ES2126045T3 - Copolimeros de bloques de composicion gradualmente variable de monovinilarenos y dienos conjugados. - Google Patents
Copolimeros de bloques de composicion gradualmente variable de monovinilarenos y dienos conjugados.Info
- Publication number
- ES2126045T3 ES2126045T3 ES94117957T ES94117957T ES2126045T3 ES 2126045 T3 ES2126045 T3 ES 2126045T3 ES 94117957 T ES94117957 T ES 94117957T ES 94117957 T ES94117957 T ES 94117957T ES 2126045 T3 ES2126045 T3 ES 2126045T3
- Authority
- ES
- Spain
- Prior art keywords
- charging
- monomer
- thereafter
- conjugated
- monovinilarenes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
- C08G81/022—Block or graft polymers containing only sequences of polymers of C08C or C08F containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
SE PRESENTA UN METODO PARA PREPARAR COPOLIMEROS DE BLOQUE QUE SON PARTICULARMENTE UTILES PARA COMPONENTES DE MEZCLA EN MEZCLAS PARA POLIMEROS DE ESTIRENO. EN LA PRIMERA CONFORMACION DE LA INVENCION LOS COPOLIMEROS SE PREPARAN EN UN PROCESO DE POLIMERIZACION CARGANDO SECUENCIALMENTE: 1) UN INICIADOR Y MONOMEROS DE MONOVINILAROMATICO EN LA PRESENCIA DE UN ALEATORIZADOR; 2) UN INICIADOR Y MONOMEROS DE MONOVINILAROMATICO; 3) UNA MEZCLA DE MONOMEROS DE DIENO CONJUGADO Y MONOVINILAROMATICOS; Y 4) UN AGENTE DE ACOPLAMIENTO; PARA PRODUCIR UN COPOLIMERO DE BLOQUE POLIMODAL. EN LA SEGUNDA CONFORMACION DE LA INVENCION LOS COPOLIMEROS DE BLOQUE SE PREPARAN EN UN PROCESO DE POLIMERIZACION CARGANDO SECUENCIALMENTE: 1) UN INICIADOR Y MONOMEROS DE MONOVINILAROMATICO EN LA PRESENCIA DE UN ALEATORIZADOR; 2) UN INICIADOR Y MONOMEROS DE MONOVINILAROMATICO; 3) UNA MEZCLA DE MONOMEROS DE MONOVINILAROMATICO Y DE DIENO CONJUGADO; 4) UNA MEZCLA DE MONOMEROS DE DIENO DE MONOVINILAROMATICO Y CONJUGADO; Y 5) UN AGENTEDE ACOPLAMIENTO; PARA PRODUCIR UN COPOLIMERO DE BLOQUE POLIMODAL. LOS COPOLIMEROS DE LA INVENCION Y LAS MEZCLAS DE LOS COPOLIMEROS DE LA INVENCION CON POLIMEROS DE ESTIRENO SON PARTICULARMENTE UTILES EN APLICACIONES TALES COMO EL EMPAQUETAMIENTO Y LOS ENVASES PARA ALIMENTOS Y BEBIDAS QUE REQUIEREN TRANSPARENCIA, FALTA DE COLOR, BUENA RESISTENCIA AL IMPACTO Y DUCTIBILIDAD.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15340893A | 1993-11-15 | 1993-11-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2126045T3 true ES2126045T3 (es) | 1999-03-16 |
ES2126045T5 ES2126045T5 (es) | 2003-07-16 |
Family
ID=22547105
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98111995T Expired - Lifetime ES2264178T3 (es) | 1993-11-15 | 1994-11-14 | Procedimiento para la produccion de copolimeros de bloques en gradiente de monovinilarenos y dienos conjugados, copolimeros asi obtenidos, mezclas y articulos. |
ES94117957T Expired - Lifetime ES2126045T5 (es) | 1993-11-15 | 1994-11-14 | Copolimeros de bloques de composicion gradualmente variable de monovinilarenos y dienos conjugados. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98111995T Expired - Lifetime ES2264178T3 (es) | 1993-11-15 | 1994-11-14 | Procedimiento para la produccion de copolimeros de bloques en gradiente de monovinilarenos y dienos conjugados, copolimeros asi obtenidos, mezclas y articulos. |
Country Status (9)
Country | Link |
---|---|
US (3) | US5545690A (es) |
EP (2) | EP0877038B1 (es) |
JP (1) | JP3529868B2 (es) |
KR (1) | KR100364160B1 (es) |
