ES2297219T3 - Sistema catalitico para la polimerizacion de olefinas. - Google Patents
Sistema catalitico para la polimerizacion de olefinas. Download PDFInfo
- Publication number
- ES2297219T3 ES2297219T3 ES03762504T ES03762504T ES2297219T3 ES 2297219 T3 ES2297219 T3 ES 2297219T3 ES 03762504 T ES03762504 T ES 03762504T ES 03762504 T ES03762504 T ES 03762504T ES 2297219 T3 ES2297219 T3 ES 2297219T3
- Authority
- ES
- Spain
- Prior art keywords
- succinate
- accordance
- catalytic component
- diethyl
- diisobutyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 36
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 13
- 230000003197 catalytic effect Effects 0.000 title claims description 41
- 239000001257 hydrogen Substances 0.000 claims abstract description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 24
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 12
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 11
- 150000002367 halogens Chemical class 0.000 claims abstract description 9
- 239000011949 solid catalyst Substances 0.000 claims abstract description 5
- 150000003890 succinate salts Chemical class 0.000 claims abstract 3
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 claims description 59
- -1 alkyl radical Chemical class 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 31
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 30
- 239000007787 solid Substances 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
- 239000003054 catalyst Substances 0.000 claims description 27
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 27
- 239000011777 magnesium Substances 0.000 claims description 21
- 229920000642 polymer Polymers 0.000 claims description 21
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 16
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 9
- 125000005842 heteroatom Chemical group 0.000 claims description 9
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 150000003609 titanium compounds Chemical class 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000011282 treatment Methods 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 claims description 2
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 claims description 2
- DJHQJVJMROPIHP-UHFFFAOYSA-N diethyl 2-ethyl-2-methylbutanedioate Chemical compound CCOC(=O)CC(C)(CC)C(=O)OCC DJHQJVJMROPIHP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 2
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims 2
- VTCHFSNTCCVHRC-UHFFFAOYSA-N dibutyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCCCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCCCC VTCHFSNTCCVHRC-UHFFFAOYSA-N 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 239000000203 mixture Substances 0.000 description 20
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- 239000005977 Ethylene Substances 0.000 description 11
- 235000011147 magnesium chloride Nutrition 0.000 description 9
