ES2154260T3 - Membranas de osmosis inversa sintetizadas interfacialmente y procedimientos para la preparacion de las mismas. - Google Patents
Membranas de osmosis inversa sintetizadas interfacialmente y procedimientos para la preparacion de las mismas.Info
- Publication number
- ES2154260T3 ES2154260T3 ES92112051T ES92112051T ES2154260T3 ES 2154260 T3 ES2154260 T3 ES 2154260T3 ES 92112051 T ES92112051 T ES 92112051T ES 92112051 T ES92112051 T ES 92112051T ES 2154260 T3 ES2154260 T3 ES 2154260T3
- Authority
- ES
- Spain
- Prior art keywords
- cis
- trans
- interfacially
- preparation
- alurus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000012528 membrane Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- -1 AMINO SALT Chemical class 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
- B01D69/1251—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction by interfacial polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0006—Organic membrane manufacture by chemical reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
- B01D69/105—Support pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1213—Laminated layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/56—Polyamides, e.g. polyester-amides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Nanotechnology (AREA)
- Manufacturing & Machinery (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polyamides (AREA)
Abstract
LAS MEMBRANAS DE OSMOSIS INVERSA PERMEABLES AL AGUA SE PREPARAN POLIMERIZANDO INTERFACIALMENTE SOBRE UN SOPORTE MICROPOROSO UN REACTANTE DE POLIAMINA ESENCIALMENTE MONOMERICA QUE TENGA AL MENOS DOS GRUPOS AMINOS FUNCIONALES POR MOLECULA DE REACTANTE, Y UN ALURO DE ACIL CICLOALIFATICO DE ANILLO SIMPLE POLIFUNCIONAL, ESENCIALMENTE MONOMERICO QUE TENGA MENOS DE 6 ATOMOS DE CARBONO POR ANILLO Y QUE TENGA UNA MEDIA DE ALREDEDOR 2.2 GRUPOS DE ALURO DE ACIL POR MOLECULA DE REACTANTE. LA POLIMERIZACION SE LLEVA PREFERIBLEMENTE A CABO EN LA PRESENCIA DE UNA SAL DE AMINO MONOMERICO, QUE INCREMENTA LA RELACION DE FLUJO DE LA MEMBRANA RESULTANTE. ADEMAS, PUEDE USARSE UN ALURO DE ACIL AROMATICO POLIFUNCIONAL EN CONJUNCION CON EL ALURO DE ACIL CICLOALIFATICO PARA INCREMENTAR LAS PROPORCIONES DE RECHAZO A LA SAL. LOS ALUROS DE ACIL CICLOALIFATICO MAS ADECUADOS SON CLORURO DE ACIDO TETRACARBOXILICO DE 1-CIS, 2-TRANS, 3-CIS, 4-TRANS CICLOPENTANO, CLORURO DE ACIDO TRETRACARBOXILICO 1-CIS, 2-TRANS, 3-CIS, 4-TRANS CICLOBUTANO Y CLORURO DE ACIDO TRICARBOXILICO DE 1-CIS, 2-TRANS, 4-CIS CICLOPENTANO. LA PREPARACION DE LOS NUEVOS ISOMEROS ALTERNATIVOS CIS / TRANS DE LOS ALUROS DEL ACIDO POLICARBOXILICO CICLOALIFATICO SE LLEVA A CABO USANDO SALES DE METAL DE LOS ACIDOS POLICARBOXILICOS DE TODOS LOS CIS.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US74419491A | 1991-08-12 | 1991-08-12 | |
US07/838,515 US5254261A (en) | 1991-08-12 | 1992-02-19 | Interfacially synthesized reverse osmosis membranes and processes for preparing the same |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2154260T3 true ES2154260T3 (es) | 2001-04-01 |
