EP3373369A1 - Matériau actif d'électrode positive pour des batteries secondaires au lithium, procédé de production d'un matériau actif d'électrode positive pour des batteries secondaires au lithium, électrode positive pour des batteries secondaires au lithium, et batterie secondaire au lithium - Google Patents

Matériau actif d'électrode positive pour des batteries secondaires au lithium, procédé de production d'un matériau actif d'électrode positive pour des batteries secondaires au lithium, électrode positive pour des batteries secondaires au lithium, et batterie secondaire au lithium Download PDF

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Publication number
EP3373369A1
EP3373369A1 EP16862195.1A EP16862195A EP3373369A1 EP 3373369 A1 EP3373369 A1 EP 3373369A1 EP 16862195 A EP16862195 A EP 16862195A EP 3373369 A1 EP3373369 A1 EP 3373369A1
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Prior art keywords
positive electrode
active material
electrode active
lithium secondary
secondary batteries
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German (de)
English (en)
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EP3373369A4 (fr
Inventor
Takashi Arimura
Jun-Ichi Kageura
Kenji Takamori
Kimiyasu Nakao
Daisuke Yamashita
Yusuke Maeda
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Tanaka Chemical Corp
Sumitomo Chemical Co Ltd
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Tanaka Chemical Corp
Sumitomo Chemical Co Ltd
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Application filed by Tanaka Chemical Corp, Sumitomo Chemical Co Ltd filed Critical Tanaka Chemical Corp
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
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    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C01P2006/82—Compositional purity water content
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present invention relates to a positive electrode active material for lithium secondary batteries, a method of producing a positive electrode active material for lithium secondary batteries, a positive electrode for lithium secondary batteries, and a lithium secondary battery.
  • a lithium-containing composite metal oxide is used as a positive electrode active material for lithium secondary batteries.
  • Lithium secondary batteries have already been put to practical use not only in small-sized power sources for portable telephones or notebook personal computers but also in middle- and large-sized power sources for automobiles or electric power storage.
  • PTL 1 discloses a lithium-containing composite oxide containing sulfuric acid radicals in a range of 0.01 weight% or more and 5 weight% or less obtained by adding lithium sulfate to a material for a positive electrode active material including an Li source and a M source (M is Co or Ni) and firing thereof.
  • PTL 2 discloses lithium nickel manganese composite oxide powders for a positive electrode material for lithium secondary batteries of which the concentration of contained sulfur is 0.06 mass% or more and 0.35 mass% or less.
  • PTL 3 discloses a non-aqueous electrolyte secondary battery in which a compound having a bond represented by -SO n - (1 ⁇ n ⁇ 4) is present in a surface of a positive electrode and a content of sulfur being present as the bond represented by -SO n -(1 ⁇ n ⁇ 4) is 0.2 atom% or more and 1.5 atom% or less in a case of being analyzed with an X-ray photoelectron spectroscopy.
  • a lithium secondary battery obtained by using the lithium-containing composite metal oxide in the related art as described above as a positive electrode active material has an improved discharge capacity retention rate, or the lithium secondary battery improves a high-rate discharge capacity or a value of low-temperature resistance while decreasing basicity (pH) of the lithium-containing composite metal oxide.
  • the present invention is invented in view of the circumstance and has an object to provide a positive electrode active material for lithium secondary batteries having favorable storage stability.
  • the present invention also has an object to provide a method of producing a positive electrode active material for lithium secondary batteries, a positive electrode using a positive electrode active material for lithium secondary batteries, and a lithium secondary battery.
  • the present invention provides a positive electrode active material for lithium secondary batteries which is able to be doped/undoped with lithium ions and contains at least Ni, in which a ratio P/Q (atom%/mass%) of a concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to a concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material is more than 0.8 and less than 5.0, and Q (mass%) is equal to or more than 0.01 to equal to or less than 2.0.
  • An aspect of the present invention preferably includes secondary particles formed of aggregated primary particles.
  • An aspect of the present invention is preferably presented by Compositional Formula (I).
  • Li[Li x (Ni a Co b Mn c M d ) 1- x ]O 2 ... (I) (Here, 0 ⁇ x ⁇ 0.2, 0 ⁇ a ⁇ 1, 0 ⁇ b ⁇ 0.4, 0 ⁇ c ⁇ 0.4, 0 ⁇ d ⁇ 0.1, a + b + c + d 1, and M represents one or more metals selected from the group consisting of Fe, Cr, Cu, Ti, Mg, Al, W, Mo, Nb, Zn, Sn, Zr, Ga, and V.)
  • the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material is preferably 0.01 or more and 2.5 or less.
  • a BET specific surface area (m 2 /g) is preferably 0.1 or more and 4 or less.
  • a method of producing a positive electrode active material for lithium secondary batteries of the present invention is a production method including the following steps of (1), (2), and (3) in this order.
  • a concentration (volume%) of oxygen in a gas phase in the reaction tank is preferably 2.0 or more and 6.0 or less.
  • the metal composite compound is preferably a metal composite compound obtained by washing the coprecipitated product slurry with at least one of a washing solution containing alkali or water, and dehydrating and isolating the resultant.
  • an aspect of the present invention provides a positive electrode for secondary batteries having the above-described positive electrode active material for lithium secondary batteries.
  • an aspect of the present invention provides a lithium secondary battery including the above-described positive electrode.
  • the present invention it is possible to provide a positive electrode active material for lithium secondary batteries having favorable storage stability.
  • a method of producing the positive electrode active material for lithium secondary batteries, a positive electrode using a positive electrode active material for lithium secondary batteries, and a lithium secondary battery it is possible to provide a method of producing the positive electrode active material for lithium secondary batteries, a positive electrode using a positive electrode active material for lithium secondary batteries, and a lithium secondary battery.
  • the positive electrode active material for lithium secondary batteries of the present invention is useful for lithium secondary batteries suitable for use in automobiles.
  • a positive electrode active material for lithium secondary batteries of the embodiment is a positive electrode active material for lithium secondary batteries that is able to be doped/undoped with lithium ions and contains at least Ni, in which a ratio P/Q (atom%/mass%) of a concentration P (atom%) of sulfur atoms being present in a surface of the positive electrode active material to a concentration Q (mass%) of sulfuric acid radicals present in the whole positive electrode active material is more than 0.8 and less than 5.0, and Q (mass%) is equal to or more than 0.01 to equal to or less than 2.0.
  • adsorption of moisture into the positive electrode active material is preferably suppressed.
  • a positive electrode active material for lithium secondary batteries into which a great amount of moisture has been adsorbed causes deterioration of paste viscosity stability of a positive electrode mixture.
  • the moisture adsorbed into the positive electrode active material for lithium secondary batteries causes side reactions such as decomposition of an electrolytic solution and generation of gas inside a battery. For this reason, it is required to reduce adsorption of moisture into the positive electrode active material for lithium secondary batteries.
  • a positive electrode active material for lithium secondary batteries of the embodiment it is possible to suppress moisture adsorption into the positive electrode active material and to provide a positive electrode active material for lithium secondary batteries having favorable storage stability.
  • the positive electrode active material for lithium secondary batteries of the embodiment preferably contains Ni from a viewpoint of obtaining a high-capacity lithium secondary battery.
  • a concentration P (atom%) of sulfur atoms being present in a surface of the positive electrode active material is obtained by analyzing the positive electrode active material by an X-ray photoelectron spectroscopy (XPS).