- 150000003900 succinic acid esters Chemical class 0.000 description 9
- 238000012512 characterization method Methods 0.000 description 8
- 239000006228 supernatant Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 238000013019 agitation Methods 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 6
- 239000012265 solid product Substances 0.000 description 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 5
- RGMSBDCQLRJNSH-UHFFFAOYSA-N 4-oxo-4-propan-2-yloxybutanoic acid Chemical compound CC(C)OC(=O)CCC(O)=O RGMSBDCQLRJNSH-UHFFFAOYSA-N 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000004711 α-olefin Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 229910003074 TiCl4 Inorganic materials 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- GIPUHGMDLPLFGZ-UHFFFAOYSA-N 2-cyclopentyl-2-propylbutanedioic acid Chemical compound CCCC(CC(O)=O)(C(O)=O)C1CCCC1 GIPUHGMDLPLFGZ-UHFFFAOYSA-N 0.000 description 2
- HZXMLBSUEZTYHZ-UHFFFAOYSA-N 4-(cyclohexylmethoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCC1CCCCC1 HZXMLBSUEZTYHZ-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 2
- GFQUHXOKHFFPGI-UHFFFAOYSA-N CCC(CC)COC(=O)CCC(O)=O Chemical compound CCC(CC)COC(=O)CCC(O)=O GFQUHXOKHFFPGI-UHFFFAOYSA-N 0.000 description 2
- XHLXMRJWRKQMCP-UHFFFAOYSA-N Diethyl methylsuccinate Chemical compound CCOC(=O)CC(C)C(=O)OCC XHLXMRJWRKQMCP-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 150000002681 magnesium compounds Chemical class 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 230000000707 stereoselective effect Effects 0.000 description 2
- VFIOZKTXVHLWRA-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CCC1CCCCN1[Si](OC)(OC)C(C)C(F)(F)F VFIOZKTXVHLWRA-UHFFFAOYSA-N 0.000 description 1
- 125000006376 (C3-C10) cycloalkyl group Chemical group 0.000 description 1
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 description 1
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 1
- CQCFISPMNREOQX-UHFFFAOYSA-N 2,2,3,3-tetraethylbutanedioic acid Chemical compound CCC(CC)(C(O)=O)C(CC)(CC)C(O)=O CQCFISPMNREOQX-UHFFFAOYSA-N 0.000 description 1
- XDMIOWTZXSLEKJ-UHFFFAOYSA-N 2,2,3,3-tetrapropylbutanedioic acid Chemical compound CCCC(CCC)(C(O)=O)C(CCC)(CCC)C(O)=O XDMIOWTZXSLEKJ-UHFFFAOYSA-N 0.000 description 1
- GOHPTLYPQCTZSE-UHFFFAOYSA-N 2,2-dimethylsuccinic acid Chemical compound OC(=O)C(C)(C)CC(O)=O GOHPTLYPQCTZSE-UHFFFAOYSA-N 0.000 description 1
- AJLCTEPRECBBKT-UHFFFAOYSA-N 2,3-bis(3-methylbutyl)butanedioic acid Chemical compound CC(C)CCC(C(O)=O)C(C(O)=O)CCC(C)C AJLCTEPRECBBKT-UHFFFAOYSA-N 0.000 description 1
- STZTXZMTXDIAOR-UHFFFAOYSA-N 2,3-bis(trimethylsilyl)butanedioic acid Chemical compound C[Si](C)(C)C(C(O)=O)C(C(O)=O)[Si](C)(C)C STZTXZMTXDIAOR-UHFFFAOYSA-N 0.000 description 1
- HSCLUIKEZDGKBP-UHFFFAOYSA-N 2,3-di(propan-2-yl)butanedioic acid Chemical compound CC(C)C(C(O)=O)C(C(C)C)C(O)=O HSCLUIKEZDGKBP-UHFFFAOYSA-N 0.000 description 1
