ES2296304T3 - Composiciones a base de poliamida resistentes al choque. - Google Patents
Composiciones a base de poliamida resistentes al choque. Download PDFInfo
- Publication number
- ES2296304T3 ES2296304T3 ES97401629T ES97401629T ES2296304T3 ES 2296304 T3 ES2296304 T3 ES 2296304T3 ES 97401629 T ES97401629 T ES 97401629T ES 97401629 T ES97401629 T ES 97401629T ES 2296304 T3 ES2296304 T3 ES 2296304T3
- Authority
- ES
- Spain
- Prior art keywords
- parts
- acid
- anhydride
- shock
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 230000035939 shock Effects 0.000 title claims abstract description 33
- 229920002647 polyamide Polymers 0.000 title claims abstract description 29
- 239000004952 Polyamide Substances 0.000 claims abstract description 25
- 239000003365 glass fiber Substances 0.000 claims abstract description 20
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000005977 Ethylene Substances 0.000 claims abstract description 18
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 12
- 150000008064 anhydrides Chemical class 0.000 claims description 31
- 229920001577 copolymer Polymers 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 24
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000008065 acid anhydrides Chemical class 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 229920002292 Nylon 6 Polymers 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 8
- 239000003607 modifier Substances 0.000 description 8
- -1 polyethylene Polymers 0.000 description 8
- 230000007423 decrease Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 125000005250 alkyl acrylate group Chemical group 0.000 description 5
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- CGPRUXZTHGTMKW-UHFFFAOYSA-N ethene;ethyl prop-2-enoate Chemical compound C=C.CCOC(=O)C=C CGPRUXZTHGTMKW-UHFFFAOYSA-N 0.000 description 3
- 239000011152 fibreglass Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 229920000572 Nylon 6/12 Polymers 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- LRQKBLKVPFOOQJ-UHFFFAOYSA-N 2-aminohexanoic acid Chemical class CCCCC(N)C(O)=O LRQKBLKVPFOOQJ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- XDOLZJYETYVRKV-UHFFFAOYSA-N 7-Aminoheptanoic acid Chemical compound NCCCCCCC(O)=O XDOLZJYETYVRKV-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 229920006097 Ultramide® Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000008202 granule composition Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- ZETYUTMSJWMKNQ-UHFFFAOYSA-N n,n',n'-trimethylhexane-1,6-diamine Chemical compound CNCCCCCCN(C)C ZETYUTMSJWMKNQ-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 1
- FBUKVWPVBMHYJY-UHFFFAOYSA-N noncarboxylic acid Natural products CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9609238 | 1996-07-23 | ||
| FR9609238 | 1996-07-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2296304T3 true ES2296304T3 (es) | 2008-04-16 |
Family
ID=9494366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97401629T Expired - Lifetime ES2296304T3 (es) | 1996-07-23 | 1997-07-08 | Composiciones a base de poliamida resistentes al choque. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5919865A (enExample) |
| EP (1) | EP0821037B1 (enExample) |
| JP (2) | JPH1067931A (enExample) |
| KR (1) | KR100231631B1 (enExample) |
| CN (1) | CN1080287C (enExample) |
| BR (1) | BR9704051A (enExample) |
| CA (1) | CA2209977A1 (enExample) |
| DE (1) | DE69738284T2 (enExample) |
| ES (1) | ES2296304T3 (enExample) |
| TW (1) | TW428010B (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0997268A1 (fr) | 1998-10-26 | 2000-05-03 | Elf Atochem S.A. | Films comprenant du polyethylene metallocene et du polyamide |