  • XPS X-ray photoelectron spectroscopy
  • Al-K ⁇ rays, Mg-K ⁇ rays, or like are used as X-rays, for example.
  • a measurement depth that can be measured with the commercially available XPS is set as a surface.
  • a concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material is obtained by dissolving powders of the positive electrode active material in a hydrochloric acid, performing an inductively coupled plasma emission analysis method (ICP), measuring sulfur elements, and converting the amount of the measured sulfur elements into sulfuric acid radicals.
  • ICP inductively coupled plasma emission analysis method
  • a ratio P/Q (atom%/mass%) of the above values is preferably 1.0 or greater, more preferably 1.2 or greater, and still more preferably 1.5 or greater.
  • the P/Q (atom%/mass%) is preferably 4.8 or less, and more preferably 4.7 or less.
  • An upper limit value and a lower limit value of the P/Q may be optionally combined.
  • the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material is preferably 0.02 or greater, and more preferably 0.03 or greater.
  • the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material is preferably 1.8 or less, more preferably 1.6 or less, and still more preferably 1.5 or less.
  • An upper limit value and a lower limit value of the Q (mass%) may be optionally combined.
  • the positive electrode active material for lithium secondary batteries of the embodiment preferably includes secondary particles formed of aggregated primary particles.
  • primary particles may be included so as not to impair the effect of the present application.
  • a ratio D 10 /D 50 of a 10% cumulative volume particle size D 10 ( ⁇ m) indicating an existence ratio of primary particles with respect to secondary particles to a 50% cumulative volume particle size D 50 ( ⁇ m) is preferably 0.05 or greater, more preferably 0.1 or greater, and still more preferably 0.2 or greater.
  • the ratio D 10 /D 50 is preferably 0.70 or less, more preferably 0.65 or less, and still more preferably 0.60 or less.
  • An upper limit value and a lower limit value of the D 10 /D 50 may be optionally combined.
  • the 10% cumulative volume particle size D 10 and the 50% cumulative volume particle size Dso are obtained from a volume particle size at the time of 10% cumulation and a volume particle size at the time of 50% cumulation, respectively, in a cumulative particle size distribution curve of an obtained volume reference by measuring particle size distribution by using a laser diffraction scattering particle size distribution measuring device.
  • x in Compositional Formula (I) is preferably 0.01 or greater, more preferably 0.02 or greater, and still more preferably 0.03 or greater.
  • x in Compositional Formula (I) is preferably 0.18 or less, more preferably 0.15 or less, and still more preferably 0.1 or less.
  • An upper limit value and a lower limit value of x may be optionally combined.
  • a "high cycle characteristic” means a high discharge capacity retention rate.
  • a in Compositional Formula (I) is preferably 0.3 or greater, more preferably 0.4 or greater, and still more preferably 0.5 or greater.
  • a in Compositional Formula (I) is preferably 0.92 or less, more preferably 0.82 or less, and still more preferably 0.72 or less.
  • An upper limit value and a lower limit value of a may be optionally combined.
  • b in Compositional Formula (I) is preferably 0.07 or greater, more preferably 0.1 or greater, and more preferably 0.13 or greater. In addition, from a viewpoint of obtaining a lithium secondary battery having high thermal stability, b in Compositional Formula (I) is preferably 0.35 or less, more preferably 0.3 or less, and still more preferably 0.25 or less.
  • An upper limit value and a lower limit value of b may be optionally combined.
  • c in Compositional Formula (I) is preferably 0.01 or greater, more preferably 0.1 or greater, more preferably 0.15 or greater, and still more preferably 0.2 or greater.
  • c in Compositional Formula (I) is preferably 0.35 or less, more preferably 0.32 or less, and still more preferably 0.30 or less.
  • An upper limit value and a lower limit value of c may be optionally combined.
  • M in Compositional Formula (I) is any one or more metals of Fe, Cr, Cu, Ti, Mg, Al, W, Mo, Nb, Zn, Sn, Zr, Ga, and V.
  • d in Compositional Formula (I) is preferably more than 0, more preferably 0.001 or greater, and still more preferably 0.005 or greater.
  • d in Compositional Formula (I) is preferably 0.08 or less, more preferably 0.04 or less, and still more preferably 0.02 or less.
  • An upper limit value and a lower limit value of d may be optionally combined.
  • M in Compositional Formula (I) is preferably at least one selected from the group consisting of Al, Zr, W, Mo, and Nb, and from a viewpoint of obtaining a lithium secondary battery having high thermal stability, M in Compositional Formula (I) is preferably at least one selected from the group consisting of Mg, Al, Zr, and W.
  • the positive electrode active material for lithium secondary batteries of the embodiment preferably satisfies a relational expression of a ⁇ b + c in Compositional Formula (I).
  • the positive electrode active material for lithium secondary batteries of the embodiment preferably satisfies a relational expression of b ⁇ c in Compositional Formula (I).
  • the concentration P (atom%) of sulfur atoms being present in the surface of the secondary particles is preferably 0.01 or greater, more preferably 0.02 or greater, and still more preferably 0.03 or greater.
  • the concentration P (atom%) of sulfur atoms being present in the surface of the secondary particles is preferably 2.5 or less, more preferably 2.0 or less, more preferably 1.7 or less, and still more preferably 1.5 or less.
  • An upper limit value and a lower limit value of the P (atom%) may be optionally combined.
  • a crystal structure of the positive electrode active material for lithium secondary batteries of the embodiment is a stacked structure, and is preferably a hexagonal crystal structure or a monoclinic crystal structure.
  • the hexagonal crystal structure belongs to any one space group selected from P3, P3 1 , P3 2 , R3, P-3, R-3, P312, P321, P3 1 12, P3 1 21, P3 2 12, P3 2 21, R32, P3m1, P31m, P3c1, P31c, R3m, R3c, P-31m, P-31c, P-3m1, P-3c1, R-3m, R-3c, P6, P6 1 , P6 5 , P6 2 , P6 4 , P6 3 , P-6, P6/m, P6 3 /m, P622, P6 1 22, P6 5 22, P6 2 22, P6 4 22, P6 3 22, P6mm, P6cc, P6 3 cm, P6 3 mc, P-6m2, P-6c2, P-62m, P-62c, P6/mmm, P6/mcc, P6 3 /mcm, and P6 3 /mmc.
  • the monoclinic crystal structure belongs to any one space group selected from the group consisting of P2, P2 1 , C2, Pm, Pc, Cm, Cc, P2/m, P2 1 /m, C2/m, P2/c, P2 1 /c, and C2/c.
  • the crystal structure is particularly preferably a hexagonal crystal structure that belongs to a space group R-3m or a monoclinic crystal structure that belongs to a C2/m.
  • a space group of the positive electrode active material for lithium secondary batteries of the embodiment can be checked in the following manner.
  • powder X-ray diffraction measurement is performed on the positive electrode active material for lithium secondary batteries of the embodiment using CuK ⁇ as a ray source and setting a measurement range of diffraction angle 2 ⁇ of 10° or more and 90° or less.
  • Rietveld analysis is performed based on the result, and the crystal structure that a lithium-containing composite metal oxide has and a space group in the crystal structure are determined.
