ES2195674A1 - Hidroxi aminas impedidas n-alcoxi sustituidas. - Google Patents

Hidroxi aminas impedidas n-alcoxi sustituidas.

Info

Publication number
ES2195674A1
ES2195674A1 ES200000419A ES200000419A ES2195674A1 ES 2195674 A1 ES2195674 A1 ES 2195674A1 ES 200000419 A ES200000419 A ES 200000419A ES 200000419 A ES200000419 A ES 200000419A ES 2195674 A1 ES2195674 A1 ES 2195674A1
Authority
ES
Spain
Prior art keywords
hindered amines
substituted
hydroxy
alkoxy hindered
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200000419A
Other languages
English (en)
Other versions
ES2195674B1 (es
Inventor
James Peter Galbo
Gerald Anthony Capocci
Nancy Nase Cliff
Robert Edward Detlefsen
Michael Peter Difazio
Ramanathan Ravichandran
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Ciba SC Holding AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/257,711 external-priority patent/US6271377B1/en
Priority claimed from US09/315,704 external-priority patent/US6166212A/en
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2195674A1 publication Critical patent/ES2195674A1/es
Application granted granted Critical
Publication of ES2195674B1 publication Critical patent/ES2195674B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/98—Nitrogen atom

Abstract

Hidroxi aminas impedidas n-alcoxi sustituidas. Las aminas impedidas sustituidas en el átomo de N por una fracción -O-E-OH son particularmente efectivas en la estabilización de poliolefina y composiciones de revestimiento de automóviles frente a los efectos perjudiciales de radiación oxidativa, térmica y actínica en donde la presencia del grupo OH sobre los compuestos adiciona propiedades importantes no obtenibles con el empleo de fracciones -O-E normales. Se preparan convenientemente haciendo reaccionar el compuesto N-oxilo correspondiente con un alcohol en presencia de un peróxido o un hidroperóxido orgánico y una cantidad catalítica de una sal metálica o complejo de metal-ligando.
ES200000419A 1999-02-25 2000-02-23 Hidroxi aminas impedidas n-alcoxi sustituidas. Expired - Fee Related ES2195674B1 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US09/257711 1999-02-25
US09/257,711 US6271377B1 (en) 1999-02-25 1999-02-25 Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
US09/315704 1999-05-20
US09/315,704 US6166212A (en) 1999-05-20 1999-05-20 Process for the synthesis of N-(hydroxyalkoxy) substituted hindered amine stabilizers

Publications (2)

Publication Number Publication Date
ES2195674A1 true ES2195674A1 (es) 2003-12-01
ES2195674B1 ES2195674B1 (es) 2005-03-16

Family

ID=26946156

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200000419A Expired - Fee Related ES2195674B1 (es) 1999-02-25 2000-02-23 Hidroxi aminas impedidas n-alcoxi sustituidas.

Country Status (18)