Family
ID=27114277
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES92112051T Expired - Lifetime ES2154260T3 (es) | 1991-08-12 | 1992-07-15 | Membranas de osmosis inversa sintetizadas interfacialmente y procedimientos para la preparacion de las mismas. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5254261A (es) |
EP (1) | EP0527348B1 (es) |
JP (1) | JPH06205952A (es) |
KR (1) | KR930003958A (es) |
CN (1) | CN1032042C (es) |
AU (1) | AU660035B2 (es) |
CA (1) | CA2074057A1 (es) |
DE (1) | DE69231483T2 (es) |
DK (1) | DK0527348T3 (es) |
ES (1) | ES2154260T3 (es) |
MX (1) | MX9204655A (es) |
Families Citing this family (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH089571B2 (ja) * | 1992-01-30 | 1996-01-31 | 日東電工株式会社 | 新規な酸塩化物 |
JP3489922B2 (ja) | 1994-12-22 | 2004-01-26 | 日東電工株式会社 | 高透過性複合逆浸透膜の製造方法 |
US5658460A (en) * | 1996-05-07 | 1997-08-19 | The Dow Chemical Company | Use of inorganic ammonium cation salts to maintain the flux and salt rejection characteristics of reverse osmosis and nanofiltration membranes during drying |
US6132804A (en) * | 1997-06-06 | 2000-10-17 | Koch Membrane Systems, Inc. | High performance composite membrane |
US6536605B2 (en) | 1997-06-06 | 2003-03-25 | Koch Membrane Systems, Inc. | High performance composite membrane |
US5922203A (en) * | 1997-10-07 | 1999-07-13 | Hydranautics | Amine monomers and their use in preparing interfacially synthesized membranes for reverse osmosis and nanofiltration |
US6368507B1 (en) * | 1998-10-14 | 2002-04-09 | Saekan Industries Incorporation | Composite polyamide reverse osmosis membrane and method of producing the same |
US6464873B1 (en) | 1999-06-15 | 2002-10-15 | Hydranautics | Interfacially polymerized, bipiperidine-polyamide membranes for reverse osmosis and/or nanofiltration and process for making the same |
US6337018B1 (en) | 2000-04-17 | 2002-01-08 | The Dow Chemical Company | Composite membrane and method for making the same |
US7001518B1 (en) | 2000-11-28 | 2006-02-21 | Hydranautics | Low pressure reverse osmosis and nanofiltration membranes and method for the production thereof |
JP4247881B2 (ja) * | 2001-03-19 | 2009-04-02 | 日東電工株式会社 | 複合半透膜、その製造方法、及びそれを用いた水処理方法 |
US7081202B2 (en) * | 2001-03-19 | 2006-07-25 | Nitto Denko Corporation | Composite semipermeable membrane, production method thereof, and water treatment method using the same |
JP4989843B2 (ja) * | 2001-07-20 | 2012-08-01 | マクマスター ユニヴァーシティ | 非対称性ゲル充填微多孔質膜 |
CA2477427A1 (en) * | 2002-03-01 | 2003-09-12 | Ge Osmonics, Inc. | A process for preparing semipermeable membranes having improved permeability |
US7604746B2 (en) | 2004-04-27 | 2009-10-20 | Mcmaster University | Pervaporation composite membranes |
JP4656502B2 (ja) * | 2004-10-01 | 2011-03-23 | 日東電工株式会社 | 複合半透膜及びその製造方法 |
JP4656503B2 (ja) * | 2004-10-01 | 2011-03-23 | 日東電工株式会社 | 複合半透膜及びその製造方法 |
JP2006102594A (ja) * | 2004-10-01 | 2006-04-20 | Nitto Denko Corp | 複合半透膜の製造方法 |