  • the Rietveld analysis is a method of analyzing a crystal structure of a material by using data of a diffraction peak (diffraction peak intensity, diffraction angle 2 ⁇ ) in the powder X-ray diffraction measurement of the material, which is a method that has been used in the related art (for example, refer to " Introduction of Practical Rietveld method of Powder X-ray Analysis", issued on February 10, 2002, edition of the X-ray Analysis Conference of the Japan Society for Analytical Chemistry ).
  • the crystallite size ⁇ ( ⁇ ) is preferably 500 or greater, more preferably 550 or greater, and still more preferably 600 or greater.
  • the crystallite size ⁇ ( ⁇ ) is preferably 1000 or less, more preferably 900 or less, and still more preferably 850 or less.
  • An upper limit value and a lower limit value of the ⁇ ( ⁇ ) may be optionally combined.
  • the crystallite size ⁇ ( ⁇ ) at the peak A of the positive electrode active material for lithium secondary batteries of the embodiment can be checked in the following manner.
  • powder X-ray diffraction measurement is performed on the positive electrode active material for lithium secondary batteries of the embodiment using CuK ⁇ as a ray source and setting a measurement range of diffraction angle 2 ⁇ of 10° or more and 90° or less, and a peak corresponding to the peak A is determined.
  • FIG. 2A illustrates a schematic view of a plane 003 in a crystallite.
  • a crystallite size in a vertical direction of the plane 003 corresponds to the crystallite size ⁇ ( ⁇ ) ( FIG. 2B ).
  • a 50% cumulative volume particle size D 50 ( ⁇ m) is preferably 1 or greater, more preferably 2 or greater, and still more preferably 3 or greater.
  • the 50% cumulative volume particle size D 50 ( ⁇ m) is preferably 20 or less, more preferably 18 or less, more preferably 15 or less, and still more preferably 12 or less.
  • An upper limit value and a lower limit value of the D 50 ( ⁇ m) may be optionally combined.
  • the ⁇ /D 50 ( ⁇ / ⁇ m) is preferably 400 or less, more preferably 350 or less, and still more preferably 300 or less.
  • An upper limit value and a lower limit value of the ⁇ /D 50 ( ⁇ / ⁇ m) may be optionally combined.
  • a BET specific surface area (m 2 /g) of the positive electrode active material for lithium secondary batteries is preferably 0.1 or greater, preferably 0.12 or greater, and more preferably 0.15 or greater.
  • the BET specific surface area is preferably 4 or less, more preferably 3.8 or less, and still more preferably 3.5 or less.
  • An upper limit value and a lower limit value of the BET specific surface area (m 2 /g) may be optionally combined.
  • the ratio P/Q (atom%/mass%) of the concentration P (atom%) of sulfur atoms being present in a surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material has a predetermined range
  • the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material has a predetermined range.
  • the sulfuric acid radicals are generally present as lithium sulfate, and it is known that the lithium sulfate has hygroscopicity and is stably present as a monohydrate. For this reason, it is considered that by reducing sulfuric acid radicals being present in the whole positive electrode active material, generation of lithium sulfate monohydrate is suppressed, and suppression of adsorption of moisture into the positive electrode active material can be achieved.
  • the positive electrode active material for lithium secondary batteries has hygroscopicity since ion exchange reaction between Li contained in the crystal structure and proton of water occurs. For this reason, in a case where there is no substance being present in the surface of the positive electrode active material, the positive electrode active material for lithium secondary batteries easily reacts with water, and thus adsorption of moisture is promoted. However, in a case where lithium sulfate is present on the surface of the positive electrode active material, lithium sulfate is stabilized when lithium sulfate becomes a monohydrate, and thus adsorption of moisture no longer occurs.
  • examples of a method of controlling the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material and the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material include a method of adjusting a particle form of a metal composite compound which is a raw material of the positive electrode active material for lithium secondary batteries and distribution of sulfur atoms.
  • a method of performing control by adjusting firing conditions to be described below is preferable. For example, by appropriately washing the metal composite compound in a state where voids are present inside particles of the metal composite compound, it is possible to control distribution of the sulfur atoms.
  • a method of producing a positive electrode active material for lithium secondary batteries of the present invention is a production method including the following steps of (1), (2), and (3) in this order.
  • an overflow type reactor is preferably used.
  • a concentration of oxygen (volume%) is preferably 2.4 or greater, more preferably 2.6 or greater, and still more preferably 2.8 or greater.
  • the concentration of oxygen (volume%) is preferably 5.5 or less, more preferably 5.0 or less, and still more preferably 4.5 or less.
  • An upper limit value and a lower limit value of the concentration of oxygen in an oxygen-containing atmosphere may be optionally combined.
  • the metal composite compound in the step (2) of the embodiment is preferably a metal composite compound obtained by washing the coprecipitated product slurry with a washing solution containing alkali, and dehydrating and isolating the resultant.
  • the washing solution containing alkali is preferably a sodium hydroxide solution.
  • a metal composite compound containing metals other than lithium, that is, nickel which is an essential metal, and optional metals such as cobalt and manganese is preferably prepared, and the metal composite compound be fired with appropriate lithium salt.
  • the metal composite compound is preferably a metal composite hydroxide or metal composite oxide.
  • a metal composite compound can be generally produced by a known batch method or coprecipitation method.
  • a metal composite compound generally at least one of metal salts used when synthesizing a metal composite hydroxide to be described below is a sulfate, or an ammonium ion supply body such as ammonium sulfate is used as a complexing agent. Therefore, the metal composite compound contains at least sulfur atoms.
  • a method of producing a metal composite hydroxide containing nickel, cobalt, and manganese as a metal will be provided.
  • a nickel salt which is a solute of the nickel salt solution is not particularly limited, and any one of nickel sulfate, nickel nitrate, nickel chloride, and nickel acetate can be used, for example.
  • a cobalt salt which is a solute of the cobalt salt solution any one of cobalt sulfate, cobalt nitrate, and cobalt chloride can be used, for example.
  • a manganese salt which is a solute of the manganese salt solution any one of manganese sulfate, manganese nitrate, and manganese chloride can be used, for example.
  • the above metal salts can be used at a proportion corresponding to a composition ratio of the Ni s Co t Mn u (OH) 2 .
  • water is used as a solvent.
  • a complexing agent is an agent that can form a complex with ions of nickel, cobalt, and manganese in an aqueous solution.
  • the complexing agent include an ammonium ion supply body (ammonium sulfate, ammonium chloride, ammonium carbonate, ammonium fluoride, and the like), hydrazine, ethylenediaminetetraacetic acid, nitrilotriacetic acid, uracil diacetic acid, and glycine.
  • an alkali aqueous solution for example, sodium hydroxide and potassium hydroxide
  • an alkali aqueous solution for example, sodium hydroxide and potassium hydroxide
  • the inside of the reaction tank is preferably in an inert atmosphere.
  • inert atmosphere it is possible to suppress aggregation of elements that are easily oxidized compared to nickel and to obtain a homogenous composite metal hydroxide.
  • the inside of the reaction tank is preferably in an appropriate oxygen-containing atmosphere or in the presence of an oxidant while maintaining the inert atmosphere.
  • This appropriately oxidizes a transition metal and makes it easy to control the shape of the metal composite hydroxide.
  • Oxygen or an oxidant in an oxygen-containing gas may contain sufficient oxygen atoms to oxidize the transition metal. If a great amount of oxygen atoms are not introduced, it is possible to maintain the inert atmosphere in the reaction tank.
  • an oxygen-containing gas may be introduced inside the reaction tank.
