ES2088046T3 - Polimeros y copolimeros de dieno unidos por acoplamiento parcial y terminados con imina sustituida. - Google Patents
Polimeros y copolimeros de dieno unidos por acoplamiento parcial y terminados con imina sustituida.Info
- Publication number
- ES2088046T3 ES2088046T3 ES92105789T ES92105789T ES2088046T3 ES 2088046 T3 ES2088046 T3 ES 2088046T3 ES 92105789 T ES92105789 T ES 92105789T ES 92105789 T ES92105789 T ES 92105789T ES 2088046 T3 ES2088046 T3 ES 2088046T3
- Authority
- ES
- Spain
- Prior art keywords
- copolymer
- polymers
- copolymers
- compounds
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Abstract
SE PRESENTAN COMPUESTOS DE POLIMEROS O COPOLIMEROS DE DIENO QUE TIENEN UNA HISTERESIS REDUCIDA. LOS COMPUESTOS COMPRENDEN UNA MEZCLA DE POLIMERO O COPOLIMERO DE DIENO QUE CONTIENEN ENLACES DE CARBONO CADENAS DEL COPOLIMERO Y EN LAS CADENAS DE LOS POLIMEROS O COPOLIMEROS QUE CONTIENEN LOS TERMINALES QUE SE DERIVAN DE LOS IMINOS SUBSTITUIDOS QUE TIENEN LA FORMULA: EN LA QUE R1 Y R2 ESTAN SELECCIONADAS ENTRE EL GRUPO QUE CONSTA DE H, ALQUIL, CICLOALQUIL, ARIL, DIALQUILAMINOARIL, ARALQUIL, Y GRUPOS APROTICOS CON CONTENIDOS DE O, N Y S ALQUIL; R3 ESTA SELECCIONADA ENTRE EL GRUPO QUE CONSTA DE ALQUIL, CICLOALQUIL, ARIL, DIALQUILAMINOARIL, ARALQUIL Y GRUPOS APROTICOS CON CONTENIDO DE O, N Y S IL Y ARALQUIL; CON LA CONDICION DE QUE AL MENOS UNA DE R1, R2 Y R3 DEBE SER UN GRUPO DE DIALQUILAMINOARIL Y QUE R1, R2 Y R3 NO PUEDEN SER TODAS GRUPOS DE ARIL. LOS COMPUESTOS DE POLIMERO O COPOLIMERO DE DIENO SE PREPARAN MEDIANTE EL ACOPLAMIENTO DE UNA PARTE DE LAS CADENAS DEL POLIMERO O COPOLIMERO DE DIENO ACTIVAS OBTENIDAS MEDIANTE POLIMERIZACION ANIONICA USANDO UN AGENTE DE ACOPLAMIENTO DE POLIALURO DE ESTAÑO Y LA POSTERIOR TERMINACION DE LAS CADENAS DEL POLIMERO O COPOLIMERO DE DIENO RESTANTES USANDO LOS IMINOS SUBSTITUIDOS. LOS COMPUESTOS DE POLIMERO O COPOLIMERO DE DIENO RESULTANTES PRESENTAN PROPIEDADES DE HISTERESIS REDUCIDA Y MEJORAN SU PROCESABILIDAD Y PUEDEN UTILIZARSE PARA FORMAR COMPUESTOS ELASTOMEROS Y NEUMATICOS PARA RUEDAS QUE TIENEN UNA RESISTENCIA AL RODAMIENTO REDUCIDA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/684,106 US5227431A (en) | 1991-04-12 | 1991-04-12 | Diene polymers and copolymers jumped by partial crosslinking and terminated with a substituted imine |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2088046T3 true ES2088046T3 (es) | 1996-08-01 |
Family
ID=24746700
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES92105789T Expired - Lifetime ES2088046T3 (es) | 1991-04-12 | 1992-04-03 | Polimeros y copolimeros de dieno unidos por acoplamiento parcial y terminados con imina sustituida. |
Country Status (9)
Country | Link |
---|---|
US (1) | US5227431A (es) |
EP (1) | EP0510410B1 (es) |
JP (1) | JP3075832B2 (es) |
KR (1) | KR100202505B1 (es) |
BR (1) | BR9201356A (es) |
CA (1) | CA2065819C (es) |
DE (1) | DE69211413T2 (es) |
ES (1) | ES2088046T3 (es) |
MX (1) | MX9201727A (es) |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0634420A1 (en) * | 1993-07-12 | 1995-01-18 | Shell Internationale Researchmaatschappij B.V. | Star polymers |
US5310798A (en) | 1993-08-16 | 1994-05-10 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated with compounds having multiple-bonded nitrogen atoms and partially crosslinked with polyfunctional reagents |
