ES2122135T3 - Copolimeros de bloques de composicion gradualmente variable de monovinilarenos y dienos conjugados. - Google Patents

Copolimeros de bloques de composicion gradualmente variable de monovinilarenos y dienos conjugados.

Info

Publication number
ES2122135T3
ES2122135T3 ES94118996T ES94118996T ES2122135T3 ES 2122135 T3 ES2122135 T3 ES 2122135T3 ES 94118996 T ES94118996 T ES 94118996T ES 94118996 T ES94118996 T ES 94118996T ES 2122135 T3 ES2122135 T3 ES 2122135T3
Authority
ES
Spain
Prior art keywords
monomer
present
until
polymerising
copolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94118996T
Other languages
English (en)
Inventor
George A Moczygemby
William J Trepka
Nancy R Knight
Nathan E Stacy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ES2122135T3 publication Critical patent/ES2122135T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

UN METODO PARA PREPARAR COPOLIMEROS BLOQUES AFILADOS EN UN PROCESO DE POLIMERIZACION CARGANDO SECUENCIALMENTE: (1) UN INICIADOR Y MONOMEROS MONOVINILAROMATICOS EN PRESENCIA DE UN ALEATORIZADOR; (2) UN INICIADOR Y MONOMERO MONOVINILAROMATICO; (3) UNA MEZCLA DE MONOMERO DE DIENO CONJUGADOS Y MONOVINILAROMATICOS; (4) UNA MEZCLA MONOMEROS DE DIENO CONJUGADOS Y MONOVINILAROMATICOS; (5) MONOMERO DE DIENO CONJUGADO, Y (6) UN AGENTE DE ACOPLAMIENTO; Y LOS COPOLIMEROS BLOQUES AFILADOS POLIMODALES ASI PREPARADOS. LOS COPOLIMEROS SON PARTICULARMENTE UTILES SOLO O EN MEZCLA PARA APLICACIONES TALES COMO ENVASADO Y CONTENEDORES DE ALIMENTO O BEBIDA QUE REQUIEREN TRANSPARENCIA Y UNA BUENA RESISTENCIA A ESFUERZO DE ROTURA MEDIOAMBIENTAL.
ES94118996T 1993-12-02 1994-12-01 Copolimeros de bloques de composicion gradualmente variable de monovinilarenos y dienos conjugados. Expired - Lifetime ES2122135T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/162,735 US5399628A (en) 1993-12-02 1993-12-02 Block copolymers of monovinylarenes and conjugated dienes containing two interior tapered blocks

Publications (1)

Publication Number Publication Date
ES2122135T3 true ES2122135T3 (es) 1998-12-16

Family

ID=22586931

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94118996T Expired - Lifetime ES2122135T3 (es) 1993-12-02 1994-12-01 Copolimeros de bloques de composicion gradualmente variable de monovinilarenos y dienos conjugados.

Country Status (10)

Country Link
US (2) US5399628A (es)
EP (1) EP0656377B1 (es)
JP (1) JP2927692B2 (es)
KR (1) KR100235553B1 (es)
AT (1) ATE172211T1 (es)
CA (1) CA2134027C (es)
DE (1) DE69413931T2 (es)
ES (1) ES2122135T3 (es)
NO (1) NO303227B1 (es)
SG (1) SG73387A1 (es)

