ES2149792T3 - Catalizadores para la polimerizacion de olefinas. - Google Patents

Catalizadores para la polimerizacion de olefinas.

Info

Publication number
ES2149792T3
ES2149792T3 ES93109585T ES93109585T ES2149792T3 ES 2149792 T3 ES2149792 T3 ES 2149792T3 ES 93109585 T ES93109585 T ES 93109585T ES 93109585 T ES93109585 T ES 93109585T ES 2149792 T3 ES2149792 T3 ES 2149792T3
Authority
ES
Spain
Prior art keywords
olefins
polymerization
catalysts
rent
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93109585T
Other languages
English (en)
Spanish (es)
Inventor
Luigi Resconi
Maurizio Galimberti
Fabrizio Piemontesi
Floriano Guglielmi
Enrico Albizzati
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from ITMI921498A external-priority patent/IT1262950B/it
Priority claimed from ITMI921497A external-priority patent/IT1262949B/it
Priority claimed from ITMI922179A external-priority patent/IT1255513B/it
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Application granted granted Critical
Publication of ES2149792T3 publication Critical patent/ES2149792T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
ES93109585T 1992-06-18 1993-06-16 Catalizadores para la polimerizacion de olefinas. Expired - Lifetime ES2149792T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI921498A IT1262950B (it) 1992-06-18 1992-06-18 Catalizzatori per la polimerizzazione di olefine
ITMI921497A IT1262949B (it) 1992-06-18 1992-06-18 Catalizzatori per la polimerizzazione di olefine
ITMI922179A IT1255513B (it) 1992-09-24 1992-09-24 Catalizzatori per la polimerizzazione di olefine

Publications (1)

Publication Number Publication Date
ES2149792T3 true ES2149792T3 (es) 2000-11-16

Family

ID=27273981

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93109585T Expired - Lifetime ES2149792T3 (es) 1992-06-18 1993-06-16 Catalizadores para la polimerizacion de olefinas.

Country Status (21)