ES2116199B1 (es) * | 1995-07-17 | 1999-04-01 | Repsol Quimica Sa | Procedimiento de preparacion de copolimeros de 1,3 butadieno y estireno utiles para la fabricacion de neumaticos con baja resistencia a la rodadura y copolimeros de 1,3-butadieno y estireno asi obtenidos, |
IT1283581B1 (it) * | 1996-04-10 | 1998-04-22 | Pirelli | Mescola di gomma vulcanizzabile, in particolare per fasce battistrada a bassa resistenza di rotolamento per pneumatici di veicoli |
US6252007B1 (en) | 1997-07-11 | 2001-06-26 | Bridgestone Corporation | Elastomers having a reduced hysteresis via interaction of polymer with silica surfaces |
US6008295A (en) * | 1997-07-11 | 1999-12-28 | Bridgestone Corporation | Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds |
US6221943B1 (en) | 1997-07-11 | 2001-04-24 | Bridgestone Corporation | Processability of silica-filled rubber stocks |
US6228908B1 (en) | 1997-07-11 | 2001-05-08 | Bridgestone Corporation | Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds |
US6369138B2 (en) | 1997-07-11 | 2002-04-09 | Bridgestone Corporation | Processability of silica-filled rubber stocks with reduced hysteresis |
US5872176A (en) | 1997-07-11 | 1999-02-16 | Bridgestone Corporation | Addition of salts to improve the interaction of silica with rubber |
US6384117B1 (en) | 1997-07-11 | 2002-05-07 | Bridgestone Corporation | Processability of silica-filled rubber stocks |
US6525118B2 (en) | 1997-07-11 | 2003-02-25 | Bridgestone Corporation | Processability of silica-filled rubber stocks with reduced hysteresis |
DE19804912A1 (de) | 1998-02-07 | 1999-08-12 | Basf Ag | Kontinuierliches Verfahren zur Herstellung thermoplastischer Formmassen |
US7056979B1 (en) * | 1998-06-12 | 2006-06-06 | Bridgestone Corporation | Reaction product derived from amine-functionalized elastomers and maleated polyolefins |
KR100290438B1 (ko) | 1998-12-19 | 2001-10-26 | 박찬구 | 양쪽말단변성랜덤공중합체의제조방법 |
WO2001034658A1 (en) * | 1999-11-12 | 2001-05-17 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
US6977281B1 (en) | 1999-11-12 | 2005-12-20 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
DE10014664A1 (de) | 2000-03-24 | 2001-09-27 | Sued Chemie Ag | Mit Schwefel vernetzbare Kautschukmischung sowie Verfahren zu Ihrer Herstellung und daraus erhältliche vernetzte Kautschukmischungen und Formkörper |
DE60114039T2 (de) * | 2000-08-18 | 2006-07-06 | Bridgestone Corp. | Kautschukzusammensetzungen und vulkanisate einschliesslich verzweigter kammpolymere |
ES2412979T3 (es) * | 2000-11-10 | 2013-07-15 | Bridgestone Corporation | Cis-1,4-polibutadieno altamente funcionalizado preparado usando nuevos agentes de funcionalización |
DE60316445T2 (de) * | 2002-08-30 | 2008-06-26 | Bridgestone Corp. | Funktionalisiertes polymer und verbesserte vulkanisate daraus |
US8030406B2 (en) | 2005-03-04 | 2011-10-04 | Bridgestone Corporation | Rubber composition and pneumatic tire using the same |
US7879952B2 (en) * | 2005-12-28 | 2011-02-01 | Bridgestone Corporation | Functionalized polymers |
US7671138B2 (en) * | 2006-05-26 | 2010-03-02 | Bridgestone Corporation | Polymers functionized with hydrobenzamides |
US20080006833A1 (en) * | 2006-06-02 | 2008-01-10 | Semiconductor Energy Laboratory Co., Ltd. | Lighting device and liquid crystal display device |
JP2007323544A (ja) * | 2006-06-05 | 2007-12-13 | Sony Corp | 情報処理システム、情報処理装置、および方法、並びにコンピュータ・プログラム |
US7875671B2 (en) | 2006-08-03 | 2011-01-25 | Bridgestone Corporation | Process for preparing filler-dispersed polymeric compositions |
