BR9913419A - Enxertamento de monÈmeros etilenicamente insaturados sobre polìmeros - Google Patents

Enxertamento de monÈmeros etilenicamente insaturados sobre polìmeros

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Publication number
BR9913419A
BR9913419A BR9913419-5A BR9913419A BR9913419A BR 9913419 A BR9913419 A BR 9913419A BR 9913419 A BR9913419 A BR 9913419A BR 9913419 A BR9913419 A BR 9913419A
Authority
BR
Brazil
Prior art keywords
polymer
ethylenically unsaturated
grafting
grafted
radical
Prior art date
Application number
BR9913419-5A
Other languages
English (en)
Inventor
Michael Roth
Rudolf Pfaendner
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of BR9913419A publication Critical patent/BR9913419A/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerization Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Patente de Invenção: <B>"ENXERTAMENTO DE MONÈMEROS ETILENICAMENTE INSATURADOS SOBRE POLìMEROS"<D>. A presente invenção refere-se a um processo para a preparação de polímeros enxertados em que uma primeira etapa A) um radical nitroxila estável é enxertado sobre um polímero, etapa a qual compreende o aquecimento de um polímero e um radical nitroxila estável (NO<sym>); e, em uma segunda etapa B) o polímero enxertado da etapa A) é aquecido na presença de um monómero ou oligómero etilenicamente insaturado até uma temperatura na qual clivagem da ligação nitroxila-polímero ocorre e a polimerização do monómero ou oligómero etilenicamente insaturado é iniciada no radical polimérico; manutenção da referida temperatura para outra polimerização e, após o que, resfriamento da mistura para uma temperatura abaixo de 60°C. Outros assuntos são polímeros enxertados preparados por meio do referido processo, o uso do iniciador de radical polimérico e o uso de radicais NO para enxertamento de polímeros.
BR9913419-5A 1998-09-03 1999-08-23 Enxertamento de monÈmeros etilenicamente insaturados sobre polìmeros BR9913419A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98810878 1998-09-03
PCT/EP1999/006171 WO2000014134A1 (en) 1998-09-03 1999-08-23 Grafting of ethylenically unsaturated monomers onto polymers

Publications (1)

Publication Number Publication Date
BR9913419A true BR9913419A (pt) 2001-05-22

Family

ID=8236299

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9913419-5A BR9913419A (pt) 1998-09-03 1999-08-23 Enxertamento de monÈmeros etilenicamente insaturados sobre polìmeros

Country Status (12)

Country Link
US (1) US6525151B1 (pt)
EP (1) EP1115765B1 (pt)
JP (1) JP4516212B2 (pt)
KR (1) KR100575170B1 (pt)
CN (1) CN1298755C (pt)
AT (1) ATE434635T1 (pt)
AU (1) AU759408B2 (pt)
BR (1) BR9913419A (pt)
CA (1) CA2341372A1 (pt)
DE (1) DE69941028D1 (pt)
ES (1) ES2325697T3 (pt)
WO (1) WO2000014134A1 (pt)

