ES2089282T3 - Copolimeros de bloques de composicion gradualmente variable de dienos conjugados y monovinilarenos. - Google Patents

Copolimeros de bloques de composicion gradualmente variable de dienos conjugados y monovinilarenos.

Info

Publication number
ES2089282T3
ES2089282T3 ES92107687T ES92107687T ES2089282T3 ES 2089282 T3 ES2089282 T3 ES 2089282T3 ES 92107687 T ES92107687 T ES 92107687T ES 92107687 T ES92107687 T ES 92107687T ES 2089282 T3 ES2089282 T3 ES 2089282T3
Authority
ES
Spain
Prior art keywords
copolymers
monovinilarenes
initiator
monovinylaromatic
variable composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92107687T
Other languages
English (en)
Inventor
William James Trepka
George Anthony Moczygemba
Ralph Coleman Farrar Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ES2089282T3 publication Critical patent/ES2089282T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SE PRESENTA UN METODO PARA PREPARAR COPOLIMEROS DE BLOQUE DE TRANSICION EN UN PROCESO DE POLIMERIZACION MEDIANTE LA CARGA SECUENCIAL: 1) DE MONOMEROS INICIADORES Y MONOVINILAROMATICOS EN LA PRESENCIA DE UN COMPONENTE ALEATORIZADOR; 2) DE UN INICIADOR Y DE UNA MEZCLA DE MONOMEROS DE DIENO MONOVINILAROMATICOS Y CONJUGADOS; 3) DE UN INICIADOR Y UNA MEZCLA DE MONOMEROS MONOVINILAROMATICOS Y CONJUGADOS; Y 4) DE UN AGENTE DE ACOPLAMIENTO PARA PRODUCIR UN COPOLIMERO DE BLOQUE DE TRANSICION POLIMODAL. LOS COPOLIMEROS SON PARTICULARMENTE UTILES PARA APLICACIONES DE EMBALAJE QUE REQUIERAN UNA BUENA RESISTENCIA A LA FRACTURA.
ES92107687T 1991-05-08 1992-05-07 Copolimeros de bloques de composicion gradualmente variable de dienos conjugados y monovinilarenos. Expired - Lifetime ES2089282T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/697,130 US5256736A (en) 1991-05-08 1991-05-08 Tapered block copolymers of conjugated dienes and monovinylarenes

Publications (1)

Publication Number Publication Date
ES2089282T3 true ES2089282T3 (es) 1996-10-01

Family

ID=24799922

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92107687T Expired - Lifetime ES2089282T3 (es) 1991-05-08 1992-05-07 Copolimeros de bloques de composicion gradualmente variable de dienos conjugados y monovinilarenos.

Country Status (12)

Country Link
US (1) US5256736A (es)
EP (1) EP0512530B1 (es)
JP (1) JP2718593B2 (es)
KR (1) KR0164613B1 (es)
AT (1) ATE139788T1 (es)
CA (1) CA2060020C (es)
DE (1) DE69211767T2 (es)
DK (1) DK0512530T3 (es)
ES (1) ES2089282T3 (es)
GR (1) GR3020724T3 (es)
MX (1) MX9201656A (es)
SG (1) SG85056A1 (es)

