ES2212552T3 - Materiales activos encapsulados y procedimiento de preparacion. - Google Patents
Materiales activos encapsulados y procedimiento de preparacion.Info
- Publication number
- ES2212552T3 ES2212552T3 ES99918850T ES99918850T ES2212552T3 ES 2212552 T3 ES2212552 T3 ES 2212552T3 ES 99918850 T ES99918850 T ES 99918850T ES 99918850 T ES99918850 T ES 99918850T ES 2212552 T3 ES2212552 T3 ES 2212552T3
- Authority
- ES
- Spain
- Prior art keywords
- active agent
- polymer
- particles
- active
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000011149 active material Substances 0.000 title description 17
- 239000002245 particle Substances 0.000 claims abstract description 133
- 239000013543 active substance Substances 0.000 claims abstract description 111
- 229920000642 polymer Polymers 0.000 claims abstract description 97
- 239000000203 mixture Substances 0.000 claims abstract description 78
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 238000000605 extraction Methods 0.000 claims abstract description 13
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 11
- 239000004014 plasticizer Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 54
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 229920001169 thermoplastic Polymers 0.000 claims description 12
- 239000004416 thermosoftening plastic Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- 239000005266 side chain polymer Substances 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 2
- 239000004626 polylactic acid Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 238000001816 cooling Methods 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 239000003054 catalyst Substances 0.000 description 48
- 238000005538 encapsulation Methods 0.000 description 41
- 238000009472 formulation Methods 0.000 description 37
- 230000000052 comparative effect Effects 0.000 description 34
- 239000000463 material Substances 0.000 description 30
- -1 polysiloxane Polymers 0.000 description 29
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 26
- 238000001723 curing Methods 0.000 description 21
- 239000000178 monomer Substances 0.000 description 16
- 230000009257 reactivity Effects 0.000 description 16
- 239000003570 air Substances 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- 239000002775 capsule Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 10
- 230000007704 transition Effects 0.000 description 10
- 230000004913 activation Effects 0.000 description 9
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 9
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- 229920000058 polyacrylate Polymers 0.000 description 9
- 239000004814 polyurethane Substances 0.000 description 9
- 229920002635 polyurethane Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- 238000001694 spray drying Methods 0.000 description 8
- 239000012974 tin catalyst Substances 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000001879 gelation Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 7
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000009833 condensation Methods 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 150000003606 tin compounds Chemical class 0.000 description 5
