ES2107207T3 - Procedimiento para la preparacion de una composicion de copolimeros de bloques. - Google Patents
Procedimiento para la preparacion de una composicion de copolimeros de bloques.Info
- Publication number
- ES2107207T3 ES2107207T3 ES94913079T ES94913079T ES2107207T3 ES 2107207 T3 ES2107207 T3 ES 2107207T3 ES 94913079 T ES94913079 T ES 94913079T ES 94913079 T ES94913079 T ES 94913079T ES 2107207 T3 ES2107207 T3 ES 2107207T3
- Authority
- ES
- Spain
- Prior art keywords
- monomer
- blocks
- polymer
- block
- derived
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
SE PRESENTA UN PROCESO PARA LA PREPARACION DE COMPOSICIONES DE POLIMEROS EN BLOQUE, CUYO PROCESO CONSISTE EN LOS PASOS SIGUIENTES: (1) SE POLIMERIZA UN MONOMERO AROMATICO DE VINILO EN UN SOLVENTE HIDROCARBURO INERTE EN PRESENCIA DE UN INICIADOR DE ORGANOLITIO HASTA QUE TENGA LUGAR UNA CONVERSION SUSTANCIALMENTE COMPLETA; (2) SE AÑADE UN MONOMERO DE DIENO CONJUGADO A LA MEZCLA DE POLIMERIZACION Y SE DEJA QUE DICHO MONOMERO DE DIENO CONJUGADO SE POLIMERICE HASTA QUE TENGA LUGAR UNA CONVERSION SUSTANCIALMENTE COMPLETA; (3) SE AÑADE UNA SEGUNDA PORCION DE UN INICIADOR DE ORGANOLITIO, SEGUIDO DE LA ADICION DE UNA SEGUNDA PORCION DE MONOMERO DE DIENO CONJUGADO Y SE DEJA QUE DICHO MONOMERO DE DIENO CONJUGADO SE POLIMERICE HASTA QUE SE PRODUZCA UNA CONVERSION SUSTANCIALMENTE COMPLETA; (4) SE AÑADE UNA SEGUNDA PORCION DE MONOMERO AROMATICO DE VINILO Y SE DEJA QUE DICHO MONOMERO AROMATICO DE VINILO SE POLIMERICE HASTA QUE SE PRODUZCA UNA CONVERSION SUSTANCIALMENTE COMPLETA; (5) SE AÑADE UN AGENTE FINALIZADOR. ADEMAS, SE PRESENTA UNA COMPOSICION DE POLIMERO EN BLOQUE QUE CONTIENE: (I) UN COPOLIMERO EN TRES BLOQUES A-B--B''-A'' QUE TIENE DOS BLOQUES FINALES POLIMERICOS IGUALES O DIFERENTES A Y A'' DERIVADOS DE UN MONOMERO AROMATICO DE VINILO Y UN BLOQUE INTERMEDIO POLIMERICO B-B'' DERIVADO DEL MONOMERO DE DIENO CONJUGADO Y (II) UN POLIMERO EN DOS BLOQUES B''-A'' QUE TIENE UN BLOQUE POLIMERICO B'' DERIVADO DEL MONOMERO DE DIENO CONJUGADO Y UN BLOQUE POLIMERICO A'' DERIVADO DEL MONOMERO AROMATICO DE VINILO, EN DONDE LA RELACION EN PESO MOLAR A'' (TRES BLOQUES)/A'' (DOS BLOQUES) ES DE 0,9 A 1,1, EN DONDE LOS DOS POLIMEROS EN BLOQUE SE OBTIENEN MEDIANTE UNA POLIMERIZACION SECUENCIAL Y EN DONDE EL POLIMERO EN TRES BLOQUES ASI COMO EL POLIMERO EN DOS BLOQUES TIENEN UN CONTENIDO AROMATICO DE VINILO DEL 55% EN PESO O INFERIOR EN BASE AL PESO TOTAL DEL POLIMERO EN TRES BLOQUES Y DEL COPOLIMERO EN DOS BLOQUES, RESPECTIVAMENTE.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93200909 | 1993-03-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2107207T3 true ES2107207T3 (es) | 1997-11-16 |
Family
ID=8213730
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94913079T Expired - Lifetime ES2107207T3 (es) | 1993-03-30 | 1994-03-28 | Procedimiento para la preparacion de una composicion de copolimeros de bloques. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5405903A (es) |
EP (1) | EP0691991B1 (es) |
JP (1) | JP3258664B2 (es) |
KR (1) | KR100312401B1 (es) |
CN (1) | CN1068344C (es) |