Country Link
EP (1) EP0575875B1 (cg-RX-API-DMAC7.html)
JP (1) JP3330424B2 (cg-RX-API-DMAC7.html)
KR (1) KR100287449B1 (cg-RX-API-DMAC7.html)
CN (1) CN1044251C (cg-RX-API-DMAC7.html)
AT (1) ATE195326T1 (cg-RX-API-DMAC7.html)
AU (1) AU660808B2 (cg-RX-API-DMAC7.html)
BR (1) BR9302392A (cg-RX-API-DMAC7.html)
CA (1) CA2098763A1 (cg-RX-API-DMAC7.html)
CZ (1) CZ119393A3 (cg-RX-API-DMAC7.html)
DE (1) DE69329170T2 (cg-RX-API-DMAC7.html)
DK (1) DK0575875T3 (cg-RX-API-DMAC7.html)
ES (1) ES2149792T3 (cg-RX-API-DMAC7.html)
FI (1) FI110101B (cg-RX-API-DMAC7.html)
GR (1) GR3034738T3 (cg-RX-API-DMAC7.html)
HU (1) HU217030B (cg-RX-API-DMAC7.html)
IL (1) IL106042A (cg-RX-API-DMAC7.html)
MY (1) MY131505A (cg-RX-API-DMAC7.html)
NO (1) NO301016B1 (cg-RX-API-DMAC7.html)
PT (1) PT575875E (cg-RX-API-DMAC7.html)
RU (1) RU2132229C1 (cg-RX-API-DMAC7.html)
TW (1) TW284770B (cg-RX-API-DMAC7.html)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1255514B (it) * 1992-09-24 1995-11-09 Luigi Resconi Copolimeri dell'etilene con monomeri olefinici, processo per la loro preparazione e catalizzatore
IT1264483B1 (it) * 1993-06-30 1996-09-23 Spherilene Srl Copolimeri elastomerici dell'etilene con propilene
IT1271407B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti
IT1273662B (it) 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propiline'
IT1273661B (it) * 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
IT1273615B (it) * 1995-05-05 1997-07-08 Enichem Spa Catalizzatore a migliorata attivita' per la (co)polimerizzazione dell'etilene
IT1276752B1 (it) 1995-06-20 1997-11-03 Spherilene S P A Ora Montell I Catalizzatori e procedimenti per la polimerizzazione di olefine
CN1090638C (zh) * 1996-07-26 2002-09-11 中国石油化工总公司 用于烯烃聚合与共聚合的催化剂及其制法和应用
FI970349A7 (fi) 1997-01-28 1998-07-29 Borealis As Uudet metalloseeniyhdisteiden aktivaattorisysteemit
WO1999021896A1 (en) 1997-10-29 1999-05-06 Montell Technology Company Bv Catalysts for the polymerization of olefins and process for the preparation thereof
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
EP0941997B1 (en) * 1998-03-09 2002-12-18 Basell Polyolefine GmbH Bridged zirconocene compounds, process for their preparation, and their use as catalyst components in the polymerization of olefins
ES2198098T3 (es) 1998-03-09 2004-01-16 Basell Poliolefine Italia S.P.A. Procedimiento multietapas para la polimerizacion de olefinas.
WO1999051648A1 (en) * 1998-04-07 1999-10-14 Exxon Chemical Patents Inc. Polymerization process
US6977283B1 (en) 1998-04-07 2005-12-20 Exxonmobil Chemical Patents Inc. Polymerization process
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
KR20010101034A (ko) 1998-11-18 2001-11-14 간디 지오프레이 에이치. 올레핀 중합 촉매 성분으로서 메틸렌 가교된 메탈로센
NZ506841A (en) * 1999-01-21 2003-01-31 Boulder Scient Co Synthesis and isomerization of 1,2-bis (indenyl) ethanes
JP2002539283A (ja) 1999-03-09 2002-11-19 バセル テクノロジー カンパニー ビー.ブイ. オレフィンの(共)重合用の多段階方法
WO2000075151A1 (en) 1999-06-04 2000-12-14 Basell Technology Company B.V. Process for the preparation of titanium complexes
DE60001901T2 (de) 1999-06-07 2003-11-06 Basell Polyolefine Gmbh Herstellung von übergangsmetall-alkylkomplexen mit einer bidentaten, dianionischen ligande
AU7288200A (en) 1999-09-22 2001-04-24 Basell Technology Company B.V. Catalyst system and process for the polymerization of olefins
DE60138657D1 (de) 2000-01-18 2009-06-18 Basell Polyolefine Gmbh Ligand für einen Metallocenkatalysator für die Polymerisation von Propylen und dessen Herstellungsverfahren
EP1257516B1 (en) 2000-02-23 2005-11-09 Akzo Nobel N.V. Process for preparing bisindenylalkanes
AU6230501A (en) 2000-05-24 2001-12-03 Basell Technology Company B.V. Propylene polymers and process for the preparation thereof
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
US6858767B1 (en) 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
EP1392740B1 (en) 2000-09-25 2008-08-20 Basell Polyolefine GmbH Process for the preparation of ethylene polymers with a bis-amido titanium compound
WO2002051877A2 (en) 2000-12-22 2002-07-04 Basell Polyolefine Gmbh Catalyst components for the polymerization of olefins
JP2006523753A (ja) 2003-04-15 2006-10-19 エクソンモービル・ケミカル・パテンツ・インク プロピレン・コポリマー用触媒
RU2510646C2 (ru) * 2012-06-26 2014-04-10 Дэлим Индастриал Ко, Лтд. Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина
KR101787830B1 (ko) 2015-09-15 2017-10-20 경북대학교 산학협력단 이종 작물 혼작용 동시 파종장치
CN105950979B (zh) * 2016-07-11 2017-11-03 钢铁研究总院 一种采用二次冷轧法制造的晶粒取向纯铁及方法
CN107973870A (zh) * 2016-10-25 2018-05-01 中国石油化工股份有限公司 一种烯烃共聚物及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0780933B2 (ja) * 1986-11-20 1995-08-30 三井石油化学工業株式会社 オレフインの重合方法
IL87717A0 (en) * 1987-09-14 1989-02-28 Exxon Chemical Patents Inc Preparation of an active metallocene-alumoxane catalyst in situ during polymerization
MY103812A (en) * 1988-02-12 1993-09-30 Mitsui Chemicals Inc Olefin polymerization catalyst and process for the polymerization of olefins.
GB2219975B (en) * 1988-06-23 1992-05-20 Hodgkinson & Corby Limited Standing frame assembly
KR920006464B1 (ko) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
US5087788A (en) * 1991-03-04 1992-02-11 Ethyl Corporation Preparation of high purity vinylindene olefin
EP0520816B1 (en) * 1991-06-27 1995-12-13 Nippon Oil Co. Ltd. Catalyst components for polymerization of olefins