US7732534B2 (en) * | 2006-08-28 | 2010-06-08 | Bridgestone Corporation | Polymers functionalized with nitro compounds |
US8088868B2 (en) | 2006-12-19 | 2012-01-03 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds |
US8063165B2 (en) | 2007-06-18 | 2011-11-22 | Bridgestone Corporation | Functional polymers prepared with sulfur-containing initiators |
US7879958B2 (en) | 2007-08-07 | 2011-02-01 | Bridgestone Corporation | Polyhydroxy compounds as polymerization quenching agents |
US8314189B2 (en) * | 2007-10-12 | 2012-11-20 | Bridgestone Corporation | Polymers functionalized with heterocyclic nitrile compounds |
ES2429447T3 (es) * | 2007-12-28 | 2013-11-14 | Bridgestone Corporation | Polímero funcionalizado y métodos para su preparación y uso |
RU2515980C2 (ru) * | 2007-12-31 | 2014-05-20 | Бриджстоун Корпорейшн | Способ получения полидиенов полимеризацией в объеме |
US8268933B2 (en) * | 2007-12-31 | 2012-09-18 | Bridgestone Corporation | Polymers functionalized with polyimine compounds |
US7906592B2 (en) * | 2008-07-03 | 2011-03-15 | Bridgestone Corporation | Polymers functionalized with imide compounds containing a protected amino group |
US8188195B2 (en) * | 2008-12-31 | 2012-05-29 | Bridgestone Corporation | Polymers functionalized with nitroso compounds |
ES2465070T3 (es) | 2009-01-23 | 2014-06-05 | Bridgestone Corporation | Polímeros funcionalizados con compuestos de nitrilo que contienen un grupo amino protegido |
US8785566B2 (en) | 2009-01-23 | 2014-07-22 | Bridgestone Corporation | Polymers functionalized with polycyano compounds |
RU2535208C2 (ru) | 2009-06-30 | 2014-12-10 | Бриджстоун Корпорейшн | Полимеры с гидроксиарильными функциональными группами |
US20110077325A1 (en) | 2009-09-30 | 2011-03-31 | Bridgestone Corporation | Functionalized polymers and methods for their manufacture |
US8338544B2 (en) * | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
ES2477228T3 (es) | 2009-12-22 | 2014-07-16 | Bridgestone Corporation | Composición mejorada de un modificador vin�lico y procedimientos para utilizarla |
WO2011082098A1 (en) | 2009-12-30 | 2011-07-07 | The Rockefeller University | Lysine and arginine methyltransferase inhibitors for treating cancer |
TW201211083A (en) | 2010-06-15 | 2012-03-16 | Styron Europe Gmbh | Low vinyl styrene-butadiene polymers and methods of making the same |
US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
EP2658727B1 (en) | 2010-12-30 | 2014-12-03 | Bridgestone Corporation | Aminosilane initiators and functionalized polymers prepared therefrom |
EP2537872B1 (en) | 2011-06-22 | 2015-08-12 | Trinseo Europe GmbH | High styrene high vinyl styrene-butadiene rubber with narrow molecular weight distribution and methods for preparation thereof |
ES2598035T3 (es) | 2011-03-04 | 2017-01-24 | Trinseo Europe Gmbh | Caucho de estireno-butadieno de alto contenido de estireno y alto contenido de vinilo y métodos para la preparación del mismo |
EP2495266A1 (en) | 2011-03-04 | 2012-09-05 | Styron Deutschland GmbH | High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof |
HUE040405T2 (hu) | 2011-06-22 | 2019-03-28 | Trinseo Europe Gmbh | Nagy sztirol- és nagy viniltartalmú sztirol-butadién gumi, szûk molekultömeg-eloszlással, valamint ezek elõállítási módszerei |
US8962766B2 (en) | 2011-09-15 | 2015-02-24 | Bridgestone Corporation | Polymers functionalized with polyhydrazone compounds |
