZPJTH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- YMHQVDAATAEZLO-UHFFFAOYSA-N cyclohexane-1,1-diamine Chemical compound NC1(N)CCCCC1 YMHQVDAATAEZLO-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 238000007172 homogeneous catalysis Methods 0.000 description 1
- 238000005216 hydrothermal crystallization Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK200200127 | 2002-01-24 | ||
| DKPA200200127 | 2002-01-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2302512T3 true ES2302512T3 (es) | 2008-07-16 |
Family
ID=8161062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES02028863T Expired - Lifetime ES2302512T3 (es) | 2002-01-24 | 2002-12-23 | Procedimiento de inmovilizacion de un catalizador homogeneo y material catalitico. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6887814B2 (ja) |
| EP (1) | EP1331032B1 (ja) |
| JP (1) | JP4459535B2 (ja) |
| CN (1) | CN1276791C (ja) |
| AT (1) | ATE389451T1 (ja) |
| DE (1) | DE60225663T2 (ja) |
| ES (1) | ES2302512T3 (ja) |
| ZA (1) | ZA200300559B (ja) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1430949B1 (en) * | 2002-12-10 | 2008-03-26 | Haldor Topsoe A/S | Process for catalytic dehydrogenation and catalyst therefore |
| JP4518242B2 (ja) * | 2004-03-10 | 2010-08-04 | 株式会社豊田中央研究所 | 錯体複合材料及びその製造方法 |
| US7211239B2 (en) | 2005-04-22 | 2007-05-01 | Basf Aktiengesellschaft | Process for preparing a nanosized zeolitic material |
| JP4691661B2 (ja) * | 2006-01-25 | 2011-06-01 | 国立大学法人 名古屋工業大学 | 錯体内包ゼオライト材料およびその利用 |
| JP4644812B2 (ja) * | 2006-01-25 | 2011-03-09 | 国立大学法人 名古屋工業大学 | ゼオライトを用いた抗菌剤 |
| JP4691660B2 (ja) * | 2006-01-25 | 2011-06-01 | 国立大学法人 名古屋工業大学 | ゼオライト材料およびその利用 |
| WO2008076566A1 (en) * | 2006-12-20 | 2008-06-26 | Anchor Bay Technologies, Inc. | Noise cancellation |
| KR102156875B1 (ko) * | 2013-04-22 | 2020-09-16 | 에스케이이노베이션 주식회사 | 구조 붕괴된 제올라이트 내에 금속 클러스터가 함유된 촉매 및 이의 용도 |
| WO2015001122A1 (en) * | 2013-07-05 | 2015-01-08 | Danmarks Tekniske Universitet | Method of producing zeolite encapsulated nanoparticles |
| EP3016741B1 (en) * | 2013-07-05 | 2020-07-01 | Danmarks Tekniske Universitet | Method for producing zeolites and zeotypes |
| JP7323115B2 (ja) * | 2017-05-31 | 2023-08-08 | 国立大学法人北海道大学 | 機能性構造体およびその製造方法 |
| JP7337318B2 (ja) * | 2017-05-31 | 2023-09-04 | 国立大学法人北海道大学 | 機能性構造体及びその製造方法 |
| JP7366431B2 (ja) * | 2018-12-03 | 2023-10-23 | 古河電気工業株式会社 | 触媒構造体およびその製造方法、ならびに該触媒構造体を用いた炭化水素の製造方法 |
| CN109718855A (zh) * | 2018-12-22 | 2019-05-07 | 中国科学院山西煤炭化学研究所 | 一种封装金属配合物于材料表面的方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4508842A (en) | 1983-03-29 | 1985-04-02 | Union Carbide Corporation | Ethylene polymerization using supported vanadium catalyst |
| SG48109A1 (en) | 1993-04-23 | 1998-04-17 | Exxon Chemical Ltd | Molecular sieve layers and processes for their manufacture |
| FR2719238B1 (fr) | 1994-04-29 | 1996-05-31 | Centre Nat Rech Scient | Matériau inorganique composite poreux, notamment sous forme de membrane, et procédé d'obtention d'un tel matériau. |
| US5990039A (en) * | 1996-01-11 | 1999-11-23 | Southwest Research Institute | Metal complex derived catalyst and method of forming |