  • a concentration of oxygen (volume%) in a gas phase inside the reaction tank is preferably 2.0 or more and 6.0 or less.
  • the oxygen-containing gas is bubbled.
  • the oxygen-containing gas include an oxygen gas or air, and a mixture gas between an oxygen gas or air and an oxygen-free gas such as nitrogen gas. From a viewpoint of easily adjusting a concentration of oxygen in the reaction tank, the mixture gas, among the above gases, is preferable.
  • an oxidant may be added inside the reaction tank.
  • the oxidant include hydrogen peroxide, chlorate, hypochlorite, perchlorate, and permanganate. From a viewpoint of preventing impurities from being easily entered a reaction system, hydrogen peroxide is preferably used.
  • a method of dehydrating a slurry containing the reaction precipitate (coprecipitated product slurry) by centrifugal separation or suction filtration is preferably used.
  • a coprecipitate obtained by the dehydration is preferably washed with a washing solution containing water or alkali.
  • the coprecipitate is more preferably washed with a sodium hydroxide solution.
  • the coprecipitate may be washed by using a washing solution containing sulfur elements.
  • a nickel cobalt manganese composite hydroxide is produced, but a nickel cobalt manganese composite oxide may be produced.
  • reaction conditions By appropriately controlling a concentration of the metal salt supplied to the reaction tank, a stirring rate, a reaction temperature, a reaction pH, an introduction amount of oxygen-containing gas, an addition amount of an oxidant, firing conditions to be described below, and the like, it is possible to control various physical properties such as a 50% cumulative volume particle size D 50 and a BET specific surface area of a lithium-containing composite metal oxide finally obtained in the following steps. Reaction conditions also depend on a size of the used reaction tank, and the like, and thus the reaction conditions may be optimized while monitoring various physical properties of the finally obtained lithium-containing composite metal oxide.
  • the drying condition is not particularly limited, and may be any one condition of a condition in which the metal composite oxide or metal composite hydroxide is not oxidized and reduced (specifically, a condition in which only an oxide or hydroxide is dried), a condition in which the metal composite hydroxide is oxidized (specifically, a drying condition in which oxidization from a hydroxide to an oxide occurs), and a condition in which the metal composite oxide is reduced (specifically, a drying condition in which oxidization from an oxide to a hydroxide occurs).
  • inert gases such as rare gases including nitrogen, helium, and argon may be used
  • a hydroxide is oxidized
  • drying may be performed in an oxygen or air atmosphere.
  • a reducing agent such as hydrazine and sodium sulfite may be used in an inert gas atmosphere.
  • a lithium salt any one of lithium carbonate, lithium nitrate, lithium acetate, lithium hydroxide, lithium hydroxide hydrate, lithium oxide, and lithium sulfate may be used, or two or more thereof may be mixed for use.
  • the metal composite oxide or the metal composite hydroxide After drying the metal composite oxide or the metal composite hydroxide, appropriate classification may be performed.
  • the above lithium salt and the metal composite oxide or metal composite hydroxide are used considering a composition ratio of a final objective product.
  • a lithium-nickel cobalt manganese composite oxide is obtained.
  • r is preferably more than 0, more preferably 0.01 or greater, and still more preferably 0.02 or greater.
  • r is preferably 0.1 or less, more preferably 0.08 or less, and still more preferably 0.06 or less.
  • An upper limit value and a lower limit value of the r may be optionally combined.
  • a firing temperature of the metal composite oxide or metal composite hydroxide and a lithium compound such as lithium hydroxide and lithium carbonate is not particularly limited, and is preferably 650°C or more and 1000°C or less, and more preferably 675°C or more and 950°C or less.
  • the firing temperature is lower than 650°C, a problem easily occurs that a charge capacity deteriorates. There is a possibility that a structural cause of inhibiting movement of Li exists in such a temperature area.
  • the firing temperature when the firing temperature is higher than 1000°C, there easily occurs a problem in preparation that it is difficult to obtain a composite oxide of an objective composition due to volatilization of Li, or a problem that initial Coulombic efficiency deteriorates. It is considered that the reason is that, when the firing temperature is higher than 1000°C, a primary particle growth rate is increased and homogeneity of particles deteriorates. In addition to this, it is considered that it may be a cause that an amount of Li loss is locally increased, and structural instability is caused.
  • the firing temperature is in a range of 675°C or more and 950°C or less, it is possible to prepare a battery exhibiting a particularly high Coulombic efficiency and having an excellent cycle characteristic. Firing time is preferably 0.5 hours to 20 hours.
  • the firing time When the firing time is longer than 20 hours, there occurs no problem in battery performance, but there is a tendency that battery performance is substantially decreased due to volatilization of Li. When the firing time is shorter than 0.5 hours, there is a tendency that development of crystal becomes poor and battery performance becomes poor. It is also effective to perform preliminary firing before the firing. Such a preliminary firing is preferably performed at a temperature in a range of 300°C to 900°C for 0.5 to 10 hours. By performing preliminary firing, it is possible to shorten the firing time.
  • the lithium-containing composite metal oxide obtained by firing is pulverized, and then appropriately classified to become a positive electrode active material for lithium secondary batteries applicable to a lithium secondary battery.
  • An example of the lithium secondary battery of the embodiment includes a positive electrode and a negative electrode, a separator interposed between the positive electrode and the negative electrode, and an electrolytic solution disposed between the positive electrode and the negative electrode.
  • FIGS. 1A and 1B are schematic views illustrating an example of the lithium secondary battery of the embodiment.
  • a cylindrical lithium secondary battery 10 of the embodiment is produced in the following manner.
  • an electrode group 4 is configured by stacking a pair of belt-like separators 1, a belt-like positive electrode 2 having a positive electrode lead 21 on one end, and a belt-like negative electrode 3 having a negative electrode lead 31 on one end to be wound in an order of the one separator 1, the positive electrode 2, the other separator 1, and the negative electrode 3.
  • the electrode group 4 and a non-illustrated insulator are housed in a battery can 5, a can bottom is sealed, and the electrode group 4 is impregnated with an electrolytic solution 6 to dispose an electrolyte between the positive electrode 2 and the negative electrode 3.
  • an electrolytic solution 6 to dispose an electrolyte between the positive electrode 2 and the negative electrode 3.
  • a top insulator 7 and a sealing body 8 it is possible to produce a lithium secondary battery 10.
  • Examples of a shape of the electrode group 4 can include a columnar shape such that a sectional shape when cutting the electrode group 4 in a vertical direction to a winding axis is a circle, an oval, a rectangle, and a rectangle with rounded corners.
  • ICE 60086 or JIS C 8500 which are standards for batteries determined by the International Electrotechnical Commission (IEC), as a shape of the lithium secondary battery including the electrode group 4 as above.
  • IEC International Electrotechnical Commission
  • shapes such as a cylindrical shape and a square shape can be exemplified.
  • the lithium secondary battery is not limited to the winding type configuration, and may have a stacking type configuration in which a stacked structure of a positive electrode, a separator, a negative electrode, and a separator are repeatedly stacked.
  • a stacking type lithium secondary battery include a so-called coin type battery, a button type battery, and a paper type (or sheet type) battery.
  • the positive electrode of the embodiment can be produced by, first, adjusting a positive electrode mixture including a positive electrode, a conductive material, and a binder, and supporting the positive electrode mixture in a positive electrode collector.