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FR2714384B1 (fr) * 1993-12-29 1996-02-02 Atochem Elf Sa Copolymère bloc étoile d'un monomère vinylaromatique et d'un diène conjugué, son procédé d'obtention, et les compositions comprenant ledit copolymère et du polystyrène cristal.
US6835778B2 (en) * 1995-08-29 2004-12-28 Chevron Phillips Chemical Company Lp Conjugated diene/monovinylarene block copolymers blends
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US6127487A (en) * 1998-10-14 2000-10-03 Phillips Petroleum Company Process to produce coupled block copolymers and said copolymers
US6372853B1 (en) * 1999-07-28 2002-04-16 China Petrochemical Corporation Butadiene/isoprene/monovinyl aromatic monomer heptablock copolymers and method for the preparation thereof
US6956084B2 (en) * 2001-10-04 2005-10-18 Bridgestone Corporation Nano-particle preparation and applications
KR100452813B1 (ko) * 2002-05-15 2004-10-14 금호석유화학 주식회사 2조성 선형 블락 공중합체， 그 제조방법 및 용도
KR100458169B1 (ko) * 2002-07-26 2004-11-20 금호석유화학 주식회사 비대칭 다중블록 ｓｂｓ 중합체 및 이의 제조 방법
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US6875818B2 (en) 2003-01-16 2005-04-05 Bridgestone Corporation Polymer nano-strings
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US7205370B2 (en) * 2004-01-12 2007-04-17 Bridgestone Corporation Polymeric nano-particles of flower-like structure and applications
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US7351767B2 (en) * 2004-02-20 2008-04-01 Chevron Phillips Chemical Company, Lp Composition for monovinylrenic-based shrink label films
US7193014B2 (en) * 2004-02-20 2007-03-20 Chevron Phillips Chemical Company, Lp Binary and ternary blends comprising monovinylarene/conjugated diene block copolymers and monovinylarene/alkyl (meth)acrylate copolymers
US7718737B2 (en) * 2004-03-02 2010-05-18 Bridgestone Corporation Rubber composition containing functionalized polymer nanoparticles
US7112369B2 (en) * 2004-03-02 2006-09-26 Bridgestone Corporation Nano-sized polymer-metal composites
US8063142B2 (en) 2004-03-02 2011-11-22 Bridgestone Corporation Method of making nano-particles of selected size distribution
US20050215693A1 (en) * 2004-03-29 2005-09-29 Xiaorong Wang Clay modified rubber composition and a method for manufacturing same
US20050228074A1 (en) * 2004-04-05 2005-10-13 Bridgestone Corporation Amphiphilic polymer micelles and use thereof
US20050282956A1 (en) * 2004-06-21 2005-12-22 Xiaorong Wang Reversible polymer/metal nano-composites and method for manufacturing same
US7998554B2 (en) * 2004-07-06 2011-08-16 Bridgestone Corporation Hydrophobic surfaces with nanoparticles
DE102004059783A1 (de) * 2004-12-10 2006-06-14 Basf Ag Transparente Mischungen linearer Styrol-Butadien-Blockcopolymerer
US7572855B2 (en) 2005-01-28 2009-08-11 Bridgestone Corporation Nano-composite and compositions manufactured thereof
US7579398B2 (en) * 2005-02-02 2009-08-25 Bridgestone Corporation Nano-composite and compositions therefrom
US7659342B2 (en) * 2005-02-03 2010-02-09 Bridgestone Corporation Polymer nano-particle with polar core and method for manufacturing same
US7538159B2 (en) 2005-12-16 2009-05-26 Bridgestone Corporation Nanoparticles with controlled architecture and method thereof
US9061900B2 (en) * 2005-12-16 2015-06-23 Bridgestone Corporation Combined use of liquid polymer and polymeric nanoparticles for rubber applications
US7884160B2 (en) 2005-12-19 2011-02-08 Bridgestone Corporation Non-spherical nanoparticles made from living triblock polymer chains
US8288473B2 (en) * 2005-12-19 2012-10-16 Bridgestone Corporation Disk-like nanoparticles
US7560510B2 (en) 2005-12-20 2009-07-14 Bridgestone Corporation Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties
US7601772B2 (en) * 2005-12-20 2009-10-13 Bridgestone Corporation Nano-composite and method thereof