JP4656511B2 (ja) * | 2004-10-04 | 2011-03-23 | 日東電工株式会社 | 複合逆浸透膜の製造方法 |
KR100680109B1 (ko) * | 2005-07-27 | 2007-02-07 | 웅진코웨이주식회사 | 폴리아미드 역삼투 복합막 및 그 제조방법 |
JP2008093544A (ja) * | 2006-10-10 | 2008-04-24 | Nitto Denko Corp | 複合半透膜及びその製造方法 |
JP4936438B2 (ja) * | 2006-10-10 | 2012-05-23 | 日東電工株式会社 | 乾燥複合半透膜の製造方法 |
US8196754B2 (en) * | 2007-01-17 | 2012-06-12 | The Ohio States University Research Foundation | Water permeable membranes and methods of making water permeable membranes |
BRPI0807930A2 (pt) * | 2007-02-14 | 2014-07-01 | Dxv Water Technologies Llc | Sistemas de filtração, de tratamento de água, de passagem dupla para a dessalinização da água e métodos de tratamento de água, de fabrico de módulo de tratamento de água e de transporte de água |
JP2008246419A (ja) * | 2007-03-30 | 2008-10-16 | Nitto Denko Corp | 複合半透膜の製造方法 |
US8177978B2 (en) * | 2008-04-15 | 2012-05-15 | Nanoh20, Inc. | Reverse osmosis membranes |
JP5287692B2 (ja) * | 2008-12-26 | 2013-09-11 | Jsr株式会社 | ポリイミド系材料、組成物及びフィルム、並びにその製造方法 |
CA2766352C (en) | 2009-06-29 | 2018-09-18 | NanoH2O Inc. | Improved hybrid tfc ro membranes with nitrogen additives |
MX2012008953A (es) | 2010-02-04 | 2012-11-23 | Dxv Water Technologies Llc | Sistemas y metodos de tratamiento de agua. |
JP5968328B2 (ja) | 2010-11-10 | 2016-08-10 | ナノエイチツーオー・インコーポレーテッド | 非金属添加剤を含む改良された混成tfcro膜 |
KR101920194B1 (ko) | 2011-01-24 | 2019-02-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 복합 폴리아미드 막 |
KR101440970B1 (ko) * | 2011-05-20 | 2014-09-17 | 주식회사 엘지화학 | 역삼투 분리막의 제조 방법 및 이에 의해 제조된 역삼투 분리막 |
CN103764264B (zh) | 2011-08-31 | 2016-11-16 | 陶氏环球技术有限责任公司 | 源自包含胺反应性官能团和含磷官能团的单体的复合聚酰胺膜 |
US9029600B2 (en) | 2011-09-29 | 2015-05-12 | Dow Global Technologies Llc | Method for preparing high purity mono-hydrolyzed acyl halide compound |
DE102011118462B4 (de) | 2011-11-14 | 2021-07-22 | Maximilian Born | Energetische Polymere als reaktive Strukturmaterialien zur Verwendung für Waffensysteme |
ES2806675T3 (es) | 2012-01-06 | 2021-02-18 | Ddp Specialty Electronic Mat Us Inc | Método de preparación de una membrana de poliamida de material compuesto |
IN2012DE01027A (es) | 2012-04-03 | 2015-07-31 | Council Scient Ind Res | |
CN104470629B (zh) | 2012-07-19 | 2016-12-07 | 陶氏环球技术有限责任公司 | 源自于多官能胺以及不同的多官能胺‑反应性单体的组合的膜 |
CN104918687A (zh) | 2013-01-14 | 2015-09-16 | 陶氏环球技术有限责任公司 | 使用非极性溶剂的掺合物经由界面聚合制造复合聚酰胺膜 |
CN104918688B (zh) | 2013-01-14 | 2016-12-14 | 陶氏环球技术有限责任公司 | 包含经取代苯甲酰胺单体的复合聚酰胺膜 |
US20160074817A1 (en) * | 2013-03-14 | 2016-03-17 | Andrew P. Murphy | Halogen Resistant Amides, Polyamides, and Membranes Made From the Same |
US9051227B2 (en) | 2013-03-16 | 2015-06-09 | Dow Global Technologies Llc | In-situ method for preparing hydrolyzed acyl halide compound |
US9051417B2 (en) | 2013-03-16 | 2015-06-09 | Dow Global Technologies Llc | Method for solubilizing carboxylic acid-containing compound in hydrocarbon solvent |