  • a carbon material can be used as a conductive material included in the positive electrode of the embodiment.
  • the carbon material include graphite powders, a carbon black (for example, acetylene black), and a fiber-like carbon material.
  • the carbon black has a large surface area in a fine particulate state. Therefore, by adding a small amount of the positive electrode mixture, it is possible to enhance conductivity inside the positive electrode and to enhance charge and discharge efficiency and output characteristics. However, when a large amount of the carbon black is added, it becomes a cause of deteriorating any one of binding force between the positive electrode mixture and the positive electrode collector by the binder and binding force inside the positive electrode mixture deteriorates and increasing internal resistance.
  • a proportion of the conductive material in the positive electrode mixture is preferably 5 parts by mass or more and 20 parts by mass or less with respect to 100 parts by mass of a positive electrode active material 100.
  • a fiber-like carbon material such as a graphitized carbon fiber and a carbon nanotube as a conductive material, it is possible to lower the proportion.
  • thermoplastic resin As a binder included in the positive electrode of the embodiment, a thermoplastic resin can be used.
  • thermoplastic resin examples include fluorine resins such as polyvinylidene fluoride (hereinafter, referred to as PVdF), polytetrafluoroethylene (hereinafter, referred to as PTFE), ethylene tetrafluoride/propylene hexafluoride/vinylidene fluoride-based copolymer, propylene hexafluoride/vinylidene fluoride-based copolymer, and ethylene tetrafluoride/perfluorovinyl ether copolymer; and polyolefin resins such as polyethylene and polypropylene.
  • PVdF polyvinylidene fluoride
  • PTFE polytetrafluoroethylene
  • ethylene tetrafluoride/propylene hexafluoride/vinylidene fluoride-based copolymer propylene hexafluoride/vinylidene fluoride-based copolymer
  • thermoplastic resins Two or more thermoplastic resins may be mixed for use.
  • a fluorine resin and a polyolefin resin as a binder, and setting a proportion of the fluorine resin to be 1 mass% or more and 10 mass% or less and a proportion of the polyolefin resin to be 0.1 mass% or more and 2 mass% or less with respect to the whole positive electrode mixture, it is possible to obtain a positive electrode mixture having high adhesion with the positive electrode collector and high bonding force inside the positive electrode mixture.
  • belt-like members serving as a forming material for forming a metal material such as Al, Ni, and stainless steel can be used.
  • a material processed in a thin film shape using Al as a forming material is preferable from a viewpoint of easy processing and inexpensive cost.
  • Examples of a method of supporting a positive electrode mixture on a positive electrode collector include a method of pressure-molding a positive electrode mixture on a positive electrode collector.
  • a positive electrode mixture may be supported on a positive electrode collector by making a positive electrode mixture into a paste using an organic solvent, coating the obtained positive electrode mixture paste on at least one side of the positive electrode collector, drying, and pressing and fixing the paste thereon.
  • an organic solvent examples include an amine-based solvent such as N,N-dimethylaminopropylamine and diethylenetriamine; an ether-based solvent such as tetrahydrofuran; a ketone-based solvent such as methyl ethyl ketone; an ester-based solvent such as methyl acetate; and an amide-based solvent such as dimethyl acetate and N-methyl-2-pyrrolidone (hereinafter, sometimes referred to as NMP).
  • an amine-based solvent such as N,N-dimethylaminopropylamine and diethylenetriamine
  • an ether-based solvent such as tetrahydrofuran
  • a ketone-based solvent such as methyl ethyl ketone
  • an ester-based solvent such as methyl acetate
  • an amide-based solvent such as dimethyl acetate and N-methyl-2-pyrrolidone
  • Examples of a method of coating the positive electrode mixture paste on the positive electrode collector include a slit die coating method, a screen coating method, a curtain coating method, a knife coating method, a gravure coating method, and an electrostatic spray method.
  • a negative electrode included in the lithium secondary battery of the embodiment is able to be doped/undoped with lithium ions at an electric potential lower than that of the positive electrode, and examples thereof include an electrode in which a negative electrode mixture containing a negative electrode active material is supported on a negative electrode collector and an electrode made of only a negative electrode active material.
  • Examples of a negative electrode active material included in the negative electrode include a carbon material, a chalcogen compound (oxide, sulfide, and the like), a nitride, a metal, or an alloy, and a material that is able to be doped/undoped with lithium ions at an electric potential lower than the positive electrode.
  • Examples of a carbon material that can be used as a negative electrode active material may include graphite such as natural graphite and artificial graphite, cokes, carbon black, pyrolytic carbons, carbon fiber, and an organic polymer compound fired body.
  • Examples of an oxide that can be used as a negative electrode active material may include an oxide of silicon represented by Formula SiO x such as SiO 2 and SiO (here, x is a positive real number); an oxide of titanium represented by Formula TiO x such as TiO 2 and TiO (here, x is a positive real number); an oxide of vanadium represented by Formula VO x such as V 2 O 5 and VO 2 (here, x is a positive real number); an oxide of iron represented by Formula FeO x such as Fe 3 O 4 , Fe 2 O 3 and FeO (here, x is a positive real number); an oxide of tin represented by SnO x such as SnO 2 and SnO (here, x is a positive real number); an oxide of tungsten represented by General Formula WO x such as WO 3 and WO 2 (here, x is a positive real number); and a composite metal oxide containing lithium and titanium or vanadium such as Li 4 Ti 5 O 12 and LiVO
  • Examples of sulfide that can be used as a negative electrode active material may include a sulfide of titanium represented by Formula TiS x such as Ti 2 S 3 , TiS 2 , and TiS (here, x is a positive real number); a sulfide of vanadium represented by Formula VS x such as V 3 S 4 , VS 2 , and VS (here, x is a positive real number); a sulfide of iron represented by Formula FeS x such as Fe 3 S 4 , FeS 2 , and FeS (here, x is a positive real number); a sulfide of molybdenum represented by Formula MoS x such as Mo 2 S 3 and MoS 2 (here, x is a positive real number); a sulfide of tin represented by Formula SnS x such as SnS 2 and SnS (here, x is a positive real number); a sulfide of tungsten represented
  • Examples of a nitride that can be used as a negative electrode active material may include a lithium-containing nitride such as Li 3 N and Li 3- x A x N (here, A is one or both of Ni and Co, 0 ⁇ x ⁇ 3).
  • a lithium-containing nitride such as Li 3 N and Li 3- x A x N (here, A is one or both of Ni and Co, 0 ⁇ x ⁇ 3).
  • the carbon material, the oxide, the sulfide and the nitride may be used, or two or more thereof may be used in combination.
  • the carbon material, the oxide, the sulfide, and the nitride may be any one of crystal materials and non-crystal materials.
  • examples of a metal that can be used as a negative electrode active material may include a lithium metal, a silicon metal, and a tin metal.
  • examples of an alloy that can be used as a negative electrode active material may include a lithium alloy such as Li-Al, Li-Ni, Li-Si, Li-Sn, and Li-Sn-Ni; a silicon alloy such as Si-Zn; a tin alloy such as Sn-Mn, Sn-Co, Sn-Ni, Sn-Cu, and Sn-La; and an alloy such as Cu 2 Sb, La 3 Ni 2 Sn 7 .