- FUFSLRDLUNRCHM-UHFFFAOYSA-N 2,3-diethyl-2,3-di(propan-2-yl)butanedioic acid Chemical compound CCC(C(C)C)(C(O)=O)C(CC)(C(C)C)C(O)=O FUFSLRDLUNRCHM-UHFFFAOYSA-N 0.000 description 1
- BEHQZIRZSPNOIT-UHFFFAOYSA-N 2,3-diethyl-2-propan-2-ylbutanedioic acid Chemical compound CCC(C(O)=O)C(CC)(C(C)C)C(O)=O BEHQZIRZSPNOIT-UHFFFAOYSA-N 0.000 description 1
- NCJIQZHBJMQVHD-UHFFFAOYSA-N 2,3-ditert-butylbutanedioic acid Chemical compound CC(C)(C)C(C(O)=O)C(C(O)=O)C(C)(C)C NCJIQZHBJMQVHD-UHFFFAOYSA-N 0.000 description 1
- BBZCDNKYGLRIFU-UHFFFAOYSA-N 2-(1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalen-1-yl)butanedioic acid Chemical compound C1(CCCC2CCCCC12)C(C(=O)O)CC(=O)O BBZCDNKYGLRIFU-UHFFFAOYSA-N 0.000 description 1
- AGFXJIDIVHRKCA-UHFFFAOYSA-N 2-(4-chlorophenyl)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)C1=CC=C(Cl)C=C1 AGFXJIDIVHRKCA-UHFFFAOYSA-N 0.000 description 1
- GWLMCHGZCQNEHQ-UHFFFAOYSA-N 2-(cyclohexylmethyl)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)CC1CCCCC1 GWLMCHGZCQNEHQ-UHFFFAOYSA-N 0.000 description 1
- AVIFPSNRFRVXMI-UHFFFAOYSA-N 2-benzyl-2-propan-2-ylbutanedioic acid Chemical compound OC(=O)CC(C(C)C)(C(O)=O)CC1=CC=CC=C1 AVIFPSNRFRVXMI-UHFFFAOYSA-N 0.000 description 1
- GTOFKXZQQDSVFH-UHFFFAOYSA-N 2-benzylsuccinic acid Chemical compound OC(=O)CC(C(O)=O)CC1=CC=CC=C1 GTOFKXZQQDSVFH-UHFFFAOYSA-N 0.000 description 1
- OKLHGPQSJDHYTQ-UHFFFAOYSA-N 2-butan-2-ylbutanedioic acid Chemical compound CCC(C)C(C(O)=O)CC(O)=O OKLHGPQSJDHYTQ-UHFFFAOYSA-N 0.000 description 1
- UFSJLOVZESXSHD-UHFFFAOYSA-N 2-butyl-2-phenylbutanedioic acid Chemical compound CCCCC(CC(O)=O)(C(O)=O)C1=CC=CC=C1 UFSJLOVZESXSHD-UHFFFAOYSA-N 0.000 description 1
- VZWZBFDXXQFDHW-UHFFFAOYSA-N 2-cyclohexyl-3-(3-methylbutyl)butanedioic acid Chemical compound CC(C)CCC(C(O)=O)C(C(O)=O)C1CCCCC1 VZWZBFDXXQFDHW-UHFFFAOYSA-N 0.000 description 1
- VQNGKYXWYAHFPF-UHFFFAOYSA-N 2-cyclohexyl-3-cyclopentylbutanedioic acid Chemical compound C1CCCC1C(C(=O)O)C(C(O)=O)C1CCCCC1 VQNGKYXWYAHFPF-UHFFFAOYSA-N 0.000 description 1
- LIJMAHQYXMQISA-UHFFFAOYSA-N 2-cyclohexyl-3-propan-2-ylbutanedioic acid Chemical compound CC(C)C(C(O)=O)C(C(O)=O)C1CCCCC1 LIJMAHQYXMQISA-UHFFFAOYSA-N 0.000 description 1
- LVFFZQQWIZURIO-UHFFFAOYSA-N 2-phenylbutanedioic acid Chemical compound OC(=O)CC(C(O)=O)C1=CC=CC=C1 LVFFZQQWIZURIO-UHFFFAOYSA-N 0.000 description 1
- RKAFKUROUOLPOL-UHFFFAOYSA-N 2-propan-2-ylbutanedioic acid Chemical compound CC(C)C(C(O)=O)CC(O)=O RKAFKUROUOLPOL-UHFFFAOYSA-N 0.000 description 1
- CSYGSMPRMSYYJY-UHFFFAOYSA-N 4-(2,2-dimethylpropoxy)-4-oxobutanoic acid Chemical compound CC(C)(C)COC(=O)CCC(O)=O CSYGSMPRMSYYJY-UHFFFAOYSA-N 0.000 description 1
- RGTLSFNPTLNPDZ-UHFFFAOYSA-N 4-(2-methylpropoxy)-4-oxobutanoic acid Chemical compound CC(C)COC(=O)CCC(O)=O RGTLSFNPTLNPDZ-UHFFFAOYSA-N 0.000 description 1