Country Link
JP (1) JP4757977B2 (es)
KR (1) KR100676473B1 (es)
CN (1) CN1230424C (es)
AR (1) AR028816A1 (es)
AU (1) AU773104B2 (es)
BE (1) BE1013530A5 (es)
BR (1) BR0000666B1 (es)
CA (1) CA2299754C (es)
DE (1) DE10008367B4 (es)
ES (1) ES2195674B1 (es)
FR (1) FR2790259B1 (es)
GB (2) GB0003326D0 (es)
IN (1) IN2000CH00150A (es)
IT (1) IT1319167B1 (es)
MX (1) MXPA00001961A (es)
NL (1) NL1014414C2 (es)
RU (1) RU2243216C2 (es)
TW (1) TW491876B (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2377703B (en) * 1998-12-14 2003-06-18 Ciba Sc Holding Ag Sterically hindered amine compounds
US6376584B1 (en) * 1999-02-25 2002-04-23 Ciba Specialty Chemicals Corporation Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
TWI273115B (en) * 2000-12-12 2007-02-11 Ciba Sc Holding Ag Improved weatherability of flame retardant polyolefin
DE10106543A1 (de) 2001-02-13 2002-08-22 Basf Ag Beschichtungsmittelzusammensetzungen
US20030040593A1 (en) * 2001-04-26 2003-02-27 Nobuya Saegusa Vinyl-polymerizable monomer having tertiary hydroxyl group and polymer
JP4562324B2 (ja) * 2001-07-06 2010-10-13 株式会社Ａｄｅｋａ 安定化されたポリウレタン樹脂
ITMI20012081A1 (it) * 2001-10-09 2003-04-09 3V Sigma Spa Composizioni liquide di perossidi stabilizzate
CN1753871A (zh) * 2003-02-26 2006-03-29 西巴特殊化学品控股有限公司 水相容空间位阻烷氧基胺和羟基取代的烷氧基胺
JP4860468B2 (ja) * 2003-07-14 2012-01-25 チバ ホールディング インコーポレーテッド 立体障害ｎ−ヒドロカルビルオキシアミンを製造するための過酸化水素触媒法
US7595011B2 (en) 2004-07-12 2009-09-29 Ciba Specialty Chemicals Corporation Stabilized electrochromic media
US7410936B2 (en) 2004-08-23 2008-08-12 Ciba Specialty Chemicals Corporation Stabilized body care products, household products, textiles and fabrics
US20070072965A1 (en) * 2005-09-23 2007-03-29 Mouhcine Kanouni Color fast polyurethanes
MX2008016304A (es) * 2006-07-05 2009-01-16 Ciba Holding Inc Proceso para la preparacion de nitroxil eteres impedidos estericamente.
ATE449072T1 (de) * 2006-07-05 2009-12-15 Basf Se Verfahren zur herstellung sterisch gehinderter nitroxylether
CN101484422B (zh) * 2006-07-05 2012-07-11 西巴控股有限公司 制备位阻硝酰基醚的方法
US20120145241A1 (en) * 2009-08-18 2012-06-14 Basf Se Photovoltaic module with stabilized polymeric encapsulant
EP2708574A1 (en) * 2012-09-18 2014-03-19 Clariant International Ltd. Oxygen scavenging plastic material
EP3052573A4 (en) * 2013-09-30 2017-03-22 CertainTeed Corporation Stain repellent and voc eliminating coatings and use thereof
EP3110883B1 (en) * 2014-02-28 2018-10-10 ExxonMobil Chemical Patents Inc. Mooney viscosity stable brominated elastomers
SA116370295B1 (ar) 2015-02-20 2016-12-06 باسف اس اى رقائق، وأشرطة وفتائل أحادية من البولي أوليفين مثبتة للضوء
CA2992593A1 (en) * 2015-07-20 2017-01-26 Basf Se Flame-retardant polyolefin systems
CN105085376B (zh) * 2015-09-07 2018-01-05 江苏裕兴薄膜科技股份有限公司 一种含受阻胺基团的二元醇单体及其聚酯共聚物
US10767073B2 (en) 2016-10-18 2020-09-08 Ppg Industries Ohio, Inc. Curable film-forming compositions containing hydroxyl functional, branched acrylic polymers and multilayer composite coatings
KR102201293B1 (ko) * 2019-05-15 2021-01-11 한국신발피혁연구원 웨더 스트립용 우레탄 아크릴레이트계 하이브리드 코팅 조성물
CN112126060B (zh) * 2019-06-25 2022-05-31 北京天罡助剂有限责任公司 一种聚合型高分子空间位阻胺及其制备方法
CN110606986B (zh) * 2019-09-20 2020-05-22 杭州聚丰新材料有限公司 一种硅橡胶交联剂及其制备方法与应用
CN110903237A (zh) * 2019-12-16 2020-03-24 兰州精细化工有限责任公司 一种双(1-辛氧基-2,2,6,6-四甲基-4-哌啶基)癸二酸酯的制备方法
US20230095019A1 (en) 2019-12-27 2023-03-30 Diahachi Chemical Industry Co., Ltd. Flame retardant composition and flame-retardant thermoplastic resin composition containing said flame retardant composit
CN112778990B (zh) * 2021-02-05 2022-06-03 西南石油大学 一种用于油田注水井的污水混配暂堵剂及其制备方法
CN113582914B (zh) * 2021-08-02 2023-11-03 天津利安隆新材料股份有限公司 含羟基的受阻胺光稳定剂的制备方法
KR102497017B1 (ko) * 2021-08-26 2023-02-07 강남제비스코 주식회사 LiDAR 기능 향상을 위한 아크릴폴리올계 서페이서 조성물
CN115746688B (zh) * 2021-12-06 2023-05-23 烟台大学 可粉末化自修复阻燃低voc聚氨酯涂料关键材料及应用
CN114940684B (zh) * 2022-05-24 2023-07-21 浙江大学温州研究院 一种白光发光的卤化铜配合物及其制备方法和应用
CN116082705B (zh) * 2022-12-05 2023-09-12 苏州易昇光学材料股份有限公司 一种抗黄变自修复凝胶

