EP4153809A1 - Fibres continues à base de cellulose et/ou de dérivés de cellulose, leur procédé de production et leur utilisation - Google Patents
Fibres continues à base de cellulose et/ou de dérivés de cellulose, leur procédé de production et leur utilisationInfo
- Publication number
- EP4153809A1 EP4153809A1 EP21727865.4A EP21727865A EP4153809A1 EP 4153809 A1 EP4153809 A1 EP 4153809A1 EP 21727865 A EP21727865 A EP 21727865A EP 4153809 A1 EP4153809 A1 EP 4153809A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cellulose
- continuous fibers
- fibers
- temperature
- din
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002678 cellulose Polymers 0.000 title claims abstract description 91
- 239000001913 cellulose Substances 0.000 title claims abstract description 91
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims description 42
- 239000001301 oxygen Substances 0.000 claims abstract description 23
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 20
- 239000004753 textile Substances 0.000 claims abstract description 19
- 230000018044 dehydration Effects 0.000 claims abstract description 15
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims description 127
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 42
- 239000004917 carbon fiber Substances 0.000 claims description 42
- 229920003043 Cellulose fiber Polymers 0.000 claims description 38
- 239000003063 flame retardant Substances 0.000 claims description 25
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 24
- 239000000243 solution Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 15
- 150000003460 sulfonic acids Chemical class 0.000 claims description 11
- 239000004627 regenerated cellulose Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 239000012298 atmosphere Substances 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 7
- 230000009970 fire resistant effect Effects 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- GDCXBZMWKSBSJG-UHFFFAOYSA-N azane;4-methylbenzenesulfonic acid Chemical group [NH4+].CC1=CC=C(S([O-])(=O)=O)C=C1 GDCXBZMWKSBSJG-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000009987 spinning Methods 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 238000003763 carbonization Methods 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 claims description 3
- 229920000297 Rayon Polymers 0.000 claims description 3
- 229920002301 cellulose acetate Polymers 0.000 claims description 3
- 229920001727 cellulose butyrate Polymers 0.000 claims description 3
- 229920006218 cellulose propionate Polymers 0.000 claims description 3
- 238000005087 graphitization Methods 0.000 claims description 3
- 125000000962 organic group Chemical group 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 15
- 239000007789 gas Substances 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000000654 additive Substances 0.000 description 12
- 208000005156 Dehydration Diseases 0.000 description 10
- 230000006641 stabilisation Effects 0.000 description 10
- 238000011105 stabilization Methods 0.000 description 10
- 230000001681 protective effect Effects 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- 238000000197 pyrolysis Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- -1 aliphatic Chemical class 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 2
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical compound [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000002860 competitive effect Effects 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 239000002608 ionic liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 description 1
- WWILHZQYNPQALT-UHFFFAOYSA-N 2-methyl-2-morpholin-4-ylpropanal Chemical compound O=CC(C)(C)N1CCOCC1 WWILHZQYNPQALT-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- YEDYJTXKZZLTNE-UHFFFAOYSA-N 3-methyl-1h-imidazol-3-ium;octanoate Chemical compound C[N+]=1C=CNC=1.CCCCCCCC([O-])=O YEDYJTXKZZLTNE-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- NUCZAXGAUZZSAM-UHFFFAOYSA-N C(CCCCCCC)(=O)[O-].C(C)[N+]1=C(NC=C1)C Chemical compound C(CCCCCCC)(=O)[O-].C(C)[N+]1=C(NC=C1)C NUCZAXGAUZZSAM-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- YXHXDEBLSQQHQE-UHFFFAOYSA-N N.N.OP(O)=O Chemical class N.N.OP(O)=O YXHXDEBLSQQHQE-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000011357 graphitized carbon fiber Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/16—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from products of vegetable origin or derivatives thereof, e.g. from cellulose acetate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
- D06M2101/08—Esters or ethers of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Definitions
- the invention relates to continuous fibers based on cellulose and / or cellulose derivatives, in particular for the production of flame-resistant textiles or carbon fibers, processes for their production and their advantageous uses.
- continuous fibers based on plastics that contain modified polyacrylonitrile in the form of, for example, acrylonitrile / acrylamidine copolymer and are precursor fibers for carbon fibers that are also used in individual cases for the production of flame-retardant textiles.
- the extruded precursor fibers of carbon fibers have to be converted into the infusible state. This makes the complex process step of oxidative thermal stabilization necessary.