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WO2000014135A1 (en) * 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
BR0014046B1 (pt) 1999-09-15 2010-11-03 estabilizadores poliméricos com grande afinidade com pasta.
US6414048B1 (en) 1999-12-07 2002-07-02 Sumitomo Electric Fine Polymer, Inc. Chemical grafting onto a substrate and coating composition
TW541303B (en) 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
CN1269860C (zh) * 2001-05-15 2006-08-16 西巴特殊化学品控股有限公司 用羟胺酯将烯属不饱和羧酸衍生物接枝到热塑性聚合物上的方法
CN100396705C (zh) * 2002-06-20 2008-06-25 西巴特殊化学品控股有限公司 硝酰基链端低聚物或聚合物在热塑性聚合物上的接枝
WO2004058881A1 (en) * 2002-12-18 2004-07-15 Crompton Corporation Styrenic polymer composites
WO2004069887A2 (en) * 2003-02-10 2004-08-19 Ciba Specialty Chemicals Holding Inc. Comb copolymers with defined side chains and process for their manufacture
US6967228B2 (en) * 2003-05-01 2005-11-22 Firestone Polymers, Llc Stable free radical polymers
US20040220345A1 (en) * 2003-05-01 2004-11-04 Firestone Polymers, Llc Stable free radical polymers
WO2005000925A1 (ja) * 2003-06-26 2005-01-06 Mitsubishi Rayon Co., Ltd. 変性ポリオレフィン樹脂および組成物
US7279527B2 (en) * 2005-04-22 2007-10-09 Bridgestone Corporation Method of converting anionic living end to protected free radical living end and applications thereof
KR100666818B1 (ko) * 2006-02-20 2007-01-09 주식회사 엘지화학 우수한 저온색상안정성을 갖는 열가소성 성형재
JP2008044996A (ja) * 2006-08-11 2008-02-28 Mitsui Chemicals Inc オレフィン系重合体
JP4819616B2 (ja) * 2006-08-11 2011-11-24 三井化学株式会社 オレフィン系重合体
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US7560509B2 (en) * 2006-12-29 2009-07-14 Bridgestone Corporation Method of directing grafting by controlling the location of high vinyl segments in a polymer
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US7737218B2 (en) 2006-12-29 2010-06-15 Bridgestone Corporation Method for generating free radical capable polymers using tin or silicon halide compounds
US20080157641A1 (en) * 2006-12-31 2008-07-03 Rachael Wren Grout Multi-use Free Standing Seating and Storage Unit
CN102167784B (zh) * 2010-12-30 2013-02-20 长春工业大学 一种水性化三元乙丙橡胶的制备方法
CN102139229B (zh) * 2011-01-19 2012-10-10 华东师范大学 一种负载型金催化剂的制备方法及其应用
CN104140484B (zh) * 2013-05-08 2016-08-17 中国石油化工股份有限公司 一种支化稀土异戊橡胶及其制备方法和橡胶组合物
CN106232646B (zh) * 2014-04-18 2018-11-20 日本A&L株式会社 接枝共聚物以及热塑性树脂组合物
CN104650766A (zh) * 2014-12-17 2015-05-27 浙江科达利实业有限公司 反应粘合剂胶料及其制造工艺
CN105419440A (zh) * 2015-12-18 2016-03-23 蚌埠市鑫晟新材料科技有限公司 一种可减少污染的内墙涂料添加剂的制备方法
CN108017744B (zh) * 2016-11-03 2021-07-30 中国石油化工股份有限公司 一种粉末羧基丁苯橡胶及其制备方法和应用
CN109485795B (zh) * 2018-11-08 2021-06-25 万华化学集团股份有限公司 一种共聚物相容剂及其制备方法和应用
CN112876614A (zh) * 2021-02-06 2021-06-01 中交第四公路工程局有限公司 一种杜仲胶与马来酸酐的熔融接枝方法
TW202330677A (zh) 2021-12-10 2023-08-01 義大利商佛沙里斯股份有限公司 橡膠強化的乙烯芳香族(共)聚合物及其製備方法

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Also Published As

Publication number Publication date
EP1115765B1 (en) 2009-06-24
DE69941028D1 (de) 2009-08-06
JP4516212B2 (ja) 2010-08-04
AU5738799A (en) 2000-03-27
KR20010072721A (ko) 2001-07-31
ES2325697T3 (es) 2009-09-14
JP2002524589A (ja) 2002-08-06
CN1315971A (zh) 2001-10-03
CA2341372A1 (en) 2000-03-16
WO2000014134A1 (en) 2000-03-16
ATE434635T1 (de) 2009-07-15
KR100575170B1 (ko) 2006-04-28
EP1115765A1 (en) 2001-07-18
US6525151B1 (en) 2003-02-25
AU759408B2 (en) 2003-04-17
CN1298755C (zh) 2007-02-07

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Legal Events

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B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements