ES2125109T3 - Catalizadores y procedimientos para la polimerizacion de olefinas. - Google Patents
Catalizadores y procedimientos para la polimerizacion de olefinas.Info
- Publication number
- ES2125109T3 ES2125109T3 ES96920823T ES96920823T ES2125109T3 ES 2125109 T3 ES2125109 T3 ES 2125109T3 ES 96920823 T ES96920823 T ES 96920823T ES 96920823 T ES96920823 T ES 96920823T ES 2125109 T3 ES2125109 T3 ES 2125109T3
- Authority
- ES
- Spain
- Prior art keywords
- catalysts
- polymerization
- components
- olefins
- procedures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical class C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
CATALIZADORES PARA LA POLIMERIZACION DE OLEFINA QUE COMPRENDEN EL PRODUCTO DE REACCION ENTRE: (A) UN PRODUCTO DE TITANIO, ZIRCONIO O HAFNIO, CON LIGANDOS DE CICLOPENTADIENO SUSTITUIDOS, (B) UNA MEZCLA DE DOS COMPUESTOS ORGANOMETALICOS DE ALUMINIO, SIENDO AL MENOS UNO DE LOS GRUPOS UNIDOS AL ALUMINIO, DIFERENTE DE UN ALQUILO LINEAL, Y (C) AGUA. CUANDO SE UTILIZAN PARA LA POLIMERIZACION DE OLEFINAS, DICHOS CATALIZADORES MUESTRAN ACTIVIDADES MAS ELEVADAS, PARA TIEMPOS DE PRESENCIA CORTOS, QUE LOS CORRESPONDIENTES CATALIZADORES, OBTENIDOS A PARTIR DE LOS COMPONENTES INDIVIDUALES DE LAS MEZCLAS DE COMPUESTOS DE ALUMINIO ANTERIORMENTE MENCIONADAS.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT95MI001316A IT1276752B1 (it) | 1995-06-20 | 1995-06-20 | Catalizzatori e procedimenti per la polimerizzazione di olefine |
PCT/EP1996/002615 WO1997000897A1 (en) | 1995-06-20 | 1996-06-18 | Catalysts and processes for the polymerization of olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2125109T3 true ES2125109T3 (es) | 1999-02-16 |
Family
ID=11371837
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96920823T Expired - Lifetime ES2125109T3 (es) | 1995-06-20 | 1996-06-18 | Catalizadores y procedimientos para la polimerizacion de olefinas. |
Country Status (10)
Country | Link |
---|---|
US (2) | US6191240B1 (es) |
EP (1) | EP0776340B1 (es) |
JP (1) | JP3781431B2 (es) |
KR (1) | KR970705580A (es) |
AT (1) | ATE172990T1 (es) |
CA (1) | CA2197643A1 (es) |
DE (1) | DE69600913T2 (es) |
ES (1) | ES2125109T3 (es) |
IT (1) | IT1276752B1 (es) |
WO (1) | WO1997000897A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6294625B1 (en) * | 1990-03-20 | 2001-09-25 | Exxonmobil Chemical Patents Inc. | Catalyst system of enhanced productivity and its use in polymerization process |
IT1276752B1 (it) * | 1995-06-20 | 1997-11-03 | Spherilene S P A Ora Montell I | Catalizzatori e procedimenti per la polimerizzazione di olefine |
US5990114A (en) * | 1996-02-28 | 1999-11-23 | Recordati, S.A., Chemical And Pharmaceutical Company | Use of 5-HT1A receptor antagonists for the treatment of urinary incontinence |
EP1105398B1 (en) * | 1998-08-17 | 2002-07-17 | The Dow Chemical Company | Activator composition comprising aluminum compound mixture |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0780933B2 (ja) * | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
US5006500A (en) * | 1988-10-27 | 1991-04-09 | Exxon Chemical Patents Inc. | Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene |
IT1237398B (it) | 1989-01-31 | 1993-06-01 | Ausimont Srl | Catalizzatori per la polimerizzazione di olefine. |
ES2149792T3 (es) * | 1992-06-18 | 2000-11-16 | Montell Technology Company Bv | Catalizadores para la polimerizacion de olefinas. |
IT1264680B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
IT1273661B (it) | 1994-07-20 | 1997-07-09 | Spherilene Srl | Catalizzatori per la polimerizzazione delle olefine |
IT1276752B1 (it) * | 1995-06-20 | 1997-11-03 | Spherilene S P A Ora Montell I | Catalizzatori e procedimenti per la polimerizzazione di olefine |
-
1995
- 1995-06-20 IT IT95MI001316A patent/IT1276752B1/it active IP Right Grant
-
1996
- 1996-06-18 WO PCT/EP1996/002615 patent/WO1997000897A1/en not_active Application Discontinuation
- 1996-06-18 CA CA002197643A patent/CA2197643A1/en not_active Abandoned
- 1996-06-18 KR KR1019970701106A patent/KR970705580A/ko not_active Application Discontinuation
- 1996-06-18 JP JP50234197A patent/JP3781431B2/ja not_active Expired - Fee Related
- 1996-06-18 EP EP96920823A patent/EP0776340B1/en not_active Expired - Lifetime
- 1996-06-18 US US08/793,863 patent/US6191240B1/en not_active Expired - Fee Related
- 1996-06-18 ES ES96920823T patent/ES2125109T3/es not_active Expired - Lifetime
- 1996-06-18 DE DE69600913T patent/DE69600913T2/de not_active Expired - Fee Related
- 1996-06-18 AT AT96920823T patent/ATE172990T1/de active
-
2000
- 2000-01-14 US US09/484,361 patent/US6534607B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0776340B1 (en) | 1998-11-04 |
KR970705580A (ko) | 1997-10-09 |
JPH10505385A (ja) | 1998-05-26 |
JP3781431B2 (ja) | 2006-05-31 |
DE69600913T2 (de) | 1999-04-15 |
ITMI951316A0 (it) | 1995-06-20 |
ATE172990T1 (de) | 1998-11-15 |
IT1276752B1 (it) | 1997-11-03 |
WO1997000897A1 (en) | 1997-01-09 |
DE69600913D1 (de) | 1998-12-10 |
US6191240B1 (en) | 2001-02-20 |
CA2197643A1 (en) | 1997-01-09 |
EP0776340A1 (en) | 1997-06-04 |
ITMI951316A1 (it) | 1996-12-20 |
US6534607B1 (en) | 2003-03-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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