- oxidative thermal stabilization is carried out under oxygen or under a protective gas atmosphere, which can be gas mixtures with different oxygen content.
- the gas pressure used in oxidative thermal stabilization is, for example, 0.5 to 1 bar.
- the thermal stabilization is based on final temperatures between 180 and 300 ° C. The final temperature is set by slowly increasing the temperature in a linear or stepwise manner.
- Elemental composition shows defects due to the onset of pyrolysis, which in particular make the production of flame-resistant textiles or carbon fibers with good performance properties impossible.
- the invention has therefore set itself the task of proposing continuous fibers based on cellulose and / or cellulose derivatives, which can be used in particular for the production of advantageous flame-resistant textiles and qualitatively improved carbon fibers.
- the aim is to optimize the oxygen content, the LOI and the density.
- advantageous carbon fibers are to be developed, without disadvantageous oxidative thermal stabilization, which are characterized in particular by a favorable density, fiber strength and elongation at break.
- the invention is intended to propose an advantageous method by which the continuous fibers can be produced. This is intended to achieve the production of competitive cellulose-based carbon fibers with a quality comparable to that of conventional oil-based carbon fibers Not inferior to polyacrylonitrile.
- the C0 2 balance and the energy costs are to be improved or reduced and sustainability increased.
- no toxic exhaust gases such as hydrogen cyanide and nitrogen oxides should be produced during manufacture.
- improved flame-retardant properties are to be achieved.
- Other possible processes that are carried out in air or atmosphere are too slow, require additives and do not achieve the required quality, e.g. cellulose fibers.
- the invention has addressed the problem that an excessively high oxygen content in the continuous fibers has the disadvantage that the continuous fibers become brittle and porous as a result of the oxidation and therefore cannot be processed into flame-resistant textiles using standard methods, for example, and also not qualitatively from these continuous fibers high quality carbon fibers can be produced.
- the above objects, from which the invention is based, are achieved by continuous fibers based on cellulose and / or cellulose derivatives, in particular for the production of flame-resistant textiles or carbon fibers, which are characterized in that the cellulose and / or the cellulose derivatives are in dehydrated form, the oxygen content 29 to 39% by weight, the oxygen find ex LOI 25 to 40 (according to DIN EN ISO 6941; 2004-05) and the density 1.3 to 1.45 g / cm 3 (according to DIN 65569-1; 1992 -10).
- the degree of dehydration of the dehydrated cellulose or the dehydrated cellulose derivatives contained in the continuous fibers according to the invention plays an outstanding role. It is preferred that the degree of dehydration is at least 1.0, preferably at least 1.5 and particularly preferably at least 2.0.
- the continuous fibers according to the invention are particularly advantageous when the degree of dehydration is at least 2.5 and in particular 3.0.
- the particular advantage associated with the mentioned degree of dehydration is that thermal stabilization of the fiber is achieved while maintaining the usage properties.
- the invention presented above is developed particularly advantageously when the oxygen content is 29 to 32% by weight, the oxygen find ex LOI is 28 to 37 and / or the density is 1.35 to 1.45.
- the following further advantageous properties characterize the invention, such as a fiber strength of 8 to 30 cN / tex, in particular 10 to 16 cN / tex (according to DIN EN ISO 5079; 1996-02), an elongation at break of 12 to 25%, in particular 10 up to 16% (according to DIN EN ISO 5079; 1996-02), and / or a fineness of 0.5 to 18 dtex, in particular from 1 to 8 dtex, (according to DIN EN ISO 1973; 1995-12).
- the starting point is cellulose and / or cellulose derivatives which, according to the invention, are present in the claimed continuous fibers in dehydrated form.
- undehydrated fibers made of cellulose, in particular regenerated cellulose, and / or cellulose derivatives are further processed into the advantageous continuous fibers by the method according to the invention described below.
- Cellulose fibers should be understood to mean fibers which consist largely of cellulose, in particular 80% by weight, preferably 90% by weight and in particular more than 98% by weight .-%, it being particularly preferred if they consist entirely of cellulose.
- these can be fibers that are produced from cellulose starting material using modern technologies, which can also be referred to as modified or synthetic cellulose fibers.
- Viscose fibers that are produced according to the viscose process can be highlighted here.
