ES2165381T3 - Proceso para la preparacion de polimeros cicloolefinicos con alta resistencia al desgarro y baja atenuacion optica. - Google Patents

Proceso para la preparacion de polimeros cicloolefinicos con alta resistencia al desgarro y baja atenuacion optica.

Info

Publication number
ES2165381T3
ES2165381T3 ES94906177T ES94906177T ES2165381T3 ES 2165381 T3 ES2165381 T3 ES 2165381T3 ES 94906177 T ES94906177 T ES 94906177T ES 94906177 T ES94906177 T ES 94906177T ES 2165381 T3 ES2165381 T3 ES 2165381T3
Authority
ES
Spain
Prior art keywords
sub
sup
group
rent
different
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94906177T
Other languages
English (en)
Inventor
Michael-Joachim Brekner
Hellmuth Deckers
Frank Osan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ticona GmbH
Original Assignee
Ticona GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ticona GmbH filed Critical Ticona GmbH
Application granted granted Critical
Publication of ES2165381T3 publication Critical patent/ES2165381T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F232/08—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/045—Light guides
    • G02B1/046—Light guides characterised by the core material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCESO PARA LA ELABORACION DE COPOLIMEROS (COC) CICLOOLEFINA CON ALTA TENACIDAD POR MEDIO DE COPOLIMERIZACION DE 0,1 HASTA 99,9 % EN PESO, EN RELACION A LA CANTIDAD TOTAL DE MONOMEROS, DE AL MENOS UN MONOMERO EN DONDE R{SUP.1}, R{SUP.2}, R{SUP.3}, R{SUP.4}, R{SUP.5}, R{SUP.6}, R{SUP.7} Y R{SUP.8} SON IGUALES O DIFERENTES Y REPRESENTAN UN ATOMO DE HIDROGENO O UN RADICAL C{SUB.1} - C{SUB.8} ALQUIL O C{SUB.6} - C{SUB.16} ARIL, DONDE LOS RADICALES IDENTICOS PUEDEN TENER UN SIGNIFICADO DIFERENTE EN VARIAS FORMULAS, 0 HASTA 99,9 % EN PESO EN RELACION A LA CANTIDAD TOTAL DE MONOMEROS, DE UNA CICLOOLEFINA EN DONDE N ES UN NUMERO DESDE 2 HASTA 10, Y 0,1 HASTA 99,9 % EN PESO, EN RELACION A LA CANTIDAD TOTAL DE MONOMEROS, DE AL MENOS UNA 1 - OLEFINA ACICLICA EN DONDE R{SUP.9}, R{SUP.10}, R{SUP.11} Y R{SUP.12} SON IGUALES O DIFERENTES Y SIGNIFICAN UN ATOMO DE HIDROGENO O UN RADICAL C{SUB.1} - C{SUB.8} ALQUIL, O RADICAL C{SUB.6} - C{SUB.16} ARIL, EN SOLUCION, EN SUSPENSION,EN EL MONOMERO CICLOOLEFINA LIQUIDO O MEZCLA DE MONOMERO CICLOOLEFINA O EN FASE GASEOSA A UNA TEMPERATURA DESDE -78 HASTA 150 SENCIA DE UN CATALIZADOR QUE CONSISTE EN UN METALOCENO COMO COMPONENTE DE METAL DE TRANSICION Y UN ALUMINOXANO PARA EL COMPONENTE DE TIPO LINEAL Y/O PARA EL TIPO CICLICO. EN LAS FORMULA (VII) Y (VIII), R{SUP.13} ES UN GRUPO C{SUB.1} - C{SUB.6} ALQUIL O FENIL O BENCIL Y N ES UN NUMERO COMPLETO DESDE 2 HASTA 50. LA POLIMERIZACION SE DIRIGE EN PRESENCIA DE UN CATALIZADOR, DONDE EL COMPONENTE DE METAL DE TRANSICION ES AL MENOS UN COMPUESTO DE LA FORMULA (IX), EN DONDE: M{SUP.1} ES TITANIO, ZIRCONIO, HAFNIO, VANADIO, NIOBIO O TANTALIO; R{SUP.14} Y R{SUP.15} SON IGUALES O DIFERENTES Y SIGNIFICAN UN ATOMO DE HIDROGENO, UN ATOMO DE HALOGENO, UN GRUPO C{SUB.1} - C{SUB.10} ALQUIL, UN GRUPO C{SUB.1} - C{SUB.10} ALCOXI, UN GRUPO C{SUB.6} - C{SUB.10} ARIL, UN GRUPO C{SUB.6} C{SUB.10} ARILOXI, UN GRUPO C{SUB.2} - C{SUB.10} ALQUENIL, UN GRUPO C{SUB.7} - C{SUB.40} ARILALQUIL, UN GRUPO C{SUB.7} C{SUB.40} ALQUILARIL O UN GRUPO C{SUB.8} C{SUB.40} ARILALQUENIL Y M PUEDE SER 1 O 2 DEPENDIENDO DE LA VALENCIA DEL ATOMO M{SUP.1} CENTRAL, R{SUP.18} ES = BR{SUP.19} = AIR{SUP.19}, - GE -, - SN - O -, - S -, = SO, = SO{SUB.2} = NR{SUP.19}, = CO, = PR{SUP.19} O = P(O)R{SUP.19}, DONDE R{SUP.19}, R{SUP.20} Y R{SUP.21} SON IGUALES O DIFERENTES Y SIGNIFICAN UN ATOMO DE HIDROGENO, UN ATOMO DE HALOGENO, UN GRUPO C{SUB.1} - C{SUB.10} ALQUIL, UN GRUPO C{SUB.1} - C{SUB.10} FLUORALQUIL, UN GRUPO C{SUB.6} - C {SUB.10} FLUORARIL, UN GRUPO C{SUB,6} - C{SUB.10} ARIL, UN GRUPO C{SUB.1} - C{SUB.10} ALCOXI, UN GRUPO C{SUB.2} - C {SUB.10} ALQUENIL, UN GRUPO C{SUB.7} - C{SUB.40} ARILALQUIL, UN GRUPO C{SUB.8} C{SUB.40} ARILALQUENIL O UN GRUPO C{SUB.7} -C{SUB.40} ALQUILARIL, O R{SUP.19} Y R{SUP.20} O R{SUP.19} Y R{SUP.21} FORMAN UN ANILLO CON LOS ATOMOS DE ENLACE, DONDE M{SUP.2} ES SILICIO, GERMANIO O ESTAÑO, R{SUP.16} O R{SUP.17} SON IGUALES O DIFERENTES Y SIGNIFICAN UN RADICAL DE HIDROCARBURO MONOO MULTINUCLEAR QUE PUEDE FORMAR UNA ESTRUCTURA SANDWICH CON EL ATOMO CENTRAL M{SUP.1}. EL METALOCENO DE LA FORMULA (IX) MUESTRA SIMETRIA C{SUB.2} SI R{SUP.16} Y R{SUP.17} SON IGUALES Y, SI R{SUP.16} Y R{SUP.17} SON DIFERENTES, UNA SIMETRIA C{SUB.1} EN RELACION A LAS LIGANDURAS R{SUB.16} Y R{SUB.17} Y A LOS ENLACES DEL ATOMO CENTRAL M{SUP.1}.
ES94906177T 1993-02-12 1994-01-31 Proceso para la preparacion de polimeros cicloolefinicos con alta resistencia al desgarro y baja atenuacion optica. Expired - Lifetime ES2165381T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4304285A DE4304285A1 (de) 1993-02-12 1993-02-12 Cycloolefincopolymere mit hoher Reißfestigkeit und niedriger optischer Dämpfung

