ES2236925T5 - Recipientes de poliester grandes y metodo de fabricacion. - Google Patents
Recipientes de poliester grandes y metodo de fabricacion. Download PDFInfo
- Publication number
- ES2236925T5 ES2236925T5 ES98937131T ES98937131T ES2236925T5 ES 2236925 T5 ES2236925 T5 ES 2236925T5 ES 98937131 T ES98937131 T ES 98937131T ES 98937131 T ES98937131 T ES 98937131T ES 2236925 T5 ES2236925 T5 ES 2236925T5
- Authority
- ES
- Spain
- Prior art keywords
- acid
- mol
- container
- polyester
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 26
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000005303 weighing Methods 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 22
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 20
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- -1 aromatic dicarboxylic acids Chemical class 0.000 claims description 9
- 150000007513 acids Chemical class 0.000 claims description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000003607 modifier Substances 0.000 claims description 6
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims description 6
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
- 150000002009 diols Chemical class 0.000 claims description 5
- ZYZYQCACSQDPSB-UHFFFAOYSA-N 12,15-dioxatricyclo[8.6.0.02,7]hexadeca-1(10),2,4,6,8-pentaene-11,16-dione Chemical compound O=C1OCCOC(=O)C2=C1C=CC1=CC=CC=C21 ZYZYQCACSQDPSB-UHFFFAOYSA-N 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 4
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 3
- YQPCHPBGAALCRT-UHFFFAOYSA-N 2-[1-(carboxymethyl)cyclohexyl]acetic acid Chemical compound OC(=O)CC1(CC(O)=O)CCCCC1 YQPCHPBGAALCRT-UHFFFAOYSA-N 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 3
- 150000002334 glycols Chemical class 0.000 claims description 3
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 claims description 2
- ICPXIRMAMWRMAD-UHFFFAOYSA-N 2-[3-[2-[3-(2-hydroxyethoxy)phenyl]propan-2-yl]phenoxy]ethanol Chemical compound C=1C=CC(OCCO)=CC=1C(C)(C)C1=CC=CC(OCCO)=C1 ICPXIRMAMWRMAD-UHFFFAOYSA-N 0.000 claims description 2
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 claims description 2
- CPHURRLSZSRQFS-UHFFFAOYSA-N 3-[4-[2-[4-(3-hydroxypropoxy)phenyl]propan-2-yl]phenoxy]propan-1-ol Chemical compound C=1C=C(OCCCO)C=CC=1C(C)(C)C1=CC=C(OCCCO)C=C1 CPHURRLSZSRQFS-UHFFFAOYSA-N 0.000 claims description 2
- CDBAMNGURPMUTG-UHFFFAOYSA-N 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol Chemical compound C1CC(O)CCC1C(C)(C)C1CCC(O)CC1 CDBAMNGURPMUTG-UHFFFAOYSA-N 0.000 claims description 2
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims 2
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 abstract description 4
- 238000000071 blow moulding Methods 0.000 description 21
- 238000002425 crystallisation Methods 0.000 description 15
- 230000008025 crystallization Effects 0.000 description 14
- 230000004048 modification Effects 0.000 description 14
- 238000012986 modification Methods 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 12
- 230000000704 physical effect Effects 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- 229920006125 amorphous polymer Polymers 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229920006127 amorphous resin Polymers 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003763 resistance to breakage Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical class [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 1
- 235000013904 zinc acetate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/185—Acids containing aromatic rings containing two or more aromatic rings
- C08G63/187—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings
- C08G63/189—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings containing a naphthalene ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5371797P | 1997-07-25 | 1997-07-25 | |
| US53717P | 1997-07-25 | ||