- a spinning solution is used that contains NMMO (N-methylmorpholine-N-oxide) as a solvent.
- Cellulose fibers whose spinning solution is obtained with ionic liquids as solvents are particularly advantageous (see WO 2007/076979). Regenerated cellulose fibers which have been produced by the air-gap spinning process are particularly advantageous. Tire cord yarns are particularly useful here.
- cellulose derivatives for producing the continuous fibers according to the invention which in this case also contain the cellulose derivatives in dehydrated form.
- Cellulose acetate, cellulose propionate, cellulose butyrate and their mixed esters are particularly suitable here. That means that each fiber is made of Cellulose acetate, cellulose propionate, cellulose butyrate and their mixed esters can be used in individual fibers, but can also be present in a mixture in a yarn.
- the following can be referred to as further advantageous cellulose derivatives: cellulose formate, cellulose carbamate and / or cellulose allophanate.
- the continuous fibers according to the invention described above can advantageously be used for the production of flame-resistant textiles.
- textiles is to be understood broadly. This includes woven fabrics, knitted fabrics, fleeces and the like.
- the special properties of the continuous fibers according to the invention in the form of textiles open up advantageous uses, such as for use in fire-resistant work clothing, fire-resistant leisure clothing, as fire-resistant textile material in technical use, especially in the automotive sector, and in filtration or thermal insulation and as a fire-resistant textile material in the construction sector.
- the continuous fibers according to the invention can equally advantageously be used in order to produce carbon fibers by carbonization, optionally with subsequent graphitization.
- the carbon fibers according to the invention, in particular produced from the continuous fibers according to the invention described above, are distinguished by the fact that they have the following advantageous physical values: a density of 1.55 to 1.75 g / cm 3 , in particular 1.6 to 1, 7 [g / cm 3 ], (according to DIN 65569-1; 1992-10), a fiber strength of 2.0 to 5 GPa, in particular 2.5 to 4, (according to DIN EN ISO 5079; 1996-02 an elongation at break of 2 to 5%, in particular 2.5 to 3.5%, (according to DIN EN ISO 5079; 1996-02).
- the continuous fibers according to the invention can therefore advantageously be carbonized. This is preferably done by heating the continuous fibers under a protective gas in a temperature range from 600 ° C. to 2,400 ° C., in particular 1,000 ° C. to 2,400 ° C., the range from 1,200 ° C. to 1,600 ° C. being preferred. Heating to a maximum of 1,600 ° C. is very particularly preferred.
- the carbon fibers obtained, which are optionally graphitized, expediently have a carbon content of more than 98% by weight.
- the optionally subsequent graphitization is preferably carried out by a thermal treatment from 1,700 to 3,000 ° C., in particular 2,000 ° C. to 2,500 ° C., under a protective gas, especially under nitrogen.
- the graphitized carbon fibers have a higher modulus of elasticity than just conventional carbonized fibers.
- the invention also relates to an advantageous method for producing continuous fibers based on cellulose and / or cellulose derivatives, in particular for use in the production of flame-resistant textiles and carbon fibers, in particular a method for producing the continuous fibers according to the invention, which is characterized in that (1 ) Continuous fibers based on cellulose and / or cellulose derivatives with a solution, in particular an aqueous solution of a salt which, under the following thermal conditions, releases a dehydrating acid for dehydrating cellulose and / or cellulose derivatives, in particular in the form of the ammonium salt of a sulfonic acid, are brought into contact, (2) the thus finished filaments are heated to a temperature of 160 ° C to 300 ° C, in particular from 180 ° C to 240 ° C, and this temperature for a period of at least 5 minutes, in particular at least 10 minutes, special rs is preferably maintained for at least 20 minutes, the finished continuous fibers being placed under a vacuum of 5 mbar to 500 mbar, in
- step (1) the continuous fibers are virtually impregnated with a suitable salt in order to then form the dehydrating acid by splitting off ammonia in the course of the subsequent thermal step (2), which in statu nascendi the dehydration of cellulose and / or cellulose derivatives relevant to the invention causes.
- This method is advantageously developed in step (2) by heating the continuous fibers finished in step (1) to a first temperature, in particular from 180 to 240 ° C., and maintaining this first temperature for a period of at least 5 minutes and then the finished continuous fibers are heated to at least one second temperature which is higher than the first temperature, in particular from 240 to 300 ° C., and the second temperature is also maintained for a period of at least 5 minutes, the finished continuous fibers during the respective heating and between the heating steps in an inert gas atmosphere, in particular in a nitrogen atmosphere, under a vacuum of 5 mbar to 500 mbar, in particular 50 mbar to 200 mbar, which leads to dehydration of the cellulose and / or the cellulose derivative due to the dehydrating acid formed.