- JSLHQOQJMVNMBF-UHFFFAOYSA-N 4-(3-bicyclo[2.2.1]heptanyloxy)-4-oxobutanoic acid Chemical compound C1CC2C(OC(=O)CCC(=O)O)CC1C2 JSLHQOQJMVNMBF-UHFFFAOYSA-N 0.000 description 1
- XKOHSLPEVWLEPS-UHFFFAOYSA-N 4-(3-methylbutoxy)-4-oxobutanoic acid Chemical compound CC(C)CCOC(=O)CCC(O)=O XKOHSLPEVWLEPS-UHFFFAOYSA-N 0.000 description 1
- RQPUMSMXKHBGMO-UHFFFAOYSA-N 4-(9H-fluoren-9-yloxy)-4-oxobutanoic acid Chemical compound C1=CC=C2C(OC(=O)CCC(=O)O)C3=CC=CC=C3C2=C1 RQPUMSMXKHBGMO-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- PCOCFIOYWNCGBM-UHFFFAOYSA-M 4-[(2-methylpropan-2-yl)oxy]-4-oxobutanoate Chemical compound CC(C)(C)OC(=O)CCC([O-])=O PCOCFIOYWNCGBM-UHFFFAOYSA-M 0.000 description 1
- CQBVVSONJDUVEJ-UHFFFAOYSA-N 4-cyclohexyloxy-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OC1CCCCC1 CQBVVSONJDUVEJ-UHFFFAOYSA-N 0.000 description 1
- KDNUUZCIPIPBKN-UHFFFAOYSA-N 4-oxo-4-(1,1,1-trifluoropropan-2-yloxy)butanoic acid Chemical compound FC(F)(F)C(C)OC(=O)CCC(O)=O KDNUUZCIPIPBKN-UHFFFAOYSA-N 0.000 description 1
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 description 1
- 229910018125 Al-Si Inorganic materials 0.000 description 1
- 229910018520 Al—Si Inorganic materials 0.000 description 1
- YUXIBTJKHLUKBD-UHFFFAOYSA-N Dibutyl succinate Chemical compound CCCCOC(=O)CCC(=O)OCCCC YUXIBTJKHLUKBD-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910003910 SiCl4 Inorganic materials 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- XSPWSCMPGMVYEL-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-methoxybutanedioate Chemical compound CC(C)(C)COC(=O)C(OC)CC(=O)OCC(C)(C)C XSPWSCMPGMVYEL-UHFFFAOYSA-N 0.000 description 1
- UXXFIMLQAGKNGU-UHFFFAOYSA-N bis(2,2-dimethylpropyl) 2-trimethylsilylbutanedioate Chemical compound CC(C)(C)COC(=O)CC([Si](C)(C)C)C(=O)OCC(C)(C)C UXXFIMLQAGKNGU-UHFFFAOYSA-N 0.000 description 1
- YRSRSXVKWCRYHR-UHFFFAOYSA-N bis(2-ethylbutyl) butanedioate Chemical compound CCC(CC)COC(=O)CCC(=O)OCC(CC)CC YRSRSXVKWCRYHR-UHFFFAOYSA-N 0.000 description 1
- FOIOGNLWKSKSQI-UHFFFAOYSA-N bis(2-methylpropyl) 2,2,3,3-tetramethylbutanedioate Chemical compound CC(C)COC(=O)C(C)(C)C(C)(C)C(=O)OCC(C)C FOIOGNLWKSKSQI-UHFFFAOYSA-N 0.000 description 1
- JRKQPCLKOWPGQK-UHFFFAOYSA-N bis(2-methylpropyl) 2,2-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)CC(C(C)C)(C(C)C)C(=O)OCC(C)C JRKQPCLKOWPGQK-UHFFFAOYSA-N 0.000 description 1
- QHMBXAPRKPBMRN-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-bis(3-methylbutyl)butanedioate Chemical compound CC(C)COC(=O)C(CCC(C)C)C(CCC(C)C)C(=O)OCC(C)C QHMBXAPRKPBMRN-UHFFFAOYSA-N 0.000 description 1
- YNNNGCCXXKAYNT-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-diethyl-2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)(CC)C(CC)(C(C)C)C(=O)OCC(C)C YNNNGCCXXKAYNT-UHFFFAOYSA-N 0.000 description 1
- WMQDUNPHMQJCQI-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-diethyl-2-propan-2-ylbutanedioate Chemical compound CC(C)COC(=O)C(CC)C(CC)(C(C)C)C(=O)OCC(C)C WMQDUNPHMQJCQI-UHFFFAOYSA-N 0.000 description 1