US8877250B2 (en) * 2005-12-20 2014-11-04 Bridgestone Corporation Hollow nano-particles and method thereof
US8697775B2 (en) * 2005-12-20 2014-04-15 Bridgestone Corporation Vulcanizable nanoparticles having a core with a high glass transition temperature
US7737216B2 (en) * 2006-01-26 2010-06-15 Chevron Phillips Chemical Company Lp Monovinylarene conjugated diene block copolymer compositions for shrinkable films
US7935184B2 (en) 2006-06-19 2011-05-03 Bridgestone Corporation Method of preparing imidazolium surfactants
EP2046575A4 (en) 2006-07-28 2010-01-13 Bridgestone Corp POLYMERS CORE SHELL NANOPARTICLES WITH AN INTERPHASE AREA
US8415429B2 (en) * 2006-12-11 2013-04-09 Chervron Phillips Chemical Company LP Styrene butadiene block copolymers for film applications
US7597959B2 (en) * 2006-12-19 2009-10-06 Bridgestone Corporation Core-shell fluorescent nanoparticles
US7649049B2 (en) * 2006-12-20 2010-01-19 Bridgestone Corporation Rubber composition containing a polymer nanoparticle
US7829624B2 (en) * 2007-06-29 2010-11-09 Bridgestone Corporation One-pot synthesis of nanoparticles and liquid polymer for rubber applications
ES2527600T3 (es) 2008-12-31 2015-01-27 Bridgestone Corporation Procedimiento de formación de nanopartículas formando primero el núcleo, nanopartícula y composición
US9062144B2 (en) * 2009-04-03 2015-06-23 Bridgestone Corporation Hairy polymeric nanoparticles with first and second shell block polymer arms
US20100272975A1 (en) * 2009-04-23 2010-10-28 Chevron Phillips Chemical Company Lp System and method for the production and use of lamination films
US20110172364A1 (en) * 2009-12-29 2011-07-14 Chen Yaohong Charged Nanoparticles And Method Of Controlling Charge
US9115222B2 (en) * 2009-12-29 2015-08-25 Bridgestone Corporation Well defined, highly crosslinked nanoparticles and method for making same
US8324309B2 (en) 2010-04-27 2012-12-04 Kraton Polymers Us Llc High melt flow block copolymers for non-woven adhesives
US9428604B1 (en) 2011-12-30 2016-08-30 Bridgestone Corporation Nanoparticle fillers and methods of mixing into elastomers
US9598524B1 (en) 2015-09-18 2017-03-21 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications
US9540475B2 (en) 2015-03-12 2017-01-10 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers for tubing applications
US9441090B1 (en) 2015-03-12 2016-09-13 Chevron Phillips Chemical Company Lp Methods for controlling hardness of styrene-butadiene block copolymers
US9738781B2 (en) 2015-09-03 2017-08-22 Ineos Styrolution Group Gmbh Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications
KR102153280B1 (ko) * 2016-01-26 2020-09-10 다이나졸 엘라스토메로스 에스에이 데 세베 카운터 테이퍼형 열가소성 엘라스토머
US10023676B2 (en) 2016-02-24 2018-07-17 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
US9828455B2 (en) 2016-02-24 2017-11-28 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
CN106397696B (zh) * 2016-08-31 2019-03-22 广东众和化塑有限公司 一种同时具备高透、高抗曲折性和高发泡效率的sbs弹性体及其制备方法
KR102646039B1 (ko) * 2018-04-16 2024-03-08 이네오스 스티롤루션 그룹 게엠베하 초고 흐름 스티렌 아크릴로니트릴 코폴리머 조성물
EP3781628B1 (en) 2018-04-16 2021-11-17 INEOS Styrolution Group GmbH Ultra-high flow acrylonitrile butadiene styrene copolymer compositions
US20200199334A1 (en) * 2018-12-20 2020-06-25 Dynasol Elastómeros, S.A. De C.V. Dual Composition Block Copolymers

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Also Published As

Publication number Publication date
US5399628A (en) 1995-03-21
EP0656377B1 (en) 1998-10-14
CA2134027C (en) 1998-10-13
DE69413931D1 (de) 1998-11-19
US5587425A (en) 1996-12-24
SG73387A1 (en) 2000-06-20
CA2134027A1 (en) 1995-06-03
KR950018108A (ko) 1995-07-22
NO303227B1 (no) 1998-06-15
JP2927692B2 (ja) 1999-07-28
NO944630D0 (no) 1994-12-01
KR100235553B1 (ko) 1999-12-15
ATE172211T1 (de) 1998-10-15
EP0656377A1 (en) 1995-06-07
JPH07252336A (ja) 1995-10-03
DE69413931T2 (de) 1999-03-18
NO944630L (no) 1995-06-06

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