- a first temperature in particular from 180 to 240 ° C.
- the above-mentioned thermal stage (2) above can advantageously be further developed as follows: It is preferred that the finished continuous fibers in stage (2) are gradually heated from the first temperature to at least one further temperature and then to the second temperature, wherein the temperature difference between the chronologically successive heating steps is at least 5 ° C., in particular at least 10 ° C., and wherein the finished continuous fibers are kept at the at least one temperature for a period of at least 3 minutes.
- the second temperature in stage (2) it is expedient for the second temperature in stage (2) to be set at least 30 ° C., in particular at least 40 ° C., higher than the first temperature. It is also considered to be advantageous if the finished continuous fibers in step (2) are kept at the first temperature, the second temperature and at least one optional intermediate temperature for at least 10 minutes, in particular at least 20 minutes.
- intermediate drying expediently takes place, in particular by contact heat on heated godets, preferably between 60 ° C and 140 ° C, in particular between 80 ° C and 139 ° C, or in a hot air duct, preferably between 60 ° C and 140 ° C, particularly preferably between 80 ° C and 120 ° C.
- This intermediate drying is preferably carried out continuously.
- the continuous fiber yarn is wound up after step (2).
- the coils obtained in this way can be stored and transported and are fed to step (2) at the appropriate time, which is preferably carried out continuously.
- the process according to the invention is preferably a continuous two-stage process, which the stages (1) and (2) referred to above.
- a continuous fiber based on cellulose and / or cellulose derivatives is treated with a solution, in particular the aqueous solution of a salt, which under the thermal conditions described in the following stage (2) a dehydrating acid for dehydrating cellulose and / or Cellulose derivatives released under the specified thermal conditions.
- a dehydrating acid for dehydrating cellulose and / or Cellulose derivatives released under the specified thermal conditions.
- This is in particular an ammonium salt of a sulfonic acid.
- These can in particular be: ammonium dihydrogen phosphate, diammonium hydrogen phosphate, ammonium phosphonates, ammonium chloride, ammonium hydrogen sulfate and / or ammonium hydrogen carbonate.
- the salt mentioned which releases the dehydrating acid for the dehydration of cellulose and / or cellulose derivatives under the thermal conditions described below, is preferably in the form of an ammonium salt of a sulfonic acid.
- the sulfonium salt used according to the invention has the formula (I) has, in which: R 1 is a hydrocarbon group and K + is a cation in the formula (II) wherein R 2 to R 5 independently of one another represent an H atom or an organic group with 1 to 20 C atoms and consequently the cation represents unsubstituted ammonium ion (NH 4 ) + or a substituted ammonium ion.
- R 1 stands for a hydrocarbon group having 1 to 20 carbon atoms, it being particularly preferred if the hydrocarbon group contains 2 to 15 carbon atoms, in particular 2 to 10 and very particularly preferably from 2 to 5 carbon atoms.
- R 1 is or contains an aromatic group.
- R 1 can optionally be a substituted aryl group, in particular an optionally substituted phenyl, diphenyl or naphthyl group, or an alkaryl group, in particular an optionally substituted phenyl, diphenyl or naphthyl group bonded to the sulfur atom via an alkylene group.
- R 2 to R 5 are , independently of one another, as already stated, an H atom and / or an organic group having 1 to 20 carbon atoms, preferably 2 to 15 carbon atoms and very particularly preferably 5 to 10 carbon atoms. In particular, this can also be an alkyl group with 1 to 4 carbon atoms.
- the quantification of the sulfonium salt originally contained in the continuous fibers can advantageously be determined in that the finished continuous fibers contain 0.1 to 5% by weight, in particular 0.3 to 2% by weight, of sulfur, based on their dry weight, if they are fed to stage (2) of the thermal treatment described below.
- the specified sulfonium salt of the formula (I) is particularly advantageous if it has a solubility in water of at least 10 parts by weight per 100 parts by weight of water (under normal conditions of 20 ° C. and 1 bar). It is of particular advantage that the sulfonium salt is ammonium tosylate.