AT (2) | ATE175686T1 (es) |
CA (1) | CA2134026C (es) |
DE (2) | DE69415935T3 (es) |
ES (2) | ES2264178T3 (es) |
SG (2) | SG73397A1 (es) |
Families Citing this family (79)
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CN1036346C (zh) * | 1995-08-04 | 1997-11-05 | 中国石油化工总公司 | 丁苯嵌段共聚物热塑弹性体及制法 |
CN1037848C (zh) * | 1995-08-04 | 1998-03-25 | 北京燕山石油化工公司研究院 | 丁苯嵌段共聚物的制造方法 |
US6835778B2 (en) * | 1995-08-29 | 2004-12-28 | Chevron Phillips Chemical Company Lp | Conjugated diene/monovinylarene block copolymers blends |
DE19615533A1 (de) * | 1996-04-19 | 1997-10-23 | Basf Ag | Thermoplastische Formmasse |
DE19621688A1 (de) * | 1996-05-30 | 1997-12-04 | Basf Ag | Transparente, nicht-blockende Folie |
US6127487A (en) * | 1998-10-14 | 2000-10-03 | Phillips Petroleum Company | Process to produce coupled block copolymers and said copolymers |
DE19914075A1 (de) | 1999-03-27 | 2000-09-28 | Basf Ag | Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren |
US6593430B1 (en) | 1999-03-27 | 2003-07-15 | Basf Aktiengesellschaft | Transparent, impact-resistant polystyrene on a styrene-butadiene block copolymer basis |
EP1059307A1 (en) * | 1999-06-10 | 2000-12-13 | Fina Research S.A. | Production of haze-free block copolymers |
KR100332458B1 (ko) * | 1999-06-29 | 2002-04-13 | 박찬구 | 블록 공중합체 수지 및 그의 제조방법 |
US6599798B2 (en) * | 2001-07-24 | 2003-07-29 | Infineon Technologies Ag | Method of preparing buried LOCOS collar in trench DRAMS |
US6734247B2 (en) * | 2001-12-13 | 2004-05-11 | Nova Chemicals Inc. | Transparent high impact alloy |
US20030181584A1 (en) | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
US20040138371A1 (en) * | 2002-02-07 | 2004-07-15 | St. Clair David John | Gels from controlled distribution block copolymers |
US7141621B2 (en) | 2002-02-07 | 2006-11-28 | Kraton Polymers U.S. Llc | Gels from controlled distribution block copolymers |
KR100452812B1 (ko) * | 2002-05-15 | 2004-10-14 | 금호석유화학 주식회사 | 2조성 선형 블락 공중합체,제조방법 및 용도 |
KR100452813B1 (ko) * | 2002-05-15 | 2004-10-14 | 금호석유화학 주식회사 | 2조성 선형 블락 공중합체, 그 제조방법 및 용도 |
EP1408061A1 (en) * | 2002-10-11 | 2004-04-14 | ATOFINA Research | Process for the production of a transparent copolymer |
US20040115381A1 (en) * | 2002-12-12 | 2004-06-17 | Chevron Phillips Chemical Company, Lp | Method for manufacturing articles with materials containing tapered polymers |
EP1605004B1 (en) * | 2003-03-19 | 2009-05-06 | Denki Kagaku Kogyo Kabushiki Kaisha | Linear block copolymer composition |
ATE366283T1 (de) * | 2003-05-14 | 2007-07-15 | Dow Global Technologies Inc | Blockcopolymerzusammensetzung und daraus hergestellte transparente elastomere gegenstände |
JP4731322B2 (ja) * | 2003-07-28 | 2011-07-20 | 電気化学工業株式会社 | ブロック共重合体の組成物 |
WO2005030821A1 (en) * | 2003-09-24 | 2005-04-07 | Kraton Polymers Research B.V. | Conjugated diene polymers and copolymer blocks having high vinyl content prepared using mixed microstructure control agents and process for preparing same |
US20050090587A1 (en) * | 2003-10-28 | 2005-04-28 | Dunn John E. | Ultraviolet light stability of monovinylarene-conjugated diene copolymer compositions |
US7037980B2 (en) * | 2003-11-10 | 2006-05-02 | Chevron Phillips Chemical Company, Lp | Monovinylarene/conjugated diene copolymers having lower glass transition temperatures |