| KR100700393B1 (ko) | 1999-06-17 | 2007-03-28 | 미쓰이 가가쿠 가부시키가이샤 | 에틸렌 (공)중합체 및 그 용도 |
| FR2847902B1 (fr) * | 2002-11-29 | 2007-02-16 | Rhodia Eng Plastics Srl | Composition a base de matrice thermoplastique |
| DE102004027872A1 (de) * | 2004-06-08 | 2006-01-05 | Lanxess Deutschland Gmbh | Polyamid-Formmassen mit verbesserter Fließfähigkeit |
| ATE421554T1 (de) * | 2004-06-08 | 2009-02-15 | Lanxess Deutschland Gmbh | Polyamid-formmassen mit verbesserter fliessfähigkeit |
| KR100888532B1 (ko) * | 2004-06-08 | 2009-03-11 | 란세스 도이치란트 게엠베하 | 열가소성 폴리에스테르를 기재로 하는 유동성이 개선된 성형 화합물 |
| EP2021410B1 (en) * | 2006-05-30 | 2011-10-26 | PolyOne Corporation | Thermoplastic elastomers for adhesion to polyamide |
| FR2907125B1 (fr) | 2006-10-12 | 2012-09-21 | Arkema France | Composition resistant au choc a base de resine polyamide et d'un melange d'au moins un copolymere greffe a blocs polyamides et de polymere ethylenique basse densite |
| WO2012027043A1 (en) | 2010-08-23 | 2012-03-01 | Cryovac, Inc. | Ovenable heat-sealed package |
| JP6139999B2 (ja) * | 2013-06-20 | 2017-05-31 | 旭化成株式会社 | ポリアミド樹脂組成物及び成形体 |
| WO2014203606A1 (ja) | 2013-06-20 | 2014-12-24 | 旭化成ケミカルズ株式会社 | ポリアミド樹脂組成物及び成形体 |
| CN109661554B (zh) | 2016-08-08 | 2021-05-11 | 提克纳有限责任公司 | 用于散热器的导热聚合物组合物 |
| JP6939004B2 (ja) * | 2017-03-24 | 2021-09-22 | 富士フイルムビジネスイノベーション株式会社 | 樹脂成形体用樹脂組成物、及び樹脂成形体 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4174358A (en) * | 1975-05-23 | 1979-11-13 | E. I. Du Pont De Nemours And Company | Tough thermoplastic nylon compositions |
| DE3220380A1 (de) * | 1982-05-29 | 1983-12-01 | Basf Ag, 6700 Ludwigshafen | Schlagzaehe polyamid-formmassen |
| JPS60202151A (ja) * | 1984-03-26 | 1985-10-12 | Du Pont Mitsui Polychem Co Ltd | ポリアミド系樹脂組成物 |
| DE3444096A1 (de) * | 1984-12-04 | 1986-06-05 | Basf Ag, 6700 Ludwigshafen | Copolymerisate des ethylens und deren verwendung als schlagzaehmodifier in thermoplasten |
| FR2580656B1 (fr) * | 1985-04-23 | 1987-09-11 | Charbonnages Ste Chimique | Compositions thermoplastiques multiphases et articles obtenus |
-
1997
- 1997-07-08 DE DE69738284T patent/DE69738284T2/de not_active Expired - Lifetime
- 1997-07-08 ES ES97401629T patent/ES2296304T3/es not_active Expired - Lifetime
- 1997-07-08 EP EP97401629A patent/EP0821037B1/fr not_active Expired - Lifetime
- 1997-07-22 CA CA002209977A patent/CA2209977A1/fr not_active Abandoned
- 1997-07-22 BR BR9704051A patent/BR9704051A/pt active Search and Examination
- 1997-07-23 JP JP9212490A patent/JPH1067931A/ja active Pending
- 1997-07-23 CN CN97117823A patent/CN1080287C/zh not_active Expired - Fee Related
- 1997-07-23 US US08/899,271 patent/US5919865A/en not_active Expired - Lifetime
- 1997-07-23 KR KR1019970034535A patent/KR100231631B1/ko not_active Expired - Fee Related
- 1997-08-07 TW TW086111341A patent/TW428010B/zh not_active IP Right Cessation
-
1999
- 1999-11-04 JP JP31412999A patent/JP4051593B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE69738284T2 (de) | 2008-09-18 |
| EP0821037A1 (fr) | 1998-01-28 |
| JP4051593B2 (ja) | 2008-02-27 |
| CN1174215A (zh) | 1998-02-25 |
| EP0821037B1 (fr) | 2007-11-14 |
| CN1080287C (zh) | 2002-03-06 |
| DE69738284D1 (de) | 2007-12-27 |
| TW428010B (en) | 2001-04-01 |
| KR980009386A (ko) | 1998-04-30 |
| BR9704051A (pt) | 1998-12-22 |
| CA2209977A1 (fr) | 1998-01-23 |
| KR100231631B1 (ko) | 1999-11-15 |
| US5919865A (en) | 1999-07-06 |
| JP2000109688A (ja) | 2000-04-18 |
| JPH1067931A (ja) | 1998-03-10 |
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