- sulfonic acid salts is preferably a solution in a hydrophilic solvent, in particular in water or in a io hydrophilic organic solvents, for example alcohol.
- Particularly preferred hydrophilic solvents are water or mixtures of water with other hydrophilic organic solvents which are infinitely miscible in water, with water in the solvent mixture preferably containing at least 50% by weight in the case of water.
- the concentration of the sulfonic acid salts in the especially aqueous solution and the contact times of the continuous fibers with the solution are expediently chosen so that the above-mentioned advantageous content of sulfonic acid salt is present in the dried continuous fiber.
- the continuous fiber can be passed through the solution for a sufficient time and / or passed in a continuous process through a sufficiently long solution bath.
- the continuous fibers are fed continuously through the solution of the sulfonic acid salt.
- the content of the sulfonic acid salts in the solution is preferably 0.05 to 5 mol / l solution, in particular 0.1 mol to 2 mol / l solution.
- the contact time of the continuous fibers with the solution of the sulfonic acid salts is preferably at least 0.5 seconds, in particular at least 2 and very particularly preferably at least 10 seconds. Generally it is no longer than 100 seconds, preferably no longer than 30 seconds.
- the continuous fibers according to the invention which are based on cellulose and / or cellulose derivatives, can additionally be equipped with further adjectives.
- the solution of the sulfonic acid salt referred to can contain such further additives.
- These can in particular be auxiliaries for stabilizing the thread run, preferably fatty acids, such as aliphatic, long-chain monocarboxylic acids. Saturated fatty acids, such as palmitic acid or oleic acid, are particularly suitable.
- additives should preferably have a solubility in water of at least 10 parts by weight, preferably at least 20 parts by weight, in particular at least 30 parts by weight per 100 parts by weight of water Have normal conditions (20 ° C, 1 bar).
- the additives are preferably low molecular weight compounds which have a molecular weight of a maximum of 1000 g / mol, in particular a maximum of 300 g / mol.
- Particularly suitable additives are soaps or acids, for example inorganic salts, inorganic acids, organic salts or organic acids, such as carboxylic acids or phosphonic acids.
- the cations can, for example, be metal cations, preferably alkali metal cations such as NFT and K + or, in particular, ammonia (NH 4+ ).
- the continuous fibers according to the invention do not contain any further additives in relevant amounts other than the sulfonic acid salt of the formula (I) explained in detail above.
- Process gas preferably an inert gas, preferably nitrogen
- the extracted gas contains not only ammonia, but also the water split off by the dehydration of cellulose and / or the cellulose derivatives.
- the extracted gas is cleaned in a corresponding post-treatment step.
- the heating elements of the process unit are illuminated so that they generate the desirable, in particular constant, temperature in their respective zone. For example, in the case of the multi-stage design, a temperature of 180 ° C. to 240 ° C. is set in the first zone.
- temperatures of 200 ° C, 220 ° C, 240 ° C and 250 ° C are set in the following zones.
- the continuous fibers are then guided through the process unit at a predetermined speed, the speed being expediently set so that the continuous fibers require about 20 to 40 minutes to be guided through the entire heated process unit.
- the continuous fibers according to the invention containing cellulose and / or cellulose derivatives in dehydrated form show salient advantages in connection with the flame retardant properties LOI, the strength, the purity, the carbon yield (high carbon yield in carbon fiber production), the density, the elongation, the top properties as a precursor for carbon fibers, preferably as advantageous carbon fibers as a result of a good ecological balance and at a low price, as flame-resistant fibers with advantageous applications.
- the process according to the invention avoids the disadvantageous stage of oxidative thermal stabilization. It uses a low pressure process and preferably uses an inert gas, especially nitrogen.
- the oxygen index (LOI) of normal cellulose fibers is 20.
- the LOI is a parameter which is used to describe the reaction to fire.
- the numerical index indicates the minimum oxygen concentration of an oxygen-nitrogen mixture below which combustion continues under the test conditions.
- the method according to the invention gives flame-retardant cellulose fibers with an increased LOI of between 25-40.
- the flame-retardant cellulose fibers are characterized by a high density between 1.3 and 1.45 g / cm 3 and also by a pore-free structure and a smooth surface.
- the individual fibers are not glued together and have a fineness between 0.90 and 1.45 dtex.