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical group CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000003252 repetitive effect Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 150000003926 acrylamides Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000000875 corresponding effect Effects 0.000 description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 description 3
- URMRQIFWDOSEQQ-UHFFFAOYSA-N dibutyltin;pentane-2,4-dione Chemical compound CC(=O)CC(C)=O.CC(=O)CC(C)=O.CCCC[Sn]CCCC URMRQIFWDOSEQQ-UHFFFAOYSA-N 0.000 description 3
- XXOYNJXVWVNOOJ-UHFFFAOYSA-N fenuron Chemical compound CN(C)C(=O)NC1=CC=CC=C1 XXOYNJXVWVNOOJ-UHFFFAOYSA-N 0.000 description 3
- 238000006459 hydrosilylation reaction Methods 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 125000005609 naphthenate group Chemical group 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000002285 radioactive effect Effects 0.000 description 3
- 102220013931 rs2746462 Human genes 0.000 description 3
- 102200061079 rs776498025 Human genes 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- IRKWBEYEYLDILZ-DYNMZUSMSA-J (Z)-but-2-enedioate dibutyltin(2+) diacetate Chemical compound CC([O-])=O.CC([O-])=O.[O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC.CCCC[Sn+2]CCCC IRKWBEYEYLDILZ-DYNMZUSMSA-J 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- CNPVJWYWYZMPDS-UHFFFAOYSA-N 2-methyldecane Chemical compound CCCCCCCCC(C)C CNPVJWYWYZMPDS-UHFFFAOYSA-N 0.000 description 2
- CSKRBHOAJUMOKJ-UHFFFAOYSA-N 3,4-diacetylhexane-2,5-dione Chemical compound CC(=O)C(C(C)=O)C(C(C)=O)C(C)=O CSKRBHOAJUMOKJ-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- CMCJNODIWQEOAI-UHFFFAOYSA-N bis(2-butoxyethyl)phthalate Chemical compound CCCCOCCOC(=O)C1=CC=CC=C1C(=O)OCCOCCCC CMCJNODIWQEOAI-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 2
- 239000008393 encapsulating agent Substances 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000008029 phthalate plasticizer Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000005077 polysulfide Substances 0.000 description 2
- 229920001021 polysulfide Polymers 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 238000007712 rapid solidification Methods 0.000 description 2
- 102220260512 rs1192077362 Human genes 0.000 description 2
- 102200027487 rs56170584 Human genes 0.000 description 2
- 102220189944 rs761687649 Human genes 0.000 description 2
- 102220214378 rs762566962 Human genes 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- YOBOXHGSEJBUPB-MTOQALJVSA-N (z)-4-hydroxypent-3-en-2-one;zirconium Chemical compound [Zr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O YOBOXHGSEJBUPB-MTOQALJVSA-N 0.000 description 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- ZFDWWDZLRKHULH-UHFFFAOYSA-N 1,2-dimethyl-5,6-dihydro-4h-pyrimidine Chemical compound CN1CCCN=C1C ZFDWWDZLRKHULH-UHFFFAOYSA-N 0.000 description 1
- GIWQSPITLQVMSG-UHFFFAOYSA-N 1,2-dimethylimidazole Chemical compound CC1=NC=CN1C GIWQSPITLQVMSG-UHFFFAOYSA-N 0.000 description 1
- FCQPNTOQFPJCMF-UHFFFAOYSA-N 1,3-bis[3-(dimethylamino)propyl]urea Chemical compound CN(C)CCCNC(=O)NCCCN(C)C FCQPNTOQFPJCMF-UHFFFAOYSA-N 0.000 description 1
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 description 1
- GEEGPFGTMRWCID-UHFFFAOYSA-N 1-n,1-n,1-n',1-n'-tetramethylbutane-1,1-diamine Chemical compound CCCC(N(C)C)N(C)C GEEGPFGTMRWCID-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 1