| US5849258A (en) | 1996-06-06 | 1998-12-15 | Intevep, S.A. | Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same |
| KR100199445B1 (ko) | 1996-06-11 | 1999-06-15 | 이서봉 | 복합분자체 화합물의 제조방법 |
| SE512222C2 (sv) | 1998-06-29 | 2000-02-14 | Johan Sterte | Förfarande för framställning av makrostrukturer av mikroporösa material |
| US6908604B2 (en) | 1999-05-17 | 2005-06-21 | Exxonmobil Chemical Patents Inc. | Macrostructures of porous inorganic material and process for their preparation |
| DK173486B1 (da) | 1998-11-18 | 2000-12-18 | Topsoe Haldor As | Fremgangsmåde til fremstilling af små, zeotype krystaller |
| DE19913396A1 (de) | 1999-03-24 | 2000-09-28 | Wolfgang Hoelderich | Chirale Heterogenkatalysatoren, Verfahren zu deren Herstellung und deren Einsatz bei stereoselektiven Oxidationen und stereoselektiven Hydrierungen |
| DE19913395A1 (de) | 1999-03-24 | 2000-09-28 | Wolfgang Hoelderich | Einschlußverbindungen mit zeolithischem Wirtsgitter, deren Herstellung und Einsatz |
| US6087513A (en) * | 1999-05-21 | 2000-07-11 | The Dow Chemical Company | Epoxidation process for aryl allyl ethers |
| US6287645B1 (en) * | 1999-05-21 | 2001-09-11 | Board Of Regents, The University Of Texas System | Preparation of laser deposited oriented films and membranes |
| ES2223372T3 (es) | 1999-12-06 | 2005-03-01 | Haldor Topsoe A/S | Procedimiento depreparacion de monocristales de zeolita. |
| US6620402B2 (en) | 1999-12-06 | 2003-09-16 | Haldor Topsoe A.S | Method of preparing zeolite single crystals with straight mesopores |
| FR2802120B1 (fr) | 1999-12-14 | 2002-02-01 | Inst Francais Du Petrole | Solide silicoaluminate micro et mesoporeux, procede de preparation, utilisation comme catalyseur et en conversion d'hydrocarbures |
| US7078364B2 (en) * | 2001-04-20 | 2006-07-18 | University Of Southern California | Ship-in-a-bottle catalysts |
| US20030008770A1 (en) * | 2001-06-28 | 2003-01-09 | Council Of Scientific & Industrial Research | Encapsulated oxo-bridged organometallic cluster catalyst and a process for the preparation thereof |
-
2002
- 2002-12-23 AT AT02028863T patent/ATE389451T1/de not_active IP Right Cessation
- 2002-12-23 DE DE60225663T patent/DE60225663T2/de not_active Expired - Lifetime
- 2002-12-23 EP EP02028863A patent/EP1331032B1/en not_active Expired - Lifetime
- 2002-12-23 ES ES02028863T patent/ES2302512T3/es not_active Expired - Lifetime
-
2003
- 2003-01-09 US US10/338,653 patent/US6887814B2/en not_active Expired - Fee Related
- 2003-01-21 ZA ZA200300559A patent/ZA200300559B/xx unknown
- 2003-01-23 JP JP2003014917A patent/JP4459535B2/ja not_active Expired - Fee Related
- 2003-01-23 CN CNB031033830A patent/CN1276791C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE60225663T2 (de) | 2009-04-16 |
| CN1276791C (zh) | 2006-09-27 |
| US20030139283A1 (en) | 2003-07-24 |
| EP1331032A2 (en) | 2003-07-30 |
| JP2003210994A (ja) | 2003-07-29 |
| EP1331032A3 (en) | 2003-10-15 |
| EP1331032B1 (en) | 2008-03-19 |
| US6887814B2 (en) | 2005-05-03 |
| ZA200300559B (en) | 2004-02-23 |
| JP4459535B2 (ja) | 2010-04-28 |
| DE60225663D1 (de) | 2008-04-30 |
| CN1433843A (zh) | 2003-08-06 |
| ATE389451T1 (de) | 2008-04-15 |
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