BR (1) | BR9405911A (es) |
DE (1) | DE69405983T2 (es) |
ES (1) | ES2107207T3 (es) |
RU (1) | RU2111220C1 (es) |
TW (1) | TW302374B (es) |
WO (1) | WO1994022931A1 (es) |
Families Citing this family (77)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW283152B (es) * | 1993-11-18 | 1996-08-11 | Shell Internat Res Schappej Bv | |
MX9505304A (es) * | 1994-12-23 | 1997-01-31 | Shell Int Research | Proceso para la fabricacion de copolimeros de bloque, radiales, asimetricos, de varios brazos. |
EP0718330B1 (en) * | 1994-12-23 | 2000-05-31 | Shell Internationale Researchmaatschappij B.V. | Process for manufacturing multiarmed asymmetrical radial block copolymers |
TW370534B (en) * | 1995-01-24 | 1999-09-21 | Shell Internattonale Res Mij B V | Process for manufacturing isoprene containing block copolymers |
USH1622H (en) * | 1995-05-30 | 1996-12-03 | Shell Oil Company | Hydrogenated diblock copolymers for adhesives and sealants with improved resistance to degradation |
WO1997039076A1 (en) * | 1996-04-16 | 1997-10-23 | Shell Internationale Research Maatschappij B.V. | Styrene-isoprene-styrene tri block copolymers with adapted diblock copolymers |
KR100241052B1 (ko) * | 1997-08-27 | 2000-02-01 | 박찬구 | 블록 공중합체의 제조방법 |
CN1062276C (zh) * | 1997-12-09 | 2001-02-21 | 北京燕山石油化工公司研究院 | 共轭二烯和单乙烯基芳烃二嵌段共聚物及其合成方法 |
CN1138830C (zh) | 1998-06-29 | 2004-02-18 | 国际壳牌研究有限公司 | 光固化聚合物组合物和含有该组合物的苯胺印板 |
ES2228167T3 (es) * | 1998-09-01 | 2005-04-01 | Kraton Polymers Research B.V. | Compuesto polimerico, uso de ese compuesto en un proceso de produccion de espuma, proceso de espumado, compuestos espumados y articulos que contienen compuestos espumados. |
BR0112058A (pt) * | 2000-06-30 | 2003-12-30 | Kraton Polymers Res Bv | Copolìmero em bloco, e, composto |
US6949593B2 (en) | 2000-09-28 | 2005-09-27 | Kraton Polymers U.S. Llc | Bituminous composition with improved ‘walk-on-ability’ and its use in roofing applications |
US6359075B1 (en) * | 2001-01-09 | 2002-03-19 | Bridgestone/Firestone, Inc. | Means of producing high diblock content thermoplastic elastomers via chain transfer |
US6417270B1 (en) * | 2001-01-09 | 2002-07-09 | Firestone Polymers, Llc | Means of producing high diblock content thermoplastic elastomers with functional termination |
US6956084B2 (en) * | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
JP3941551B2 (ja) * | 2002-03-11 | 2007-07-04 | 日本ゼオン株式会社 | 粘着剤用エラストマー組成物の製造方法 |
JP4333581B2 (ja) * | 2002-07-31 | 2009-09-16 | 日本ゼオン株式会社 | 熱可塑性エラストマー成形体 |
KR20040032488A (ko) * | 2002-10-10 | 2004-04-17 | 금호석유화학 주식회사 | 3원 블록 공중합체 및 제조방법 |
JP4683928B2 (ja) * | 2002-12-18 | 2011-05-18 | 株式会社ブリヂストン | クレイの剥離方法、該方法から得られた組成物、及び該組成物を含む変性ゴム |
EP1431349A1 (en) * | 2002-12-20 | 2004-06-23 | KRATON Polymers Research B.V. | Bituminous compositions |
US6875818B2 (en) | 2003-01-16 | 2005-04-05 | Bridgestone Corporation | Polymer nano-strings |
JP4069389B2 (ja) * | 2003-03-07 | 2008-04-02 | ジェイエスアール クレイトン エラストマー株式会社 | アスファルト改質用ブロック共重合体組成物、その製造方法、およびアスファルト組成物 |