- MLPBASQNOQYIGL-UHFFFAOYSA-N 2-(2-propan-2-yl-1h-imidazol-5-yl)propanenitrile Chemical compound CC(C)C1=NC=C(C(C)C#N)N1 MLPBASQNOQYIGL-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- PQAMFDRRWURCFQ-UHFFFAOYSA-N 2-ethyl-1h-imidazole Chemical class CCC1=NC=CN1 PQAMFDRRWURCFQ-UHFFFAOYSA-N 0.000 description 1
- YTWBFUCJVWKCCK-UHFFFAOYSA-N 2-heptadecyl-1h-imidazole Chemical class CCCCCCCCCCCCCCCCCC1=NC=CN1 YTWBFUCJVWKCCK-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical class CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical class C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 description 1
- FUOZJYASZOSONT-UHFFFAOYSA-N 2-propan-2-yl-1h-imidazole Chemical class CC(C)C1=NC=CN1 FUOZJYASZOSONT-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- LLEASVZEQBICSN-UHFFFAOYSA-N 2-undecyl-1h-imidazole Chemical class CCCCCCCCCCCC1=NC=CN1 LLEASVZEQBICSN-UHFFFAOYSA-N 0.000 description 1
- KOKYZJXQQKRSJC-UHFFFAOYSA-N 3,3-diacetylheptane-2,4,6-trione;titanium Chemical compound [Ti].CC(=O)CC(=O)C(C(C)=O)(C(C)=O)C(C)=O KOKYZJXQQKRSJC-UHFFFAOYSA-N 0.000 description 1
- UIDDPPKZYZTEGS-UHFFFAOYSA-N 3-(2-ethyl-4-methylimidazol-1-yl)propanenitrile Chemical compound CCC1=NC(C)=CN1CCC#N UIDDPPKZYZTEGS-UHFFFAOYSA-N 0.000 description 1
- SESYNEDUKZDRJL-UHFFFAOYSA-N 3-(2-methylimidazol-1-yl)propanenitrile Chemical compound CC1=NC=CN1CCC#N SESYNEDUKZDRJL-UHFFFAOYSA-N 0.000 description 1
- BVYPJEBKDLFIDL-UHFFFAOYSA-N 3-(2-phenylimidazol-1-yl)propanenitrile Chemical compound N#CCCN1C=CN=C1C1=CC=CC=C1 BVYPJEBKDLFIDL-UHFFFAOYSA-N 0.000 description 1
- SZUPZARBRLCVCB-UHFFFAOYSA-N 3-(2-undecylimidazol-1-yl)propanenitrile Chemical compound CCCCCCCCCCCC1=NC=CN1CCC#N SZUPZARBRLCVCB-UHFFFAOYSA-N 0.000 description 1
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 1
- KDQTUCKOAOGTLT-UHFFFAOYSA-N 3-[3-(dimethylcarbamoylamino)-4-methylphenyl]-1,1-dimethylurea Chemical compound CN(C)C(=O)NC1=CC=C(C)C(NC(=O)N(C)C)=C1 KDQTUCKOAOGTLT-UHFFFAOYSA-N 0.000 description 1
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- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical class [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 1
- SYRHIZPPCHMRIT-UHFFFAOYSA-N tin(4+) Chemical compound [Sn+4] SYRHIZPPCHMRIT-UHFFFAOYSA-N 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 1
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- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening
- B01J13/206—Hardening; drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
- Y10T428/2987—Addition polymer from unsaturated monomers only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2989—Microcapsule with solid core [includes liposome]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8312798P | 1998-04-27 | 1998-04-27 | |
| US83127P | 1998-04-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2212552T3 true ES2212552T3 (es) | 2004-07-16 |
Family
ID=22176365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99918850T Expired - Lifetime ES2212552T3 (es) | 1998-04-27 | 1999-04-27 | Materiales activos encapsulados y procedimiento de preparacion. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6224793B1 (cg-RX-API-DMAC10.html) |
| EP (1) | EP1077763B1 (cg-RX-API-DMAC10.html) |
| JP (2) | JP2002513045A (cg-RX-API-DMAC10.html) |
| KR (1) | KR100577629B1 (cg-RX-API-DMAC10.html) |
| CN (1) | CN1207090C (cg-RX-API-DMAC10.html) |
| AT (1) | ATE259257T1 (cg-RX-API-DMAC10.html) |
| AU (1) | AU3666799A (cg-RX-API-DMAC10.html) |