| US106294 | 1998-06-29 | ||
| US09/106,294 US6309718B1 (en) | 1997-07-25 | 1998-06-29 | Large polyester containers and method for making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2236925T3 ES2236925T3 (es) | 2005-07-16 |
| ES2236925T5 true ES2236925T5 (es) | 2008-06-16 |
Family
ID=26732168
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98937131T Expired - Lifetime ES2236925T5 (es) | 1997-07-25 | 1998-07-24 | Recipientes de poliester grandes y metodo de fabricacion. |
| ES04028385T Expired - Lifetime ES2275166T3 (es) | 1997-07-25 | 1998-07-24 | Recipientes grandes de poliester y metodo para obtenerlos. |
| ES04028382T Expired - Lifetime ES2273146T3 (es) | 1997-07-25 | 1998-07-24 | Recipientes grandes de poliester y metodo para obtenerlos. |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES04028385T Expired - Lifetime ES2275166T3 (es) | 1997-07-25 | 1998-07-24 | Recipientes grandes de poliester y metodo para obtenerlos. |
| ES04028382T Expired - Lifetime ES2273146T3 (es) | 1997-07-25 | 1998-07-24 | Recipientes grandes de poliester y metodo para obtenerlos. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6309718B1 (enExample) |
| EP (1) | EP0998512B2 (enExample) |
| JP (1) | JP2001510869A (enExample) |
| CN (1) | CN1271368A (enExample) |
| AR (1) | AR016533A1 (enExample) |
| BR (1) | BR9811033A (enExample) |
| CA (1) | CA2297008C (enExample) |
| DE (3) | DE69829378T3 (enExample) |
| ES (3) | ES2236925T5 (enExample) |
| WO (1) | WO1999005197A1 (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040091651A1 (en) * | 2002-11-01 | 2004-05-13 | Mark Rule | Pet copolymer composition with enhanced mechanical properties and stretch ratio, articles made therewith, and methods |
| US20050260371A1 (en) * | 2002-11-01 | 2005-11-24 | Yu Shi | Preform for low natural stretch ratio polymer, container made therewith and methods |
| EP1433804A1 (en) * | 2002-12-03 | 2004-06-30 | Nan Ya Plastics Corp. | Copolyester composition for manufacturing large volume polyester bottle |
| US6913806B2 (en) * | 2002-12-20 | 2005-07-05 | Nan Ya Plastics Corporation | Copolyester composition for manufacturing large volume polyester bottle |
| US20050261462A1 (en) * | 2004-05-20 | 2005-11-24 | Nichols Carl S | Methods of making titanium-catalyzed polyester resins |
| JP2007504352A (ja) * | 2003-05-21 | 2007-03-01 | ウェルマン・インコーポレーテッド | 遅延性結晶化ポリエステル樹脂 |
| US7094863B2 (en) * | 2003-05-21 | 2006-08-22 | Wellman, Inc. | Polyester preforms useful for enhanced heat-set bottles |
| US20070059465A1 (en) * | 2004-05-20 | 2007-03-15 | Thompson David E | Polyester Resins for High-Strength Articles |
| WO2004113414A1 (en) * | 2003-06-18 | 2004-12-29 | The Coca-Cola Company | Polyester composition for hot fill applications, containers made therewith, and methods |
| US7238770B2 (en) * | 2004-01-29 | 2007-07-03 | Wellman, Inc. | Methods of making imide-modified polyester resins |
| TW200528484A (en) * | 2004-01-29 | 2005-09-01 | Wellman Inc | Imide-modified polyester resins and methods of making the same |
| US20080009574A1 (en) * | 2005-01-24 | 2008-01-10 | Wellman, Inc. | Polyamide-Polyester Polymer Blends and Methods of Making the Same |
| US7803440B2 (en) | 2005-06-17 | 2010-09-28 | Eastman Chemical Company | Bottles comprising polyester compositions which comprise cyclobutanediol |
| WO2007053548A2 (en) | 2005-10-28 | 2007-05-10 | Eastman Chemical Company | Polyester compositions comprising minimal amounts of cyclobutanediol |
| US7820257B2 (en) * | 2005-05-11 | 2010-10-26 | The Coca-Cola Company | Preforms for preparing lightweight stretch blow molded PET copolymer containers and methods for making and using same |
| US7572493B2 (en) * | 2005-05-11 | 2009-08-11 | The Coca-Cola Company | Low IV pet based copolymer preform with enhanced mechanical properties and cycle time, container made therewith and methods |