US9289729B2 (en) | 2013-03-16 | 2016-03-22 | Dow Global Technologies Llc | Composite polyamide membrane derived from carboxylic acid containing acyl halide monomer |
US9387442B2 (en) | 2013-05-03 | 2016-07-12 | Dow Global Technologies Llc | Composite polyamide membrane derived from an aliphatic acyclic tertiary amine compound |
CN104248917B (zh) * | 2013-06-28 | 2016-03-30 | 中国石油化工股份有限公司 | 一种反渗透膜及其制备方法 |
WO2015084511A1 (en) | 2013-12-02 | 2015-06-11 | Dow Global Technologies Llc | Composite polyamide membrane post treated with nitrious acid |
EP3077089B1 (en) | 2013-12-02 | 2018-02-28 | Dow Global Technologies LLC | Method of forming a composite polyamide membrane treated with dihyroxyaryl compounds and nitrous acid |
KR102273550B1 (ko) | 2014-01-09 | 2021-07-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 아조 함량 및 높은 산 함량을 갖는 복합 폴리아미드 막 |
US9616392B2 (en) | 2014-01-09 | 2017-04-11 | Dow Global Technologies Llc | Composite polyamide membrane having high acid content and low azo content |
US9555378B2 (en) | 2014-01-09 | 2017-01-31 | Dow Global Technologies Llc | Composite polyamide membrane having preferred azo content |
CN105080352B (zh) * | 2014-04-24 | 2017-09-26 | 中国石油化工股份有限公司 | 一种复合反渗透膜及制备方法 |
JP2017513703A (ja) | 2014-04-28 | 2017-06-01 | ダウ グローバル テクノロジーズ エルエルシー | 亜硝酸で後処理される複合ポリアミド膜 |
US9943810B2 (en) | 2014-05-14 | 2018-04-17 | Dow Global Technologies Llc | Composite polyamide membrane post-treated with nitrous acid |
US9795928B2 (en) | 2014-06-24 | 2017-10-24 | Nano And Advanced Materials Institute Limited | Stepwise interfacial polymerization technique with different reagent solution designs to prepare hollow fiber nanofiltration membrane composites |
JP2017527822A (ja) * | 2014-06-27 | 2017-09-21 | パルス ヘルス エルエルシー | 蛍光検出アセンブリ |
US10513446B2 (en) | 2014-10-10 | 2019-12-24 | EcoDesal, LLC | Depth exposed membrane for water extraction |
CN104437110B (zh) | 2014-12-15 | 2016-09-28 | 湖南澳维环保科技有限公司 | 一种大通量聚酰胺复合膜 |
US9861940B2 (en) | 2015-08-31 | 2018-01-09 | Lg Baboh2O, Inc. | Additives for salt rejection enhancement of a membrane |
US9737859B2 (en) | 2016-01-11 | 2017-08-22 | Lg Nanoh2O, Inc. | Process for improved water flux through a TFC membrane |
US10155203B2 (en) | 2016-03-03 | 2018-12-18 | Lg Nanoh2O, Inc. | Methods of enhancing water flux of a TFC membrane using oxidizing and reducing agents |
CN108465377B (zh) * | 2018-02-26 | 2021-01-26 | 福建工程学院 | 一种再生纤维素/壳聚糖复合抗菌纳滤膜的制备方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2079631A5 (es) * | 1970-02-06 | 1971-11-12 | Charbonnages Ste Chimique | |
US3904519A (en) * | 1971-10-19 | 1975-09-09 | Us Interior | Reverse osmosis process using crosslinked aromatic polyamide membranes |
GB1462171A (en) * | 1972-12-21 | 1977-01-19 | Nederlandse Appl Scient Res | Process for making thin polymer foils and their use in a dynamic membrane |
US4277344A (en) * | 1979-02-22 | 1981-07-07 | Filmtec Corporation | Interfacially synthesized reverse osmosis membrane |
JPS5727102A (en) * | 1980-07-28 | 1982-02-13 | Nitto Electric Ind Co Ltd | Composite semipermeable membrane and its production |