- QFESMHZEKSRNQO-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-ditert-butylbutanedioate Chemical compound CC(C)COC(=O)C(C(C)(C)C)C(C(C)(C)C)C(=O)OCC(C)C QFESMHZEKSRNQO-UHFFFAOYSA-N 0.000 description 1
- RIVWTMWVUNCJIZ-UHFFFAOYSA-N bis(2-methylpropyl) 2-(2,2-dimethylpropyl)butanedioate Chemical compound CC(C)COC(=O)CC(CC(C)(C)C)C(=O)OCC(C)C RIVWTMWVUNCJIZ-UHFFFAOYSA-N 0.000 description 1
- LTHVLULMJOHJOG-UHFFFAOYSA-N bis(2-methylpropyl) 2-(3-methylbutyl)butanedioate Chemical compound CC(C)COC(=O)C(CCC(C)C)CC(=O)OCC(C)C LTHVLULMJOHJOG-UHFFFAOYSA-N 0.000 description 1
- ZZSZAXSJPKIQPT-UHFFFAOYSA-N bis(2-methylpropyl) 2-(4-methoxyphenyl)butanedioate Chemical compound COC1=CC=C(C(CC(=O)OCC(C)C)C(=O)OCC(C)C)C=C1 ZZSZAXSJPKIQPT-UHFFFAOYSA-N 0.000 description 1
- FGDQEXVZBKMTKR-UHFFFAOYSA-N bis(2-methylpropyl) 2-butan-2-ylbutanedioate Chemical compound CC(C)COC(=O)C(C(C)CC)CC(=O)OCC(C)C FGDQEXVZBKMTKR-UHFFFAOYSA-N 0.000 description 1
- RWHFRGWHTJMEQP-UHFFFAOYSA-N bis(2-methylpropyl) 2-cyclohexyl-3-(3-methylbutyl)butanedioate Chemical compound CC(C)COC(=O)C(CCC(C)C)C(C(=O)OCC(C)C)C1CCCCC1 RWHFRGWHTJMEQP-UHFFFAOYSA-N 0.000 description 1
- WNEPUWJGDDGVJV-UHFFFAOYSA-N bis(2-methylpropyl) 2-cyclohexyl-3-propan-2-ylbutanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(=O)OCC(C)C)C1CCCCC1 WNEPUWJGDDGVJV-UHFFFAOYSA-N 0.000 description 1
- LKANLVAQPVLHDG-UHFFFAOYSA-N bis(2-methylpropyl) 2-cyclohexylbutanedioate Chemical compound CC(C)COC(=O)CC(C(=O)OCC(C)C)C1CCCCC1 LKANLVAQPVLHDG-UHFFFAOYSA-N 0.000 description 1
- NKUQLJXKUPCQCT-UHFFFAOYSA-N bis(2-methylpropyl) 2-cyclopropylbutanedioate Chemical compound CC(C)COC(=O)CC(C(=O)OCC(C)C)C1CC1 NKUQLJXKUPCQCT-UHFFFAOYSA-N 0.000 description 1
- YONSTJLJDXVRIZ-UHFFFAOYSA-N bis(2-methylpropyl) 2-hexylbutanedioate Chemical compound CCCCCCC(C(=O)OCC(C)C)CC(=O)OCC(C)C YONSTJLJDXVRIZ-UHFFFAOYSA-N 0.000 description 1
- TXOZEOKLILEHRC-UHFFFAOYSA-N bis(2-methylpropyl) 2-methoxybutanedioate Chemical compound CC(C)COC(=O)C(OC)CC(=O)OCC(C)C TXOZEOKLILEHRC-UHFFFAOYSA-N 0.000 description 1
- XTTGRHGECXALTK-UHFFFAOYSA-N bis(2-methylpropyl) 2-phenyl-2-propylbutanedioate Chemical compound CC(C)COC(=O)CC(CCC)(C(=O)OCC(C)C)C1=CC=CC=C1 XTTGRHGECXALTK-UHFFFAOYSA-N 0.000 description 1
- OBGJKHQDAQAHDZ-UHFFFAOYSA-N bis(2-methylpropyl) 2-phenylbutanedioate Chemical compound CC(C)COC(=O)CC(C(=O)OCC(C)C)C1=CC=CC=C1 OBGJKHQDAQAHDZ-UHFFFAOYSA-N 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- OZDDMYZVHZPZJS-UHFFFAOYSA-N diethyl 2,2,3,3-tetraethylbutanedioate Chemical compound CCOC(=O)C(CC)(CC)C(CC)(CC)C(=O)OCC OZDDMYZVHZPZJS-UHFFFAOYSA-N 0.000 description 1
- DRVYAVWIBGKJNA-UHFFFAOYSA-N diethyl 2,2,3,3-tetramethylbutanedioate Chemical compound CCOC(=O)C(C)(C)C(C)(C)C(=O)OCC DRVYAVWIBGKJNA-UHFFFAOYSA-N 0.000 description 1