  • a lithium alloy such as Li-Al, Li-Ni, Li-Si, Li-Sn, and Li-Sn-Ni
  • a silicon alloy such as Si-Zn
  • a tin alloy such as Sn-Mn, Sn-Co, Sn-Ni, Sn-Cu, and Sn-La
  • an alloy such as Cu 2 Sb, La 3 Ni 2 Sn 7 .
  • These metals or alloys are mainly used alone as an electrode after being processed in a foil shape, for example.
  • the carbon material having graphite such as natural graphite and artificial graphite as a main component is preferably used since an electrical potential of a negative electrode is nearly not changed from a non-charge state to a full charge state during charging (electric potential flatness is good), an average discharge electric potential is low, a capacity retention rate at the time of repeated charge and discharge is high (a cycle characteristic is good), and the like.
  • the shape of the carbon material may be any one of a flake shape such as natural graphite, a spherical shape such as mesocarbon microbeads, a fiber shape such as graphite carbon fiber, and an aggregate such as fine powders.
  • the negative electrode mixture may contain a binder depending on the necessity.
  • the binder may include a thermoplastic resin, specifically, PVdF, thermoplastic polyimide, carboxymethyl cellulose, polyethylene, and polypropylene.
  • Examples of the negative electrode collector included in a negative electrode may include a belt-like member including a metal material such as Cu, Ni, and stainless steel as a forming material.
  • a belt-like member having Cu as a forming material and processed in a flake shape is preferable from a viewpoint of difficulty in creating an alloy with lithium and easiness in processing.
  • Examples of a method of supporting a negative electrode mixture on a negative electrode collector include a method of pressure-molding and a method of making a negative electrode mixture into a paste using a solvent and the like, coating the negative electrode mixture paste on a negative electrode collector, drying, and pressing and fixing the paste thereon, similar to the case of the positive electrode.
  • separator included in the lithium secondary battery of the embodiment materials made of a polyolefin resin such as polyethylene and polypropylene, a fluorine resin, a nitrogen-containing aromatic polymer, and the like and having a form of a porous film, a non-woven fabric, a woven fabric, and the like may be used.
  • the separator may be formed by using two or more of these materials, or the separator may be formed by stacking these materials.
  • an air impermeability by the Gurley method defined in JIS P 8117 is preferably 50 sec/100 cc or more and 300 sec/100 cc or less, and more preferably 50 sec/100 cc or more and 200 sec/100 cc or less.
  • a porosity of the separator is preferably 30 volume% or more and 80 volume% or less, and more preferably 40 volume% or more and 70 volume% or less.
  • the separator may be a separator in which separators having different porosities are stacked.
  • An electrolyte included in the lithium secondary battery of the embodiment contains an electrolyte and an organic solvent.
  • Examples of the electrolyte contained in the electrolytic solution include lithium salts such as LiClO 4 , LiPF 6 , LiAsF 6 , LiSbF 6 , LiBF 4 , UCF 3 SO 3 , LiN(SO 2 CF 3 ) 2 , LiN (SO 2 C 2 F 5 ) 2 , LiN(SO 2 CF 3 ) (COCF 3 ), Li(C 4 F 9 SO 3 ), LiC(SO 2 CF 3 ) 3 , Li 2 B 10 Cl 10 , LiBOB (here, BOB is bis(oxalate)borate), LiFSI (here, FSI is bis(fluorosulfonyl)imide), a lower aliphatic carboxylic acid lithium salt, and LiAlCl 4 , and a mixture of two or more thereof may be used.
  • lithium salts such as LiClO 4 , LiPF 6 , LiAsF 6 , LiSbF 6 , LiBF 4 , UCF 3 SO
  • an electrolyte containing at least one selected from the group consisting of LiPF 6 , LiAsF 6 , LiSbF 6 , LiBF 4 , LiCF 3 SO 3 , LiN(SO 2 CF 3 ) 2 , and LiC(SO 2 CF 3 ) 3 containing fluorine is preferably used.
  • carbonates such as propylene carbonate, ethylene carbonate, dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, 4-trifluoromethyl-1,3-dioxolane-2-on, and 1,2-di(methoxycarbonyloxy) ethane
  • ethers such as 1,2-dimethoxyethane, 1,3-dimethoxypropane, pentafluoropropyl methyl ether, 2,2,3,3-tetrafluoropropyl difluoromethyl ether, tetrahydrofuran, and 2-methyltetrahydrofuran
  • esters such as methyl formate, methyl acetate, and ⁇ -butyrolactone
  • nitriles such as acetonitrile and butyronitrile
  • amides such as N,N-dimethylformamide, and N,N-dimethyl acetoamide
  • carbamates such as 3-methyl-2-o
  • the organic solvent two or more thereof are preferably mixed for use.
  • a mixture solvent containing carbonates is preferable, and a mixture solvent of cyclic carbonate and non-cyclic carbonate and a mixture solvent of cyclic carbonate and ethers are more preferable.
  • a mixture solvent of cyclic carbonate and non-cyclic carbonate a mixture solvent containing ethylene carbonate, dimethyl carbonate, and ethyl methyl carbonate is preferable.
  • An electrolytic solution using such a mixture solvent has a lot of advantages in that the electrolytic solution has a wide operation temperature range, hardly deteriorates even if charging and discharging are performed at a high current rate, hardly deteriorates even if the electrolytic solution is used for a long time, and is hardly decomposable even in a case of using a graphite material such as natural graphite and artificial graphite as a negative electrode active material.
  • an electrolytic solution including a lithium salt containing fluorine such as LiPF 6 and an organic solvent containing a fluorine substituent are preferably used from a viewpoint of obtaining a lithium secondary battery having high safety.
  • a mixture solvent including ethers containing a fluorine substituent such as pentafluoropropyl methyl ether and 2,2,3,3,-tetrafluoropropyl difluoro methyl ether is more preferable from a viewpoint of obtaining a high capacity retention rate even if charging and discharging are performed at a high current rate.
  • a solid electrolyte may be used.
  • an organic polymer electrolyte such as a polyethylene oxide-based polymer compound and a polymer compound containing at least one of polyorganosiloxane chains and polyoxyalkylene chains may be used.
  • a so-called gel type electrolyte in which a non-aqueous electrolytic solution is held in a polymer compound may be used.
  • examples of the solid electrolyte include an inorganic solid electrolyte containing a sulfide such as Li 2 S-SiS 2 , Li 2 S-GeS 2 , Li 2 S-P 2 S 5 , Li 2 S-B 2 S 3 , Li 2 S-SiS 2 -Li 3 PO 4 , Li 2 S-SiS 2 -Li 2 SO 4 , and Li 2 S-GeS 2 -P 2 S 5 , and two or more of mixtures thereof may be used.
  • a sulfide such as Li 2 S-SiS 2 , Li 2 S-GeS 2 , Li 2 S-P 2 S 5 , Li 2 S-B 2 S 3 , Li 2 S-SiS 2 -Li 3 PO 4 , Li 2 S-SiS 2 -Li 2 SO 4 , and Li 2 S-GeS 2 -P 2 S 5 , and two or more of mixtures thereof may be used.
  • a positive electrode active material having the above configuration uses the above-described lithium-containing composite metal oxide of the embodiment, it is possible to suppress side reactions generated inside a lithium secondary battery using the positive electrode active material.
  • the positive electrode having the above configuration has the above-described positive electrode active material for lithium secondary batteries of the embodiment, it is possible to suppress side reactions generated inside a lithium secondary battery.