US7517932B2 (en) * | 2003-03-24 | 2009-04-14 | Kraton Polymers U.S. Llc | Poly(styrene-butadiene-styrene)polymers having a high vinyl content in the butadiene block and hot melt adhesive composition comprising said polymers |
US7205370B2 (en) * | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
US7112369B2 (en) * | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
US8063142B2 (en) | 2004-03-02 | 2011-11-22 | Bridgestone Corporation | Method of making nano-particles of selected size distribution |
US7718737B2 (en) * | 2004-03-02 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing functionalized polymer nanoparticles |
US20050215693A1 (en) * | 2004-03-29 | 2005-09-29 | Xiaorong Wang | Clay modified rubber composition and a method for manufacturing same |
US20050228074A1 (en) * | 2004-04-05 | 2005-10-13 | Bridgestone Corporation | Amphiphilic polymer micelles and use thereof |
US20050282956A1 (en) * | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
US7998554B2 (en) * | 2004-07-06 | 2011-08-16 | Bridgestone Corporation | Hydrophobic surfaces with nanoparticles |
CN100503697C (zh) | 2004-09-03 | 2009-06-24 | 克雷顿聚合物研究公司 | 可发泡聚合组合物和包含发泡组合物的物体 |
DE102004059783A1 (de) * | 2004-12-10 | 2006-06-14 | Basf Ag | Transparente Mischungen linearer Styrol-Butadien-Blockcopolymerer |
EP1674530A1 (en) | 2004-12-24 | 2006-06-28 | Kraton Polymers Research B.V. | High melt strength thermoplastic elastomer composition |
US7572855B2 (en) | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
US7579398B2 (en) * | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
US7659342B2 (en) * | 2005-02-03 | 2010-02-09 | Bridgestone Corporation | Polymer nano-particle with polar core and method for manufacturing same |
US20060205904A1 (en) * | 2005-03-11 | 2006-09-14 | St Clair David J | Oil gels of controlled distribution block copolymers and ester oils |
US7645507B2 (en) | 2005-10-24 | 2010-01-12 | Kraton Polymers U.S. Llc | Protective films and pressure sensitive adhesives |
CN101374906B (zh) | 2005-11-14 | 2015-04-22 | 克拉通聚合物研究有限公司 | 制备沥青质粘合剂组合物的方法 |
US7538159B2 (en) | 2005-12-16 | 2009-05-26 | Bridgestone Corporation | Nanoparticles with controlled architecture and method thereof |
US9061900B2 (en) * | 2005-12-16 | 2015-06-23 | Bridgestone Corporation | Combined use of liquid polymer and polymeric nanoparticles for rubber applications |
US7884160B2 (en) | 2005-12-19 | 2011-02-08 | Bridgestone Corporation | Non-spherical nanoparticles made from living triblock polymer chains |
US8288473B2 (en) | 2005-12-19 | 2012-10-16 | Bridgestone Corporation | Disk-like nanoparticles |
US8697775B2 (en) * | 2005-12-20 | 2014-04-15 | Bridgestone Corporation | Vulcanizable nanoparticles having a core with a high glass transition temperature |
US7560510B2 (en) | 2005-12-20 | 2009-07-14 | Bridgestone Corporation | Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties |
US7601772B2 (en) * | 2005-12-20 | 2009-10-13 | Bridgestone Corporation | Nano-composite and method thereof |
US8877250B2 (en) | 2005-12-20 | 2014-11-04 | Bridgestone Corporation | Hollow nano-particles and method thereof |
US7935184B2 (en) | 2006-06-19 | 2011-05-03 | Bridgestone Corporation | Method of preparing imidazolium surfactants |