- ZNLCVPWTHDWROY-UHFFFAOYSA-N diethyl 2,2,3,3-tetrapropylbutanedioate Chemical compound CCOC(=O)C(CCC)(CCC)C(CCC)(CCC)C(=O)OCC ZNLCVPWTHDWROY-UHFFFAOYSA-N 0.000 description 1
- YCYHZGIPKZHEEL-UHFFFAOYSA-N diethyl 2,3-bis(2,2-dimethylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)(C)C)C(CC(C)(C)C)C(=O)OCC YCYHZGIPKZHEEL-UHFFFAOYSA-N 0.000 description 1
- AVLHXEDOBYYTGV-UHFFFAOYSA-N diethyl 2,3-bis(2-methylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)C)C(CC(C)C)C(=O)OCC AVLHXEDOBYYTGV-UHFFFAOYSA-N 0.000 description 1
- YNVIZPLGYONUJC-UHFFFAOYSA-N diethyl 2,3-bis(3-methylbutyl)butanedioate Chemical compound CCOC(=O)C(CCC(C)C)C(CCC(C)C)C(=O)OCC YNVIZPLGYONUJC-UHFFFAOYSA-N 0.000 description 1
- MTFYCMNQWCTXII-UHFFFAOYSA-N diethyl 2,3-diethyl-2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(CC)(C(C)C)C(CC)(C(C)C)C(=O)OCC MTFYCMNQWCTXII-UHFFFAOYSA-N 0.000 description 1
- DQNUPKXJISAAFG-UHFFFAOYSA-N diethyl 2,3-diethyl-2-propan-2-ylbutanedioate Chemical compound CCOC(=O)C(CC)C(CC)(C(C)C)C(=O)OCC DQNUPKXJISAAFG-UHFFFAOYSA-N 0.000 description 1
- YMSISMQFJRKKET-UHFFFAOYSA-N diethyl 2-(1,1,1-trifluoropropan-2-yl)butanedioate Chemical compound CCOC(=O)CC(C(C)C(F)(F)F)C(=O)OCC YMSISMQFJRKKET-UHFFFAOYSA-N 0.000 description 1
- JHAJGFZBBOGWCQ-UHFFFAOYSA-N diethyl 2-(2,2-dimethylpropyl)butanedioate Chemical compound CCOC(=O)CC(CC(C)(C)C)C(=O)OCC JHAJGFZBBOGWCQ-UHFFFAOYSA-N 0.000 description 1
- WAHPMEKTSDWXIH-UHFFFAOYSA-N diethyl 2-(3-methylbutyl)butanedioate Chemical compound CCOC(=O)CC(CCC(C)C)C(=O)OCC WAHPMEKTSDWXIH-UHFFFAOYSA-N 0.000 description 1
- OKFRLPHKPXFFBE-UHFFFAOYSA-N diethyl 2-(4-chlorophenyl)butanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=C(Cl)C=C1 OKFRLPHKPXFFBE-UHFFFAOYSA-N 0.000 description 1
- GBEDNFHCEKAPAV-UHFFFAOYSA-N diethyl 2-(4-methoxyphenyl)butanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=C(OC)C=C1 GBEDNFHCEKAPAV-UHFFFAOYSA-N 0.000 description 1
- TXRNMKWGVBBYLW-UHFFFAOYSA-N diethyl 2-benzyl-2-propan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)(C(C)C)CC1=CC=CC=C1 TXRNMKWGVBBYLW-UHFFFAOYSA-N 0.000 description 1
- JZJPBADSXBZWAZ-UHFFFAOYSA-N diethyl 2-benzylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)CC1=CC=CC=C1 JZJPBADSXBZWAZ-UHFFFAOYSA-N 0.000 description 1
- UKZUISCHPZZJME-UHFFFAOYSA-N diethyl 2-butan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C(C)CC)C(=O)OCC UKZUISCHPZZJME-UHFFFAOYSA-N 0.000 description 1
- GKCJIKJXEOGKJU-UHFFFAOYSA-N diethyl 2-butyl-2-phenylbutanedioate Chemical compound CCOC(=O)CC(CCCC)(C(=O)OCC)C1=CC=CC=C1 GKCJIKJXEOGKJU-UHFFFAOYSA-N 0.000 description 1
- RKYAIEFZJCCTFW-UHFFFAOYSA-N diethyl 2-cyclohexyl-3-(3-methylbutyl)butanedioate Chemical compound CCOC(=O)C(CCC(C)C)C(C(=O)OCC)C1CCCCC1 RKYAIEFZJCCTFW-UHFFFAOYSA-N 0.000 description 1
- VCDQCWPPWOKHRK-UHFFFAOYSA-N diethyl 2-cyclohexyl-3-cyclopentylbutanedioate Chemical compound C1CCCC1C(C(=O)OCC)C(C(=O)OCC)C1CCCCC1 VCDQCWPPWOKHRK-UHFFFAOYSA-N 0.000 description 1