| BR (1) | BR9910337B1 (cg-RX-API-DMAC10.html) |
| CA (1) | CA2330472C (cg-RX-API-DMAC10.html) |
| DE (1) | DE69914739T2 (cg-RX-API-DMAC10.html) |
| ES (1) | ES2212552T3 (cg-RX-API-DMAC10.html) |
| WO (1) | WO1999055454A1 (cg-RX-API-DMAC10.html) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999055794A1 (en) * | 1998-04-27 | 1999-11-04 | The Dow Chemical Company | Cure on demand adhesives and window module with cure on demand adhesive thereon |
| JP2000044636A (ja) * | 1998-05-27 | 2000-02-15 | Hitachi Chem Co Ltd | 熱硬化性樹脂組成物及びこれを用いたコイルの製造法 |
| JP2000273323A (ja) * | 1999-03-24 | 2000-10-03 | Hitachi Chem Co Ltd | 硬化剤組成物、熱硬化性樹脂組成物、これを用いた管ライニング材及び管ライニング工法 |
| JP2001200021A (ja) * | 2000-01-19 | 2001-07-24 | Hitachi Chem Co Ltd | 樹脂組成物 |
| US6518330B2 (en) * | 2001-02-13 | 2003-02-11 | Board Of Trustees Of University Of Illinois | Multifunctional autonomically healing composite material |
| GB2377661B (en) | 2001-07-20 | 2005-04-20 | Univ Newcastle | Methods of manufacturing particles |
| MXPA03002222A (es) * | 2002-03-28 | 2004-10-29 | Rohm & Haas | Polvos de recubrimiento, metodos para su elaboracion y articulos formados a partir de los mismos. |
| US7179766B2 (en) * | 2002-12-19 | 2007-02-20 | Sud-Chemie Inc. | Method and apparatus for production of enrobed catalyst pastilles or flakes |
| US7192991B2 (en) * | 2003-11-26 | 2007-03-20 | 3M Innovative Properties Company | Cationically curable composition |
| DE102004020429A1 (de) * | 2004-04-27 | 2005-11-24 | Degussa Ag | Uretdiongruppenhaltige Polyurethanzusammensetzungen, welche bei niedriger Temperatur härtbar sind und (teil-)kristalline Harze enthalten |
| US7566747B2 (en) * | 2004-05-07 | 2009-07-28 | The Board Of Trustees Of The University Of Illinois | Wax particles for protection of activators, and multifunctional autonomically healing composite materials |
| JP4733933B2 (ja) * | 2004-06-18 | 2011-07-27 | 東レ・ダウコーニング株式会社 | 硬化性オルガノポリシロキサン組成物 |
| EP1784302B1 (en) * | 2004-09-01 | 2016-07-06 | Encapsys, Llc | Encapsulated cure systems |
| EP1690528A1 (de) * | 2005-02-11 | 2006-08-16 | Abbott GmbH & Co. KG | Herstellung von Dosierungsformen mit einer festen Dispersion eines mikrokristallinen Wirkstoffs |
| WO2006109747A1 (ja) * | 2005-04-07 | 2006-10-19 | Mitsui Chemicals, Inc. | オレフィン系重合体からなるカプセル状の微粒子 |
| US7612152B2 (en) * | 2005-05-06 | 2009-11-03 | The Board Of Trustees Of The University Of Illinois | Self-healing polymers |
| JP4678591B2 (ja) * | 2005-08-31 | 2011-04-27 | カシオ電子工業株式会社 | 超音波破壊用マイクロカプセル |
| DE102006040123A1 (de) * | 2006-08-26 | 2008-03-20 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Mikropartikeln |
| EP1973972A2 (en) * | 2006-01-05 | 2008-10-01 | The Board Of Trustees Of The University Of Illinois | Self-healing coating system |
| US20070173602A1 (en) * | 2006-01-25 | 2007-07-26 | Brinkman Larry F | Encapsulated Michael addition catalyst |
| EP2407148B1 (en) * | 2006-05-11 | 2018-02-21 | Evonik Degussa GmbH | Personal care compositions containing functionalized polymers |
| US7569625B2 (en) * | 2006-06-02 | 2009-08-04 | The Board Of Trustees Of The University Of Illinois | Self-healing elastomer system |
| US20090263346A1 (en) * | 2006-12-05 | 2009-10-22 | David Taft | Systems and methods for delivery of drugs |
| US20100210792A1 (en) * | 2006-12-05 | 2010-08-19 | David Taft | Drug delivery |