  • a lithium secondary battery having the above configuration has the above-described positive electrode, and thus is a lithium secondary battery in which side reactions generated inside the battery are suppressed, compared to the related art.
  • evaluation of a positive electrode active material for lithium secondary batteries and preparation evaluation of a positive electrode and a lithium secondary battery were performed in the following manner.
  • Composition analysis of a lithium-containing composite metal oxide produced in the method to be described below was performed by dissolving powders of an obtained lithium-containing composite metal oxide in a hydrochloric acid, using an inductively coupled plasma emission analysis apparatus (SPS 3000, manufactured by SII Nano Technology Inc.).
  • SPS 3000 inductively coupled plasma emission analysis apparatus
  • Concentration analysis of sulfur atoms being present in a surface of a lithium-containing composite metal oxide was performed using XPS (Quantera SXM, manufactured by ULVAC-PHI Co., Ltd). Specifically, an obtained lithium-containing composite metal oxide was charged in a dedicated substrate, and measurement was performed using AlK ⁇ rays with a photoelectron extraction angle of 45° and an aperture diameter of 100 ⁇ m to obtain data.
  • a concentration P of sulfur atoms being present in a surface of a positive electrode active material was calculated from an intensity of a peak derived from sulfur atoms being present in a range of 165 to 175 eV.
  • Powder X-ray diffraction measurement of the lithium-containing composite metal oxide was performed using an X-ray diffraction apparatus (X 'Prt PRO, manufactured by PANalytical).
  • a half value width of a peak corresponding to a peak A was obtained from the powder X-ray diffraction figure using JADE 5 which is a software for a full analysis of powder X-ray diffraction, and a crystallite size ⁇ was calculated by the Scherrer Equation.
  • Zero point one gram of powders of the lithium-containing composite metal oxide to be measured was put into 50 ml of an aqueous solution of 0.2 mass% sodium hexametaphosphate to obtain a dispersion liquid in which the powders were dispersed.
  • a particle size distribution of the obtained dispersion liquid was measured using Mastersizer 2000 (laser diffraction scattering particle size distribution measurement apparatus) manufactured by Malvern Instruments Ltd. to obtain a cumulative particle size distribution curve of a volume reference.
  • a volume particle size at the time of 10% cumulation was set as a 10% cumulative volume particle size D 10 of the positive electrode active material for lithium secondary batteries and a volume particle size at the time of 50% cumulation was set as a 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries.
  • One gram g of powders of the lithium-containing composite metal oxide to be measured was dried at 150°C for 15 minutes in a nitrogen atmosphere and then measurement was performed using Flowsorb II 2300 manufactured by Micromeritics Instrument Corporation.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, and a manganese sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, and manganese atoms was 0.315: 0.330: 0.355, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 2.6%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.5, and then nickel cobalt manganese composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated using a centrifugal separator, and dried at 105°C to obtain a nickel cobalt manganese composite hydroxide 1.
  • a BET specific surface area of the nickel cobalt manganese composite hydroxide 1 was 37.2 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 1 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.34 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 1 was 1.09 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 3.21 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 1 was 857 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 1 was 3.8 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 1 was 2.50 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 1 was 1857 ppm.
  • Example 2 The same operations as those in Example 1 were performed except that a sodium hydroxide aqueous solution was timely dropped such that a pH of a solution in a reaction tank was 12.3. In this manner, a nickel cobalt manganese composite hydroxide 2 was obtained. A BET specific surface area of the nickel cobalt manganese composite hydroxide 2 was 34.7 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 2 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.34 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 2 was 1.13 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 3.32 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 2 was 936 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 2 was 3.6 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 2 was 2.40 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 2 was 1914 ppm.
  • Example 2 The same operations as those in Example 1 were performed except that an oxygen-containing gas was bubbled such that an oxygen concentration in a gas phase in a reaction tank was 2.4% and a sodium hydroxide aqueous solution was timely dropped such that a pH of a solution in the reaction tank was 12.3.
  • a nickel cobalt manganese composite hydroxide 3 was obtained.
  • a BET specific surface area of the nickel cobalt manganese composite hydroxide 3 was 25.2 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 3 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.24 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 3 was 1.02 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 4.25 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 3 was 866 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 3 was 3.6 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 3 was 1.92 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 3 was 1414 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, and a manganese sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, and manganese atoms was 0.55: 0.21: 0.24, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 3.0%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.5, and then nickel cobalt manganese composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated by suction filtration, and dried at 105°C to obtain a nickel cobalt manganese composite hydroxide 4.
  • a BET specific surface area of the nickel cobalt manganese composite hydroxide 4 was 82.3 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 4 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.49 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 4 was 1.67 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 3.41 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 4 was 782 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 4 was 4.2 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 4 was 2.70 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 4 was 2343 ppm.
  • Example 4 The same operations as those in Example 4 were performed except that an oxygen-containing gas was bubbled such that an oxygen concentration in a gas phase in a reaction tank was 2.5%. In this manner, a nickel cobalt manganese composite hydroxide 5 was obtained. A BET specific surface area of the nickel cobalt manganese composite hydroxide 5 was 79.0 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 5 was performed.
  • x 0.04
  • a 0.552
  • b 0.207
  • c 0.241
  • d 0.00.
  • a concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 0.36 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 5 was 1.66 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 4.61 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 5 was 805 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 5 was 4.2 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 5 was 2.60 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 5 was 2590 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, and a manganese sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, and manganese atoms was 0.58: 0.17: 0.25, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 5.5%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.5, and then nickel cobalt manganese composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated using a centrifugal separator, and dried at 250°C to obtain a nickel cobalt manganese composite hydroxide 6.
  • a BET specific surface area of the nickel cobalt manganese composite hydroxide 6 was 66.5 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 6 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.64 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 6 was 1.43 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 2.23 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 6 was 848 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 6 was 5.3 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 6 was 0.69 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 6 was 1531 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, a manganese sulfide aqueous solution, and an aluminum sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, manganese atoms, and aluminum atoms was 0.90: 0.07: 0.02: 0.01, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 2.0%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.2, and then nickel cobalt manganese aluminum composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated by suction filtration, and dried at 105°C to obtain a nickel cobalt manganese aluminum composite hydroxide 7.
  • a BET specific surface area of the nickel cobalt manganese aluminum composite hydroxide 7 was 18.4 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 7 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.23 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 7 was 0.39 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 1.70 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 7 was 822 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 7 was 12.1 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 7 was 0.24 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 7 was 1934 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, and a manganese sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, and manganese atoms was 0.60: 0.20: 0.20, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 6.3%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.4, and then nickel cobalt manganese composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated using a centrifugal separator, and dried at 105°C to obtain a nickel cobalt manganese composite hydroxide 8.
  • a BET specific surface area of the nickel cobalt manganese composite hydroxide 8 was 73.4 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 8 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 1.64 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 8 was 1.28 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 0.78 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 8 was 905 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 8 was 6.0 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 8 was 0.90 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 8 was 4621 ppm.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 9 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 1.60 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 9 was 1.22 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 0.76 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 9 was 875 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 9 was 5.7 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 9 was 1.20 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 9 was 4805 ppm.