- NLLYHAKHAPQUBQ-UHFFFAOYSA-N diethyl 2-cyclopentyl-2-propylbutanedioate Chemical compound CCOC(=O)CC(CCC)(C(=O)OCC)C1CCCC1 NLLYHAKHAPQUBQ-UHFFFAOYSA-N 0.000 description 1
- XMVGCOWCTAZJNT-UHFFFAOYSA-N diethyl 2-cyclopropylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1CC1 XMVGCOWCTAZJNT-UHFFFAOYSA-N 0.000 description 1
- CRFNZTOCCSXWQM-UHFFFAOYSA-N diethyl 2-methoxybutanedioate Chemical compound CCOC(=O)CC(OC)C(=O)OCC CRFNZTOCCSXWQM-UHFFFAOYSA-N 0.000 description 1
- JVQDNCKPHSZFSO-UHFFFAOYSA-N diethyl 2-phenylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1=CC=CC=C1 JVQDNCKPHSZFSO-UHFFFAOYSA-N 0.000 description 1
- SSQLHHBLAVHVOU-UHFFFAOYSA-N diethyl 2-propan-2-ylbutanedioate Chemical compound CCOC(=O)CC(C(C)C)C(=O)OCC SSQLHHBLAVHVOU-UHFFFAOYSA-N 0.000 description 1
- PDDRPHDGSQRRJM-UHFFFAOYSA-N diethyl 2-tert-butyl-3-propan-2-ylbutanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)(C)C)C(=O)OCC PDDRPHDGSQRRJM-UHFFFAOYSA-N 0.000 description 1
- AQFKFFFGIFNPMT-UHFFFAOYSA-N diethyl 2-trimethylsilylbutanedioate Chemical compound CCOC(=O)CC([Si](C)(C)C)C(=O)OCC AQFKFFFGIFNPMT-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- BTJCEVZMRIJBSM-UHFFFAOYSA-N dimethoxy-methyl-(1,1,1-trifluoropropan-2-yl)silane Chemical compound CO[Si](C)(OC)C(C)C(F)(F)F BTJCEVZMRIJBSM-UHFFFAOYSA-N 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- YTHSGTQAXRQVOX-UHFFFAOYSA-N ethyl 1-(2-cyclohexyl-2-ethoxyacetyl)cyclohexane-1-carboxylate Chemical compound C1CCCCC1(C(=O)OCC)C(=O)C(OCC)C1CCCCC1 YTHSGTQAXRQVOX-UHFFFAOYSA-N 0.000 description 1
- NRHVQXVUPKOBAI-UHFFFAOYSA-N ethyl 1-(2-ethoxyacetyl)-2,5-dimethylcyclopentane-1-carboxylate Chemical compound CCOCC(=O)C1(C(=O)OCC)C(C)CCC1C NRHVQXVUPKOBAI-UHFFFAOYSA-N 0.000 description 1
- JYEMURZLFONTNE-UHFFFAOYSA-N ethyl 1-(2-ethoxyacetyl)-2,6-dimethylcyclohexane-1-carboxylate Chemical compound CCOCC(=O)C1(C(=O)OCC)C(C)CCCC1C JYEMURZLFONTNE-UHFFFAOYSA-N 0.000 description 1
- HCBWCZGDFODQIF-UHFFFAOYSA-N ethyl 1-(3-ethoxy-2-oxopropyl)-2-methylcyclohexane-1-carboxylate Chemical compound CCOCC(=O)CC1(C(=O)OCC)CCCCC1C HCBWCZGDFODQIF-UHFFFAOYSA-N 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 238000011177 media preparation Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 125000002734 organomagnesium group Chemical group 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- NETBVGNWMHLXRP-UHFFFAOYSA-N tert-butyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C(C)(C)C NETBVGNWMHLXRP-UHFFFAOYSA-N 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02077653 | 2002-07-02 | ||
| EP02077653 | 2002-07-02 | ||
| US41888402P | 2002-10-15 | 2002-10-15 | |
| US418884P | 2002-10-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2297219T3 true ES2297219T3 (es) | 2008-05-01 |
Family
ID=56290445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03762504T Expired - Lifetime ES2297219T3 (es) | 2002-07-02 | 2003-06-23 | Sistema catalitico para la polimerizacion de olefinas. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1525231B1 (enExample) |