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0845458A1 (en) * 1996-12-02 1998-06-03 Ciba SC Holding AG 1,2-Bis-adducts of stable nitroxides with substituted enthylenes and stabilized compositions
FR2763949A1 (fr) * 1997-05-27 1998-12-04 Ciba Geigy Ag Compose stabilisant, composition le contenant et procede l'utilisant
EP1083186A1 (de) * 1999-09-07 2001-03-14 Bayer Ag Oligomere und polymere Telechelen
EP1188742A1 (en) * 1999-06-23 2002-03-20 Nof Corporation Vinylated alkoxyamine, use thereof, and process for producing the same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU571240B2 (en) * 1983-07-11 1988-04-14 Commonwealth Scientific And Industrial Research Organisation Alkoxy-amines, useful as initiators
EP0155912A3 (de) * 1984-03-20 1986-06-04 Ciba-Geigy Ag Strahlenstabilisierte polymere Zusammensetzungen
EP0365481A1 (en) * 1988-10-19 1990-04-25 Ciba-Geigy Ag Polymeric substrates stabilized with N-substituted hindered amines
TW270131B (es) * 1993-07-13 1996-02-11 Ciba Geigy
JPH0952975A (ja) * 1995-08-18 1997-02-25 Clariant Internatl Ltd 顔料の安定化方法及びこの方法に用いる組成物
US5627248A (en) * 1995-09-26 1997-05-06 The Dow Chemical Company Difunctional living free radical polymerization initiators

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0845458A1 (en) * 1996-12-02 1998-06-03 Ciba SC Holding AG 1,2-Bis-adducts of stable nitroxides with substituted enthylenes and stabilized compositions
FR2763949A1 (fr) * 1997-05-27 1998-12-04 Ciba Geigy Ag Compose stabilisant, composition le contenant et procede l'utilisant
EP1188742A1 (en) * 1999-06-23 2002-03-20 Nof Corporation Vinylated alkoxyamine, use thereof, and process for producing the same
EP1083186A1 (de) * 1999-09-07 2001-03-14 Bayer Ag Oligomere und polymere Telechelen

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
C.J. HAWKER et al. "Radical Crossover in Nitroxide Mediated Living Free Radical Polymerizations", J. Am. Chem. Soc., 1996, Vol. 118, Nö 46, páginas 11467-11471, ver compuesto 6. *
D.J. GRAVERT et al. "Soluble Supports Tailored for Organic Synthesis: Parallel Polymer Synthesis via Sequential Normal/Living Free Radical Processes", J. Am. Chem. Soc., 1998, Vol. 120, Nö 37, páginas 9481-9495, ver esquema 2, compuesto 17. *
S. NIGAM et al. "Electron Transfer and Addition Reactions of Free Nitroxyl Radicals with Radiation Induced Radicals", J. Chem. Soc. Faraday Trans.1, 1976, Vol. 72, Nö 10, páginas 2324-2340, ver tablas 1 y 2. *

Also Published As

Publication number Publication date
AR028816A1 (es) 2003-05-28
BR0000666A (pt) 2001-01-16
RU2243216C2 (ru) 2004-12-27
JP4757977B2 (ja) 2011-08-24
CA2299754A1 (en) 2000-08-25
MXPA00001961A (es) 2002-05-23
IT1319167B1 (it) 2003-09-26
GB0004127D0 (en) 2000-04-12
ES2195674B1 (es) 2005-03-16
FR2790259A1 (fr) 2000-09-01
DE10008367A1 (de) 2000-08-31
NL1014414A1 (nl) 2000-08-28
JP2000302758A (ja) 2000-10-31
KR20010014505A (ko) 2001-02-26
CN1273241A (zh) 2000-11-15
NL1014414C2 (nl) 2001-07-17
TW491876B (en) 2002-06-21
BR0000666B1 (pt) 2011-03-09
CN1230424C (zh) 2005-12-07
AU773104B2 (en) 2004-05-13
AU1945400A (en) 2000-09-14
KR100676473B1 (ko) 2007-02-05
GB2347928B (en) 2001-11-28
DE10008367B4 (de) 2014-08-28
GB0003326D0 (en) 2000-04-05
ITMI20000327A1 (it) 2001-08-23
GB2347928A (en) 2000-09-20
CA2299754C (en) 2010-02-09
ITMI20000327A0 (it) 2000-02-23
FR2790259B1 (fr) 2004-10-01
IN2000CH00150A (es) 2007-04-27
BE1013530A5 (fr) 2002-03-05

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