- the carbon content of the flame-retardant cellulose fibers is between 55 and 60% by weight, and the oxygen content is 29 to 39% by weight.
- cellulose fibers Two types are used in the examples. Both are synthetic fibers made from regenerated or coagulated cellulose.
- the regenerated cellulose fiber used in car tires is a tire cord fiber.
- the coagulated cellulose fibers were produced from cellulose dissolved in ionic liquid (1-ethyl-2methylimidazolium octanoate [EMIM] [Oct]). In the following, they are referred to as IL fibers. Both fiber types are characterized by their particularly high tear strength.
- the flame-retardant cellulose fibers can be processed into carbon fibers (CF).
- the flame-retardant cellulose fibers are converted into a CF by pyrolysis.
- the pyrolysis is generally carried out at temperatures of 500 to 1400 ° C. It can be carried out under protective gas, for example nitrogen or flelium.
- the received Carbon fibers have very good mechanical properties, especially good strength and elasticity.
- the method according to the invention enables an increased carbon yield.
- the carbon yield is 70 to 90%, that is, the carbon fiber contains between 70 and 90% by weight of the carbon which is contained in the cellulose fiber.
- the finishing and drying of the fibers takes place in a continuous process on godets. All godets have a speed of 10 m / min.
- the first godet serves as the unwinding unit for the fibers.
- the fibers are washed with water (95 ° C.) in washing baths and godets sprayed with water.
- the fiber is then passed through an aqueous ammonium tosylate solution (concentration of the ammonium tosylate 0.35 mol / kg). This is followed by drying on a heated godet (80 ° C).
- the dried fiber is wound up with a tension-controlled winder under a pre-tension of 0.3 cN / tex (level 1).
- the regenerated cellulose fiber equipped with the dehydrating additive is then processed further under protective gas (nitrogen) under reduced pressure (200 mbar).
- protective gas nitrogen
- a low-pressure furnace with 24 heating zones is used for this.
- the fibers are unwound over a trio godet and drawn into the process channel of the furnace through three pressure locks.
- the pressure locks are sealed from one another by a pair of rollers.
- the pressure in the locks and in the process channel is regulated by vacuum pumps and a nitrogen supply.
- the finished cellulose fibers are drawn through the oven at a speed of 0.2 m / min, which corresponds to a dwell time of 60 min.
- the temperature is set between 195 and 240 ° C.
- the fibers are then discharged from the oven again via three pressure locks and wound up with a pre-tension of 4 cN / tex (level 2).
- the residual fiber mass is 86% by weight, the density of the fibers is 1.42 g / cm 3 , the strength 16 cN / tex, the elongation at break 25%, the LOI 30.5 and the oxygen content 30% by weight.
- the fiber is positioned as in Example 1.
- the dwell time in the low-pressure oven is shortened to 30 minutes.
- the residual fiber mass is 86% by weight, the density of the fibers is 1.40 g / cm 3 , the strength 16 cN / tex, the elongation at break 21%, the LOI 29 and the oxygen content 32% by weight.
- the fiber is positioned as in Example 1.
- the dwell time in the low-pressure oven is shortened to 15 minutes.
- the residual fiber mass is 86% by weight, the density of the fibers is 1.39 g / cm 3 , the strength 13cN / tex, the elongation at break 21%, the LOI 26 and the oxygen content 38% by weight.
- the flame-retardant cellulose fibers are made, as described in Example 1, by means of a regenerated cellulose fiber equipped with additives, a so-called tire cord fiber, which is processed using the low-pressure process.
- the flame-retardant cellulose fibers produced in this way are then processed into carbon fibers in two stages under protective gas. In the first stage, the fiber is treated at a maximum temperature of 750 ° C. The fibers are then treated in a second stage at 1400 ° C.
- the carbon yield is 72% by weight, the strength of the carbon fibers is 2.5 GPa, the modulus of elasticity is 96 GPa, the elongation at break is 2.5% and the density is 1.42 g / cm 3 .
- the production of carbon fibers from the flame-retardant cellulose fibers according to the invention is described.
- the flame-retardant cellulose fibers are produced, as described in Example 2, by means of a tire cord fiber equipped with additives, which is processed using the low-pressure process.
- the flame-retardant fibers are then processed into carbon fibers under protective gas in two stages, as described in Example 4.
- the carbon yield is 72% by weight, the strength of the carbon fibers 23.2 GPa, the modulus of elasticity 110 GPa, the elongation at break 2.8% and the density 1.7 g / cm 3 .