| JP (1) | JP2005531675A (enExample) |
| CN (1) | CN1285623C (enExample) |
| AT (1) | ATE380204T1 (enExample) |
| AU (1) | AU2003249866A1 (enExample) |
| BR (1) | BR0305623A (enExample) |
| DE (1) | DE60317903T2 (enExample) |
| ES (1) | ES2297219T3 (enExample) |
| WO (1) | WO2004005359A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100439317C (zh) | 2002-08-05 | 2008-12-03 | 巴塞尔聚烯烃意大利有限公司 | 用于制备烷叉基取代的1,4-二酮衍生物的方法 |
| JP4464275B2 (ja) | 2002-08-05 | 2010-05-19 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | アルキリデン置換−１，４−ジオン誘導体の製造法 |
| WO2008010459A1 (en) * | 2006-07-18 | 2008-01-24 | Mitsui Chemicals, Inc. | Solid titanium catalyst ingredient, catalyst for olefin polymerization, and method of olefin polymerization |
| KR101769275B1 (ko) | 2009-06-19 | 2017-08-18 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 내충격성 프로필렌 중합체 조성물의 제조 방법 |
| WO2013091033A1 (pt) * | 2011-12-22 | 2013-06-27 | Petróleo Brasileiro S.A. - Petrobras | Catalisador suportado em alumina para uso em polimerização de olefinas e método de preparo do mesmo |
| CN104610062B (zh) * | 2013-11-01 | 2017-06-30 | 中国石油化工股份有限公司 | 一种化合物、催化剂组分及催化剂 |
| JP2025020611A (ja) * | 2023-07-31 | 2025-02-13 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、オレフィン類重合用固体触媒成分の製造方法、オレフィン類重合用触媒、及びオレフィン類重合体の製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS59207904A (ja) * | 1983-05-11 | 1984-11-26 | Mitsui Petrochem Ind Ltd | オレフイン重合体の製造方法 |
| KR920000173B1 (ko) * | 1986-10-09 | 1992-01-09 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체 |
| KR100700957B1 (ko) * | 1999-04-15 | 2007-03-28 | 바셀 테크놀로지 컴퍼니 비.브이. | 올레핀 중합반응을 위한 성분 및 촉매 |
-
2003
- 2003-06-23 EP EP03762504A patent/EP1525231B1/en not_active Expired - Lifetime
- 2003-06-23 DE DE60317903T patent/DE60317903T2/de not_active Expired - Lifetime
- 2003-06-23 CN CNB038008742A patent/CN1285623C/zh not_active Expired - Fee Related
- 2003-06-23 BR BR0305623-6A patent/BR0305623A/pt not_active Application Discontinuation
- 2003-06-23 AU AU2003249866A patent/AU2003249866A1/en not_active Abandoned
- 2003-06-23 ES ES03762504T patent/ES2297219T3/es not_active Expired - Lifetime
- 2003-06-23 JP JP2004518555A patent/JP2005531675A/ja active Pending
- 2003-06-23 WO PCT/EP2003/006635 patent/WO2004005359A1/en not_active Ceased
- 2003-06-23 AT AT03762504T patent/ATE380204T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1525231B1 (en) | 2007-12-05 |
| ATE380204T1 (de) | 2007-12-15 |
| CN1285623C (zh) | 2006-11-22 |
| CN1545525A (zh) | 2004-11-10 |
| DE60317903D1 (de) | 2008-01-17 |
| BR0305623A (pt) | 2004-10-19 |
| AU2003249866A1 (en) | 2004-01-23 |
| WO2004005359A1 (en) | 2004-01-15 |
| JP2005531675A (ja) | 2005-10-20 |
| EP1525231A1 (en) | 2005-04-27 |
| DE60317903T2 (de) | 2008-11-13 |
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