EP2046575A4 (en) | 2006-07-28 | 2010-01-13 | Bridgestone Corp | POLYMERS CORE SHELL NANOPARTICLES WITH AN INTERPHASE AREA |
RU2459845C2 (ru) | 2006-11-13 | 2012-08-27 | КРЭЙТОН ПОЛИМЕРС ЮЭс ЭлЭлСи | Битумные эмульсии |
US7597959B2 (en) * | 2006-12-19 | 2009-10-06 | Bridgestone Corporation | Core-shell fluorescent nanoparticles |
US7649049B2 (en) * | 2006-12-20 | 2010-01-19 | Bridgestone Corporation | Rubber composition containing a polymer nanoparticle |
CN101675114B (zh) | 2007-05-01 | 2012-09-26 | 科腾聚合物美国有限责任公司 | 沥青粘合剂组合物及其制备方法 |
US7829624B2 (en) * | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
US20090062457A1 (en) * | 2007-09-04 | 2009-03-05 | Kraton Polymers U.S. Llc | Styrenic block copolymers and compositions containing the same |
US7704676B2 (en) | 2007-09-04 | 2010-04-27 | Kraton Polymers U.S. Llc | Block copolymers having distinct isoprene and butadiene midblocks, method for making same, and uses for such block copolymers |
EP2283080B1 (en) | 2008-04-17 | 2017-03-01 | Kraton Polymers U.S. LLC | A block copolymer and polymer modified bituminous binder compositon for use in base course asphalt paving application |
HUE027362T2 (en) * | 2008-04-30 | 2016-09-28 | Trinseo Europe Gmbh | Styrene-grade styrene-butadiene polymers and their preparation method |
ES2527600T3 (es) | 2008-12-31 | 2015-01-27 | Bridgestone Corporation | Procedimiento de formación de nanopartículas formando primero el núcleo, nanopartícula y composición |
US9062144B2 (en) * | 2009-04-03 | 2015-06-23 | Bridgestone Corporation | Hairy polymeric nanoparticles with first and second shell block polymer arms |
US20110172364A1 (en) * | 2009-12-29 | 2011-07-14 | Chen Yaohong | Charged Nanoparticles And Method Of Controlling Charge |
US9115222B2 (en) * | 2009-12-29 | 2015-08-25 | Bridgestone Corporation | Well defined, highly crosslinked nanoparticles and method for making same |
CN102453304B (zh) * | 2010-10-28 | 2013-07-03 | 中国石油化工股份有限公司 | 单乙烯基芳烃和共轭二烯烃嵌段共聚物组合物、其制备方法及其应用 |
US9182560B2 (en) | 2011-02-18 | 2015-11-10 | Kraton Polymers U.S. Llc | Curable polymeric compositions for cable filling |
HUE031642T2 (en) * | 2011-03-04 | 2017-07-28 | Trinseo Europe Gmbh | Styrene-butadiene rubber with high styrene and high vinyl content and methods for its production |
US9428604B1 (en) | 2011-12-30 | 2016-08-30 | Bridgestone Corporation | Nanoparticle fillers and methods of mixing into elastomers |
CN104558411B (zh) * | 2013-10-17 | 2017-03-22 | 中国石油化工股份有限公司 | 一种共轭二烯烃‑单乙烯基芳烃共聚物及其制备方法 |
CN108076641B (zh) * | 2015-03-12 | 2021-05-25 | 英力士苯领集团股份公司 | 管道用苯乙烯-丁二烯嵌段共聚物 |
WO2016149375A1 (en) | 2015-03-16 | 2016-09-22 | H.B. Fuller Company | Low application temperature hot melt adhesive composition |
FR3041355B1 (fr) | 2015-09-18 | 2017-09-01 | Total Marketing Services | Composition bitume / polymere presentant des proprietes mecaniques ameliorees |
US9790360B2 (en) | 2015-12-30 | 2017-10-17 | Kraton Polymers U.S. Llc | Oil gel for asphalt modification and rejuvenation |
US10793720B2 (en) | 2017-03-20 | 2020-10-06 | Kraton Polymers U.S. Llc | Reclaimed asphalt composition and methods of making and using same |