- the production of carbon fibers from the flame-retardant cellulose fibers according to the invention is described.
- the flame-retardant cellulose fibers are produced, as described in Example 3, by means of a tire cord fiber equipped with additives, which is processed using the low-pressure process.
- the flame-retardant fibers are then processed into carbon fibers under protective gas in two stages, as described in Example 4.
- the carbon yield is 82% by weight, the strength of the carbon fibers 2.6 GPa, the modulus of elasticity 82 GPa, the elongation at break 2.5% and the density 1.68 g / cm 3 .
- the production of flame-retardant cellulose fibers according to the invention is described.
- the starting material used is regenerated cellulose fibers from an airgap spinning process, directly spun from ethyl, methyl imidazolium octanoate (IL fibers), with a single filament denier of 2.2 dtex and 1000 filaments.
- the production of the flame-retardant cellulose fibers takes place as in Example 1 after finishing with an additive (ammonium tosylate) by the low-pressure process.
- the residual fiber mass is 78% by weight, the density of the fibers 1.38 to 1.42 g / cm 3 , the strength 12 cN / tex, the elongation at break 13% and the LOI 31.
- Example 7 Describes the position of carbon fibers from the flame-retardant IL fibers according to the invention.
- the flame-retardant cellulose fibers are fused as in Example 7.
- the flame-retardant fibers are then processed into carbon fibers under protective gas in two stages, as described in Example 4.
- the carbon yield is 80% by weight, the strength of the carbon fibers is 2.5 GPa, the modulus of elasticity is 90 GPa, the elongation at break is 2.5% and the density is 1.69 g / cm 3 .
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Inorganic Fibers (AREA)
Abstract
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DE102020113807.5A DE102020113807A1 (de) | 2020-05-22 | 2020-05-22 | Endlosfasern auf Basis von Cellulose und/oder Cellulosederivaten, Verfahren zu deren Herstellung sowie deren Verwendung |
PCT/EP2021/063669 WO2021234152A1 (fr) | 2020-05-22 | 2021-05-21 | Fibres continues à base de cellulose et/ou de dérivés de cellulose, leur procédé de production et leur utilisation |
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US (1) | US20230193521A1 (fr) |
EP (1) | EP4153809A1 (fr) |
JP (1) | JP2023536777A (fr) |
KR (1) | KR20230027057A (fr) |
CN (1) | CN115917074A (fr) |
DE (1) | DE102020113807A1 (fr) |
MX (1) | MX2022014658A (fr) |
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JPS5813722A (ja) * | 1981-07-13 | 1983-01-26 | Asahi Chem Ind Co Ltd | 活性炭素繊維の製法 |
FR2760759B1 (fr) * | 1997-03-14 | 1999-06-11 | Carbone Ind | Procede de realisation de textures activees en fibres de carbone |
US20070021300A1 (en) | 2003-05-09 | 2007-01-25 | Jean-Pierre Farant | Process for the production of activated carbon |
WO2007076979A1 (fr) | 2005-12-23 | 2007-07-12 | Basf Se | Solution a base de liquides ioniques fondus, sa fabrication et son utilisation pour la fabrication d'hydrates de carbone regeneres |
JP5271887B2 (ja) | 2009-05-08 | 2013-08-21 | 国防科学研究所 | ライオセル系炭素繊維及び炭素織物の製造方法 |
EA201692291A1 (ru) * | 2014-05-16 | 2017-04-28 | Басф Се | Способ получения углеродных волокон из целлюлозных волокон |
ES2954633T3 (es) | 2016-02-11 | 2023-11-23 | Technikum Laubholz Gmbh | Procedimiento de producción de fibras de carbono a partir de fibras de celulosa tratadas con sales de ácido sulfónico |
TW202022182A (zh) * | 2018-10-10 | 2020-06-16 | 德商商先創國際股份有限公司 | 穩定先質纖維或薄膜以生產碳纖維或薄膜的方法 |
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DE102020113807A1 (de) | 2021-11-25 |
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TW202212668A (zh) | 2022-04-01 |
KR20230027057A (ko) | 2023-02-27 |
WO2021234152A1 (fr) | 2021-11-25 |
JP2023536777A (ja) | 2023-08-30 |
CN115917074A (zh) | 2023-04-04 |
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