ES2157303T3 - Procedimiento mejorado para formar polimeros. - Google Patents

Procedimiento mejorado para formar polimeros.

Info

Publication number
ES2157303T3
ES2157303T3 ES95307215T ES95307215T ES2157303T3 ES 2157303 T3 ES2157303 T3 ES 2157303T3 ES 95307215 T ES95307215 T ES 95307215T ES 95307215 T ES95307215 T ES 95307215T ES 2157303 T3 ES2157303 T3 ES 2157303T3
Authority
ES
Spain
Prior art keywords
water
monomero
solubility
low
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95307215T
Other languages
English (en)
Inventor
Willie Lau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Application granted granted Critical
Publication of ES2157303T3 publication Critical patent/ES2157303T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
    • C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
    • C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
    • C08B37/0012—Cyclodextrin [CD], e.g. cycle with 6 units (alpha), with 7 units (beta) and with 8 units (gamma), large-ring cyclodextrin or cycloamylose with 9 units or more; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

SE PRESENTA UN METODO DE POLIMERIZACION ACUOSO PARA LA FORMACION DE POLIMEROS QUE CONTENGA, COMO UNIDADES POLIMERIZADAS, AL MENOS UN MONOMERO QUE TENGA UNA BAJA SOLUBILIDAD AL AGUA, Y QUE INCLUYE LAS FASES DE: (1) COMPLEXAR AL MENOS UN MONOMERO QUE TENGA BAJA SOLUBILIDAD AL AGUA CON UN COMPUESTO ORGANICO MACROMOLECULAR QUE TENGA UNA CAVIDAD HIDROFOBA; Y (2) POLIMERIZAR EN UN SISTEMA ACUOSO DE ALREDEDOR DE 0,1% A ALREDEDOR DE 100% DEL PESO DEL COMPONENTE MONOMERO, BASADO EN EL PESO TOTAL DEL POLIMERO, DEL MONOMERO COMPLEJO QUE TENGA UNA BAJA SOLUBILIDAD AL AGUA DE ALREDEDOR DE 0% A ALREDEDOR DE 99,9% DEL PESO, BASADO EN EL PESO TOTAL DEL POLIMERO, DE AL MENOS UN MONOMERO QUE TENGA UNA ALTA SOLUBILIDAD AL AGUA. EL METODO TAMBIEN ES UTIL PARA FORMAR POLIMEROS DE SOLUCION ACUOSA QUE TENGAN BAJA SOLUBILIDAD AL AGUA. EL METODO ES UTIL PARA POLIMERIZAR, EN UN SISTEMA ACUOSO, POLIMEROS DE SOLUCION ACUOSA O POLIMEROS DE EMULSION, EN CONCRETO LOS COPOLIMEROS ALEATORIOS, DE MONOMEROS QUE TENGAN UNA BAJA SOLUBILIDAD AL AGUA QUE HASTA AHORA NO PODIAN FABRICARSE SATISFACTORIAMENTE SIN LA ADICION DE UN SOLVENTE ORGANICO, COMONOMERO O UN SURFACTANTE DE ALTO NIVEL PARA AYUDAR A LA SOLUBILIZACION DEL MONOMERO QUE TIENE UNA BAJA SOLUBILIDAD AL AGUA. EL METODO TAMBIEN ES UTIL PARA MEJORAR LA EFICACIA DE LOS AGENTES DE TRANSFERENCIA DE CADENA QUE TIENEN UNA BAJA SOLUBILIDAD AL AGUA, UTILIZADOS EN SOLUCION ACUOSA O EN POLIMERIZACIONES DE EMULSION.
ES95307215T 1994-10-28 1995-10-11 Procedimiento mejorado para formar polimeros. Expired - Lifetime ES2157303T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/330,660 US5521266A (en) 1994-10-28 1994-10-28 Method for forming polymers

Publications (1)

Publication Number Publication Date
ES2157303T3 true ES2157303T3 (es) 2001-08-16

Family

ID=23290744

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95307215T Expired - Lifetime ES2157303T3 (es) 1994-10-28 1995-10-11 Procedimiento mejorado para formar polimeros.

Country Status (19)

Country Link
US (3) US5521266A (es)
EP (1) EP0710675B1 (es)
JP (3) JP3938795B2 (es)
KR (1) KR100389098B1 (es)
CN (2) CN1055936C (es)
AU (1) AU705906B2 (es)
BR (1) BR9504598A (es)
CA (1) CA2161620A1 (es)
DE (1) DE69521009T2 (es)
ES (1) ES2157303T3 (es)
FI (1) FI954863A (es)
IL (1) IL115660A0 (es)
MX (1) MX9504424A (es)
MY (1) MY119199A (es)
PH (1) PH31645A (es)
RU (2) RU2177953C2 (es)
SG (1) SG54088A1 (es)
TW (1) TW363977B (es)
ZA (1) ZA958846B (es)

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KR960014158A (ko) 1996-05-22
SG54088A1 (en) 1998-11-16
TW363977B (en) 1999-07-11
EP0710675B1 (en) 2001-05-23
AU3442395A (en) 1996-05-09
EP0710675A2 (en) 1996-05-08
CA2161620A1 (en) 1996-04-29
RU2177953C2 (ru) 2002-01-10
PH31645A (en) 1999-01-12
ZA958846B (en) 1996-07-25
MX9504424A (es) 1997-04-30
FI954863A0 (fi) 1995-10-12
EP0710675A3 (en) 1997-03-12
US5521266A (en) 1996-05-28
JP4052661B2 (ja) 2008-02-27
KR100389098B1 (ko) 2003-12-31
CN1055936C (zh) 2000-08-30
JPH08208727A (ja) 1996-08-13
CN1275582A (zh) 2000-12-06
JP2007204747A (ja) 2007-08-16
JP4218902B2 (ja) 2009-02-04
DE69521009D1 (de) 2001-06-28
IL115660A0 (en) 1996-01-19
JP2006131919A (ja) 2006-05-25
DE69521009T2 (de) 2001-11-15
JP3938795B2 (ja) 2007-06-27
FI954863A (fi) 1996-04-29
MY119199A (en) 2005-04-30
US5710226A (en) 1998-01-20
RU2228338C2 (ru) 2004-05-10
AU705906B2 (en) 1999-06-03
BR9504598A (pt) 1997-05-27
CN1133849A (zh) 1996-10-23
CN1122053C (zh) 2003-09-24
US5760129A (en) 1998-06-02

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