EP3434697B1 (en) | 2017-07-27 | 2021-09-01 | Trinseo Europe GmbH | In-situ polymer blend for a tire |
KR102507153B1 (ko) * | 2019-10-08 | 2023-03-07 | 주식회사 엘지화학 | 핫 멜트 점착제 조성물 및 이의 제조방법 |
RU2756588C2 (ru) * | 2020-02-26 | 2021-10-01 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" | Способ получения термоэластопластов |
WO2023006474A1 (en) | 2021-07-26 | 2023-02-02 | Basf Coatings Gmbh | Peelable coating system and methods for forming the peelable coating system |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4096203A (en) * | 1976-07-30 | 1978-06-20 | Shell Oil Company | Process to control cohesive strength of block copolymer composition |
DE2940861A1 (de) * | 1979-10-09 | 1981-04-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen linearer dreiblockcopolymerisate sowie formteile aus diesen |
US4391949A (en) * | 1981-11-12 | 1983-07-05 | Shell Oil Company | Asymmetric block copolymers and corresponding adhesive formulations |
JPS61254650A (ja) * | 1985-05-07 | 1986-11-12 | Asahi Chem Ind Co Ltd | ブロツク共重合体組成物及びその製造方法 |
ES2036568T3 (es) * | 1986-03-21 | 1993-06-01 | Shell Internationale Research Maatschappij B.V. | Composiciones de cierre hermetico de fusion en caliente. |
US4704434A (en) * | 1986-03-24 | 1987-11-03 | Phillips Petroleum Company | Craze-resistant polymodal linear block copolymers with terminal tapered blocks |
JPH0755999B2 (ja) * | 1986-09-05 | 1995-06-14 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | ブロツク共重合体組成物 |
US5304598A (en) * | 1988-12-23 | 1994-04-19 | Enichem Elastomeri S.P.A. | Polymeric compositions and method for preparing them |
CA2028410C (en) * | 1990-01-02 | 1996-09-17 | William J. Trepka | Tapered block styrene/butadiene copolymers |
US5256736A (en) * | 1991-05-08 | 1993-10-26 | Phillips Petroleum Company | Tapered block copolymers of conjugated dienes and monovinylarenes |
-
1994
- 1994-03-09 US US08/208,414 patent/US5405903A/en not_active Expired - Lifetime
- 1994-03-18 TW TW083102382A patent/TW302374B/zh active
- 1994-03-28 BR BR9405911A patent/BR9405911A/pt not_active IP Right Cessation
- 1994-03-28 ES ES94913079T patent/ES2107207T3/es not_active Expired - Lifetime
- 1994-03-28 RU RU95121813A patent/RU2111220C1/ru not_active IP Right Cessation
- 1994-03-28 DE DE69405983T patent/DE69405983T2/de not_active Expired - Lifetime
- 1994-03-28 CN CN94191637A patent/CN1068344C/zh not_active Expired - Lifetime
- 1994-03-28 KR KR1019950704217A patent/KR100312401B1/ko not_active IP Right Cessation
- 1994-03-28 EP EP94913079A patent/EP0691991B1/en not_active Expired - Lifetime
- 1994-03-28 WO PCT/EP1994/000988 patent/WO1994022931A1/en active IP Right Grant
- 1994-03-28 JP JP52166794A patent/JP3258664B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69405983D1 (de) | 1997-11-06 |
JP3258664B2 (ja) | 2002-02-18 |
CN1068344C (zh) | 2001-07-11 |
WO1994022931A1 (en) | 1994-10-13 |
KR100312401B1 (ko) | 2001-12-28 |
BR9405911A (pt) | 1995-12-26 |
TW302374B (es) | 1997-04-11 |
EP0691991B1 (en) | 1997-10-01 |
US5405903A (en) | 1995-04-11 |