| US7704605B2 (en) | 2006-03-28 | 2010-04-27 | Eastman Chemical Company | Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein |
| WO2007044623A1 (en) * | 2005-10-07 | 2007-04-19 | Invista Technologies, S.A.R.L. | Articles having improved gas barrier properties |
| US9777111B2 (en) * | 2005-10-20 | 2017-10-03 | Grupo Petrotemex, S.A. De C.V. | PET polymer with improved properties |
| US8193302B2 (en) | 2005-10-28 | 2012-06-05 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
| WO2007059128A1 (en) * | 2005-11-15 | 2007-05-24 | Wellman, Inc. | Alumina-enhanced polyester resins |
| US9598533B2 (en) | 2005-11-22 | 2017-03-21 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US7737246B2 (en) | 2005-12-15 | 2010-06-15 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
| US9169388B2 (en) | 2006-03-28 | 2015-10-27 | Eastman Chemical Company | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| BRPI0714188A2 (pt) * | 2006-07-11 | 2012-12-25 | Wellman Inc | catalisador de polimerizaÇço de fase sàlida compàsito |
| KR101895184B1 (ko) | 2007-11-21 | 2018-09-04 | 이스트만 케미칼 컴파니 | 플라스틱 젖병, 다른 취입 성형된 제품, 및 이들의 제조 방법 |
| US8501287B2 (en) | 2007-11-21 | 2013-08-06 | Eastman Chemical Company | Plastic baby bottles, other blow molded articles, and processes for their manufacture |
| US8791225B2 (en) * | 2008-06-06 | 2014-07-29 | Dak Americas Mississippi Inc. | Titanium-nitride catalyzed polyester |
| US8198371B2 (en) | 2008-06-27 | 2012-06-12 | Eastman Chemical Company | Blends of polyesters and ABS copolymers |
| US8895654B2 (en) | 2008-12-18 | 2014-11-25 | Eastman Chemical Company | Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid |
| TWI400272B (zh) * | 2009-12-18 | 2013-07-01 | Nanya Plastics Corp | Titanium-containing copolyesters for the production of large-volume PET bottles and their products |
| US8420869B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US8420868B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US8394997B2 (en) | 2010-12-09 | 2013-03-12 | Eastman Chemical Company | Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
| US20130029068A1 (en) * | 2011-07-28 | 2013-01-31 | Eastman Chemical Company | Extrusion blow molded articles |
| US20130217830A1 (en) | 2012-02-16 | 2013-08-22 | Eastman Chemical Company | Clear Semi-Crystalline Articles with Improved Heat Resistance |
| JP6167798B2 (ja) * | 2012-09-27 | 2017-07-26 | 東洋紡株式会社 | ポリエステルフィルム |
| JP6167797B2 (ja) * | 2012-09-27 | 2017-07-26 | 東洋紡株式会社 | ポリエステルフィルム |
| US11186713B2 (en) * | 2016-04-11 | 2021-11-30 | Dak Americas Llc | Polyester containers and films with reduced gas permeability |
| US11261292B2 (en) | 2018-09-06 | 2022-03-01 | Alpek Polyester, S.A. De C.V. | Pet composition, pet preform, refillable pet bottle and methods for making the same |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU610555B2 (en) | 1987-02-06 | 1991-05-23 | Mitsubishi Gas Chemical Company, Inc. | Parison and blow-moulded containers and processes for production thereof |
| JPH04500982A (ja) | 1988-10-06 | 1992-02-20 | イーストマン コダック カンパニー | 改良された加工性を有する改質ポリ（エチレン２，６―ナフタレンジカルボキシレート） |
| US4983711A (en) | 1989-12-04 | 1991-01-08 | Eastman Kodak Company | Copolyesters and articles extrusion blow-molded therefrom |
| GB9013481D0 (en) | 1990-06-15 | 1990-08-08 | Ici Plc | Polyester polymer products |
| US5217128A (en) | 1991-10-28 | 1993-06-08 | Johnson Enterprises, Inc. | Thermoplastic bottle with reinforcing ribs |
| EP0543265A1 (de) † | 1991-11-14 | 1993-05-26 | Hoechst Aktiengesellschaft | Modifiziertes Polyethylenterephthalat und seine Verwendung zur Herstellung von Behältern durch Blasextrusion |
| US5344912A (en) * | 1992-02-03 | 1994-09-06 | Therma-Plate Corporation | Elevated temperature dimensionally stable polyester with low gas permeability |
| ATE177049T1 (de) | 1992-07-07 | 1999-03-15 | Continental Pet Technologies | Verfahren zum formen eines mehrlagigen vorformlings und behälter mit niedrig kristalliner innenschicht |