| US20100004124A1 (en) * | 2006-12-05 | 2010-01-07 | David Taft | Systems and methods for delivery of materials for agriculture and aquaculture |
| US8399007B2 (en) * | 2006-12-05 | 2013-03-19 | Landec Corporation | Method for formulating a controlled-release pharmaceutical formulation |
| US20090246155A1 (en) * | 2006-12-05 | 2009-10-01 | Landec Corporation | Compositions and methods for personal care |
| JP5340956B2 (ja) * | 2006-12-20 | 2013-11-13 | アーケマ・インコーポレイテッド | ポリマーの封入および／または結合 |
| US7842146B2 (en) * | 2007-01-26 | 2010-11-30 | Dow Global Technologies Inc. | Ultrasonic energy for adhesive bonding |
| EP1953199A1 (en) * | 2007-02-01 | 2008-08-06 | Stichting Dutch Polymer Institute | Powder coating composition comprising an encapsulated crosslinker |
| US7846551B2 (en) | 2007-03-16 | 2010-12-07 | Tdy Industries, Inc. | Composite articles |
| US20080299391A1 (en) * | 2007-05-31 | 2008-12-04 | White Scott R | Capsules, methods for making capsules, and self-healing composites including the same |
| US8114883B2 (en) | 2007-12-04 | 2012-02-14 | Landec Corporation | Polymer formulations for delivery of bioactive materials |
| US20090181254A1 (en) * | 2008-01-15 | 2009-07-16 | The Board Of Trustees Of The University Of Illinois | Multi-capsule system and its use for encapsulating active agents |
| US9233063B2 (en) * | 2009-12-17 | 2016-01-12 | Air Products And Chemicals, Inc. | Polymeric compositions for personal care products |
| US8663596B2 (en) * | 2010-01-25 | 2014-03-04 | Fluor Enterprises, Inc. | Reactor, a structure packing, and a method for improving oxidation of hydrogen sulfide or polysulfides in liquid sulfur |
| US8361432B2 (en) | 2010-12-08 | 2013-01-29 | Fluor Enterprises, Inc. | Reactor, a retained catalyst structure, and a method for improving decomposition of polysulfides and removal of hydrogen sulfide in liquid sulfur |
| CA2871595C (en) | 2011-06-14 | 2019-03-26 | Signa Chemistry, Inc. | Foamed cement compositions containing metal silicides usable in subterranean well operations |
| CN102417613A (zh) * | 2011-07-26 | 2012-04-18 | 东莞市贝特利新材料有限公司 | 一种应用于加成型液体硅橡胶中的添加剂的制备方法 |
| MX367905B (es) * | 2012-02-02 | 2019-09-11 | Arkema Inc | Vida util mejorada de mezclas de polioles que contienen olefinas halogenadas por encapsulacion de los componentes activos. |
| CN104540922B (zh) | 2012-06-25 | 2017-12-29 | 西格纳化学有限责任公司 | 在烃生产和运输中的金属硅化物 |
| JP6057589B2 (ja) * | 2012-07-27 | 2017-01-11 | 東レ・ダウコーニング株式会社 | 微粒子及びそれを含む硬化性オルガノポリシロキサン組成物 |
| TW201414796A (zh) * | 2012-07-27 | 2014-04-16 | Dow Corning | 自黏結可固化聚矽氧黏著劑之組成物及製造彼之方法 |
| JP6075074B2 (ja) * | 2013-01-22 | 2017-02-08 | 住友ベークライト株式会社 | 注入剤および充填方法 |
| US10035338B2 (en) * | 2013-07-01 | 2018-07-31 | Mark Andy, Inc. | Method and apparatus for in-line solventless lamination |
| US9018327B1 (en) * | 2013-11-08 | 2015-04-28 | Ppg Industries Ohio, Inc. | Catalyst compositions and methods of preparing them |
| US9683129B2 (en) | 2014-12-04 | 2017-06-20 | Prc-Desoto International, Inc. | Polythioether sealants with extended working time |
| JP6824274B2 (ja) * | 2015-12-10 | 2021-02-03 | ピーアールシー−デソト インターナショナル，インコーポレイティド | キュア・オン・デマンド湿気硬化型ウレタン含有耐燃料性プレポリマーおよびその組成物 |
| CN106833098A (zh) * | 2017-02-16 | 2017-06-13 | 佛山市涂亿装饰材料科技有限公司 | 一种专用于低温固化的热固性粉末涂料超细微胶囊固化促进剂产品的生产工艺 |
| US11559777B2 (en) * | 2017-03-09 | 2023-01-24 | Construction Research & Technology Gmbh | Microencapsulated polyaddition catalyst |