Also Published As

Publication number Publication date
DE69329170T2 (de) 2001-03-29
JPH0680713A (ja) 1994-03-22
AU660808B2 (en) 1995-07-06
RU2132229C1 (ru) 1999-06-27
HU217030B (hu) 1999-11-29
GR3034738T3 (en) 2001-01-31
BR9302392A (pt) 1994-01-11
FI932802L (fi) 1993-12-19
ATE195326T1 (de) 2000-08-15
CN1083490A (zh) 1994-03-09
EP0575875A3 (en) 1994-07-27
MY131505A (en) 2007-08-30
AU4128193A (en) 1993-12-23
NO932238D0 (no) 1993-06-17
HU9301755D0 (en) 1993-09-28
PT575875E (pt) 2001-01-31
EP0575875A2 (en) 1993-12-29
EP0575875B1 (en) 2000-08-09
JP3330424B2 (ja) 2002-09-30
CA2098763A1 (en) 1993-12-19
DK0575875T3 (da) 2000-09-18
HUT66787A (en) 1994-12-28
FI110101B (fi) 2002-11-29
NO932238L (no) 1993-12-20
CZ119393A3 (en) 1994-01-19
KR100287449B1 (ko) 2001-04-16
IL106042A (en) 1999-05-09
KR940005680A (ko) 1994-03-22
CN1044251C (zh) 1999-07-21
FI932802A0 (fi) 1993-06-17
TW284770B (cg-RX-API-DMAC7.html) 1996-09-01
NO301016B1 (no) 1997-09-01
DE69329170D1 (de) 2000-09-14

Similar Documents

Publication Publication Date Title
ES2149792T3 (es) Catalizadores para la polimerizacion de olefinas.
RU93047795A (ru) Катализаторы для полимеризации олефинов, способ получения гомо- или сополимеров олефинов
NO306553B1 (no) Metallocener, deres anvendelse som katalysatorer, samt katalysatorsystem omfattende forbindelsene
CA2008907A1 (en) Catalysts for the polymerization of olefins
IT8919253A0 (it) Catalizzatori per la polimerizzazione di olefine.
FI943238L (fi) Kantajalla olevia katalysaattoreita olefiinien polymerointiin
EP0748822A3 (en) Olefin polymerization catalyst
ES2113448T3 (es) Catalizador de polimerizacion de olefinas, procedimiento para su preparacion y su utilizacion.
IT1269931B (it) Componenti e catalizzatori per la polimerizzazione di olefine
IT8920329A0 (it) Componenti e catalizzatori per la polimerizzazione di olefine.
DE69104033D1 (de) Übergangsmetall enthaltende katalysatorzusammensetzung zur polymerisation von olefinen.
ES2022352B3 (es) Sistema catalizador de polimerizacion de alfaolefinas que incluye un componente modificador ventajoso.
BR9606593A (pt) Componente de catalisador sólido e catalisador para a polimerização de olefinas
BR9307696A (pt) Catalisador e processo para uma polimeração ziegler
MX9204069A (es) Componente solido de catalizador y procedimiento para su preparacion
ITMI912682A0 (it) Catalizzatori per la polimerizzazione delle olefine
DZ1438A1 (fr) Procédé de polymérisation d'une oléfine.
DZ1596A1 (fr) Catalyseur pour la polymérisation ou la copolymérisation de l'éthylène.
ES2137959T3 (es) Articulos conformados para uso biomedico.
ES2142515T3 (es) Procedimiento para la preparacion de (co)polimeros de alfa-olefinas.
ATE247126T1 (de) Olefinpolymerisation in gegenwart von dialcoxysilacyclohexanen
IT1262949B (it) Catalizzatori per la polimerizzazione di olefine
FI942344A0 (fi) Erittäin aktiiviset katalysaattorit olefiinipolymerointiin ja polymerointimenetelmä käyttäen näitä katalysaattoreita
IT9019985A0 (it) Catalizzatori per la polimerizzazione 1,4-cis del butadiene
IT1262950B (it) Catalizzatori per la polimerizzazione di olefine

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 575875

Country of ref document: ES