DE10352695B4 (de) * | 2003-11-12 | 2019-07-18 | Jungheinrich Aktiengesellschaft | Deichsel für kraftgetriebenes Flurförderzeug |
US7211611B2 (en) * | 2003-12-11 | 2007-05-01 | Nike, Inc. | Rubber compositions with non-petroleum oils |
US20050166551A1 (en) * | 2004-02-02 | 2005-08-04 | Keane J. A. | Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer |
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US5256736A (en) * | 1991-05-08 | 1993-10-26 | Phillips Petroleum Company | Tapered block copolymers of conjugated dienes and monovinylarenes |
US5290875A (en) * | 1992-11-30 | 1994-03-01 | Phillips Petroleum Company | Conjugated diene/monovinylarene block copolymers with multiple tapered blocks |
US5436298A (en) * | 1993-09-30 | 1995-07-25 | Phillips Petroleum Company | Block copolymers of monovinylarenes and conjugated dienes and preparation thereof |
US5399628A (en) * | 1993-12-02 | 1995-03-21 | Phillips Petroleum Company | Block copolymers of monovinylarenes and conjugated dienes containing two interior tapered blocks |
US5438103A (en) * | 1994-03-23 | 1995-08-01 | Phillips Petroleum Company | Block copolymers of monovinylaromatic and conjugated diene monomers |
-
1994
- 1994-10-21 CA CA002134026A patent/CA2134026C/en not_active Expired - Fee Related
- 1994-11-14 SG SG1996005986A patent/SG73397A1/en unknown
- 1994-11-14 ES ES98111995T patent/ES2264178T3/es not_active Expired - Lifetime
- 1994-11-14 ES ES94117957T patent/ES2126045T5/es not_active Expired - Lifetime
- 1994-11-14 EP EP98111995A patent/EP0877038B1/en not_active Expired - Lifetime
- 1994-11-14 DE DE69415935T patent/DE69415935T3/de not_active Expired - Lifetime
- 1994-11-14 JP JP31546094A patent/JP3529868B2/ja not_active Expired - Lifetime
- 1994-11-14 AT AT94117957T patent/ATE175686T1/de not_active IP Right Cessation
- 1994-11-14 EP EP94117957A patent/EP0654488B2/en not_active Expired - Lifetime
- 1994-11-14 SG SG200006018A patent/SG96577A1/en unknown
- 1994-11-14 AT AT98111995T patent/ATE328921T1/de not_active IP Right Cessation
- 1994-11-14 DE DE69434761T patent/DE69434761T2/de not_active Expired - Lifetime
- 1994-11-14 KR KR1019940029809A patent/KR100364160B1/ko not_active IP Right Cessation
-
1995
- 1995-06-07 US US08/478,306 patent/US5545690A/en not_active Expired - Lifetime
-
1997
- 1997-11-04 US US08/963,964 patent/US5910546A/en not_active Expired - Lifetime
- 1997-11-12 US US08/968,001 patent/US6265485B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5545690A (en) | 1996-08-13 |
EP0654488A1 (en) | 1995-05-24 |
ES2126045T5 (es) | 2003-07-16 |
DE69434761D1 (de) | 2006-07-20 |
SG73397A1 (en) | 2000-06-20 |
US6265485B1 (en) | 2001-07-24 |
CA2134026C (en) | 1998-06-09 |
EP0654488B1 (en) | 1999-01-13 |
CA2134026A1 (en) | 1995-05-16 |
EP0877038A3 (en) | 1999-05-26 |
SG96577A1 (en) | 2003-06-16 |
ATE175686T1 (de) | 1999-01-15 |
EP0877038A2 (en) | 1998-11-11 |
DE69415935D1 (de) | 1999-02-25 |
KR100364160B1 (ko) | 2003-02-07 |
KR950014161A (ko) | 1995-06-15 |
ES2264178T3 (es) | 2006-12-16 |
EP0654488B2 (en) | 2003-03-19 |
DE69415935T3 (de) | 2003-12-24 |
DE69415935T2 (de) | 1999-06-02 |
DE69434761T2 (de) | 2007-05-10 |
JPH07252335A (ja) | 1995-10-03 |
EP0877038B1 (en) | 2006-06-07 |
ATE328921T1 (de) | 2006-06-15 |
US5910546A (en) | 1999-06-08 |
JP3529868B2 (ja) | 2004-05-24 |
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