TWI585115B (zh) | 2011-12-15 | 2017-06-01 | 普利司通股份有限公司 | 經穩定之多價陰離子聚合反應引發劑及其製備方法 |
EP2844678B1 (en) | 2012-05-01 | 2017-02-22 | Bridgestone Corporation | Polydienes and diene copolymers having organophosphine functionality |
WO2015089356A2 (en) | 2013-12-12 | 2015-06-18 | Firestone Polymers, Llc | Method for producing polymeric compositions including functionalized polymers |
CN105985487B (zh) * | 2015-01-29 | 2018-03-13 | 中国石油天然气股份有限公司 | 一种双端官能化丁二烯‑异戊二烯共聚橡胶及其制备方法 |
US10519266B2 (en) | 2015-09-23 | 2019-12-31 | Bridgestone Corporation | Polydienes and diene copolymers using 1,1-bis(hydrocarbylthio)hydrocarbyl-1-ene compounds |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3178398A (en) * | 1960-10-24 | 1965-04-13 | Phillips Petroleum Co | Production and curing of polymers containing terminally reactive nitrogen |
NL86588C (es) * | 1980-09-20 | |||
JPS5773030A (en) * | 1980-09-20 | 1982-05-07 | Bridgestone Corp | Rubber composition for tire |
JPS59140240A (ja) * | 1983-01-31 | 1984-08-11 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
US4616069A (en) * | 1984-10-26 | 1986-10-07 | Nippon Zeon Co., Ltd. | Process for making diene polymer rubbers |
JPS61225202A (ja) * | 1985-03-29 | 1986-10-07 | Nippon Zeon Co Ltd | ゴムの変性方法 |
DE3772476D1 (de) * | 1986-01-10 | 1991-10-02 | Asahi Chemical Ind | Kautschukartige polymere fuer reifenlaufflaechen, ein verfahren zu deren herstellung, und zusammensetzungen, die diese polymere enthalten. |
JPS63118343A (ja) * | 1986-11-07 | 1988-05-23 | Japan Synthetic Rubber Co Ltd | 共役ジエン系ゴム組成物 |
DE3639569A1 (de) * | 1986-11-20 | 1988-06-01 | Basf Ag | Am kettenende funktionalisierte polymere und verfahren zu ihrer herstellung |
US4845165A (en) * | 1987-03-13 | 1989-07-04 | The Goodyear Tire & Rubber Company | Anionic diene polymerization process with branching |
JPS63297438A (ja) * | 1987-05-28 | 1988-12-05 | Toyo Tire & Rubber Co Ltd | タイヤトレッド用ゴム組成物 |
US4935471A (en) * | 1987-10-15 | 1990-06-19 | The Goodyear Tire & Rubber Company | Capped polydienes |
US5109907A (en) * | 1990-04-09 | 1992-05-05 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines |
-
1991
- 1991-04-12 US US07/684,106 patent/US5227431A/en not_active Expired - Lifetime
-
1992
- 1992-04-03 DE DE69211413T patent/DE69211413T2/de not_active Expired - Fee Related
- 1992-04-03 ES ES92105789T patent/ES2088046T3/es not_active Expired - Lifetime
- 1992-04-03 EP EP92105789A patent/EP0510410B1/en not_active Expired - Lifetime
- 1992-04-10 JP JP04116748A patent/JP3075832B2/ja not_active Expired - Lifetime
- 1992-04-10 CA CA002065819A patent/CA2065819C/en not_active Expired - Fee Related
- 1992-04-13 MX MX9201727A patent/MX9201727A/es unknown
- 1992-04-13 BR BR929201356A patent/BR9201356A/pt not_active IP Right Cessation
- 1992-04-13 KR KR1019920006115A patent/KR100202505B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
BR9201356A (pt) | 1992-12-01 |
CA2065819A1 (en) | 1992-10-13 |
US5227431A (en) | 1993-07-13 |
EP0510410B1 (en) | 1996-06-12 |
JPH05148315A (ja) | 1993-06-15 |
KR100202505B1 (ko) | 1999-06-15 |
CA2065819C (en) | 1999-11-30 |
JP3075832B2 (ja) | 2000-08-14 |
MX9201727A (es) | 1992-10-01 |
DE69211413D1 (de) | 1996-07-18 |
KR920019824A (ko) | 1992-11-20 |
DE69211413T2 (de) | 1996-11-14 |
EP0510410A1 (en) | 1992-10-28 |
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