| WO2018162519A1 (en) | 2017-03-09 | 2018-09-13 | Basf Se | Polyurethane formulations for the production of composite elements |
| AU2019212991B2 (en) | 2018-01-26 | 2024-05-23 | Allnex Netherlands B.V. | Powder coating composition |
| JP7318250B2 (ja) * | 2018-03-29 | 2023-08-01 | 東ソー株式会社 | 触媒内包ポリビニル樹脂微粒子、該微粒子組成物、触媒内包ポリビニル樹脂微粒子及び該微粒子組成物の製造方法 |
| WO2020165135A1 (en) | 2019-02-11 | 2020-08-20 | Basf Se | Acrylic copolymer capsule designed to open up at < 90°c for controlled release of in-situ forming pu/pir catalyst |
| CN110549037B (zh) * | 2019-09-23 | 2021-06-01 | 广东省科学院中乌焊接研究所 | 囊壳材料、软钎焊用微胶囊活性剂及其制备方法、锡膏及其应用 |
| JP7501130B2 (ja) * | 2020-06-10 | 2024-06-18 | 東ソー株式会社 | 脂質微粒子 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3317433A (en) | 1958-10-23 | 1967-05-02 | Ncr Co | Heat rupturable capsules |
| DE2526603A1 (de) | 1975-06-13 | 1976-12-16 | Ruetgerswerke Ag | Lagerstabile, sehr schnell aushaertbare, einkomponentige dichtungsmasse auf basis merkaptoendstaendiger polymere |
| US4091130A (en) | 1976-06-21 | 1978-05-23 | Allied Paper Incorporated | Method for obtaining controlled cure in the coating of papers |
| EP0018950B1 (de) | 1979-05-08 | 1983-07-13 | Ciba-Geigy Ag | Einkomponentensysteme auf der Basis kristalliner Epoxidharze und ihre Verwendung |
| US4461854A (en) | 1982-08-11 | 1984-07-24 | General Electric Company | Room temperature vulcanizable polysiloxane having a heat-activated catalyst |
| FR2553784B1 (fr) | 1983-10-19 | 1986-12-12 | Rhone Poulenc Spec Chim | Encapsulation de l'accelerateur de durcissement de compositions organopolysiloxaniques contenant des polyacyloxysilanes et durcissant en elastomeres |
| US4517337A (en) | 1984-02-24 | 1985-05-14 | General Electric Company | Room temperature vulcanizable organopolysiloxane compositions and method for making |
| US4503161A (en) | 1984-03-23 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Latent Lewis acid catalyst encapsulated within polymerized cycloaliphatic epoxide and polyhydric alcohol |
| US4528354A (en) | 1984-04-25 | 1985-07-09 | Mcdougal John R | Process and composition for the manufacture of products from silicone rubber |
| HU198403B (en) | 1984-05-18 | 1989-10-30 | Univ Washington | Method and apparatus for coating solid particles or liquid drops |
| EP0169536B1 (en) | 1984-07-26 | 1994-05-18 | Kanegafuchi Chemical Industry Co., Ltd. | Curable polymer composition |
| US5310786A (en) | 1987-01-08 | 1994-05-10 | Hoechst Aktiengesellschaft | Reversibly precipitable, water-soluble polymer conjugates |
| US4788170A (en) | 1987-07-06 | 1988-11-29 | General Electric Company | Method for preparing tin complex curing catalyst |
| US4766176A (en) | 1987-07-20 | 1988-08-23 | Dow Corning Corporation | Storage stable heat curable organosiloxane compositions containing microencapsulated platinum-containing catalysts |
| GB8729069D0 (en) | 1987-12-12 | 1988-01-27 | Rapra Techn Ltd | Temperature activated catalysts for liquid polymer cures |
| US5010119A (en) | 1987-12-23 | 1991-04-23 | Mcelrath Jr Kenneth O | Ternary adhesive compositions |
| FR2625745B1 (fr) | 1988-01-08 | 1992-10-09 | Picardie Lainiere | Produit textile thermocollant comprenant un agent de reticulation microencapsule |
| FR2630444B1 (fr) | 1988-04-21 | 1990-09-07 | Rhone Poulenc Chimie | Composes d'etain utilisables notamment comme catalyseurs latents pour la preparation de polyurethannes |