RU2111220C1 (ru) | 1998-05-20 |
EP0691991A1 (en) | 1996-01-17 |
JPH08508309A (ja) | 1996-09-03 |
DE69405983T2 (de) | 1998-02-12 |
KR960701911A (ko) | 1996-03-28 |
CN1120342A (zh) | 1996-04-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2107207T3 (es) | Procedimiento para la preparacion de una composicion de copolimeros de bloques. | |
RU95121813A (ru) | Способ получения блоксополимерной композиции и блок-сополимерная композиция | |
Saunders et al. | Synthesis of amphiphilic star block copolymers using ring-opening metathesis polymerization | |
RU96113057A (ru) | Блок-сополимеры с улучшенными сочетаниями свойств | |
BR9507868A (pt) | Processo de polimerização para a preparação de resinas contendo acrilato homopolimérico de polimerização de radical livre para a preparação de resima termoplástica contendo acrilato homopolímero e de polimerização de readical livre para a preparação de uma resina termoplástica de copolímero de bloco ou multibloco contendo homoacrilato | |
ES441031A1 (es) | Procedimiento para preparar una mezcla copolimerica en blo- que de un dieno conjugado y un hidrocarburo vinilaromatico. | |
ATE172211T1 (de) | Blockcopolymerisate von monovinylarenen und konjugierten dienen mit endblöcken kontinuierlich sich ändernder zusammensetzung | |
KR890010074A (ko) | 개선된 가공성 이소올레핀 중합체 | |
MX9307085A (es) | Proceso de polimerizacion por radicales libres para al preparacion de una resina o resinas termoplasticas y composicion de pigmento organico que comprende tales resinas. | |
ES2094927T3 (es) | Copolimero insaturado de etileno-dieno no conjugado y su preparacion por polimerizacion por radicales. | |
KR960705863A (ko) | 특성의 개선된 조합을 갖는 블록 공중합체(block copolymers having improved combinations of properties) | |
DE59408237D1 (de) | Vernetzbare Copolymere und Hydrogele | |
RU2007115855A (ru) | Полимеры и их использование в асфальтовых композициях и покрытиях | |
DK1029030T3 (da) | Skumningsresistente carbonhydridoliesammensætninger | |
JPS52101287A (en) | Preparation of conjugated diene polymers | |
KR880002908A (ko) | 부타디엔 및 이소프렌게 abc 블럭 공중합체, 그의 제조방법 및 그의 용도 | |
DK0717756T3 (da) | Fremgangsmåde til fremstilling af koblede asymmetriske polymerer | |
BR0116204A (pt) | Composto n-acóxi-4,4-dióxi-polialquil-pireridina, com grupos glicidila ou alquilcarbonila como iniciadores funcionais para polimerização de radical controlada | |
WO2003097704A8 (fr) | Procedes de polymerisation radicalaire et polymeres halogenes | |
CA2064756A1 (en) | Humidity tolerant charge director compositions | |
GB2020670A (en) | Liquid polymer and liquid copolymers of Butadiene and the preparation thereof. | |
ES2121435T3 (es) | Composicion util para articulos elastomericos y articulos preparados a partir de la composicion. | |
GB2007686A (en) | Multi-Arm Star Copolymers | |
Urushido et al. | Polymerization of allyl esters of unsaturated acids. I. Cyclopolymerization of methyl allyl maleate | |
KR900000391A (ko) | 부타디엔, 이소프렌 및 스티렌을 기본으로 하는 ab 블럭 공중합체, 이의 제조방법 및 이의 용도 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 691991 Country of ref document: ES |