US4544484A (en) * | 1983-06-24 | 1985-10-01 | E. I. Du Pont De Nemours And Company | Reverse osmosis membrane quenching |
US4520044A (en) * | 1984-07-30 | 1985-05-28 | E. I. Du Pont De Nemours And Company | Production of composite membranes |
US4529646A (en) * | 1984-07-30 | 1985-07-16 | E. I. Du Pont De Nemours And Company | Production of composite membranes |
US4643829A (en) * | 1984-07-30 | 1987-02-17 | E. I. Du Pont De Nemours And Company | Multilayer reverse osmosis membrane in which one layer is poly-meta-phenylene cyclohexane-1,3,5-tricarboxamide |
US4661254A (en) * | 1985-05-23 | 1987-04-28 | Uop Inc. | Chlorine-resistant semipermeable membranes |
US4761234A (en) * | 1985-08-05 | 1988-08-02 | Toray Industries, Inc. | Interfacially synthesized reverse osmosis membrane |
JPS62247808A (ja) * | 1986-04-18 | 1987-10-28 | Toray Ind Inc | 半透性複合膜の製造法 |
US4626468A (en) * | 1986-04-23 | 1986-12-02 | E. I. Du Pont De Nemours And Company | Microporous support layer with interfacially polymerized copolyamide thereon |
US4828708A (en) * | 1987-09-28 | 1989-05-09 | Desalination Systems | Semipermeable membranes |
US4749488A (en) * | 1987-10-08 | 1988-06-07 | E. I. Du Pont De Nemours And Company | Multilayer reverse osmosis membrane in which one layer is poly-meta-phenylene tetrahydrofuran-2,3,4,5-tetracarboxamide |
US4783346A (en) * | 1987-12-10 | 1988-11-08 | E. I. Du Pont De Nemours And Company | Process for preparing composite membranes |
US5147553A (en) * | 1988-05-04 | 1992-09-15 | Ionics, Incorporated | Selectively permeable barriers |
US4872991A (en) * | 1988-07-05 | 1989-10-10 | Texaco Inc. | Treatment of water |
US4948507A (en) * | 1988-09-28 | 1990-08-14 | Hydranautics Corporation | Interfacially synthesized reverse osmosis membrane containing an amine salt and processes for preparing the same |
US4872984A (en) * | 1988-09-28 | 1989-10-10 | Hydranautics Corporation | Interfacially synthesized reverse osmosis membrane containing an amine salt and processes for preparing the same |
-
1992
- 1992-02-19 US US07/838,515 patent/US5254261A/en not_active Expired - Lifetime
- 1992-07-15 EP EP92112051A patent/EP0527348B1/en not_active Expired - Lifetime
- 1992-07-15 AU AU20300/92A patent/AU660035B2/en not_active Ceased
- 1992-07-15 ES ES92112051T patent/ES2154260T3/es not_active Expired - Lifetime
- 1992-07-15 DE DE69231483T patent/DE69231483T2/de not_active Expired - Fee Related
- 1992-07-15 DK DK92112051T patent/DK0527348T3/da active
- 1992-07-16 CA CA002074057A patent/CA2074057A1/en not_active Abandoned
- 1992-08-07 JP JP4231544A patent/JPH06205952A/ja active Pending
- 1992-08-11 KR KR1019920014404A patent/KR930003958A/ko not_active Application Discontinuation
- 1992-08-11 CN CN92109321A patent/CN1032042C/zh not_active Expired - Fee Related
- 1992-08-11 MX MX9204655A patent/MX9204655A/es not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1070592A (zh) | 1993-04-07 |
EP0527348A1 (en) | 1993-02-17 |