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CA2117708C (en) * 1993-09-30 2002-10-22 William J. Trepka Block copolymers of monovinylarenes and conjugated dienes and preparation thereof
CA2134026C (en) * 1993-11-15 1998-06-09 William J. Trepka Tapered block copolymers of monovinylarenes and conjugated dienes
US5399628A (en) * 1993-12-02 1995-03-21 Phillips Petroleum Company Block copolymers of monovinylarenes and conjugated dienes containing two interior tapered blocks
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CN1036346C (zh) * 1995-08-04 1997-11-05 中国石油化工总公司 丁苯嵌段共聚物热塑弹性体及制法
US6835778B2 (en) * 1995-08-29 2004-12-28 Chevron Phillips Chemical Company Lp Conjugated diene/monovinylarene block copolymers blends
DE19615533A1 (de) * 1996-04-19 1997-10-23 Basf Ag Thermoplastische Formmasse
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DE19727770A1 (de) * 1997-06-30 1999-01-07 Basf Ag Glycicylether aliphatischer Polyalkohole als Kopplungsmittel in der anionischen Polymerisation
US6956084B2 (en) 2001-10-04 2005-10-18 Bridgestone Corporation Nano-particle preparation and applications
US20040115381A1 (en) * 2002-12-12 2004-06-17 Chevron Phillips Chemical Company, Lp Method for manufacturing articles with materials containing tapered polymers
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US7205370B2 (en) 2004-01-12 2007-04-17 Bridgestone Corporation Polymeric nano-particles of flower-like structure and applications
US20050166551A1 (en) * 2004-02-02 2005-08-04 Keane J. A. Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer
US8063142B2 (en) 2004-03-02 2011-11-22 Bridgestone Corporation Method of making nano-particles of selected size distribution
US7718737B2 (en) 2004-03-02 2010-05-18 Bridgestone Corporation Rubber composition containing functionalized polymer nanoparticles
US7112369B2 (en) 2004-03-02 2006-09-26 Bridgestone Corporation Nano-sized polymer-metal composites
US7905872B2 (en) 2004-06-04 2011-03-15 The Procter & Gamble Company Absorbent articles comprising a slow recovery stretch laminate
US7717893B2 (en) 2004-06-04 2010-05-18 The Procter & Gamble Company Absorbent articles comprising a slow recovery elastomer
US20050282956A1 (en) 2004-06-21 2005-12-22 Xiaorong Wang Reversible polymer/metal nano-composites and method for manufacturing same
US7998554B2 (en) 2004-07-06 2011-08-16 Bridgestone Corporation Hydrophobic surfaces with nanoparticles
US8419701B2 (en) 2005-01-10 2013-04-16 The Procter & Gamble Company Absorbent articles with stretch zones comprising slow recovery elastic materials
ATE539723T1 (de) 2005-01-26 2012-01-15 Procter & Gamble Einwegwindel mit elastischer taille und geringer stärke sowie langer wiederherstellungszeit
US7572855B2 (en) 2005-01-28 2009-08-11 Bridgestone Corporation Nano-composite and compositions manufactured thereof
US7579398B2 (en) 2005-02-02 2009-08-25 Bridgestone Corporation Nano-composite and compositions therefrom
US7659342B2 (en) 2005-02-03 2010-02-09 Bridgestone Corporation Polymer nano-particle with polar core and method for manufacturing same
US9061900B2 (en) 2005-12-16 2015-06-23 Bridgestone Corporation Combined use of liquid polymer and polymeric nanoparticles for rubber applications
US7538159B2 (en) 2005-12-16 2009-05-26 Bridgestone Corporation Nanoparticles with controlled architecture and method thereof
US7884160B2 (en) 2005-12-19 2011-02-08 Bridgestone Corporation Non-spherical nanoparticles made from living triblock polymer chains
US8288473B2 (en) 2005-12-19 2012-10-16 Bridgestone Corporation Disk-like nanoparticles
US8877250B2 (en) 2005-12-20 2014-11-04 Bridgestone Corporation Hollow nano-particles and method thereof
US7601772B2 (en) 2005-12-20 2009-10-13 Bridgestone Corporation Nano-composite and method thereof
US8697775B2 (en) 2005-12-20 2014-04-15 Bridgestone Corporation Vulcanizable nanoparticles having a core with a high glass transition temperature
US7560510B2 (en) 2005-12-20 2009-07-14 Bridgestone Corporation Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties
US7935184B2 (en) 2006-06-19 2011-05-03 Bridgestone Corporation Method of preparing imidazolium surfactants
WO2008014464A2 (en) 2006-07-28 2008-01-31 Bridgestone Corporation Polymeric core-shell nanoparticles with interphase region
US8415429B2 (en) * 2006-12-11 2013-04-09 Chervron Phillips Chemical Company LP Styrene butadiene block copolymers for film applications
US7597959B2 (en) 2006-12-19 2009-10-06 Bridgestone Corporation Core-shell fluorescent nanoparticles
US7649049B2 (en) 2006-12-20 2010-01-19 Bridgestone Corporation Rubber composition containing a polymer nanoparticle
US7829624B2 (en) 2007-06-29 2010-11-09 Bridgestone Corporation One-pot synthesis of nanoparticles and liquid polymer for rubber applications
US8323257B2 (en) 2007-11-21 2012-12-04 The Procter & Gamble Company Absorbent articles comprising a slow recovery stretch laminate and method for making the same
EP2370349B1 (en) 2008-12-31 2014-10-29 Bridgestone Corporation Core-first nanoparticle formation process, nanoparticle, and composition
US9062144B2 (en) 2009-04-03 2015-06-23 Bridgestone Corporation Hairy polymeric nanoparticles with first and second shell block polymer arms
US9115222B2 (en) 2009-12-29 2015-08-25 Bridgestone Corporation Well defined, highly crosslinked nanoparticles and method for making same
JP5594826B2 (ja) * 2010-07-07 2014-09-24 旭化成ケミカルズ株式会社 プラスチックダンボール用ブロック共重合体、プラスチックダンボール用樹脂組成物、及びプラスチックダンボール
US9017305B2 (en) 2010-11-12 2015-04-28 The Procter Gamble Company Elastomeric compositions that resist force loss and disintegration
CN103347912B (zh) * 2011-01-30 2018-06-05 戴纳索尔伊莱斯托米罗斯公司 递变三嵌段共聚物
US9428604B1 (en) 2011-12-30 2016-08-30 Bridgestone Corporation Nanoparticle fillers and methods of mixing into elastomers
US9540475B2 (en) 2015-03-12 2017-01-10 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers for tubing applications
US9598524B1 (en) 2015-09-18 2017-03-21 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications
US9441090B1 (en) 2015-03-12 2016-09-13 Chevron Phillips Chemical Company Lp Methods for controlling hardness of styrene-butadiene block copolymers
US9738781B2 (en) 2015-09-03 2017-08-22 Ineos Styrolution Group Gmbh Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications
US9828455B2 (en) 2016-02-24 2017-11-28 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
US10023676B2 (en) 2016-02-24 2018-07-17 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
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US4089913A (en) * 1974-01-10 1978-05-16 Sumitomo Chemical Company, Limited Process for producing transparent block copolymer resin
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CA2028410C (en) * 1990-01-02 1996-09-17 William J. Trepka Tapered block styrene/butadiene copolymers

Also Published As

Publication number Publication date
KR920021611A (ko) 1992-12-18
DK0512530T3 (da) 1996-07-29
EP0512530A1 (en) 1992-11-11
GR3020724T3 (en) 1996-11-30
ATE139788T1 (de) 1996-07-15
DE69211767D1 (de) 1996-08-01
MX9201656A (es) 1992-11-01
CA2060020C (en) 1996-09-17
CA2060020A1 (en) 1992-11-09
DE69211767T2 (de) 1996-11-07
US5256736A (en) 1993-10-26
JPH05155951A (ja) 1993-06-22
KR0164613B1 (ko) 1999-03-20
EP0512530B1 (en) 1996-06-26
JP2718593B2 (ja) 1998-02-25
SG85056A1 (en) 2001-12-19

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