| DE3824771C1 (cg-RX-API-DMAC10.html) | 1988-07-21 | 1990-04-05 | Teroson Gmbh, 6900 Heidelberg, De | |
| JPH02117960A (ja) | 1988-09-02 | 1990-05-02 | Dow Corning Corp | マイクロカプセル化された成分を含有してなる貯蔵安定性オルガノシロキサン組成物の硬化方法 |
| FR2652580B1 (fr) | 1989-10-02 | 1993-06-25 | Rhone Poulenc Chimie | Composes d'etain (iv) eventuellement chelates utilisables notamment comme catalyseurs latents. |
| US5120349A (en) | 1990-12-07 | 1992-06-09 | Landec Labs, Inc. | Microcapsule having temperature-dependent permeability profile |
| DE69225586T2 (de) | 1991-02-12 | 1999-01-28 | Landec Corp., Menlo Park, Calif. | Temperaturzonen spezifische druckempfindliche klebmittelzusammensetzungen, klebmittelgebinde und damit verbundene verfahren zu ihrer benutzung |
| US5194460A (en) | 1992-01-02 | 1993-03-16 | Dow Corning Corporation | Storage stable heat curable organosiloxane compositions containing a microencapsulated catalyst and method for preparing said catalyst |
| CA2113961A1 (en) | 1993-03-31 | 1994-10-01 | Alexander Henderson | One part cross-linkable hot melt adhesives |
| US5601761A (en) * | 1994-09-26 | 1997-02-11 | The Dow Chemical Company | Encapsulated active materials and method for preparing same |
| EP0839166B1 (en) | 1995-03-07 | 2004-06-02 | Landec Corporation | Polymeric composition |
| US5665428A (en) | 1995-10-25 | 1997-09-09 | Macromed, Inc. | Preparation of peptide containing biodegradable microspheres by melt process |
| EP0925332A1 (en) | 1996-09-12 | 1999-06-30 | Landec Corporation | Polymer composition comprising a modifying agent |
-
1999
- 1999-04-27 AU AU36667/99A patent/AU3666799A/en not_active Abandoned
- 1999-04-27 CN CNB998055018A patent/CN1207090C/zh not_active Expired - Fee Related
- 1999-04-27 KR KR1020007011990A patent/KR100577629B1/ko not_active Expired - Fee Related
- 1999-04-27 DE DE69914739T patent/DE69914739T2/de not_active Expired - Lifetime
- 1999-04-27 JP JP2000545641A patent/JP2002513045A/ja not_active Withdrawn
- 1999-04-27 US US09/300,339 patent/US6224793B1/en not_active Expired - Lifetime
- 1999-04-27 CA CA002330472A patent/CA2330472C/en not_active Expired - Fee Related
- 1999-04-27 WO PCT/US1999/009105 patent/WO1999055454A1/en not_active Ceased
- 1999-04-27 AT AT99918850T patent/ATE259257T1/de not_active IP Right Cessation
- 1999-04-27 ES ES99918850T patent/ES2212552T3/es not_active Expired - Lifetime
- 1999-04-27 BR BRPI9910337-0A patent/BR9910337B1/pt not_active IP Right Cessation
- 1999-04-27 EP EP99918850A patent/EP1077763B1/en not_active Expired - Lifetime
-
2010
- 2010-11-25 JP JP2010262560A patent/JP5351131B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR9910337B1 (pt) | 2010-08-24 |
| KR100577629B1 (ko) | 2006-05-10 |
| KR20010043104A (ko) | 2001-05-25 |
| JP2002513045A (ja) | 2002-05-08 |
| DE69914739D1 (de) | 2004-03-18 |
| JP2011072999A (ja) | 2011-04-14 |
| CA2330472A1 (en) | 1999-11-04 |
| CN1298321A (zh) | 2001-06-06 |
| BR9910337A (pt) | 2001-01-09 |
| EP1077763A1 (en) | 2001-02-28 |
| CA2330472C (en) | 2007-09-04 |
| AU3666799A (en) | 1999-11-16 |
| JP5351131B2 (ja) | 2013-11-27 |
| US6224793B1 (en) | 2001-05-01 |
| WO1999055454A1 (en) | 1999-11-04 |
| EP1077763B1 (en) | 2004-02-11 |
| ATE259257T1 (de) | 2004-02-15 |
| CN1207090C (zh) | 2005-06-22 |
| DE69914739T2 (de) | 2004-09-30 |
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