Publications (1)

Publication Number Publication Date
ES2165381T3 true ES2165381T3 (es) 2002-03-16

Family

ID=6480335

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94906177T Expired - Lifetime ES2165381T3 (es) 1993-02-12 1994-01-31 Proceso para la preparacion de polimeros cicloolefinicos con alta resistencia al desgarro y baja atenuacion optica.

Country Status (11)

Country Link
EP (1) EP0683798B1 (es)
JP (1) JP3361809B2 (es)
KR (1) KR960701110A (es)
CN (1) CN1117738A (es)
AU (2) AU6000094A (es)
BR (1) BR9405833A (es)
CA (1) CA2155937C (es)
DE (2) DE4304285A1 (es)
ES (1) ES2165381T3 (es)
MX (1) MX9401123A (es)
WO (1) WO1994018252A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4304291A1 (de) * 1993-02-12 1994-08-18 Hoechst Ag Cycloolefincopolymere mit niedriger Schmelzeviskosität und niedriger optischer Dämpfung
FI105196B (fi) * 1995-05-08 2000-06-30 Optatech Oy Amorfiset olefiini-ko/terpolymeerit
DE19522106A1 (de) * 1995-06-19 1997-01-02 Hoechst Ag Verfahren zur Herstellung von Cycloolefincopolymeren
DE19633641A1 (de) * 1996-08-21 1998-02-26 Hoechst Ag Elastomere Cycloolefincopolymere
WO2013153901A1 (ja) * 2012-04-11 2013-10-17 ポリプラスチックス株式会社 三元共重合体及びそれを用いた成形体
CN106832119B (zh) * 2017-02-17 2019-03-29 宁波工程学院 降冰片烯类、四氟乙烯和全氟甲基乙烯基醚三元共聚催化剂以及三元共聚方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
TW227005B (es) * 1990-11-14 1994-07-21 Hoechst Ag
DE4104392A1 (de) * 1991-02-14 1992-08-20 Hoechst Ag Polymere optische fasern auf der basis von fluor- und fluoralkylsubstituierten poly(norbornen)- und poly(norbornadien)-derivaten und verfahren zu deren herstellung
ATE223440T1 (de) * 1991-03-09 2002-09-15 Basell Polyolefine Gmbh Metallocen und katalysator

Also Published As

Publication number Publication date
EP0683798B1 (de) 2001-10-10
DE4304285A1 (de) 1994-08-18
KR960701110A (ko) 1996-02-24
WO1994018252A1 (de) 1994-08-18
MX9401123A (es) 1994-08-31
AU7749198A (en) 1998-10-01
CA2155937C (en) 2007-06-19
JPH08507801A (ja) 1996-08-20
CN1117738A (zh) 1996-02-28
AU6000094A (en) 1994-08-29
DE59409905D1 (de) 2001-11-15
EP0683798A1 (de) 1995-11-29
JP3361809B2 (ja) 2003-01-07
BR9405833A (pt) 1995-12-26
CA2155937A1 (en) 1994-08-18

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