  • Example 4 The same operations as those in Example 4 were performed except that an oxygen-containing gas was bubbled such that an oxygen concentration in a gas phase in a reaction tank was 1.7%, a sodium hydroxide aqueous solution was timely dropped such that a pH of a solution in the reaction tank was 12.6, and isolated nickel cobalt manganese composite hydroxide particles were dried at 250°C. In this manner, a nickel cobalt manganese composite hydroxide 10 was obtained. A BET specific surface area of the nickel cobalt manganese composite hydroxide 10 was 95.2 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 10 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.13 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 10 was 0.65 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 5.00 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 10 was 866 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 10 was 4.0 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 10 was 1.60 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 10 was 3275 ppm.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 11 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.04 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 11 was 0.59 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 14.75 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 11 was 732 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 11 was 3.2 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 11 was 3.50 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 11 was 5449 ppm.
  • Example 4 The same operations as those in Example 4 were performed except that an oxygen-containing gas was bubbled such that an oxygen concentration in a gas phase in a reaction tank was 1.8%. In this manner, a nickel cobalt manganese composite hydroxide 12 was obtained. A BET specific surface area of the nickel cobalt manganese composite hydroxide 12 was 82.0 m 2 /g.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 12 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.22 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 12 was 1.47 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 6.68 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 12 was 813 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 12 was 4.1 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 12 was 2.80 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 12 was 5147 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, and a manganese sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, and manganese atoms was 0.55: 0.21: 0.24, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 3.7%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.5, and then nickel cobalt manganese composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated by suction filtration, and dried at 105°C to obtain a nickel cobalt manganese composite hydroxide 13.
  • a BET specific surface area of the nickel cobalt manganese composite hydroxide 13 was 90.3 m 2 /g.
  • a LiOH aqueous solution in which WO 3 was dissolved at 61 g/L was prepared.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 13 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.39 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 13 was 0.94 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 2.41 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 13 was 875 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 13 was 3.3 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 13 was 1.80 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 13 was 2981 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, and a manganese sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, and manganese atoms was 0.51: 0.22: 0.27, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 2.6%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.5, and then nickel cobalt manganese composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated by suction filtration, and dried at 105°C to obtain a nickel cobalt manganese composite hydroxide 14.
  • a BET specific surface area of the nickel cobalt manganese composite hydroxide 14 was 42.8 m 2 /g.
  • a LiOH aqueous solution in which WO 3 was dissolved at 61 g/L was prepared.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 14 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.17 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 14 was 0.82 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 4.82 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 14 was 857 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 14 was 5.1 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 14 was 1.55 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 14 was 2428 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, a manganese sulfide aqueous solution, and an aluminum sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, manganese atoms, and aluminum atoms was 0.875: 0.095: 0.02: 0.01, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 7.0%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 11.0, and then nickel cobalt manganese composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated by suction filtration, and dried at 105°C to obtain a nickel cobalt manganese composite hydroxide 15.
  • a BET specific surface area of the nickel cobalt manganese composite hydroxide 15 was 20.6 m 2 /g.
  • a LiOH aqueous solution in which WO 3 was dissolved at 61 g/L was prepared.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 15 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.33 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 15 was 1.58 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atomsbeing present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 4.83 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 15 was 925 ⁇ .
  • the 50% cumulative volume particle size Dso of the positive electrode active material for lithium secondary batteries 15 was 9.6 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 15 was 0.28 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 15 was 2112 ppm.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 16 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.33 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 16 was 1.19 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 3.64 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 16 was 805 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 16 was 7.9 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 16 was 0.35 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 16 was 2776 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, and a manganese sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, and manganese atoms was 0.55: 0.21: 0.24, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 3.6%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.5, and then nickel cobalt manganese composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated by suction filtration, and dried at 105°C to obtain a nickel cobalt manganese composite hydroxide 17.
  • the obtained mixture powders were fired at 850°C for 10 hours in an atmospheric atmosphere to obtain an objective positive electrode active material for lithium secondary batteries 17.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 17 was performed.
  • a concentration Q of sulfuric acid radicals being present in the whole positive electrode active material was 0.40 mass%.
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 17 was 1.04 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 2.60 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 17 was 925 ⁇ .
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 17 was 3.9 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 17 was 1.10 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 17 was 1953 ppm.
  • a nickel sulfide aqueous solution, a cobalt sulfide aqueous solution, a manganese sulfide aqueous solution, and a zirconium sulfide aqueous solution were mixed such that an atom ratio between nickel atoms, cobalt atoms, manganese atoms, and zirconium atoms was 0.5489: 0.2096: 0.2395: 0.002, and the mixture raw material solution was adjusted.
  • the mixture raw material solution and an ammonium sulfide aqueous solution were consecutively added to the reaction tank as complexing agents while stirring, and an oxygen-containing gas was bubbled such that an oxygen concentration was 2.7%.
  • a sodium hydroxide aqueous solution was timely dropped such that a pH of the solution in the reaction tank was 12.5, and then nickel cobalt manganese zirconium composite hydroxide particles were obtained, washed with the sodium hydroxide aqueous solution, dehydrated and isolated by suction filtration, and dried at 105°C to obtain a nickel cobalt manganese zirconium composite hydroxide 18.
  • composition analysis of the obtained positive electrode active material for lithium secondary batteries 18 was performed.
  • x 0.04
  • a 0.550
  • b 0.209
  • c 0.239
  • d 0.002
  • the concentration P of sulfur atoms being present in the surface of the positive electrode active material for lithium secondary batteries 18 was 1.00 atom%, and a ratio P/Q of the concentration P (atom%) of sulfur atoms being present in the surface of the positive electrode active material to the concentration Q (mass%) of sulfuric acid radicals being present in the whole positive electrode active material was 4.76 atom%/mass%.
  • a crystallite size ⁇ calculated from a peak A of the positive electrode active material for lithium secondary batteries 18 was 797 A.
  • the 50% cumulative volume particle size D 50 of the positive electrode active material for lithium secondary batteries 18 was 4.3 ⁇ m.
  • the BET specific surface area of the positive electrode active material for lithium secondary batteries 18 was 2.30 m 2 /g.
  • An adsorbed moisture amount of the positive electrode active material for lithium secondary batteries 18 was 2297 ppm.
  • N-methyl-2-pyrrolidone was used as an organic solvent. When the obtained positive electrode mixture was left to stand, precipitation was not generated.
  • N-methyl-2-pyrrolidone was used as an organic solvent. When the obtained positive electrode mixture was left to stand, precipitation was generated.
  • the present invention it is possible to provide a positive electrode active material for lithium secondary batteries having favorable storage stability.
  • a method of producing such a positive electrode active material for lithium secondary batteries, a positive electrode using a positive electrode active material for lithium secondary batteries, and a lithium secondary battery is useful for a lithium secondary battery suitable for use in automobiles.

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EP16862195.1A 2015-11-05 2016-11-04 Matériau actif d'électrode positive pour des batteries secondaires au lithium, procédé de production d'un matériau actif d'électrode positive pour des batteries secondaires au lithium, électrode positive pour des batteries secondaires au lithium, et batterie secondaire au lithium Pending EP3373369A4 (fr)

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JP7178615B2 (ja) * 2017-12-28 2022-11-28 パナソニックＩｐマネジメント株式会社 非水電解質二次電池用正極活物質の製造方法
JP6988502B2 (ja) * 2018-01-17 2022-01-05 トヨタ自動車株式会社 全固体電池用正極合剤、全固体電池用正極、全固体電池及びこれらの製造方法
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US20180316008A1 (en) 2018-11-01
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US11437618B2 (en) 2022-09-06
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