| WO1995003977A1 (en) | 1993-07-30 | 1995-02-09 | Nicoleon Petrou | Bottle with internal skeleton |
| IL117945A (en) | 1995-04-18 | 2000-01-31 | Coca Cola Co | Preform and bottle using pet/pen blends and copolymers |
| US6060140A (en) * | 1997-04-25 | 2000-05-09 | Eastman Chemical Company | Lightweight bottles and method for making same |
-
1998
- 1998-06-29 US US09/106,294 patent/US6309718B1/en not_active Expired - Lifetime
- 1998-07-22 AR ARP980103603A patent/AR016533A1/es active IP Right Grant
- 1998-07-24 DE DE69829378T patent/DE69829378T3/de not_active Expired - Lifetime
- 1998-07-24 ES ES98937131T patent/ES2236925T5/es not_active Expired - Lifetime
- 1998-07-24 ES ES04028385T patent/ES2275166T3/es not_active Expired - Lifetime
- 1998-07-24 DE DE69836509T patent/DE69836509T2/de not_active Expired - Lifetime
- 1998-07-24 EP EP98937131A patent/EP0998512B2/en not_active Expired - Lifetime
- 1998-07-24 DE DE69836770T patent/DE69836770T2/de not_active Expired - Lifetime
- 1998-07-24 BR BR9811033-0A patent/BR9811033A/pt not_active IP Right Cessation
- 1998-07-24 CN CN98809424A patent/CN1271368A/zh active Pending
- 1998-07-24 JP JP2000504184A patent/JP2001510869A/ja active Pending
- 1998-07-24 CA CA002297008A patent/CA2297008C/en not_active Expired - Lifetime
- 1998-07-24 ES ES04028382T patent/ES2273146T3/es not_active Expired - Lifetime
- 1998-07-24 WO PCT/US1998/015467 patent/WO1999005197A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN1271368A (zh) | 2000-10-25 |
| DE69836509T2 (de) | 2007-05-03 |
| JP2001510869A (ja) | 2001-08-07 |
| WO1999005197A1 (en) | 1999-02-04 |
| DE69829378T2 (de) | 2006-05-04 |
| EP0998512A1 (en) | 2000-05-10 |
| ES2236925T3 (es) | 2005-07-16 |
| DE69836770T2 (de) | 2007-10-11 |
| DE69829378D1 (de) | 2005-04-21 |
| ES2273146T3 (es) | 2007-05-01 |
| CA2297008A1 (en) | 1999-02-04 |
| BR9811033A (pt) | 2000-08-08 |
| DE69836509D1 (de) | 2007-01-04 |
| DE69836770D1 (de) | 2007-02-08 |
| AR016533A1 (es) | 2001-07-25 |
| DE69829378T3 (de) | 2008-07-31 |
| CA2297008C (en) | 2003-12-09 |
| US6309718B1 (en) | 2001-10-30 |
| EP0998512B1 (en) | 2005-03-16 |
| ES2275166T3 (es) | 2007-06-01 |
| EP0998512B2 (en) | 2008-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2236925T5 (es) | Recipientes de poliester grandes y metodo de fabricacion. | |
| KR102138388B1 (ko) | 내열성이 개선된 투명한 반-결정질 물품 | |
| TW555779B (en) | Novel polyester pellets and process for preparing the same | |
| EP0368278A2 (en) | Copolyester, polyester composition containing the copolyester, and polyester laminated structure having layer composed of the copolyester or the polyester composition | |
| US5030705A (en) | Copolymerized polyester from phenylene di(oxyaceteic acid) and isophthalic acid | |
| US5239045A (en) | Copolyester and hollow container and oriented film comprising the copolyester | |
| US20090162589A1 (en) | Polyester compositions having reduced gas permeation and methods for their production | |
| JP2001524041A (ja) | 軽量ボトル及びその製造方法 | |
| EP0368690A1 (en) | Food container made from modified poly(ethylene 2,6-naphthalenedicarboxylate) | |
| JP2953534B2 (ja) | ポリエステル樹脂組成物およびその用途 | |
| JP3594379B2 (ja) | ポリエステル樹脂組成物の製造方法 | |
| US6476180B1 (en) | Process for producing an oriented shaped article | |
| JP3716510B2 (ja) | 延伸ブローボトル | |
| EP1518876B1 (en) | Large polyester containers and method for making same | |
| JPH0834910A (ja) | 紫外線遮断性透明中空成形体 | |
| JPH0710926B2 (ja) | ポリエステル中空成形体 | |
| JPH02263619A (ja) | ポリエステル中空容器 | |
| KR102528324B1 (ko) | 폴리에스테르 수지 성형품 제조 방법 | |
| JP2574728B2 (ja) | 中空容器 | |
| JPH0464284B2 (enExample) | ||
| JPH0531789A (ja) | ブローボトルの製造方法 | |
| CN121241100A (zh) | 聚酯树脂组合物及其成型品 | |
| MXPA00000853A (en) | Large polyester containers and method for making same | |
| TW202509116A (zh) | 聚酯樹脂組成物、及其成形品 | |
| JPS6225151A (ja) | ポリエステル組成物およびその用途 |