EP0527348B1 (en) | 2000-09-27 |
DE69231483D1 (de) | 2000-11-02 |
DE69231483T2 (de) | 2001-06-07 |
AU660035B2 (en) | 1995-06-08 |
JPH06205952A (ja) | 1994-07-26 |
MX9204655A (es) | 1994-01-31 |
CN1032042C (zh) | 1996-06-19 |
CA2074057A1 (en) | 1993-02-13 |
AU2030092A (en) | 1993-02-18 |
KR930003958A (ko) | 1993-03-22 |
US5254261A (en) | 1993-10-19 |
DK0527348T3 (da) | 2001-01-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2154260T3 (es) | Membranas de osmosis inversa sintetizadas interfacialmente y procedimientos para la preparacion de las mismas. | |
FR2391752A1 (fr) | Membranes semi-permeables a base de polyepoxydes modifies | |
ATE106860T1 (de) | R-enantiomer von n-propargyl-1-aminoindan, dessen herstellung und dieses enthaltende pharmazeutische zusammensetzungen. | |
ES555281A0 (es) | Procedimiento para la produccion de una solucion a base de una poliariletersulfona sulfonada y bario | |
DE69333295D1 (de) | Herstellung von D-Pantoinsäure und D-Pantothensäure | |
ES2100037T3 (es) | Proceso para preparar enantiomeros sustancialmente puros de acidos fenilpropionicos. | |
GB1394542A (en) | Optically active isomers of hydroxyamines | |
ES2063499T3 (es) | Procedimiento para la preparacion del acido cis-beta-fenilglicidico-(2r,3r). | |
CA2428817A1 (en) | Copolyvidone-containing preparation | |
DE3889871T2 (de) | Verfahren zur Herstellung von hochreinem 2,2-Bis(4-hydroxyphenyl)propan. | |
DE3778431D1 (de) | Herstellung von zellen. | |
PT666252E (pt) | Guanidinas de acidos alquilcarboxilicos substituidas com grupos fenilo possuindo grupos perfluoroalquilo processo para a sua preparacao sua utilizacao como medicamento ou meio de diagnostico bem como medicamento que as contem | |
DE3687238T2 (de) | Polyamidharze. | |
JPH01135506A (ja) | 精製水の製造方法 | |
KR900017993A (ko) | 거울상 이성체 글루타르아미드 이뇨제 | |
ES547303A0 (es) | Procedimiento para la obtencion de una membrana compuesta semipermeable sobre un substrato microporoso, basada en un polimero reticulado. | |
MX9200910A (es) | Procedimiento microbiologico para la preparacion de s-(+)-2,2- dimetilciclopropancarboxamida y acido r-(-)-2,2-dimetilciclopropancarboxilico. | |
GB1428197A (en) | Polyamides | |
DE69521887T2 (de) | Verbessertes verfahren zur herstellung von 6,9[(zaminoethyl)amino]benzo[g]isochinoline-5,10 dione und sein dimaleinsaeure salz | |
ATE142616T1 (de) | Verfahren zur herstellung von phenylessigsäureester-derivaten | |
FR2665897B1 (fr) | Procede de transformation de l'acide (benzoyl-3 phenyl)-2 propionique-r(-) en isomere s(+). | |
MX171048B (es) | Mejoras en proceso para la preparacion de membranas semipermeables de poliester, resistentes al cloro | |
Fromm | Growth stimulation by ammonium sulfamate in low concentration | |
DE59109240D1 (de) | Verfahren zur Herstellung von (S)-3-Methyl-1-(2-piperidino-phenyl)-1-butylamin | |
MacDougal | Osmotic Pressure in Saprophytes and Parasites |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 527348 Country of ref document: ES |